按条件检索“63”条记录

已选条件: 数据来源: CSCD × 出版物中文: 化学学报 × 机构: 化学与化工学院 × 文献类型: 期刊论文 ×
导出
  • 排序
  • 显示
III-->II were observed from above three kinds of phase diagrams with increasing the concentration of alcohol, It was observed from the Winsor phase diagram that the phase types, the phase volumes and the concentrations of alcohol at the start point and end point of the Winsor microemulsion formation change with the increase of the concentration of alcohol. From the delta-gamma fishlike phase diagram, some important parameters were calculated, such as the mass fraction of 1-butanol in the hydrophile-lipophile balanced interfacial layer, A(s), the coordinates of the start point and the end point of the Winsor microemulsion formation, and the solubilities of APG and 1-butanol in n-octane phase. The modified epsilon-beta fishlike phase diagram was presented for the first time by us. With the epsilon-beta fishlike phase diagram, the above experimental phenomena were observed and the physico-chemical parameters were calculated precisely. The epsilon-beta fishlike phase diagram has some advantages over the Winsor and delta-gamma fishlike phase diagrams in visual observations of the phase changes, and calculation of the related physico-chemical parameters. [author_in] => [Chai, J.-L] Key Laboratory for Colloid and Interface Chemistry, Ministry of Education, Shandong University, Jinan 250100, China, Department of Chemistry, Shandong Normal University, Jinan 250014, China@@@[ Li, D.-X] Key Laboratory for Colloid and Interface Chemistry, Ministry of Education, Shandong University, Jinan 250100, China@@@[ Li, G.-Z] Key Laboratory for Colloid and Interface Chemistry, Ministry of Education, Shandong University, Jinan 250100, China@@@[ Liang, F.-Z] Department of Chemistry, Shandong Normal University, Jinan 250014, China@@@[ Zhang, G.-Y] Key Laboratory for Colloid and Interface Chemistry, Ministry of Education, Shandong University, Jinan 250100, China@@@[ Xia, R] Beijing Municipal Institute of Drug Controls, Beijing 100035, China [publication_type] => J [begin_page] => 47 [author_en] => Chai, JL; Li, DX; Li, GZ; Liang, FZ; Zhang, GY; Xia, R [volume] => 62 [get_data] => 2018-08-29 [publisher] => SCIENCE CHINA PRESS [keyword_en] => middle-phase microemulsion; fishlike phase diagram; alkyl polyglucoside;; solubilization [format_publication_cn] => 6918be3b26b1fa6ec0424f6071208a75331227575 [keyword_plu] => GLYCEROL ETHER; BEHAVIOR; SYSTEMS; SURFACTANTS [publication_iso] => Acta Chim. Sin. [format_title_en] => 1db85632938bc923976cb234e5915152-1543514454 [publisher_city] => BEIJING [hx_id] => 2377,2378,2371 [reference_No] => 17 [email] => coliw@sdu.edu.cn [cite_awos] => 16 [wos_No] => WOS:000187998100010 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [check_180] => 0 [publisher_ad] => 16 DONGHUANGCHENGGEN NORTH ST, BEIJING 100717, PEOPLES R CHINA [title_en] => Studies on the middle-phase microemulsions of alkyl polyglucosides with mixed hydrocarbon chain [format_publication_en] => 169b60c7845c9e5f36906950b18f11111348184734 [jl_language] => chinese [jl_publication_cn] => 化学学报 [jl_article_dt] => 期刊论文 [jl_publication_en] => actachimicasinica [jl_country] => 中国,中国 [jl_keyword_en] => ,middlephasemicroemulsion,alkylpolyglucoside,solubilization,fishlikephasediagram [jl_keyword_cn] => ,鱼状相图,增溶,烷基聚葡糖苷,中相微乳液 [jl_clc] => o6433 [jl_publisher] => sciencechinapress [company_id] => 0,43,169 [author_id] => 25398 [author_test] => Array ( [0] => Array ( [sure] => 0 [irmagnum] => 0 [u_index] => 5 [name] => 张国艳 [irtag] => 7 [t_index] => 0 [person_id] => 25398 ) ) [sys_author_id_arr] => [cscd_No] => CSCD:1512178 [jl_publication_cn_publication_en] => actachimicasinica,化学学报 [jl_keyword_cn_keyword_en] => 鱼状相图,solubilization,中相微乳液,middlephasemicroemulsion,增溶,烷基聚葡糖苷,fishlikephasediagram,alkylpolyglucoside [sys_author_id] => [format_cscd_No] => 827cc9d9bddcf023ff6aecc92b464f51-1880333689 [format_title_en_publication_en_pub_year] => 5ec49a2bfd5426a67629896066b45d5c-52340373 [format_wos_No] => 7de5565e81b162ef4f02ca9cb93cef34583655459 [format_title_en_issn_pub_year] => f510fa03368cd5e01554fb4ec74d85ff251112082 [datebase] => Scopus [format_scopus_No] => ff0433967aa3b3cfe39884e50471aa13-1890847460 [cite_scopus] => 12 [sys_priority_field] => 76 [standard_in] => Key Laboratory for Colloid and Interface Chemistry, Ministry of Education, Shandong University, Jinan 250100, China; Department of Chemistry, Shandong Normal University, Jinan 250014, China; Beijing Municipal Institute of Drug Controls, Beijing 100035, China [scopus_No] => 2-s2.0-30744475113 [sys_subject_sort] => 0,0 [college_parent_id] => 43,169 [company_test] => Array,Array [id] => zw1FvmUBFjIhTVEbZaRs [tags] => 0 ) [6] => Array ( [batch2] => 1,2,6 [batch] => 3249,3250,3241,3254,3243,3252 [tag] => 0 [abstract_cn] => 在烷基聚葡糖苷C10G1.54/正丁醇/环己烷/磷酸盐缓冲液体系形成的油包水微乳液中,研究了在较高底物浓度下,脂肪酶催化正己酸和正丁醇的酯合成反应动力学及其影响因素.结果表明,在正己酸的初始浓度C0HA较小时,反应初速率V0随正己酸浓度增大而增大,但随正丁醇表观浓度增大而减小;在C0HA较大时,反应初速率V0随正丁醇表观浓度增大而增大,但随正己酸浓度增大而减小.在正己酸和正丁醇摩尔浓度之比为3.0左右反应速率最大.这些实验结果与传统的米氏反应不符,为此,从界面膜的构成,尤其是两种底物在界面膜上的分布情况入手进行了探讨.考察了C10G1.54浓度、正丁醇浓度和两者总浓度等对反应初速率V0的影响. [keyword_cn] => 烷基聚葡糖苷;油包水微乳液;脂肪酶;催化反应;酯;反应动力学;表面活性剂;反应介质; [clc] => O623.624 O647.2 [author_jg] => [柴金岭] 山东师范大学化学系, 济南, 山东 250014, 中国.@@@[高延红] 山东师范大学化学系, 济南, 山东 250014, 中国.@@@[王金山] 山东师范大学化学系, 济南, 山东 250014, 中国.@@@[李干佐] 山东大学, 胶体与界面化学教育部重点实验室, 济南, 山东 250100, 中国.@@@[张高勇] 山东大学, 胶体与界面化学教育部重点实验室, 济南, 山东 250100, 中国.@@@[徐清] 诺维信(中国)有限公司, 北京 100085, 中国 [format_title_cn_publication_cn_pub_year] => 832e8294522e6721b1f11d52e575042c1848137835 [from_id] => 76,75,73,80,78,85 [issue] => 19 [sys_level_num] => 2_1 [sys_jg_type] => 9,11,3,5 [source_type] => 351 [pub_year] => 2004 [article_id] => 490231,648080,329294,68525,661719,238385 [pages] => 7 [hints] => 4 [author_cn] => 柴金岭 [1];高延红 [2];王金山 [2];李干佐 [3];张高勇 [3];徐清 [4] [issn] => 0567-7351 [uri] => https://www.scopus.com/inward/record.uri?eid=2-s2.0-33750451999&partnerID=40&md5=0824e409ea518b1ccb64552a018c2142 [publication_cn] => 化学学报 [title_cn] => 烷基聚葡糖苷微乳液中脂肪酶催化的酯合成反应动力学 [CSSN] => 31-1320/O6 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => e2ffd4d1bf71bce1d75be6c6845699801989104070 [hb_type] => 2 [hb_batch] => title_cn_publication_cn_pub_year_2_3 [publication_en] => ACTA CHIMICA SINICA [cite_wos] => 1 [fund_No] => 山东省自然科学基金 [check_3Y] => 2 [language] => Chinese [delivery_No] => 863BZ [format_title] => 1618843fad033ea8fee182c18a1cfb92102803433 [cauthor_ad] => [Chai, JL]Shandong Normal Univ, Dept Chem, Jinan 250014, Peoples R China. [author_fn] => Chai, JL; Gao, YH; Qang, JS; Li, GZ; Zhang, GY; Xu, Q [reference] => BRU R, 1995, BIOCHEM J, V310, P721, DOI 10.1042/bj3100721@@@[柴金岭 Chai Jinling], 2002, [化学通报, Chemistry], V65, P506@@@Chai JL, 2003, CHINESE J CHEM, V21, P25@@@Delimitsou C, 2002, BIOCATAL BIOTRANSFOR, V20, P319, DOI@@@10.1080/10242420290025539@@@Fendler J H, 1982, Membrane Mimetic Chemistry@@@GAVIN EC, 1995, BIOTECHNOL BIOENG, V48, P78@@@Kurt D P, 2002, Surfactant Science Series, P91@@@MARTINEK K, 1986, EUR J BIOCHEM, V155, P453, DOI@@@10.1111/j.1432-1033.1986.tb09512.x@@@Oh SG, 1996, J COLLOID INTERF SCI, V181, P341, DOI@@@10.1006/jcis.1996.0388@@@ORLICH B, 2001, ENZYME MICROB TECHNO, V28, P344@@@SINGH CP, 1994, J AM OIL CHEM SOC, V71, P1405, DOI 10.1007/BF02541363@@@STAMATIS H, 1993, BIOTECHNOL BIOENG, V42, P931, DOI@@@10.1002/bit.260420803@@@Stradner A, 1999, J PHYS CHEM B, V103, P6680, DOI 10.1021/jp9905171@@@@@@Zhu H, 1998, PROG BIOCHEM BIOPHYS, V25, P204@@@周国伟, 2001, 化学学报, V59, P344@@@周国伟, 2001, 日用化学工业, P35@@@夏仕文, 1998, 化学通报, V61, P8@@@陈石根, 2001, 酶学 [publication_29] => ACTA CHIM SINICA [end_page] => 1900 [abstract_en] => The kinetics and its influencing factors of esterication reaction of hexanole acid with n-butanol, catalyzed by lipase, were studied in water-in-oil microemulsions formed by alkyl polyglucoside C(10)G(1.54)/n-butanol/cyclohexane/phosphate buffer solution system. The result shows that the initial rate V(0) of the esterification reaction increases as hexanoic acid concentration increases or as n-butanol concentration decreases, when the initial concentration of hexanoic acid is small; and the initial rate V(0) decreases as hexanoic acid concentration increases or as n-butanol concentration decreases, when the initial concentration of hexanoic acid is large. When the molar concentration ratio of n-butanol to hexanoic acid is about 3.0, the initial rate V(0) gets the maximum value, which is explained with the fish-like phase diagram. In addition, the effects of the lipase concentration, the pH values of water buffer solutions, and the kinds of hydrocarbon molecules and alcohols on the kinetics were also investigated. [author_in] => [Chai, J.-L] Department of Chemistry, Shandong Normal University, Jinan 250014, China, Key Laboratory for Colloid and Interface Chemistry of State Education Ministry, Shandong University, Jinan 250100, China@@@[ Gao, Y.-H] Department of Chemistry, Shandong Normal University, Jinan 250014, China@@@[ Wang, J.-S] Department of Chemistry, Shandong Normal University, Jinan 250014, China@@@[ Li, G.-Z] Key Laboratory for Colloid and Interface Chemistry of State Education Ministry, Shandong University, Jinan 250100, China@@@[ Zhang, G.-Y] Key Laboratory for Colloid and Interface Chemistry of State Education Ministry, Shandong University, Jinan 250100, China@@@[ Xu, Q] Novozym Company of Beijing, Beijing 100085, China [publication_type] => J [begin_page] => 1894 [article_dt] => Article [author_en] => Chai, JL; Gao, YH; Qang, JS; Li, GZ; Zhang, GY; Xu, Q [volume] => 62 [get_data] => 2018-08-29 [publisher] => SCIENCE PRESS [keyword_en] => alkyl polyglucoside; W/O microemulsion; lipase catalysis; kinetics [format_publication_cn] => 6918be3b26b1fa6ec0424f6071208a75331227575 [keyword_plu] => ESTERIFICATION; SURFACTANT; ORGANOGELS; SYSTEMS [publication_iso] => Acta Chim. Sin. [format_title_en] => 9ddaf8b01d395809d1d8a42ee39e2be3-1100015552 [publisher_city] => BEIJING [pub_date] => OCT 14 [hx_id] => 2377,2378,2371 [reference_No] => 18 [email] => jlchai99@sina.com [cite_awos] => 2 [wos_No] => WOS:000224536500008 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [check_180] => 0 [publisher_ad] => 16 DONGHUANGCHENGGEN NORTH ST, BEIJING 100717, PEOPLES R CHINA [title_en] => Kinetics of esterication reaction catalyzed by lipase in W/O microemulsions of alkyl polyglucoside [format_publication_en] => 169b60c7845c9e5f36906950b18f11111348184734 [jl_language] => chinese [jl_publication_cn] => 化学学报 [jl_article_dt] => 期刊论文 [jl_publication_en] => actachimicasinica [jl_country] => 中国,中国 [jl_keyword_en] => kinetics,alkylpolyglucoside,lipasecatalysis,womicroemulsion [jl_keyword_cn] => 反应动力学,,催化反应,脂肪酶,烷基聚葡糖苷,反应介质,油包水微乳液,酯,表面活性剂 [jl_clc] => o623624o6472 [jl_publisher] => sciencepress [company_id] => 43,169 [author_id] => 25398 [author_test] => Array ( [0] => Array ( [sure] => 0 [irmagnum] => 0 [u_index] => 5 [name] => 张国艳 [irtag] => 7 [t_index] => 0 [person_id] => 25398 ) ) [sys_author_id_arr] => [cscd_No] => CSCD:1689334 [jl_publication_cn_publication_en] => actachimicasinica,化学学报 [jl_keyword_cn_keyword_en] => 催化反应,反应动力学,lipasecatalysis,alkylpolyglucoside,kinetics,酯,表面活性剂,脂肪酶,油包水微乳液,反应介质,烷基聚葡糖苷,womicroemulsion [sys_author_id] => [format_cscd_No] => 7f6154e1ecbadb92449b214dd9a8f261-1120425960 [format_title_en_publication_en_pub_year] => 9cae3e8e3056c13681918443b00557ff2145877790 [format_wos_No] => a74a14149e5835a744b330e04ec27752-145375568 [format_title_en_issn_pub_year] => 4f1461208b414e74dd0d811212defb05-1011979358 [cauthor] => Chai, JL(jlchai99@sina.com) [datebase] => Scopus [format_scopus_No] => 818a43a398f436acf8f1d28f6fb759fb-1893426165 [page] => 1894-1900 [format_issn_issue_page_pub_year] => 6230e87f7fe340c1c04818ae244d8790-1035586320 [sys_priority_field] => 76 [standard_in] => Department of Chemistry, Shandong Normal University, Jinan 250014, China; Key Laboratory for Colloid and Interface Chemistry of State Education Ministry, Shandong University, Jinan 250100, China; Novozym Company of Beijing, Beijing 100085, China [scopus_No] => 2-s2.0-33750451999 [sys_subject_sort] => 0,0 [college_parent_id] => 43,169 [company_test] => Array,Array [id] => IAkxvmUBFjIhTVEbTvGU [tags] => 0 ) [7] => Array ( [batch2] => 1,2,6 [batch] => 3249,3250,3252,3254,3243,3241 [tag] => 0 [abstract_cn] => 研究了新的含 3 6个丁氧基偶氮苯介晶基元的二代光致变色液晶树枝状碳硅烷 (D2 )在氯仿、四氢呋喃溶液中的光强 ,吸收光强 ,摩尔消光系数 ,最大吸收波长 ,量子产率 ,活化能 ,异构转换率 ,光回复异构化反应平衡常数 ,反 -顺光异构化反应速率常数 ,光回复异构化正 /逆和热回复异构化反应速率常数 [keyword_cn] => 光致变色液晶树状大分子;光电信息功能材料;反顺光异构化;光回复异构;热回复异构;反/顺异构组分比;活化能 [article_id] => 26634,249262,490019,661665,330441,629389 [clc] => O753.2 [author_jg] => [张其震] 山东大学化学化工学院, 济南, 山东 250100, 中国.@@@[刘建强] 山东大学化学化工学院, 济南, 山东 250100, 中国.@@@[张静智] 山东大学化学化工学院, 济南, 山东 250100, 中国 [format_title_cn_publication_cn_pub_year] => 6aa548e34d4a83f069437161b71f254f [hints] => 4 [issue] => 3 [sys_level_num] => 2_3 [sys_jg_type] => 11,10,3,5 [format_issn_issue_page_pub_year] => 19ab6c5dbf7d63b9caf00565c3930291 [source_type] => 351 [pub_year] => 2004 [pub_date] => FEB 14 [pages] => 7 [from_id] => 76,75,73,80,78,85 [author_cn] => 张其震,刘建强,张静智 [issn] => 0567-7351 [uri] => https://www.scopus.com/inward/record.uri?eid=2-s2.0-18444368897&partnerID=40&md5=9bcad671ec7091720264df3960688091 [publication_cn] => 化学学报 [title_cn] => 二代光致变色液晶树枝状碳硅烷的光化学研究——端基含36个丁氧基偶氮苯介晶基元 [CSSN] => 31-1320/O6 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => 26981317e147d8e7ddbbccc3dbfbd3fd [page] => 317-323 [hb_type] => 2 [article_dt] => Article [hb_batch] => title_cn_publication_cn_pub_year_2_3 [publication_en] => ACTA CHIMICA SINICA [cite_wos] => 9 [fund_No] => 国家自然科学基金; 山东省自然科学基金; 中国科学院高分子物理重点实验室 [check_3Y] => 1 [language] => Chinese [delivery_No] => 773BK [format_title] => 389a1681bd495ab732a6c82ec648f59f1327318726 [cauthor_ad] => [Zhang, QZ]Shandong Univ, Sch Chem & Chem Engn, Jinan 250100, Peoples R China. [author_fn] => Zhang, QZ; Liu, JQ; Zhang, JZ [reference] => Archut A, 1998, J AM CHEM SOC, V120, P12187, DOI 10.1021/ja9822409@@@@@@CHEN X, 1997, MOL CRYST LIQ CRYST, V295, P93@@@IKEDA T, 1995, SCIENCE, V268, P1873, DOI 10.1126/science.268.5219.1873@@@Junge DM, 1999, J AM CHEM SOC, V121, P4912, DOI 10.1021/ja990387+@@@Nagasaki T, 1997, CHEM LETT, P717, DOI 10.1246/cl.1997.717@@@NIEMANN M, 1993, MAKROMOL CHEM, V194, P1169@@@PERKAMPUS HH, 1986, UV VIS SPEKTROSKOPIE, P158@@@[张其震 Zhang Qizhen], 2003, [化学学报, Acta Chemical Sinica], V61, P1108@@@[张其震 Zhang Qizhen], 2003, [化学学报, Acta Chemical Sinica], V61, P416@@@[张其震 Zhang Qizhen], 2002, [化学学报, Acta Chemical Sinica], V60, P2232@@@张其震, 1997, 高等学校化学学报, V18, P158@@@张静智, 1997, 化学学报, V55, P930@@@张其震, 1996, 高分子学报, P121 [publication_29] => ACTA CHIM SINICA [end_page] => 323 [abstract_en] => The photochemical behavior of a new photochromic liquid crystalline (LC) carbosilane dendrimer of the second generation (D2) in CHCl3 and THF was described. Thirty-six 4-butoxyazobenzene mesogenic fragments were attached in its periphery. The intensity of light, intensity of absorption light, molar extinction coefficient, maximum absorption wave length, quantum yield, activation energy, reaction rate constant of trans/cis photochemical isomerization, photochemical back-isomerization, thermal back-isomerization and the equilibrium constant of photochemical back-isomerization reaction were discussed. [author_in] => [Zhang, Q.-Z] School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China@@@[ Liu, J.-Q] School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China, School of Physics and Microelectronics, Shandong University, Jinan 250100, China@@@[ Zhang, J.-Z] School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China [publication_type] => J [begin_page] => 317 [author_en] => Zhang, QZ; Liu, JQ; Zhang, JZ [volume] => 62 [get_data] => 2018-08-29 [publisher] => SCIENCE CHINA PRESS [keyword_en] => photochromic liquid crystalline dendrimer; photo-electro information; functional material; trans/cis photoisomerization; photo chemical; back-isomerization; trans/cis isomer ratio; thermal back-isomerization;; activation energy [format_publication_cn] => 6918be3b26b1fa6ec0424f6071208a75331227575 [keyword_plu] => AZOBENZENE MOIETIES; 1ST GENERATION; POLYMERS [publication_iso] => Acta Chim. Sin. [format_title_en] => f32610c7febb31b078d31beb2ba3a013-746276801 [publisher_city] => BEIJING [hx_id] => 2377,2378,2371 [reference_No] => 14 [email] => qzzhang@sdu.edu.cn [cite_awos] => 9 [wos_No] => WOS:000188877700016 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [check_180] => 0 [publisher_ad] => 16 DONGHUANGCHENGGEN NORTH ST, BEIJING 100717, PEOPLES R CHINA [title_en] => Study on photochemistry of photochromic liquid crystalline carbosilane dendrimer of the second generation - Containing thirty-six 4-butoxyazobenzene mesogenic groups in its periphery [format_publication_en] => 169b60c7845c9e5f36906950b18f11111348184734 [jl_language] => chinese [jl_publication_cn] => 化学学报 [jl_article_dt] => 期刊论文 [jl_publication_en] => actachimicasinica [jl_country] => 中国,纳米比亚,瑞士,印度 [jl_keyword_en] => photochemical,photochromicliquidcrystallinedendrimer,functionalmaterial,photoelectroinformation,thermalbackisomerization,transcisphotoisomerization,transcisisomerratio,activationenergy,backisomerization [jl_keyword_cn] => 光致变色液晶树状大分子,活化能,光回复异构,热回复异构,光电信息功能材料,反顺光异构化,反顺异构组分比 [jl_clc] => o7532 [jl_publisher] => sciencechinapress [company_id] => 133,5,43,169 [sys_subject_sort] => 0,0,0,0 [college_parent_id] => 133,5,43,169 [company_test] => Array,Array,Array,Array [author_id] => [author_test] => Array ( [0] => Array ( [sure] => 0 [irmagnum] => 0 [u_index] => 0 [name] => 刘建强 [irtag] => 7 [t_index] => 0 [person_id] => 22294 ) ) [sys_author_id_arr] => 22294刘建强 [cscd_No] => CSCD:1612589 [jl_publication_cn_publication_en] => 化学学报,actachimicasinica [jl_keyword_cn_keyword_en] => photochemical,photochromicliquidcrystallinedendrimer,transcisphotoisomerization,光致变色液晶树状大分子,活化能,光回复异构,热回复异构,functionalmaterial,光电信息功能材料,反顺光异构化,photoelectroinformation,thermalbackisomerization,反顺异构组分比,transcisisomerratio,activationenergy,backisomerization [sys_author_id] => [format_cscd_No] => 4c0a930f5ae95dd7bfe6ca6cd0acf346 [format_title_en_publication_en_pub_year] => 3f9dfc7789a0be892a89af30f688fd87 [format_wos_No] => 94777c92cf48abefced7051eeb4a7fb1 [format_title_en_issn_pub_year] => 74fa36f5fc329e3f73fbcf4a3a80e5f3 [format_scopus_No] => 10bc1aeda4e43080819a4f7c0df81624 [standard_in] => School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China; School of Physics and Microelectronics, Shandong University, Jinan 250100, China [cauthor] => Zhang, QZ(qzzhang@sflu.edu.cn) [datebase] => Scopus [cite_scopus] => 6 [sys_priority_field] => 76 [scopus_No] => 2-s2.0-18444368897 [jl_pub_year] => 2004 [jl_author_test] => upersonid22294,usureu0,uuindex0,utindex0,uirtag7,uirmagnum0,unameuu5218u5efau5f3a [sys_author_jg_last_arr] => 中国 [jl_company_test] => unameuu5316u5b66u4e0eu5316u5de5u5b66u9662,uorgidu5,uparentidu43,unameuu7269u7406u5b66u9662,uircu0,uorgidu43,ulevelu1,uparentidu5 [sys_author_in_last_arr] => china [id] => zQ1FvmUBFjIhTVEbZaRs [tags] => 0 ) [8] => Array ( [issn] => 0567-7351 [reference] => Archut A, 1998, J AM CHEM SOC, V120, P12187, DOI 10.1021/ja9822409@@@@@@CHEN X, 1998, SUPRAMOL SCI, P591@@@CHEN X, 1997, MOL CRYST LIQ CRYST, V295, P93@@@Junge DM, 1999, J AM CHEM SOC, V121, P4912, DOI 10.1021/ja990387+@@@Nagasaki T, 1997, CHEM LETT, P717, DOI 10.1246/cl.1997.717@@@NIEMANN M, 1993, MAKROMOL CHEM, V194, P1169@@@PERKAMPUS HH, 1986, UV VIS SPEKTROSKOPIE, P158@@@[张其震 Zhang Qizhen], 2003, [化学学报, Acta Chemical Sinica], V61, P1478@@@[张其震 Zhang Qizhen], 2004, [化学学报, Acta Chemical Sinica], V62, P317@@@[张其震 Zhang Qizhen], 2004, [化学学报, Acta Chemical Sinica], V62, P312@@@[张其震 Zhang Qizhen], 2003, [化学学报, Acta Chemical Sinica], V61, P619@@@[张其震 Zhang Qizhen], 2003, [化学学报, Acta Chemical Sinica], V61, P1108@@@[张其震 Zhang Qizhen], 2003, [化学学报, Acta Chemical Sinica], V61, P416@@@[张其震 Zhang Qizhen], 2002, [化学学报, Acta Chemical Sinica], V60, P2232@@@张其震, 1997, 高等学校化学学报, V18, P158@@@张静智, 1997, 化学学报, V55, P930@@@张其震, 1996, 高分子学报, P121 [batch2] => 1,2,6 [format_cscd_No] => 95475d265a5f15f2542b018dc7e160611649727276 [begin_page] => 1822 [tag] => 0 [research_area] => Chemistry [publication_info] => 0567-7351(2004)62:18<1822:DJH4GD>2.0.TX;2-N [abstract_en] => The photochemical behavior of a new photochromic liquid crystalline (LC) carbosilane dendrimer of the zero generation (D0) in CHCl3 and THF was described. Four 4-butoxyazobenzene mesogenic fragments were attached in its periphery. The intensity of light absorbed, molar extinction coefficient, maximum absorption wave length, quantum yield and activation energy were determined. The reaction rate constants of trans/cis photochemical isomerization, photochemical back-isomerization and thermal back-isomerization and the equilibrium constant of photochemical back-isomerization reaction were discussed. Photochromic reaction rate constant of DO is 10(-1) s(-1), but that of photochromic LC polysiloxanes containing azobenzene moieties is 10(-8) s(-1), thus the photoresponsive rate of LC dendrimer D0 is 10(7) times larger than that of the latter. [abstract_cn] => 研究了新化合物含 4个丁氧基偶氮苯介晶基元的零代 (D0 )光致变色液晶树状物在氯仿和四氢呋喃中的吸收光强、最大吸收波长、摩尔消光系数、量子产率、活化能、异构转换率、反 -顺光异构化反应速率常数、热回复异构化反应速率常数、光回复异构化反应平衡常数及速率常数 .D0的光致变色反应速率常数为 10 -1s-1,而含偶氮基元液晶聚硅氧烷的光致变色反应速率常数为 10 -8s-1,因此液晶树状物D0的光响应速度比后者快 10 7倍 . [keyword_cn] => 光致变色液晶树状物;;光电信息功能材料;;光回复异构化;;热回复异构化;;反/顺异构体组分比;;活化能;;量子产率;;吸收光强 [fund_No] => 国家自然科学基金; 山东省自然科学基金资助项目 [format_title_en_publication_en_pub_year] => d59861b5f917caeb78364568de481c4d-1746764523 [publication_type] => J [author_jg] => [张其震] 山东大学化学与化工学院, 济南, 山东 250100, 中国.@@@[刘建强] 山东大学化学与化工学院, 济南, 山东 250100, 中国.@@@[唐新德] 山东大学化学与化工学院, 济南, 山东 250100, 中国.@@@[张静智] 山东大学化学与化工学院, 济南, 山东 250100, 中国 [cite_cscd] => 6 [cite_awos] => 6 [from_id] => 76,75,73,80,78 [issue] => 18 [email] => qzzhang@sdu.edu.cn [email_c] => qzzhang@sdu.edu.cn [sys_level_num] => 1_1 [format_title_cn_publication_cn_pub_year] => dd88ffd96ad2124d76ae3ae0a8b0c010-2119956134 [sys_jg_type] => 11,3,5 [format_issn_issue_page_pub_year] => 0c4585dbe6735e110c59f7894644c7e21340444278 [title_en] => Study on photochemistry of photochromic liquid crystalline dendrimer containing four 4-butoxyazobenzene mesogenic groups in its periphery [volume] => 62 [author_fn] => Zhang, QZ; Liu, JQ; Tang, XD; Zhang, JZ [pub_year] => 2004 [check_180] => 0 [keyword_en] => photochromic liquid crystalline dendrimer; photoelectric information; functional material; photochemical back-isomerization; thermal; back-isomerization; trans/cis isomer ratio; activation energy; quantum; yield; intensity of light absorbed [end_page] => 1828 [article_id] => 490004,648083,661662,329251,249286 [pages] => 7 [hints] => 10 [author_cn] => 张其震;刘建强;唐新德;张静智 [language] => Chinese [source_type] => 351 [reference_No] => 17 [cscd_No] => CSCD:1801328 [batch] => 3250,3243,3249,3252,3241 [publication_en] => ACTA CHIMICA SINICA [hx_id] => 2377,2378,2371 [author_in] => [Zhang, Q.-Z] School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China@@@[ Liu, J.-Q] School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China, School of Physics and Microelectronics, Shandong University, Jinan 250100, China@@@[ Tang, X.-D] School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China@@@[ Zhang, J.-Z] School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China [format_title_en_issn_pub_year] => 94f2cbd347226842df8402a7a31532c8-1106952369 [check_3Y] => 1 [publication_cn] => 化学学报 [title_cn] => 端基含4个丁氧基偶氮苯介晶基元光致变色液晶树状物的光化学研究 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => 66346bcb52d3eb412aee357d41738d14647000490 [page] => 1822-1828 [hb_type] => 2 [article_dt] => Article [hb_batch] => issn_issue_page_pub_year_1_7 [cite_wos] => 6 [delivery_No] => 856RW [format_title] => af589c90669781a48302ee8ccc13a9b3627729457 [cauthor_ad] => [Zhang, QZ]Shandong Univ, Sch Chem & Chem Engn, Jinan 250100, Peoples R China. [publication_29] => ACTA CHIM SINICA [author_en] => Zhang, QZ; Liu, JQ; Tang, XD; Zhang, JZ [get_data] => 2018-08-29 [publisher] => SCIENCE CHINA PRESS [format_publication_cn] => 6918be3b26b1fa6ec0424f6071208a75331227575 [keyword_plu] => 1ST GENERATION; AZOBENZENE MOIETIES; 2ND-GENERATION; POLYMERS [publication_iso] => Acta Chim. Sin. [format_title_en] => aaad24011934f9289a908fed50266d831203431834 [publisher_city] => BEIJING [pub_date] => SEP 28 [wos_No] => WOS:000224063500028 [sys_priority_field] => 76 [wos_sub] => Chemistry, Multidisciplinary [publisher_ad] => 16 DONGHUANGCHENGGEN NORTH ST, BEIJING 100717, PEOPLES R CHINA [format_publication_en] => 169b60c7845c9e5f36906950b18f11111348184734 [jl_language] => chinese [jl_publication_cn] => 化学学报 [jl_article_dt] => 期刊论文 [jl_publication_en] => actachimicasinica [jl_country] => 中国 [jl_keyword_en] => intensityoflightabsorbed,photochromicliquidcrystallinedendrimer,thermal,yield,photoelectricinformation,functionalmaterial,quantum,transcisisomerratio,activationenergy,backisomerization,photochemicalbackisomerization [jl_keyword_cn] => ,光电信息功能材料,活化能,量子产率,光回复异构化,反顺异构体组分比,光致变色液晶树状物,热回复异构化,吸收光强 [jl_publisher] => sciencechinapress [author_first] => 张其震 [cite_wanfang] => 12 [clc] => O626 [CSSN] => 31-1320/O6 [uri] => https://www.scopus.com/inward/record.uri?eid=2-s2.0-33749141735&partnerID=40&md5=102db311323dae82ab4fcb0e324e7ca4 [jl_clc] => o626 [company_id] => 133,0,5,43,169 [sys_subject_sort] => 0,0,0,0 [college_parent_id] => 133,5,43,169 [company_test] => Array,Array,Array,Array [author_id] => [author_test] => Array ( ) [sys_author_id_arr] => 22294刘建强 [jl_publication_cn_publication_en] => actachimicasinica,化学学报 [jl_keyword_cn_keyword_en] => activationenergy,photochromicliquidcrystallinedendrimer,吸收光强,光回复异构化,intensityoflightabsorbed,活化能,热回复异构化,functionalmaterial,yield,backisomerization,quantum,thermal,量子产率,光电信息功能材料,光致变色液晶树状物,transcisisomerratio,反顺异构体组分比,photoelectricinformation,photochemicalbackisomerization [format_scopus_No] => c373bb2c8109d33a196abd06b354f1ba1115482350 [format_wos_No] => 2d2b0e4ee96ae8156a6c78a8db0670c0-1792231234 [standard_in] => School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China; School of Physics and Microelectronics, Shandong University, Jinan 250100, China [cauthor] => Zhang, QZ(qzzhang@sdu.edu.cn) [datebase] => Scopus [cite_scopus] => 6 [scopus_No] => 2-s2.0-33749141735 [jl_author_test] => usureu0,unameuu5f20u5e86u7af9,unameuu5f20u7eaau829d,uirauthortype0,uirauthortype3,unameuu5218u5efau5f3a,uirtstag0,upersonid22294,upersonid25613,uuindex2,uuindex1,uuindex4,utindex0,uirtag7,uirinspecttag0,utindex1,uirtag0,uirtypical3,uirtypical1,unameuu5f20u7fa4u59ff,upersonid25608,upersonid25441 [sys_author_jg_last_arr] => 中国,中国,中国,中国 [jl_company_test] => unameuu5316u5b66u4e0eu5316u5de5u5b66u9662,uorgidu5,uparentidu43,unameuu7269u7406u5b66u9662,uircu0,uorgidu43,ulevelu1,uparentidu5 [sys_author_in_last_arr] => china [sys_author_id] => [id] => 6gZ1vWUBFjIhTVEbZoNm [tags] => 0 ) [9] => Array ( [batch2] => 1,2,6 [batch] => 3250,3243,3249,3252,3241 [tag] => 0 [abstract_cn] => 在G3 (MP2 )水平上 ,通过对CH3 S与NO反应势能面 (PES)上关键驻点的能量计算 ,共找到 3种中间体、7个过渡态、9种产物通道 ,并对其反应机理进行了讨论 .结果表明此反应主要以两种方式进行 :一是加成反应 ,先生成CH3 SNO ,然后发生单分子解离和异构化反应 ;二是直接抽提反应 ,生成CH2 S +HNO .用多通道RRKM TST模型计算了反应随温度和压力变化的速率常数 .以 2 95K的N2 作浴气 ,在 2 0 0 0~ 3 9996 6Pa压力范围的速率常数为 1 6× 10 -12 ~ 1 2 8× 10 -11cm3 ·molecule-1·s-1.我们计算... [keyword_cn] => 从头算方法;甲基硫自由基(CH3S);TSTRRKM理论;反应机理 [article_id] => 643651,490093,661225,329869,238387 [clc] => R373 [author_jg] => [王少坤] 山东大学化学与化工学院, 济南, 山东 250100, 中国.@@@[张庆竹] 山东大学化学与化工学院, 济南, 山东 250100, 中国.@@@[顾月姝] 山东大学化学与化工学院, 济南, 山东 250100, 中国.@@@[周建华] 山东轻工业学院化工系, 济南, 山东 250100, 中国 [format_title_cn_publication_cn_pub_year] => b535123117bbbf129e0e1023199bd059 [hints] => 16 [issue] => 6 [sys_level_num] => 2_3 [sys_jg_type] => 9,11,5,10 [format_issn_issue_page_pub_year] => 472f00f9ca5e3c0db94325d46231ff74 [source_type] => 351 [pub_year] => 2004 [pub_date] => MAR 28 [pages] => 6 [from_id] => 76,75,73,80,78 [author_cn] => 王少坤,张庆竹,周建华,顾月姝 [issn] => 0567-7351 [uri] => https://www.scopus.com/inward/record.uri?eid=2-s2.0-33646009594&partnerID=40&md5=b29dfee8643ed58d16489e619b91bd57 [publication_cn] => 化学学报 [title_cn] => CH_3S与NO基态反应的机理及动力学 [CSSN] => 31-1320/O6 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => 0d5710ae30e09adbe12f8e0b013381ff [page] => 550-555+531 [hb_type] => 2 [article_dt] => Article [hb_batch] => title_cn_publication_cn_pub_year_2_3 [publication_en] => ACTA CHIMICA SINICA [cite_wos] => 20 [fund_No] => 高等学校博士点专项科研基金 [check_3Y] => 4 [language] => Chinese [delivery_No] => 806MF [format_title] => 089170b6b13cb9d08ea4c975604911691055337905 [cauthor_ad] => [Wang, SK]Shandong Univ, Sch Chem & Chem Engn, Jinan 250100, Peoples R China. [author_fn] => Wang, SK; Zhang, QZ; Zhou, JH; Gu, YS [reference] => ATKINSON R, 1984, J PHYS CHEM-US, V88, P1584, DOI 10.1021/j150652a029@@@@@@BALLA RJ, 1986, CHEM PHYS, V109, P101, DOI 10.1016/0301-0104(86)80188-4@@@BARNES I, 1987, CHEM PHYS LETT, V140, P451, DOI@@@10.1016/0009-2614(87)80467-0@@@Chang PF, 2000, J PHYS CHEM A, V104, P5525, DOI 10.1021/jp000294a@@@DOMINE F, 1990, J PHYS CHEM-US, V94, P5839, DOI 10.1021/j100378a043@@@@@@FARNELL L, 1983, J PHYS CHEM-US, V87, P79, DOI 10.1021/j100224a019@@@Ignatyev IS, 1997, J CHEM PHYS, V107, P141, DOI 10.1063/1.474610@@@Martinez E, 1999, CHEM PHYS LETT, V308, P37, DOI@@@10.1016/S0009-2614(99)00579-5@@@MCDOUALL JJW, 1989, J CHEM PHYS, V90, P2363, DOI 10.1063/1.455978@@@NIKI H, 1983, J PHYS CHEM-US, V87, P7, DOI 10.1021/j100224a003@@@@@@SCHLEGEL HB, 1988, CHEM PHYS LETT, V145, P329, DOI@@@10.1016/0009-2614(88)80016-2@@@TYNDALL GS, 1989, J PHYS CHEM-US, V93, P2426, DOI 10.1021/j100343a041@@@@@@TYNDALL GS, 1991, INT J CHEM KINET, V23, P483, DOI 10.1002/kin.550230604@@@WINE PH, 1981, J PHYS CHEM-US, V85, P2660, DOI 10.1021/j150618a019@@@YIN FD, 1990, J ATMOS CHEM, V11, P309, DOI 10.1007/BF00053780@@@ [publication_29] => ACTA CHIM SINICA [end_page] => 555 [abstract_en] => A series of key stationary points of potential energy surface ( PES) for the CH3S + NO system was calculated at the G3(MP2) level. The calculations reveal three intermediates, seven transition states and nine product channels. With the stationary point energies and TST-RRKM theory, the reaction rates were calculated in the temperature range of 200 similar to 1700 K, and the gas phase reaction mechanism of CH3S + NO was discussed. At low temperature, the production of CH3SNO is the main reaction channel. At high temperature, H-abstraction mechanism to give products of CH2S + HNO is the dominant reaction channel, and the other products might be neglected. This result is compared with the experimental value. [author_in] => [Wang, S.-K] School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China@@@[ Zhang, Q.-Z] School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China@@@[ Zhou, J.-H] Department of Chemical Engineering, Shandong Institute of Light Industry, Jinan 250100, China@@@[ Gu, Y.-S] School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China [publication_type] => J [begin_page] => 550 [author_en] => Wang, SK; Zhang, QZ; Zhou, JH; Gu, YS [volume] => 62 [get_data] => 2018-08-29 [publisher] => SCIENCE CHINA PRESS [keyword_en] => ab initio; methylthiyl; TST-RRKM; reaction mechanism [format_publication_cn] => 6918be3b26b1fa6ec0424f6071208a75331227575 [keyword_plu] => PLESSET PERTURBATION-THEORY; DIMETHYL SULFIDE; KINETICS; MECHANISM; TEMPERATURE [publication_iso] => Acta Chim. Sin. [format_title_en] => 616244e808cf7b84858cb52b6c84aee11642860376 [publisher_city] => BEIJING [hx_id] => 2377,2378,2371 [reference_No] => 15 [email] => wangsk@sdu.edu.cn [cite_awos] => 24 [wos_No] => WOS:000220437300004 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [check_180] => 0 [publisher_ad] => 16 DONGHUANGCHENGGEN NORTH ST, BEIJING 100717, PEOPLES R CHINA [title_en] => Theoretical study on the gas phase reaction of CH3S with NO [format_publication_en] => 169b60c7845c9e5f36906950b18f11111348184734 [jl_language] => chinese [jl_publication_cn] => 化学学报 [jl_article_dt] => 期刊论文 [jl_publication_en] => actachimicasinica [jl_country] => 中国,纳米比亚,瑞士,印度 [jl_keyword_en] => methylthiyl,abinitio,tstrrkm,reactionmechanism [jl_keyword_cn] => tstrrkm理论,从头算方法,反应机理,甲基硫自由基ch3s [jl_clc] => r373 [jl_publisher] => sciencechinapress [author_id] => 24162 [author_test] => Array ( [0] => Array ( [sure] => 1 [irmagnum] => 0 [u_index] => 0 [name] => 王少坤 [sys_author_id] => Array ( [0] => 24162 ) [irtag] => 0 [t_index] => 0 [person_id] => 24162 ) ) [company_id] => 43,169 [sys_subject_sort] => 0,0 [college_parent_id] => 43,169 [company_test] => Array,Array [sys_author_id_arr] => [cscd_No] => CSCD:1703473 [jl_publication_cn_publication_en] => 化学学报,actachimicasinica [jl_keyword_cn_keyword_en] => 从头算方法,反应机理,甲基硫自由基ch3s,tstrrkm理论,reactionmechanism,methylthiyl,abinitio,tstrrkm [sys_author_id] => [format_cscd_No] => cf85065247f79d88846b8ea890c2d4ae [format_title_en_publication_en_pub_year] => d96b43c9867a9b1b1cfdbc8959a11462 [format_wos_No] => 3c7a95c163ba4d57ed8fca099caa8a63 [format_title_en_issn_pub_year] => 1ff997c4a5cb42d1a7ff162f85414019 [format_scopus_No] => 52dba7db5265522f15642f0b77e93938 [standard_in] => School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China; Department of Chemical Engineering, Shandong Institute of Light Industry, Jinan 250100, China [cauthor] => Wang, SK(wangsk@sdu.edu.cn) [datebase] => Scopus [cite_scopus] => 19 [sys_priority_field] => 76 [scopus_No] => 2-s2.0-33646009594 [jl_pub_year] => 2004 [jl_author_test] => unameuu738bu5c11u5764,usureu0,usureu1,unameuu5f20u5e86u7af9,upersonid24162,uuindex0,uirtag0,utindex0,uirtag7,upersonid25608,uirmagnum0,usysauthoridu24162 [sys_author_jg_last_arr] => 中国 [jl_company_test] => uircu0,unameuu5316u5b66u4e0eu5316u5de5u5b66u9662,uparentidu43,uorgidu43,ulevelu1 [sys_author_in_last_arr] => china [id] => 2A1EvmUBFjIhTVEbcW5w [tags] => 0 ) [10] => Array ( [batch2] => 1,2,6 [batch] => 3243,3241,3252,3254,3249 [tag] => 0 [abstract_cn] => 用发散法合成周边含丁氧基偶氮苯介晶基元(M5)端基新的三代树状碳硅烷(D3)液晶,并用元素分析、核磁共振、激光解吸电离飞行时间质谱(MALDI-TOF-MS)、红外、紫外、偏光显微镜、差示扫描量热(DSC)和广角X射线衍射(WAXD)表征,D3为向列相与M5相同,树状物相态由介晶基元相态决定,D3相行为:K79N126I116N,D3熔点比M5降低33℃,D3清亮点比M5增加2℃,D3液晶态温区比M5加宽35℃. [keyword_cn] => 三代树状碳硅烷液晶;丁氧基偶氮苯;介晶基元;合成; [clc] => O627.41 [author_jg] => [张其震] 山东大学化学化工学院, 济南, 山东 201000, 中国.@@@[殷晓颖] 山东大学化学化工学院, 济南, 山东 201000, 中国.@@@[王大庆] 山东师范大学测试中心, 济南, 山东 250014, 中国.@@@[李光] 中国科学院长春应用化学研究所, 长春, 吉林 130022, 中国.@@@[季怡萍] 中国科学院长春应用化学研究所, 长春, 吉林 130022, 中国.@@@[赵晓光] 中国科学院长春应用化学研究所, 长春, 吉林 130022, 中国 [format_title_cn_publication_cn_pub_year] => c3d74c8769eeb474471588e2b9468abe [from_id] => 76,75,73,80,85 [issue] => 4 [sys_level_num] => 2_1 [sys_jg_type] => 9,11,5 [source_type] => 351 [pub_year] => 2003 [article_id] => 491930,331282,249323,664145,105804 [pages] => 6 [hints] => 2 [author_cn] => 张其震[1];殷晓颖[1];王大庆[2];李光[3];季怡萍[3];赵晓光[3] [issn] => 0567-7351 [uri] => https://www.scopus.com/inward/record.uri?eid=2-s2.0-26844510584&partnerID=40&md5=e707963f7c9a5bbcf39e39065a62febd [publication_cn] => 化学学报 [title_cn] => 三代树状碳硅烷液晶研究——端基含丁氧基偶氮苯介晶基元 [CSSN] => 31-1320/O6 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => bebb9a49860900115e7910def4a518e5 [hb_type] => 2 [hb_batch] => title_cn_publication_cn_pub_year_2_3 [publication_en] => ACTA CHIMICA SINICA [cite_wos] => 11 [fund_No] => 国家自然科学基金(Nos. 29874020,59573029); 中国科学院高分子和物理重点实验室基金(长春应用化学所)资助项目 [check_3Y] => 1 [language] => Chinese [delivery_No] => 757DL [format_title] => 08d1a8dd84723aab8b9d3255906b4da5-1651263843 [cauthor_ad] => [Zhang, QZ]Shandong Univ, Sch Chem & Chem Engn, Jinan 250100, Peoples R China. [author_fn] => Zhang, QZ; Yin, XY; Wang, DQ; Li, G; Ji, YP; Zhao, XG [reference] => de Gennes P G, 1974, The Physics of Liquid Crystal, P10@@@De Viries A, 1985, Mol. Cryst. Liq. Cryst., V131, P125@@@FINKELMAN H, 1991, LIQUID CRYSTALLINITY, P256@@@FISHWICK M, 1970, J ORGANOMET CHEM, V25, P69, DOI@@@10.1016/S0022-328X(00)86206-3@@@@@@Karstedt B D, 1974, Chem. Abstr, V80, P135655@@@Karstedt B D, 1973, US 3775 452@@@LECOIN D, 1975, MOL CRYST LIQ CRYST, V31, P233, DOI@@@10.1080/15421407508082875@@@Lorenz K, 1996, ADV MATER, V8, P414, DOI 10.1002/adma.19960080509@@@PERCEC V, 1995, J AM CHEM SOC, V117, P11441, DOI 10.1021/ja00151a008@@@Ponomarenko SA, 1996, LIQ CRYST, V21, P1, DOI 10.1080/02678299608033789@@@van der Made A W, 1992, J. Chem. Soc., Chem. Commun, P1400@@@WOOLEY KL, 1993, MACROMOLECULES, V26, P1514, DOI 10.1021/ma00059a006@@@[张其震 Zhang Qizhen], 2003, [化学学报, Acta Chemical Sinica], V61, P416@@@[张其震 Zhang Qizhen], 2002, [化学学报, Acta Chemical Sinica], V60, P2232@@@张其震, 1998, 高等学校化学学报, V19, P1175@@@张其震, 1998, 高等学校化学学报, V19, P827@@@张其震, 1997, 高等学校化学学报, V18, P158@@@张其震, 1998, 湘潭大学自然科学学报, V20, P74@@@周其凤, 1994, 液晶高分子, P75@@@周其凤, 1999, 高分子通报, P54@@@张其震, 2000, 功能高分子材料 [publication_29] => ACTA CHIM SINICA [end_page] => 624 [abstract_en] => A divergent synthesis of a new carbosilane liquid crystalline (LC) dendrimer of the third generation (W) is described. 4-Butoxyazobenzene groups (NO) are used as mesogenic fragments and attached in its periphery. Structure and properties of D3 were characterized by elemental analysis, H-1 NMR, MALDI-TOF-MS, IR, UV, polarizing optical micrograph, DSC and WAXD. Similar to NO, D3 is nematic liquid crystal. The mesomorphic state of dendrimer depends on that of mesogenic units. Phase behavior of D3 in LC state is K79N126I116N. The melting point of D3 is 33 degreesC lower than that of M5. The clearing point of D3 is 2 T higher than that of M5. The mesophase region of D3 is 35 degreesC wider than that of M5. [author_in] => [Zhang, Q.-Z] School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China@@@[ Yin, X.-Y] School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China@@@[ Wang, D.-Q] Analysis and Test Centre, Shandong Normal University, Jinan 250014, China@@@[ Li, G] Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China@@@[ Ji, Y.-P] Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China@@@[ Zhao, X.-G] Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China [publication_type] => J [begin_page] => 619 [article_dt] => Article [author_en] => Zhang, QZ; Yin, XY; Wang, DQ; Li, G; Ji, YP; Zhao, XG [volume] => 61 [get_data] => 2018-08-29 [publisher] => SCIENCE CHINA PRESS [keyword_en] => nematic liquid crystal; dendrimer of the third generation;; 4-butoxyazobenzene carbosilane [format_publication_cn] => 6918be3b26b1fa6ec0424f6071208a75331227575 [keyword_plu] => 1ST GENERATION [publication_iso] => Acta Chim. Sin. [format_title_en] => 2296d66fc55dd2dddd372d64d5e402ce-552963141 [publisher_city] => BEIJING [pub_date] => APR [hx_id] => 2377,2378,2371 [reference_No] => 21 [email] => qzzhang@sdu.edu.cn [cite_awos] => 13 [wos_No] => WOS:000187533500030 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [check_180] => 0 [publisher_ad] => 16 DONGHUANGCHENGGEN NORTH ST, BEIJING 100717, PEOPLES R CHINA [title_en] => Study on a carbosilane liquid crystalline dendrimer of the third generation - Containing 4-butoxyazobenzene mesogenic groups in its periphery [format_publication_en] => 169b60c7845c9e5f36906950b18f11111348184734 [jl_language] => chinese [jl_publication_cn] => 化学学报 [jl_article_dt] => 期刊论文 [jl_publication_en] => actachimicasinica [jl_country] => 中国,纳米比亚,瑞士,印度 [jl_keyword_en] => dendrimerofthethirdgeneration,4butoxyazobenzenecarbosilane,nematicliquidcrystal [jl_keyword_cn] => 合成,介晶基元,三代树状碳硅烷液晶,丁氧基偶氮苯 [jl_clc] => o62741 [jl_publisher] => sciencechinapress [company_id] => 43,169 [sys_subject_sort] => 0,0 [college_parent_id] => 43,169 [company_test] => Array,Array [author_id] => 21651,25088,21654,25613,23827,25608,25110 [author_test] => Array ( [0] => Array ( [sure] => 0 [irmagnum] => 0 [u_index] => 4 [name] => 李广 [irtag] => 7 [t_index] => 0 [person_id] => 21654 ) [1] => Array ( [sure] => 0 [irmagnum] => 0 [u_index] => 1 [name] => 张群姿 [irtag] => 8 [t_index] => 1 [person_id] => 25613 ) [2] => Array ( [sure] => 0 [irmagnum] => 0 [u_index] => 1 [name] => 张庆竹 [irtag] => 7 [t_index] => 1 [person_id] => 25608 ) [3] => Array ( [sure] => 0 [irmagnum] => 0 [u_index] => 3 [name] => 王德强 [irtag] => 7 [t_index] => 0 [person_id] => 23827 ) [4] => Array ( [sure] => 0 [irmagnum] => 0 [u_index] => 2 [name] => 尹向勇 [irtag] => 7 [t_index] => 0 [person_id] => 25110 ) [5] => Array ( [sure] => 0 [irmagnum] => 0 [u_index] => 4 [name] => 李刚 [irtag] => 7 [t_index] => 0 [person_id] => 21651 ) [6] => Array ( [sure] => 0 [irmagnum] => 0 [u_index] => 2 [name] => 殷向阳 [irtag] => 7 [t_index] => 0 [person_id] => 25088 ) ) [sys_author_id_arr] => [cscd_No] => CSCD:1152549 [jl_publication_cn_publication_en] => 化学学报,actachimicasinica [jl_keyword_cn_keyword_en] => 合成,4butoxyazobenzenecarbosilane,nematicliquidcrystal,dendrimerofthethirdgeneration,介晶基元,三代树状碳硅烷液晶,丁氧基偶氮苯 [sys_author_id] => [format_cscd_No] => 893c4b149fd277f1dbab2a769ee3b3f2 [format_title_en_publication_en_pub_year] => 5612211dc813eda732fc7878820d9f8f [format_wos_No] => 65ede2bbca4c357a9f7f6ada26c5c180 [format_title_en_issn_pub_year] => d46005cb6bfdf8e459a69acbb458d828 [format_scopus_No] => 6c2a32a1258f89fe8c33f77a4f95fa2a [standard_in] => School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China; Analysis and Test Centre, Shandong Normal University, Jinan 250014, China; Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China [cauthor] => Zhang, QZ(qzzhang@sdu.edu.cn) [datebase] => Scopus [page] => 619-624 [cite_scopus] => 10 [format_issn_issue_page_pub_year] => 3acfaae906a57d6bbebbf494d72a4937 [sys_priority_field] => 76 [scopus_No] => 2-s2.0-26844510584 [jl_pub_year] => 2003 [jl_author_test] => usureu0,unameuu5f20u5e86u7af9,upersonid21654,upersonid21651,upersonid25088,unameuu6bb7u5411u9633,unameuu5c39u5411u52c7,unameuu738bu5fb7u5f3a,upersonid25613,uuindex2,uuindex3,uuindex1,uuindex4,utindex0,uirtag7,upersonid23827,utindex1,unameuu674eu521a,uirtag8,upersonid25110,unameuu5f20u7fa4u59ff,upersonid25608,unameuu674eu5e7f [sys_author_jg_last_arr] => 中国 [jl_company_test] => uircu0,unameuu5316u5b66u4e0eu5316u5de5u5b66u9662,uparentidu43,uorgidu43,ulevelu1 [sys_author_in_last_arr] => china [id] => MQkvvmUBFjIhTVEbe2kX [tags] => 0 ) [11] => Array ( [batch2] => 1,2 [batch] => 3250,3249,3241,3254,3252 [tag] => 0 [abstract_cn] => 利用Lie代数方法研究了四原子分子振转相互作用 ,在代数框架内首次给出四原子分子振转相互作用的张量算子非对角矩阵元的表达式 ,利用这些表达式对线型四原子分子HCCF振转相互作用的l doubling进行了计算 [keyword_cn] => Lie代数方法;振转相互作用;张量算子;约化矩阵元 [article_id] => 648260,105803,663282,330896,239568 [clc] => O626 [author_jg] => [冯东太] 山东大学物理与微电子学院/化学院, 济南, 山东 250100, 中国.@@@[丁世良] 山东大学物理与微电子学院/化学院, 济南, 山东 250100, 中国.@@@[王美山] 山东大学物理与微电子学院/化学院, 济南, 山东 250100, 中国 [format_title_cn_publication_cn_pub_year] => 6c51670fe343dd186c9401034741036c-790449544 [hints] => 7 [issue] => 11 [sys_level_num] => 2_3 [sys_jg_type] => 0,3,5 [format_issn_issue_page_pub_year] => a582f6087f4cf87dfc5e895003efa052914792534 [source_type] => 351 [pub_year] => 2003 [pub_date] => NOV [pages] => 5 [from_id] => 75,78,73,80,85 [author_cn] => 冯东太,丁世良,王美山 [issn] => 0567-7351 [uri] => http://kns.cnki.net/kns/detail/detail.aspx?FileName=HXXB200311006&DbName=CJFQ2003 [publication_cn] => 化学学报 [title_cn] => 四原子分子振转相互作用的Lie代数方法 [CSSN] => 31-1320/O6 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => 70d719d2707db0f42e4ba49e613d2792-1639994130 [page] => 1729-1733+1692 [hb_type] => 2 [article_dt] => Article [hb_batch] => title_cn_publication_cn_pub_year_2_3 [publication_en] => ACTA CHIMICA SINICA [cite_wos] => 0 [fund_No] => 国家自然科学基金(Nos.19664033,29773027); 吉林大学理论和计算机化学国家重点实验室基金(No.9801); 山东省自然科学基金(No.Y96B03022) [check_3Y] => 1 [language] => Chinese [delivery_No] => 765AY [format_title] => ce0cf2d619de9633edd206a2f730d776-1304099826 [cauthor_ad] => [Feng, DT]Shandong Univ, Sch Chem, Sch Phys & Microelect, Jinan 250100, Peoples R China. [author_fn] => Feng, DT; Ding, SL; Wang, MS [reference] => HOLLAND JK, 1992, J MOL SPECTROSC, V151, P346, DOI@@@10.1016/0022-2852(92)90571-5@@@IACHELLO F, 1993, MOL PHYS, V78, P561, DOI 10.1080/00268979300100391@@@IACHELLO F, 1994, J CHEM PHYS, V101, P3531, DOI 10.1063/1.467539@@@Levine R D, 1995, Alhebraic Theory of Moleules@@@Wang MS, 2002, PHYS REV A, V66, DOI 10.1103/PhysRevA.66.022506@@@Wybourne B G, 1974, Classical Group for Physicists@@@Zare R. N., 1988, ANGULAR MOMENTUM [publication_29] => ACTA CHIM SINICA [end_page] => 1733 [abstract_en] => The ro-vibrational interaction of tetratomic molecules is studied by using Lie algebra. It is the first time to give the formulae of non-diagonal matrix elements of tensor operators which can be employed to describe the ro-vibrational interaction for linear tetratomic molecules. As an example, the l-doubling of ro-vibrational interaction of HCCF is computed by using these formulae. [author_in] => [Feng, DT; Ding, SL; Wang, MS]Shandong Univ, Sch Chem, Sch Phys & Microelect, Jinan 250100, Peoples R China.@@@[Feng, DT; Ding, SL; Wang, MS] Shandong Univ, Dept Phys, Zibo 255000, Peoples R China. [publication_type] => J [begin_page] => 1729 [author_en] => Feng, DT; Ding, SL; Wang, MS [volume] => 61 [get_data] => 2018-08-29 [publisher] => SCIENCE PRESS [keyword_en] => Lie algebraic approach; Ro-vibrational interaction; tensor operator;; reduced matrix element [format_publication_cn] => 6918be3b26b1fa6ec0424f6071208a75331227575 [keyword_plu] => SPECTRA [publication_iso] => Acta Chim. Sin. [format_title_en] => 209945cd69593824a778c37136f7f931-926062034 [publisher_city] => BEIJING [hx_id] => 2377,2371 [reference_No] => 7 [email] => shlaudin@sdu.edu.cn [cite_awos] => 0 [wos_No] => WOS:000188245800007 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [check_180] => 0 [publisher_ad] => 16 DONGHUANGCHENGGEN NORTH ST, BEIJING 100717, PEOPLES R CHINA [title_en] => Lie algebraic approach to Ro-vibrational interaction of tetratonuc molecules [format_publication_en] => 169b60c7845c9e5f36906950b18f11111348184734 [jl_language] => chinese [jl_publication_cn] => 化学学报 [jl_article_dt] => 期刊论文 [jl_publication_en] => actachimicasinica [jl_country] => 中国,中国 [jl_keyword_en] => ,liealgebraicapproach,reducedmatrixelement,tensoroperator,rovibrationalinteraction [jl_keyword_cn] => 张量算子,lie代数方法,约化矩阵元,振转相互作用 [jl_clc] => o626 [jl_publisher] => sciencepress [company_id] => 43,35,133,5,169,161 [sys_subject_sort] => 0,0,0,0,0,0 [college_parent_id] => 43,35,133,5,169,161 [company_test] => Array,Array,Array,Array,Array,Array [author_id] => [author_test] => Array ( ) [sys_author_id_arr] => [cscd_No] => CSCD:1239762 [jl_publication_cn_publication_en] => actachimicasinica,化学学报 [jl_keyword_cn_keyword_en] => 约化矩阵元,reducedmatrixelement,振转相互作用,rovibrationalinteraction,tensoroperator,张量算子,liealgebraicapproach,lie代数方法 [sys_author_id] => [format_cscd_No] => 9c7fc640f578bb3263d88bc312649b93-1033166157 [format_title_en_publication_en_pub_year] => 6f161173391f0099e069b053cf99d7571532765160 [format_wos_No] => 5b76a0e5b19a3c678717be5068340e59188064840 [format_title_en_issn_pub_year] => b2e0dc86f23c2f8da257e3afd14e5f7d351521430 [id] => ig1EvmUBFjIhTVEbKmEG [tags] => 0 ) [12] => Array ( [batch2] => 1,2 [batch] => 3250,3249,3241,3252 [tag] => 0 [abstract_cn] => 用发散法合成周边含 36个丁氧基偶氮苯介晶基元 (M 5 )端基新的二代树状碳硅烷液晶 (D2 ) ,并用元素分析 ,氢谱 ,激光质谱 ,红外 ,紫外 ,偏光显微镜 ,DSC和WAXD法表征 .D2为向列相 ,与M 5相同 ,二代树状物相态由介晶基元相态决定 .D2液晶态相行为是K85N10 7I10 3N69K ,其熔点比M 5降低 2 7~ 41℃ ,清亮点比M 5降低 17~ 18℃ ,液晶态温区比M 5加宽 10~ 2 3℃ .二代碳硅烷 (D2 )与一代碳硅烷 (D1)相比熔点增加 2~ 3℃ ,清亮点降低 2 6~ 2 9℃ ,液晶态温区减少 2 9~ 31℃ .在二代树状物中观察... [keyword_cn] => 树状化合物;液晶;向列相;高强向错;碳硅烷;第二代;4-丁氧基偶氮苯 [article_id] => 539416,663260,331348,239380 [clc] => O621 [author_jg] => [张其震,刘建强,殷晓颖,张静智,季怡萍,赵晓光,李光]山东大学化学化工学院,山东大学化学化工学院,山东大学化学化工学院,山东大学化学化工学院,中国科学院长春应用化学研究所,中国科学院长春应用化学研究所,中国科学院长春应用化学研究所 济南250100,济南250100,济南250100,济南250100,长春130022,长春130022,长春130022 [format_title_cn_publication_cn_pub_year] => 4e9ec77295c3a623b348b98bd3cff6441115578849 [hints] => 4 [issue] => 3 [sys_level_num] => 2_3 [sys_jg_type] => 5 [format_issn_issue_page_pub_year] => 083f6b034ab247b5d9aaaa0a49bb3ea2-1035600146 [source_type] => 351 [pub_year] => 2003 [pub_date] => MAR [pages] => 6 [from_id] => 75,73,80,78 [author_cn] => 张其震,刘建强,殷晓颖,张静智,季怡萍,赵晓光,李光 [issn] => 0567-7351 [uri] => http://kns.cnki.net/kns/detail/detail.aspx?FileName=HXXB200303021&DbName=CJFQ2003 [publication_cn] => 化学学报 [title_cn] => 二代树状碳硅烷液晶研究Ⅰ.端基含36个丁氧基偶氮苯介晶基元 [CSSN] => 31-1320/O6 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => 764638a33e39a8c76008a4e636a9aad5-475647038 [page] => 416-421 [hb_type] => 2 [article_dt] => Article [jl_publication_cn] => 化学学报 [jl_article_dt] => 期刊论文 [jl_keyword_cn] => 第二代,树状化合物,碳硅烷,液晶,向列相,4丁氧基偶氮苯,高强向错 [jl_clc] => o621 [author_in] => [Zhang, QZ; Liu, JQ; Yin, XY; Zhang, JZ; Ji, YP; Zhao, XG; Li, G]Shandong Univ, Sch Chem & Chem Engn, Jinan 250100, Peoples R China.@@@[Zhang, QZ; Liu, JQ; Yin, XY; Zhang, JZ; Ji, YP; Zhao, XG; Li, G] Chinese Acad Sci, Changchun Inst Appl Chem, Changchun 130022, Peoples R China. [company_id] => 0,43,169 [sys_subject_sort] => 0,0 [college_parent_id] => 43,169 [company_test] => Array,Array [author_id] => 22294 [author_test] => Array ( [0] => Array ( [sure] => 0 [irmagnum] => 0 [u_index] => 2 [name] => 刘建强 [irtag] => 7 [t_index] => 0 [person_id] => 22294 ) ) [sys_author_id_arr] => [jl_publication_cn_publication_en] => 化学学报 [jl_keyword_cn_keyword_en] => 碳硅烷,液晶,树状化合物,高强向错,4丁氧基偶氮苯,向列相,第二代 [sys_author_id] => [hb_batch] => grant_no [cite_wos] => 13 [publication_en] => ACTA CHIMICA SINICA [fund_No] => 国家自然科学基金(Nos.29874020,59573029); 中国科学院高分子物理国家重点实验室(Nos.R149833C,R159633Q,)资助项目 [check_3Y] => 1 [language] => Chinese [delivery_No] => 668FN [cauthor_ad] => [Zhang, QZ]Shandong Univ, Sch Chem & Chem Engn, Jinan 250100, Peoples R China. [format_title] => 7d44cad644202f968203a0a7656e84db-397546160 [author_fn] => Zhang, QZ; Liu, JQ; Yin, XY; Zhang, JZ; Ji, YP; Zhao, XG; Li, G [reference] => de Gennes P G, 1974, The Physics of Liquid Crystal, P10@@@de Vries A, 1985, Mol.Cryst.Liq.Cryst, V131, P125@@@FINKELMAN H, 1991, LIQUID CRYSTALLINITY, P256@@@FISHWICK M, 1970, J ORGANOMET CHEM, V25, P69, DOI@@@10.1016/S0022-328X(00)86206-3@@@@@@GRAY GW, 1984, SMECTIC LIQUID CRYST, P21@@@Karstedt B D, 1974, Chem. Abstr, V80, P135655@@@KELLER P, 1988, MOL CRYST LIQ CRYST, V155, P71@@@LECOIN D, 1975, MOL CRYST LIQ CRYST, V31, P233, DOI@@@10.1080/15421407508082875@@@Lorenz K, 1996, ADV MATER, V8, P414, DOI 10.1002/adma.19960080509@@@NEHRING J, 1972, J CHEM SOC FARAD T 2, V68, P1, DOI 10.1039/f29726800001@@@Percec V, 1995, Chem.Soc, V117, P11441@@@Ponomareno S A, 1996, Liquid Crystals, P1@@@SONG WH, 1993, MAKROMOL CHEM-RAPID, V14, P605@@@Van der Made, 1992, J.Chem.Soc.Chem.Commun, P1400@@@WOOLEY KL, 1993, MACROMOLECULES, V26, P1514, DOI 10.1021/ma00059a006@@@张其震, 1996, 高等学校化学学报, V17, P1804@@@张其震, 1998, 高等学校化学学报, V19, P1175@@@张其震, 1998, 高等学校化学学报, V19, P827@@@张其震, 1997, 高等学校铧学学报, V18, P158@@@张其震, 1998, 湘潭大学自然科学学报, V20, P74@@@殷晓颖, 1999, [硕士论文]@@@周其凤, 1999, 高分子通报, P54@@@张其震, 2000, 功能高分子材料@@@周其凤, 1994, 液晶高分子, P121 [cite_wanfang] => 15 [format_title_en_issn_pub_year] => 537f65bcedfff6d9b2caacfcfc023ee5-978890551 [publication_29] => ACTA CHIM SINICA [end_page] => 421 [abstract_en] => The divergent synthesis of a new carbosilane liquid crystalline (LC) dendrimer (D2) of the second generation is described. Thirty. six 4-butoxyazobenzene groups (NO) are used as mesogenic fragments and attached in its periphery. Structure and properties of D2 were characterized by elemental analysis, H-1 NMR, MAIDI-TOF-MS, IR, UV, polarizing optical micrograph, DSC and WAXD. Similar to NB, D2 is a nematic liquid crystal. The mesomorphic state of the dendrimer of second generation (D2) depends on that of mesogenic units. Phase behavior of D2 in LC state is K85N107I103N69K. The melting point of D2 is 27similar to41degreesC less than that of M5, the clearing point of D2 is 17similar to18degreesC less than that of M5 and the mosophase region of D2 is 10similar to23degreesC greater than that of M5. The melting point of D2 is 2similar to3degreesC greater than that of D1, the clearing point of D2 is 26similar to29degreesC less than that of D1 and the mesophase region is 29similar to31degreesC less than that of D1. Six extinguished brushes emanating from a stationary point were observed, corresponding to the high-strength disclination of S = +3/2 of dendrimer D2. [publication_type] => J [begin_page] => 416 [author_en] => Zhang, QZ; Liu, JQ; Yin, XY; Zhang, JZ; Ji, YP; Zhao, XG; Li, G [format_cscd_No] => 669923c20074193f009f44f3a0e8a3b41158887864 [volume] => 61 [publisher] => SCIENCE CHINA PRESS [get_data] => 2018-08-29 [keyword_en] => dendrimer; liquid crystal; nematic; high-strength disclination;; carbosilane; second generation; 4-butoxyazobenzene [keyword_plu] => SCHLIEREN TEXTURE; POLYMER [format_publication_cn] => 6918be3b26b1fa6ec0424f6071208a75331227575 [publication_iso] => Acta Chim. Sin. [format_title_en_publication_en_pub_year] => 0c965047fdd52cff6d7d958c9dbffce81175390040 [format_title_en] => 5c90f1330ebc7964661be906cad222711633937203 [publisher_city] => BEIJING [cite_cscd] => 13 [publication_info] => 0567-7351(2003)61:3<416:EDSZTG>2.0.TX;2-M [hx_id] => 2377,2371 [email_c] => qzzhang@sdu.edu.cn [email] => qzzhang@sdu.edu.cn [reference_No] => 24 [cite_awos] => 13 [cscd_No] => CSCD:1358636 [wos_No] => WOS:000182279800022 [format_wos_No] => a15c490350a460be1a51dddcbfb4bdc3392482587 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [check_180] => 0 [publisher_ad] => 16 DONGHUANGCHENGGEN NORTH ST, BEIJING 100717, PEOPLES R CHINA [title_en] => Study on a carbosilane liquid crystalline dendrimer of the second generation - 1. Containing thirty-six 4-butoxyazobenzene groups in its periphery [format_publication_en] => 169b60c7845c9e5f36906950b18f11111348184734 [id] => BA9KvmUBFjIhTVEbYgUg [tags] => 0 ) [13] => Array ( [batch2] => 1,2,6 [batch] => 3249,3250,3252,3254,3243,3241 [tag] => 0 [abstract_cn] => 用发散法合成了以四碳硅烷为核心 ,周边含 12个 4 硝基偶氮苯介晶基元 (M 5 )端基的新的一代树状碳硅烷 (D1)液晶 ,并用元素分析、核磁共振、基质辅助激光解吸离子化飞行时间质谱 (MALDI TOF MS)、红外、紫外、偏光显微镜、差示扫描量热 (DSC)和X射线衍射法 (WAXD)表征 .介晶基元化合物 (M 5 )显示向列相 ,树状物D1显示胆甾相和SE 相 .D1的液晶相相行为是K70Ch188I185Ch5 8SE48K . [keyword_cn] => SE相液晶;胆甾相液晶;一代树状化合物;4-硝基偶氮苯;碳硅烷 [article_id] => 661939,491947,239576,331008,105806,539408 [clc] => O621 [author_jg] => [张其震] 山东大学化学化工学院, 济南, 山东 250100, 中国.@@@[盛昕] 山东大学化学化工学院, 济南, 山东 250100, 中国.@@@[殷晓颖] 山东大学化学化工学院, 济南, 山东 250100, 中国.@@@[季怡萍] 中国科学院长春应用化学研究所, 长春, 吉林 130022, 中国.@@@[李光] 中国科学院长春应用化学研究所, 长春, 吉林 130022, 中国.@@@[赵晓光] 中国科学院长春应用化学研究所, 长春, 吉林 130022, 中国 [format_title_cn_publication_cn_pub_year] => 8170dfac23db0c4ed46e5db92b935c16 [hints] => 3 [issue] => 9 [sys_level_num] => 2_3 [sys_jg_type] => 11,5 [format_issn_issue_page_pub_year] => c1db1e67b6543d484c32d48aa06c3e5f [source_type] => 351 [pub_year] => 2003 [pub_date] => SEP [pages] => 6 [from_id] => 76,75,73,80,78,85 [author_cn] => 张其震,盛昕,殷晓颖,季怡萍,李光,赵晓光 [issn] => 0567-7351 [uri] => https://www.scopus.com/inward/record.uri?eid=2-s2.0-33750478392&partnerID=40&md5=15bb4c1b81de8c4567709cc21599978d [publication_cn] => 化学学报 [title_cn] => 一代树状碳硅烷液晶研究——端基含12个4-硝基偶氮苯介晶基元 [CSSN] => 31-1320/O6 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => e9121686c8acc7935fee06bf45efc226 [page] => 1478-1483 [hb_type] => 2 [article_dt] => Article [hb_batch] => title_cn_publication_cn_pub_year_2_3 [publication_en] => ACTA CHIMICA SINICA [cite_wos] => 10 [fund_No] => 国家自然科学基金(Nos.29874020,59573029); 中国科学院高分子物理重点实验室基金(中国科学院长春应用化学研究所Nos.R 149833C,R159633Q,R159833C)资助项目; 山东省自然科学基金(No.Y95B0720) [check_3Y] => 1 [language] => Chinese [delivery_No] => 765AX [format_title] => 18dc671fa82aae1df82250ae3dad3429-2143997399 [cauthor_ad] => [Zhang, QZ]Shandong Univ, Sch Chem & Chem Engn, Jinan 250100, Peoples R China. [author_fn] => Zhang, QZ; Sheng, X; Yin, XY; Ji, YP; Li, G; Zhao, XG [reference] => Archut A, 1998, J AM CHEM SOC, V120, P12187, DOI 10.1021/ja9822409@@@@@@de Vries A, 1985, Mol. Cryst. Liq. Cryst., V131, P125@@@DEMUS L, 1978, TEXTURES LIQUID CRYS, P55@@@FINKELMAN H, 1991, LIQUID CRYSTALLINITY, P256@@@FISHWICK M, 1970, J ORGANOMET CHEM, V25, P69, DOI@@@10.1016/S0022-328X(00)86206-3@@@@@@FURNISS BS, 1978, VOGELS TXB PRACTICAL, P715@@@GRAY CW, 1984, SMECTIC LIQUID CRYST, P21@@@Hudson SD, 1997, SCIENCE, V278, P449, DOI 10.1126/science.278.5337.449@@@JANGE DM, 1999, J AM CHEM SOC, V121, P4912@@@KANG SK, 1985, SYNTHESIS-STUTTGART, P1161@@@Karstedt B, 1973, US 3775452@@@Nagasaki T, 1997, CHEM LETT, P717, DOI 10.1246/cl.1997.717@@@PERCEC V, 1995, J AM CHEM SOC, V117, P11441, DOI 10.1021/ja00151a008@@@Pesak DJ, 1997, ANGEW CHEM INT EDIT, V36, P1636, DOI@@@10.1002/anie.199716361@@@@@@Ponomarenko SA, 1996, LIQ CRYST, V21, P1, DOI 10.1080/02678299608033789@@@[唐新德 Tang XinDe], 2003, [有机化学, Chinese Journal of Organic Chemistry],@@@V23, P238@@@van der Made A W, 1992, J. Chem. Soc., Chem. Commun, P1400@@@[张其震 Zhang Qizhen], 2003, [化学学报, Acta Chemical Sinica], V61, P619@@@[张其震 Zhang Qizhen], 2003, [化学学报, Acta Chemical Sinica], V61, P1108@@@[张其震 Zhang Qizhen], 2003, [化学学报, Acta Chemical Sinica], V61, P416@@@[张其震 Zhang Qizhen], 2002, [化学学报, Acta Chemical Sinica], V60, P2232@@@张其震, 1998, 高等学校化学学报, V19, P1175@@@张其震, 1998, 高等学校化学学报, V19, P827@@@张其震, 1997, 高等学校化学学报, V18, P158@@@周其凤, 1994, 液晶高分子@@@张其震, 2000, 功能高分子材料 [publication_29] => ACTA CHIM SINICA [end_page] => 1483 [abstract_en] => The divergent synthesis of a new carbosilane liquid crystalline (LC) dendrimer of the first generation (D1) is described. Twelve 4-nitroazobenzene are used as mesogenic fragments and attached in its periphery and fourcarbosilane as core. Structure and properties of D1 were characterized by elemental analysis, H-1 NMR, MALDITOF-MS, IR, UV-vis, polarizing optical micrograph, DSC and WAXD. Mesogenic compound NU exhibits nematic and dendrimer D1 reveals cholesteryl and smectic E liquid crystalline state. Phase behavior of D1 in LC state is K70Ch188I185Ch58S(E)48K. [author_in] => [Zhang, Q.-Z] School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China@@@[ Sheng, X] School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China@@@[ Yin, X.-Y] School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China@@@[ Ji, Y.-P] Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China@@@[ Li, G] Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China@@@[ Zhao, X.-G] Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China [publication_type] => J [begin_page] => 1478 [author_en] => Zhang, QZ; Sheng, X; Yin, XY; Ji, YP; Li, G; Zhao, XG [volume] => 61 [get_data] => 2018-08-29 [publisher] => SCIENCE CHINA PRESS [keyword_en] => smectic E liquid crystal; cholesteryl liquid crystal; dendrimer of the; first generation; 4-nitroazobenzene; carbosilane [format_publication_cn] => 6918be3b26b1fa6ec0424f6071208a75331227575 [keyword_plu] => MOLECULES [publication_iso] => Acta Chim. Sin. [format_title_en] => 72e6a710dc200fc72d3fa13a072b072f1961440278 [publisher_city] => BEIJING [hx_id] => 2377,2378,2371 [reference_No] => 26 [email] => qzzhang@sdu.edu.cn [cite_awos] => 10 [wos_No] => WOS:000188245700026 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [check_180] => 0 [publisher_ad] => 16 DONGHUANGCHENGGEN NORTH ST, BEIJING 100717, PEOPLES R CHINA [title_en] => Study on a carbosilane liquid crystalline dendrimer of the first generation - Containing twelve 4-nitroazobenzene mesogen in its periphery [format_publication_en] => 169b60c7845c9e5f36906950b18f11111348184734 [jl_language] => chinese [jl_publication_cn] => 化学学报 [jl_article_dt] => 期刊论文 [jl_publication_en] => actachimicasinica [jl_country] => 中国,纳米比亚,瑞士,印度 [jl_keyword_en] => dendrimerofthe,carbosilane,smecticeliquidcrystal,firstgeneration,cholesterylliquidcrystal,4nitroazobenzene [jl_keyword_cn] => 碳硅烷,se相液晶,一代树状化合物,4硝基偶氮苯,胆甾相液晶 [jl_clc] => o621 [jl_publisher] => sciencechinapress [company_id] => 43,169 [sys_subject_sort] => 0,0 [college_parent_id] => 43,169 [company_test] => Array,Array [author_id] => 21651,25088,21654,25613,25608,25110 [author_test] => Array ( [0] => Array ( [sure] => 0 [irmagnum] => 0 [u_index] => 5 [name] => 李广 [irtag] => 7 [t_index] => 0 [person_id] => 21654 ) [1] => Array ( [sure] => 0 [irmagnum] => 0 [u_index] => 1 [name] => 张群姿 [irtag] => 8 [t_index] => 1 [person_id] => 25613 ) [2] => Array ( [sure] => 0 [irmagnum] => 0 [u_index] => 1 [name] => 张庆竹 [irtag] => 7 [t_index] => 1 [person_id] => 25608 ) [3] => Array ( [sure] => 0 [irmagnum] => 0 [u_index] => 3 [name] => 尹向勇 [irtag] => 7 [t_index] => 0 [person_id] => 25110 ) [4] => Array ( [sure] => 0 [irmagnum] => 0 [u_index] => 5 [name] => 李刚 [irtag] => 7 [t_index] => 0 [person_id] => 21651 ) [5] => Array ( [sure] => 0 [irmagnum] => 0 [u_index] => 3 [name] => 殷向阳 [irtag] => 7 [t_index] => 0 [person_id] => 25088 ) ) [sys_author_id_arr] => [cscd_No] => CSCD:1240527 [jl_publication_cn_publication_en] => 化学学报,actachimicasinica [jl_keyword_cn_keyword_en] => 碳硅烷,胆甾相液晶,4硝基偶氮苯,一代树状化合物,se相液晶,dendrimerofthe,carbosilane,smecticeliquidcrystal,4nitroazobenzene,cholesterylliquidcrystal,firstgeneration [sys_author_id] => [format_cscd_No] => 1a6c961ad307e103e8df8f6f9926c588 [format_title_en_publication_en_pub_year] => 9ad6c9357e51940acf84d2006a097042 [format_wos_No] => 637169992029da2a60fba69bc1ad9797 [format_title_en_issn_pub_year] => 69741bfe6e6e1b16603d457bb97c0f65 [format_scopus_No] => d0da8f3645bfba0c40230695d3bc7d88 [standard_in] => School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China; Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China [cauthor] => Zhang, QZ(qzzhang@sdu.edu.cn) [datebase] => Scopus [cite_scopus] => 8 [sys_priority_field] => 76 [scopus_No] => 2-s2.0-33750478392 [jl_pub_year] => 2003 [jl_author_test] => unameuu5f20u7fa4u59ff,usureu0,unameuu6bb7u5411u9633,unameuu5f20u5e86u7af9,unameuu5c39u5411u52c7,uuindex3,uuindex1,upersonid25110,utindex1,utindex0,uirtag7,upersonid21654,upersonid21651,upersonid25608,upersonid25088,unameuu674eu521a,unameuu674eu5e7f,uuindex5,upersonid25613,uirtag8 [sys_author_jg_last_arr] => 中国 [jl_company_test] => uircu0,unameuu5316u5b66u4e0eu5316u5de5u5b66u9662,uparentidu43,uorgidu43,ulevelu1 [sys_author_in_last_arr] => china [id] => _A9KvmUBFjIhTVEbYgQg [tags] => 0 ) [14] => Array ( [batch2] => 1,2,6 [uri] => https://www.scopus.com/inward/record.uri?eid=2-s2.0-33750439156&partnerID=40&md5=2f93640f6aaf8a2eaf206d877b9856a8 [tag] => 0 [abstract_cn] => 用自组装技术在铜电极表面上制备了纯烯丙基硫脲自组装膜 ,并以十二烷基硫醇进一步修饰得到混合自组装膜 .最后 ,将混合膜覆盖的铜电极浸入NaCl溶液中 ,进行交流电处理 .电化学交流阻抗谱和极化曲线测定表明 ,经过交流电处理后 ,在 0 .5mol·dm- 3NaCl溶液中 ,电荷传递电阻增大 ,腐蚀电流密度下降 ,膜的最大覆盖度为 98.6% ,对金属铜腐蚀的缓蚀效率为 98.5 % .而且 ,不论交流电处理与否 ,混合自组装膜在较宽的电极电位范围内均表现出很强的稳定性 [keyword_cn] => 自组装;;电化学交流阻抗;;交流电处理;;缓蚀效率 [fund_No] => 国家自然科学基金(No.20173033); 国家重点基础研究专项经费(No.G19990650)资助项目 [article_id] => 239574,26628,581877,491802,663281,331608 [clc] => O657.3 [author_jg] => [王春涛] 山东大学化学与化工学院, 济南, 山东 250100, 中国.@@@[陈慎豪] 山东大学化学与化工学院, 济南, 山东 250100, 中国.@@@[赵世勇] 山东大学化学与化工学院, 济南, 山东 250100, 中国.@@@[李德刚] 山东大学化学与化工学院, 济南, 山东 250100, 中国 [format_title_cn_publication_cn_pub_year] => 4082d1972ebf7559942ffbe91d38d2ed-764640997 [hints] => 4 [issue] => 2 [author_first] => 王春涛 [sys_level_num] => 2_3 [sys_jg_type] => 3,5 [format_issn_issue_page_pub_year] => d28b087a20aed739c97d6e9ea62e8334141953952 [source_type] => 351 [pub_year] => 2003 [pub_date] => FEB [pages] => 5 [from_id] => 76,75,73,80,78,85 [author_cn] => 王春涛;陈慎豪;赵世勇;李德刚 [issn] => 0567-7351 [batch] => 3249,3250,3252,3254,3243,3241 [publication_cn] => 化学学报 [title_cn] => 烯丙基硫脲和十二烷基硫醇对铜的缓蚀作用 [CSSN] => 31-1320/O6 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => e789edab9d93e455fcd7f4da14d9ca14-1441745287 [page] => 151-155 [hb_type] => 2 [article_dt] => Article [hb_batch] => title_cn_publication_cn_pub_year_2_3 [publication_en] => ACTA CHIMICA SINICA [cite_wos] => 10 [check_3Y] => 4 [language] => Chinese [delivery_No] => 648VU [format_title] => 44258f7c814e336542632261bf46d5b91006423409 [cauthor_ad] => [Chen, SH]Shandong Univ, Sch Chem & Chem Engn, Jinan 250100, Peoples R China. [author_fn] => Wang, CT; Chen, SH; Zhao, SY; Li, DG [reference] => BARCIA OE, 1993, J ELECTROCHEM SOC, V140, P2825, DOI 10.1149/1.2220917@@@Brown G M, 1995, J electroanal Chem, V38, P161@@@Cui XL, 2000, COLLOID SURFACE A, V175, P141, DOI@@@10.1016/S0927-7757(00)00528-8@@@@@@Deslouis C, 1988, J Appl Electrochem, V16, P374@@@Diao P, 1999, J ELECTROANAL CHEM, V464, P61, DOI@@@10.1016/S0022-0728(98)00470-7@@@Feng Y, 1996, CORROS SCI, V38, P369, DOI 10.1016/0010-938X(96)00110-2@@@Feng YQ, 1997, J ELECTROCHEM SOC, V144, P55, DOI 10.1149/1.1837365@@@Folquer ME, 2002, CORROSION, V58, P240, DOI 10.5006/1.3279875@@@@@@Itoh M, 1995, Electrochem Soc, V142, P1839@@@Jennings GK, 1998, LANGMUIR, V14, P6130, DOI 10.1021/la980333y@@@Kim T, 1997, J AM CHEM SOC, V119, P189, DOI 10.1021/ja9617956@@@@@@LAIBINIS PE, 1992, J AM CHEM SOC, V114, P9022, DOI 10.1021/ja00049a038@@@Lee H P, 1996, Electrochem Soc, V133, P2035@@@LOO BH, 1982, CHEM PHYS LETT, V89, P346, DOI@@@10.1016/0009-2614(82)83513-6@@@@@@Ma H, 2002, J APPL ELECTROCHEM, V32, P65, DOI 10.1023/A:1014242112512@@@Matsumoto F, 1999, LANGMUIR, V15, P857, DOI 10.1021/la980919k@@@NAHIR TM, 1994, ELECTROCHIM ACTA, V39, P2347, DOI@@@10.1016/0013-4686(94)00209-6@@@@@@SABATANI E, 1993, LANGMUIR, V9, P2974, DOI 10.1021/la00035a040@@@SCHONENBERGER C, 1994, LANGMUIR, V10, P611, DOI 10.1021/la00015a001@@@TIAN ZQ, 1990, ELECTROCHIM ACTA, V35, P879, DOI@@@10.1016/0013-4686(90)90084-D@@@@@@Wang J, 2000, ANAL SCI, V16, P457, DOI 10.2116/analsci.16.457@@@Yamamoto Y, 1993, Electrochem Soc, V140, P436 [publication_29] => ACTA CHIM SINICA [end_page] => 155 [abstract_en] => Self-assembled monolayer of allylthiourea (AT) was first formed on copper surface. 1-Dodecanethiol (DT) was then self-assembled on the surface for subsequent modification: Finally, AC voltage was loaded on copper covered with the mixed film for further improvement. After these processes, an effective inhibition film was obtained as indicated by the high charge-transfer resistance shown in electrochemical impedance spectroscopy and low corrosion current density in polarization curves. The maximum coverage and inhibition efficiency for copper corrosion was 98.6% and 98.5%, respectively. The mixed film was stable in a wide range of potential before and after AC voltage treatment. [author_in] => [Wang, C.-T] School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China@@@[ Chen, S.-H] School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China, State Key Laboratory for Corrosion and Protection, Shenyang 110015, China@@@[ Zhao, S.-Y] School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China@@@[ Li, D.-G] School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China [publication_type] => J [begin_page] => 151 [author_en] => Wang, CT; Chen, SH; Zhao, SY; Li, DG [volume] => 61 [get_data] => 2018-08-29 [publisher] => SCIENCE CHINA PRESS [keyword_en] => self-assembly; electrochemical impedance spectroscopy; AC treatment;; inhibition efficiency [format_publication_cn] => 6918be3b26b1fa6ec0424f6071208a75331227575 [keyword_plu] => SELF-ASSEMBLED MONOLAYERS; IMPEDANCE SPECTROSCOPY; ACID-SOLUTION; GOLD; PROTECTION; ALKANETHIOLS; ELECTRODE; THIOUREA; ELECTRODISSOLUTION; MECHANISMS [publication_iso] => Acta Chim. Sin. [format_title_en] => a4faf1840cf4804e1442d842aa84613c-302212588 [publisher_city] => BEIJING [hx_id] => 2377,2378,2371 [reference_No] => 22 [cite_awos] => 17 [wos_No] => WOS:000181172200001 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [check_180] => 1 [publisher_ad] => 16 DONGHUANGCHENGGEN NORTH ST, BEIJING 100717, PEOPLES R CHINA [title_en] => Inhibition effect of allylthiourea and 1-dodecanethiol on copper corrosion [format_publication_en] => 169b60c7845c9e5f36906950b18f11111348184734 [jl_language] => chinese [jl_publication_cn] => 化学学报 [jl_article_dt] => 期刊论文 [jl_publication_en] => actachimicasinica [jl_country] => 中国,中国 [jl_keyword_en] => ,selfassembly,inhibitionefficiency,electrochemicalimpedancespectroscopy,actreatment [jl_keyword_cn] => ,电化学交流阻抗,缓蚀效率,自组装,交流电处理 [jl_clc] => o6573 [jl_publisher] => sciencechinapress [company_id] => 0,43,169 [sys_subject_sort] => 0,0 [college_parent_id] => 43,169 [company_test] => Array,Array [author_id] => 21630,25925 [author_test] => Array ( [0] => Array ( [sure] => 0 [irmagnum] => 0 [u_index] => 4 [name] => 李德广 [irtag] => 7 [t_index] => 0 [person_id] => 21630 ) [1] => Array ( [sure] => 0 [irmagnum] => 0 [u_index] => 3 [name] => 赵双宜 [irtag] => 7 [t_index] => 0 [person_id] => 25925 ) ) [sys_author_id_arr] => [cscd_No] => CSCD:1336537 [jl_publication_cn_publication_en] => actachimicasinica,化学学报 [jl_keyword_cn_keyword_en] => selfassembly,自组装,电化学交流阻抗,缓蚀效率,electrochemicalimpedancespectroscopy,交流电处理,actreatment,inhibitionefficiency [sys_author_id] => [format_cscd_No] => 8a3b1d0f183a636c89058d79260675841607284196 [format_title_en_publication_en_pub_year] => 7aab03bcb657701d93c15b41b08c0f37-1175645358 [format_wos_No] => 9cbbef4d1d1fec8b5f5420a661067c72-847442823 [format_title_en_issn_pub_year] => 2b078fec6705dfb6f25534f890d51631746151285 [format_scopus_No] => 4a5f999cfb62ad56336c6deadba8913d-137805215 [standard_in] => School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China; State Key Laboratory for Corrosion and Protection, Shenyang 110015, China [datebase] => Scopus [cite_scopus] => 11 [sys_priority_field] => 76 [scopus_No] => 2-s2.0-33750439156 [id] => wg5IvmUBFjIhTVEbRWIm [tags] => 0 ) [15] => Array ( [batch2] => 1,2,6 [batch] => 3249,3250,3252,3254,3243,3241 [tag] => 0 [abstract_cn] => 研究了新的含12个丁氧基偶氮苯介晶基元的一代树状碳硅烷液晶D1及偶氮苯介晶基元化合物M5在氯仿、四氢呋喃、N,N-二甲基甲酰胺、乙醇和苯等溶剂中的量子产率、反-顺光异构化、光回复异构、反/顺异构组分比、热回复异构及活化能.D1和M5的光致变色速率常数为10~(-1)s~(-1),而含同一偶氮基元的光致变色液晶聚硅氧烷的光致变色速率常数为10~(-8)s~(-1),因此,液晶树状物D1的光响应速度比后者快10~7倍. [keyword_cn] => 树枝状化合物;液晶;光电信息功能材料;量子产率;反-顺光异构化;光回复异构;反/顺异构组分化;热回复异构;活化能 [article_id] => 597892,239571,491858,664148,330995,68716 [clc] => Q516 [author_jg] => [张其震,刘建强,殷晓颖,张静智]山东大学化学化工学院,山东大学化学化工学院物理与微电子学院,山东大学化学化工学院,山东大学化学化工学院 济南 250100, 济南 250100, 济南 250100, 济南 250100 [format_title_cn_publication_cn_pub_year] => c18ac09dab157f52dcba8c7a9e7e1443324757932 [hints] => 8 [issue] => 7 [sys_level_num] => 2_3 [sys_jg_type] => 11,3,5 [format_issn_issue_page_pub_year] => d752225e0173ccee25f836f85dbd62e6-277651012 [source_type] => 351 [pub_year] => 2003 [pub_date] => JUL [pages] => 6 [from_id] => 76,75,73,80,85,78 [author_cn] => 张其震,刘建强,殷晓颖,张静智 [issn] => 0567-7351 [uri] => http://kns.cnki.net/kns/detail/detail.aspx?FileName=HXXB200307025&DbName=CJFQ2003 [publication_cn] => 化学学报 [title_cn] => 一代树状碳硅烷液晶的光化学研究——端基含12个4-丁氧基偶氮苯介晶基元 [CSSN] => 31-1320/O6 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => c2b6637872211b85f7a63df52b38e8b945432130 [page] => 1108-1113 [hb_type] => 2 [article_dt] => Article [hb_batch] => title_cn_publication_cn_pub_year_2_3 [format_title_en] => 13d15c6ce0b42526df172c769b9f7deb1508578682 [format_title] => 845ed12b002349b8631ae8d2afc096ef758132574 [hx_id] => 2377,2378,2371 [format_publication_cn] => 6918be3b26b1fa6ec0424f6071208a75331227575 [format_publication_en] => 169b60c7845c9e5f36906950b18f11111348184734 [jl_publication_cn] => 化学学报 [jl_article_dt] => 期刊论文 [jl_keyword_cn] => 光电信息功能材料,热回复异构,活化能,量子产率,反顺异构组分化,光回复异构,液晶,反顺光异构化,树枝状化合物 [jl_clc] => q516 [author_in] => [Zhang, Q.-Z] School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China@@@[ Liu, J.-Q] School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China, School of Physics and Microelectronics, Shandong University, Jinan 250100, China@@@[ Yin, X.-Y] School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China@@@[ Zhang, J.-Z] School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China [company_id] => 43,35,133,0,5,169 [sys_subject_sort] => 0,0,0,0,0 [college_parent_id] => 133,5,43,35,169 [company_test] => Array,Array,Array,Array,Array [author_id] => [author_test] => Array ( ) [sys_author_id_arr] => [jl_publication_cn_publication_en] => 化学学报 [jl_keyword_cn_keyword_en] => 液晶,树枝状化合物,活化能,光回复异构,热回复异构,量子产率,反顺光异构化,光电信息功能材料,反顺异构组分化 [cite_wos] => 11 [publication_en] => ACTA CHIMICA SINICA [fund_No] => 国家自然科学基金(Nos. 29874020, 59573029); 山东省自然科学基金(No. Y95B0720); 中国科学院高分子物理重点实验室(长春应用化学研究所)资助项目 [check_3Y] => 1 [language] => Chinese [delivery_No] => 715TM [cauthor_ad] => [Zhang, QZ]Shandong Univ, Sch Chem & Chem Engn, Jinan 250100, Peoples R China. [author_fn] => Zhang, QZ; Liu, JQ; Yin, XY; Zhang, JZ [reference] => Archut A, 1998, Am. Chem. Soc, V120, P12187@@@IKEDA T, 1995, SCIENCE, V268, P1873, DOI 10.1126/science.268.5219.1873@@@Junge DM, 1999, J AM CHEM SOC, V121, P4912, DOI 10.1021/ja990387+@@@Lorenz K, 1996, ADV MATER, V8, P414, DOI 10.1002/adma.19960080509@@@Nagasaki T, 1997, CHEM LETT, P717, DOI 10.1246/cl.1997.717@@@PERCEC V, 1995, J AM CHEM SOC, V117, P11441, DOI 10.1021/ja00151a008@@@Ponomarenko SA, 1996, LIQ CRYST, V21, P1, DOI 10.1080/02678299608033789@@@[张其震 Zhang Qizhen], 2003, [化学学报, Acta Chemical Sinica], V61, P619@@@[张其震 Zhang Qizhen], 2003, [化学学报, Acta Chemical Sinica], V61, P416@@@[张其震 Zhang Qizhen], 2002, [化学学报, Acta Chemical Sinica], V60, P2232@@@张其震, 1998, 高等学校化学学报, V19, P1175@@@张其震, 1997, 高等学校化学学报, V18, P158@@@张静智, 1997, 化学学报, V55, P930@@@张其震, 1996, 高分子学报, P121@@@张其震, 1998, 高等学校化学学报.J, V9, P827@@@张其震, 2000, 功能高分子材料.第11章 [cite_wanfang] => 20 [cauthor] => Zhang, QZ(qzzhang@sdu.edu.cn) [format_title_en_issn_pub_year] => 10b075ae498dedd5458421154f7a484e-637982662 [datebase] => Scopus [format_scopus_No] => 422ae9e09c743448639fa4f02177c67c-610934877 [publication_29] => ACTA CHIM SINICA [end_page] => 1113 [abstract_en] => The quantum yield, trans/cis photoisomerization, photo back-isomerization, trans/cis isomer ratio, thermal back-isomerization activation energy of a new carbosilane liquid crystalline (LC) dendrimer of the first generation (D1) containing twelve 4-butoxyazobenzene mesogen in its periphery and azobenzene unit compound M5 in CHCl3, THF, DMF, EtOH and C6H6 are described. Photochromic rate constant of D1 and M5 are 10(-1) s(-1), but that of photochromic LC polysiloxanes containing the same azobenzene moieties is 10(-8) s(-1) thus the photoresponsive rate of LC dendrimer D1 is 10(7) times larger than that of the latter. [publication_type] => J [begin_page] => 1108 [author_en] => Zhang, QZ; Liu, JQ; Yin, XY; Zhang, JZ [format_cscd_No] => a683658c518b49748c7282b0f35cef0c513362855 [volume] => 61 [publisher] => SCIENCE CHINA PRESS [get_data] => 2018-08-29 [keyword_en] => dendrimer; liquid crystal; photo-electro informational functional; material; quantum yield; trans/cis photoisomerization; photo; back-isomerization; trans/cis isomer ratio; thermal back-isomerization;; activation energy [publication_iso] => Acta Chim. Sin. [format_title_en_publication_en_pub_year] => 12bbbb9a92a516e3bc667dbbf9346732-1858133464 [cite_scopus] => 11 [publisher_city] => BEIJING [cite_cscd] => 10 [publication_info] => 0567-7351(2003)61:7<1108:YDSZTG>2.0.TX;2-N [email_c] => qzzhang@sdu.edu.cn [email] => qzzhang@sdu.edu.cn [reference_No] => 16 [cite_awos] => 12 [cscd_No] => CSCD:1174257 [wos_No] => WOS:000184988400026 [format_wos_No] => 6066d39809f3d47fb1420d1ab73aa683-1747501829 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [check_180] => 0 [publisher_ad] => 16 DONGHUANGCHENGGEN NORTH ST, BEIJING 100717, PEOPLES R CHINA [standard_in] => School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China; School of Physics and Microelectronics, Shandong University, Jinan 250100, China [scopus_No] => 2-s2.0-20444453950 [title_en] => Study on photochemistry of carbosilane liquid crystalline dendrimer of the first generation - Containing twelve 4-butoxyazobenzene mesogenic groups in its periphery [jl_language] => chinese [jl_publication_en] => actachimicasinica [sys_author_jg_last_arr] => 济南250100 [jl_company_test] => unameuu5316u5b66u4e0eu5316u5de5u5b66u9662,unameuu5faeu7535u5b50u5b66u9662,uorgidu5,uparentidu35,uparentidu43,unameuu7269u7406u5b66u9662,uircu0,uorgidu43,ulevelu1,uorgidu35,uparentidu5 [jl_country] => 中国 [jl_keyword_en] => ,photoelectroinformationalfunctional,photo,material,backisomerization,thermalbackisomerization,transcisphotoisomerization,transcisisomerratio,liquidcrystal,activationenergy,dendrimer,quantumyield [sys_author_in_last_arr] => china [jl_publisher] => sciencechinapress [sys_author_id] => [id] => MA5HvmUBFjIhTVEbZSTq [tags] => 0 ) [16] => Array ( [batch2] => 1,2 [uri] => http://kns.cnki.net/kns/detail/detail.aspx?FileName=HXXB200208032&DbName=CJFQ2002 [tag] => 0 [abstract_cn] => 用四醋酸铅将七元 (6 O 二甲基叔丁基硅基 ) β 环糊精选择氧化、并用三氟化硼乙醚脱硅基保护基后 ,再经分离、纯化 ,可获得具有“楔筒状”空腔的单 2 ,3 二醛基 β 环糊精 .单 2 ,3 二醛基 β 环糊精较 β 环糊精有更好的水溶性 .用单 2 ,3 二醛基 β 环糊精作TLC流动相手性添加剂时 ,可将肾上腺素对映体在硅胶薄层板上有效拆分 . [keyword_cn] => β-环糊精;;单-2,3-二醛基-β-环糊精;;楔筒状大环分子 [fund_No] => 国家自然科学基金(No. 29902004) [article_id] => 332083,554758,239539,664158,45669 [clc] => O636 [author_jg] => [郝爱友] 山东大学化学与化工学院, 济南, 山东 250100, 中国.@@@[王金山] 山东师范大学化学系, 济南, 山东 250014, 中国 [format_title_cn_publication_cn_pub_year] => d38d24495e6e88049be1f33fef48ed25132746493 [hints] => 3 [issue] => 8 [author_first] => 郝爱友 [sys_level_num] => 2_3 [sys_jg_type] => 10,5 [format_issn_issue_page_pub_year] => 3fcf7898a18c17e0c20454e2ed8b9165-1178556098 [source_type] => 351 [pub_year] => 2002 [pub_date] => AUG [pages] => 3 [from_id] => 75,78,73,80,85 [author_cn] => 郝爱友;王金山 [issn] => 0567-7351 [batch] => 3250,3249,3241,3254,3252 [publication_cn] => 化学学报 [title_cn] => 用环糊精合成楔筒状主体分子新模型 [CSSN] => 31-1320/O6 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => faf2c36a896a2ca5ef2c5754ef9f6ffd1924117586 [page] => 1536-1538+1356 [hb_type] => 2 [article_dt] => Article [hb_batch] => title_cn_publication_cn_pub_year_2_3 [publication_en] => ACTA CHIMICA SINICA [cite_wos] => 5 [check_3Y] => 1 [language] => Chinese [delivery_No] => 587LH [format_title] => b18bfede19623310dd019ce10bac2b73-1545227800 [cauthor_ad] => [Hao, AY]Shandong Univ, Sch Chem & Chem Engn, Jinan 250100, Peoples R China. [author_fn] => Hao, AY; Wang, JS [reference] => Gu LQ, 1999, NATURE, V398, P686@@@Hao A Y, 2000, Commun, V30, P3703@@@Hao A Y, 1999, Inclusion Phenomena and Macrocyclic Chemistry, V34, P445@@@HAO AY, 1995, ANAL LETT, V28, P2041, DOI 10.1080/00032719508000023@@@@@@Kuwabara T, 1999, ANAL CHEM, V71, P2844, DOI 10.1021/ac9814041@@@Kuwabara T, 1998, Org. Chem., V63, P8729@@@Schneider H J, 1990, Frontiers in Supramolecular Organic CHemistry and@@@Photochemistry, VCH, Weinheim@@@郝爱友, 1996, 化学通报, P16@@@张希(译), 1995, 超分子化学@@@刘育, 1999, 中国科学(B辑), V29, P532 [publication_29] => ACTA CHIM SINICA [end_page] => 1538 [abstract_en] => beta-Cyclodextrin with the 6-hydroxyls protected by dimethyl-tert-butylsilyl was selectively oxidized by lead tetraacetate. After the silyl groups were removed off by boron fluoride-etherate, mono-2, 3-dialdehydo-beta-cyclodextrin as a cuniform molecule could be constructed. Mono-2,3-dialdehydo-beta-cyclodextrin is more soluble in water than beta-cyclodextrin. Mono-2,3-dialdehydo-beta-cyclodextrin could be used as the mobile phase additives for effective resolution of DL-adrendine on silica gel plates. [author_in] => [Hao, AY]Shandong Univ, Sch Chem & Chem Engn, Jinan 250100, Peoples R China.@@@[ Wang, JS] Shandong Normal Univ, Dept Chem, Jinan 250014, Peoples R China. [publication_type] => J [begin_page] => 1536 [author_en] => Hao, AY; Wang, JS [volume] => 60 [get_data] => 2018-08-29 [publisher] => SCIENCE CHINA PRESS [keyword_en] => beta-cyclodextrin; mono-2,3-dialdehydo-beta-cyclodextrin; cuniform; molecule [format_publication_cn] => 6918be3b26b1fa6ec0424f6071208a75331227575 [publication_iso] => Acta Chim. Sin. [format_title_en] => 93777d13ac1b4eac6316fd0701616d9d-975946120 [publisher_city] => BEIJING [hx_id] => 2377,2371 [reference_No] => 10 [email] => haoay@sdu.edu.cn [cite_awos] => 6 [wos_No] => WOS:000177641800033 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [check_180] => 0 [publisher_ad] => 16 DONGHUANGCHENGGEN NORTH ST, BEIJING 100717, PEOPLES R CHINA [title_en] => Synthesis of new cuniform molecular host model based on beta-cyclodextrin [format_publication_en] => 169b60c7845c9e5f36906950b18f11111348184734 [jl_language] => chinese [jl_publication_cn] => 化学学报 [jl_article_dt] => 期刊论文 [jl_publication_en] => actachimicasinica [jl_country] => 中国,中国 [jl_keyword_en] => mono2,molecule,cuniform,betacyclodextrin,3dialdehydobetacyclodextrin [jl_keyword_cn] => ,β环糊精,3二醛基β环糊精,楔筒状大环分子,单2 [jl_clc] => o636 [jl_publisher] => sciencechinapress [author_id] => 21076 [author_test] => Array ( [0] => Array ( [sure] => 1 [irmagnum] => 0 [u_index] => 1 [name] => 郝爱友 [sys_author_id] => Array ( [0] => 21076 ) [irtag] => 0 [t_index] => 0 [person_id] => 21076 ) ) [company_id] => 43,169 [sys_subject_sort] => 0,0 [college_parent_id] => 43,169 [company_test] => Array,Array [sys_author_id_arr] => 21076郝爱友 [cscd_No] => CSCD:1009220 [jl_publication_cn_publication_en] => actachimicasinica,化学学报 [jl_keyword_cn_keyword_en] => molecule,betacyclodextrin,单2,mono2,3二醛基β环糊精,cuniform,3dialdehydobetacyclodextrin,β环糊精,楔筒状大环分子 [sys_author_id] => 21076 [format_cscd_No] => 8c1573dd78118e81f602604b33dc0dfa1152032683 [format_title_en_publication_en_pub_year] => f47a698b58734b427185502ad49170e2-1071988493 [format_wos_No] => cd3c4b62723e55bd2ee8f94ae3b432ad-333059642 [format_title_en_issn_pub_year] => b321dda114884c6225790751b7b2c3321377953343 [id] => lg5JvmUBFjIhTVEbudND [tags] => 0 ) [17] => Array ( [batch2] => 1,2,6 [batch] => 3249,3250,3252,3254,3243,3241 [tag] => 0 [abstract_cn] => 在密度泛函理论的框架下 ,应用对称性破损方法 ,研究了以N—N基团为单桥的二嗪类双核Cu(Ⅱ )体系的磁耦合强度及磁 -结构关联 .计算结果表明 ,随着旋转角θ的减小 ,反铁磁性耦合作用逐渐减小 ,直至出现铁磁性耦合 ,与实验得到的趋势一致 .破损态能量随着θ的增大发生逆转 ,先降低后增大 .磁耦合常数J与 (ε1 -ε2 ) 2 的关系受到破损态能量逆转的影响 .当θ由 6 5°逐渐增大到 14 0°时 ,破损态能量依次降低 ,J与 (ε1 -ε2 ) 2 呈线性关系 ;当θ=15 0°时 ,破损态能量发生逆转 ,由降低变为升高 ,二者不再保持原有线性关系 .另外 ,(ε1 -ε2 ) 2 ... [keyword_cn] => 密度泛函理论;对称性破损;磁耦合作用;双核铜配合物;磁-结构关联 [article_id] => 664912,239540,105800,648077,494897,332086 [clc] => O643.1 [author_jg] => [毕思玮,刘成卜]山东大学理论化学研究所,山东大学理论化学研究所 济南250100曲阜师范大学化学系曲阜273165,济南250100 [format_title_cn_publication_cn_pub_year] => 7797319c99675bdc92004acacbdcb531-1626447428 [hints] => 2 [issue] => 8 [sys_level_num] => 2_3 [sys_jg_type] => 0,3,5 [format_issn_issue_page_pub_year] => f7882615849f74fffc3c79a47cf0adb7-1822644077 [source_type] => 351 [pub_year] => 2002 [pub_date] => AUG [pages] => 6 [from_id] => 76,75,73,80,85,78 [author_cn] => 毕思玮,刘成卜 [issn] => 0567-7351 [uri] => http://kns.cnki.net/kns/detail/detail.aspx?FileName=HXXB200208006&DbName=CJFQ2002 [publication_cn] => 化学学报 [title_cn] => 以N—N基团为单桥的双核Cu(Ⅱ)体系磁-结构关联的理论研究 [CSSN] => 31-1320/O6 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => 9331659e6a814cb9c99a04c7505a73171808255713 [page] => 1390-1395+1348 [hb_type] => 2 [article_dt] => Article [hb_batch] => title_cn_publication_cn_pub_year_2_3 [format_title_en] => 32d7fe14752c8409a1bcdf1d9753ab4c1360630654 [format_title] => d46cf55dbf85537cfdbb0c211b72c1827870088 [hx_id] => 2377,2378,2371 [format_publication_cn] => 6918be3b26b1fa6ec0424f6071208a75331227575 [format_publication_en] => 169b60c7845c9e5f36906950b18f11111348184734 [jl_publication_cn] => 化学学报 [jl_article_dt] => 期刊论文 [jl_keyword_cn] => 磁耦合作用,对称性破损,密度泛函理论,磁结构关联,双核铜配合物 [jl_clc] => o6431 [author_in] => [Bi, S.-W] Institute of Theoretical Chemistry, Shandong University, Jinan 250100, China, Department of Chemistry, Qufu Normal University, Qufu 273165, China@@@[ Liu, C.-B] Institute of Theoretical Chemistry, Shandong University, Jinan 250100, China [company_id] => 0,43,169 [author_id] => [author_test] => Array ( ) [sys_author_id_arr] => [jl_publication_cn_publication_en] => 化学学报 [jl_keyword_cn_keyword_en] => 对称性破损,双核铜配合物,磁结构关联,密度泛函理论,磁耦合作用 [cite_wos] => 0 [publication_en] => ACTA CHIMICA SINICA [fund_No] => 国家自然科学基金(No. 20133020); 山东省自然科学基金(No. Z2000B02) [check_3Y] => 0 [language] => Chinese [delivery_No] => 587LH [cauthor_ad] => [Bi, SW]Shandong Univ, Inst Theoret Chem, Jinan 250100, Peoples R China. [author_fn] => Bi, SW; Liu, CB [reference] => Bacchi A, 1996, Chem. Soc., Dalton. Trans., P2699@@@BECKE AD, 1988, PHYS REV A, V38, P3098, DOI 10.1103/PhysRevA.38.3098@@@Bi SW, 2001, CHEM PHYS LETT, V350, P551, DOI@@@10.1016/S0009-2614(01)01340-9@@@Ferlay S, 1995, Verdaguer, M. Nature, V378, P701@@@FINK K, 1994, INORG CHEM, V33, P6219, DOI 10.1021/ic00104a036@@@@@@Hay P J, 1975, Am. Chem. Soc, V97, P4884@@@HOLM RH, 1995, PURE APPL CHEM, V67, P217, DOI 10.1351/pac199567020217@@@@@@HU H, 2001, J MOL STRUC-THEOCHEM, V546, P73@@@Hu HQ, 2000, CHEM PHYS LETT, V329, P255, DOI@@@10.1016/S0009-2614(00)01015-0@@@Kahn O, 1993, VCH@@@Kahn O, Angew. Chem., Int. Ed. Engl., V24, P834@@@Noodleman L. J., 1981, CHEM PHYS, V74, P5737@@@OCONNOR CJ, 1983, INORG CHEM, V22, P449, DOI 10.1021/ic00145a016@@@@@@PERDEW JP, 1995, PHYS REV A, V51, P4531, DOI 10.1103/PhysRevA.51.4531@@@PERDEW JP, 1986, PHYS REV B, V33, P8822, DOI 10.1103/PhysRevB.33.8822@@@Ruiz E, 1998, CHEM COMMUN, P2767, DOI 10.1039/a807973k@@@@@@Ruiz E, 1997, INORG CHEM, V36, P3683, DOI 10.1021/ic970310r@@@Ruiz E, 1997, J AM CHEM SOC, V119, P1297, DOI 10.1021/ja961199b@@@Ruiz E, 1999, P. J. Comput. Chem, V20, P1391@@@Ruiz E, 1998, P. J. Am. Chem. Soc., V120, P11122@@@Solomon EI, 2000, CHEM REV, V100, P235, DOI 10.1021/cr9900275@@@Thompson LK, 1998, INORG CHEM, V37, P3217, DOI 10.1021/ic9715198@@@VOSKO SH, 1980, CAN J PHYS, V58, P1200, DOI 10.1139/p80-159@@@Xu ZQ, 1997, INORG CHEM, V36, P3985, DOI 10.1021/ic970235k@@@@@@项生昌, 2001, 化学学报, V59, P173 [cite_wanfang] => 1 [format_title_en_issn_pub_year] => 9e0834f61fe819ba9fcd93c3dec5d3ff-1647500621 [datebase] => Scopus [format_scopus_No] => 401580fcd3e64a506ac17c4a35ffb5ed725083505 [publication_29] => ACTA CHIM SINICA [end_page] => 1395 [abstract_en] => A theoretical study on magneto-structural correlation for binuclear Cu( U) complexes bridged by single N-N group from diazine has been investigated by using broken-symmetry approach within the framework of density functional theory. Calculated results show that antiferromagnetic coupling interaction gradually reduces, and finally turns into ferromagnetic coupling interaction with the decrease of rotation angle theta around N-N bond from 150degrees to 65degrees, which is in agreement with the experimental facts. The variation of molecular energy has a reversion with rotation angle theta passing through 140degrees. The linear relationship between J and (epsilon(1) - epsilon(2))(2) is broken with the reversion of the energy of broken-symmetry state from decrease to increase. This reversion of the energy of broken-symmetry state also affects the relationship between (epsilon(1) - epsilon(2))(2) and theta. The figure for the relationship between J and theta is similar to that for the relationship between (epsilon(1) - epsilon(2))(2) and theta in the woe range theta = 65degrees similar to 140degrees where no reversion of the energy of broken-symmetry state occurs. So in this angle range, (epsilon(1) - epsilon(2))(2) can replace J to explore the relationship between structure and magnetic properties. The reversion of the energy of broken-symmetry state has little influence on the variation of J values, and rotation angle theta is a key factor influencing the magnitude of magnetic coupling interaction. [publication_type] => J [begin_page] => 1390 [author_en] => Bi, SW; Liu, CB [format_cscd_No] => fbc75daa5c14c849d2a5a178d13f301a-1191077239 [volume] => 60 [publisher] => SCIENCE CHINA PRESS [get_data] => 2018-08-29 [keyword_en] => DFT; broken-symmetry; magnetic coupling interaction; Cu(II) binuclear complex; magneto-structural correlation [keyword_plu] => TRANSITION-METAL COMPLEXES; AB-INITIO CALCULATION; DICOPPER(II) COMPLEXES; COPPER(II); APPROXIMATION; BEHAVIOR; ENERGY; DIMERS [publication_iso] => Acta Chim. Sin. [format_title_en_publication_en_pub_year] => d49e33afa9fefd9d66c9b8a2b5e50eb9-1708582297 [publisher_city] => BEIJING [cite_cscd] => 0 [publication_info] => 0567-7351(2002)60:8<1390:YNJQWD>2.0.TX;2-F [email_c] => cbliu@sdu.edu.cn [email] => cbliu@sdu.edu.cn [reference_No] => 25 [cite_awos] => 0 [cscd_No] => CSCD:1008458 [wos_No] => WOS:000177641800007 [format_wos_No] => 974fbf6de40b09d60f93cf0f4ca08939-1067090404 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [check_180] => 0 [publisher_ad] => 16 DONGHUANGCHENGGEN NORTH ST, BEIJING 100717, PEOPLES R CHINA [standard_in] => Institute of Theoretical Chemistry, Shandong University, Jinan 250100, China; Department of Chemistry, Qufu Normal University, Qufu 273165, China [scopus_No] => 2-s2.0-0442268936 [title_en] => Theoretical investigation on magneto-structural correlation for Cu(II) binuclear system bridged by single N-N group [jl_language] => chinese [jl_publication_en] => actachimicasinica [sys_author_jg_last_arr] => 济南250100 [jl_country] => 中国 [jl_keyword_en] => dft,magneticcouplinginteraction,cuiibinuclearcomplex,magnetostructuralcorrelation,brokensymmetry [sys_author_in_last_arr] => china [jl_publisher] => sciencechinapress [sys_author_id] => [sys_subject_sort] => 0,0 [college_parent_id] => 43,169 [company_test] => Array,Array [id] => 1A1EvmUBFjIhTVEbKGBy [tags] => 0 ) [18] => Array ( [batch2] => 1,2,5,6 [batch] => 3249,0,3250,3241,3254,3243,3252 [tag] => 0 [abstract_cn] => 通过选择性氧化 ,将水溶性优良的羟丙基 β 环糊精转化为丙酮基羟丙基 β 环糊精 .再利用乙二胺分子作为柔性链和连接剂键连制得水溶性的甲基红基乙二胺基羟丙基 β 环糊精 .在甲基红基乙二胺基羟丙基 β 环糊精的稀水溶液中 (6× 10 - 8~ 2× 10 - 5mol·dm- 3)加入环己烷等疏水性客体分子时 ,甲基红基团可被掎到 β 环糊精空腔外 .若是在酸性介质中 ,甲基红基团还会同时发生偶氮基团的质子化反应 ,并伴随颜色的变化 (由黄色→红色 ) ,该变色程度与客体分子的外型、体积及极性等有关 ,从而起到分子检测器的作用 . [keyword_cn] => 甲基红基乙二胺基羟丙基-β-环糊精;水溶性;显色;分子识别器 [article_id] => 581868,494928,26629,664458,239538,332085 [clc] => O641.4 [author_jg] => [郝爱友,王金山,辛志荣]山东大学化学与化工学院,山东师范大学化学系,长春应用化学研究所 济南250100,济南250014,博士生 [format_title_cn_publication_cn_pub_year] => 84307804b3d9d36d664d356690c48d96-42825371 [hints] => 2 [issue] => 8 [sys_level_num] => 2_3 [sys_jg_type] => 11 [format_issn_issue_page_pub_year] => 17ddee9804c0dfc926978468e83e92f21918644961 [source_type] => 351 [pub_year] => 2002 [pub_date] => AUG [pages] => 5 [from_id] => 76,75,73,80,85,78 [author_cn] => 郝爱友,王金山,辛志荣 [issn] => 0567-7351 [uri] => http://kns.cnki.net/kns/detail/detail.aspx?FileName=HXXB200208031&DbName=CJFQ2002 [publication_cn] => 化学学报 [title_cn] => 水溶性显色型分子识别器——甲基红基乙二胺基羟丙基-β-环糊精 [CSSN] => 31-1320/O6 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => 7b5687a9db237d109fbba18636cdbd401580502229 [page] => 1531-1535+1355 [hb_type] => 2 [article_dt] => Article [hb_batch] => title_cn_publication_cn_pub_year_2_3 [format_title_en] => ff3a1ea6aa204b243a0c95662fa6b7e2-400297030 [format_title] => c68eda9a33d41ceeb2a2b2730a69b539-411899465 [hx_id] => 2378,2377,2378,2371 [format_publication_cn] => 6918be3b26b1fa6ec0424f6071208a75331227575 [format_publication_en] => 169b60c7845c9e5f36906950b18f11111348184734 [jl_publication_cn] => 化学学报 [jl_article_dt] => 期刊论文 [jl_keyword_cn] => 水溶性,甲基红基乙二胺基羟丙基β环糊精,分子识别器,显色 [jl_clc] => o6414 [author_in] => [Hao, A.-Y] School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China@@@[ Wang, J.-S] Department of Chemistry, Shandong Normal University, Jinan 250014, China@@@[ Xin, Z.-R] School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China [company_id] => 0,43,169 [sys_subject_sort] => 0,0 [college_parent_id] => 43,169 [company_test] => Array,Array [author_id] => [author_test] => Array ( ) [sys_author_id_arr] => [jl_publication_cn_publication_en] => 化学学报 [jl_keyword_cn_keyword_en] => 水溶性,分子识别器,显色,甲基红基乙二胺基羟丙基β环糊精 [imf_once] => 0.536 [jcr_wos] => Q3 [imf_5] => 0 [fund_No] => 国家自然科学基金(No.29902004) [profession_stu] => [thesis_au] => [cauthor_ad] => [Hao, AY]Shandong Univ, Sch Chem & Chem Engn, Jinan 250100, Peoples R China. [author_fn] => Hao, AY; Wang, JS; Xin, ZR [highly_article] => [student_No] => [grant_bulletin_No] => [dom_ranking] => [province] => [complete_time] => [format_title_en_issn_pub_year] => 1c418b4d199eb8bda72c128bfc03802695237075 [format_scopus_No] => ed90f03f038b1fc1b2ba2434335dd043-771216539 [bulletin_date] => [publication_29] => ACTA CHIM SINICA [fund_amount] => [attachment_text] => [begin_page] => 1531 [author_en] => Hao, AY; Wang, JS; Xin, ZR [name_editor] => [format_cscd_No] => dbbc7aadad4176f7288906df8b4bb410-236758581 [subject_gb1] => [phone] => [book_alias] => [application_date] => [get_data] => 2018-08-29 [keyword_plu] => CYCLODEXTRIN [publication_iso] => Acta Chim. Sin. [fund_type] => [publisher_city] => BEIJING [isbn_10] => [cite_cscd] => 0 [classification_No] => [cssci_No] => [responsibility] => [uncontrolled_terms] => [publication_info] => 0567-7351(2002)60:8<1531:SRXXSX>2.0.TX;2-7 [controlled_terms] => [email] => haoay@sdu.edu.cn [top_article] => [reference_No] => 9 [student_type] => [agency] => [cite_awos] => 0 [wos_No] => WOS:000177641800032 [format_wos_No] => 1b440200275ae682cef3477ac55aa32b-1692214960 [wos_sub] => Chemistry, Multidisciplinary [publisher_ad] => 16 DONGHUANGCHENGGEN NORTH ST, BEIJING 100717, PEOPLES R CHINA [standard_in] => School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China; Department of Chemistry, Shandong Normal University, Jinan 250014, China [title_en] => Water-soluble methyl red-modiflied hydroxypropyl beta-CD via ethylenediamine as a molecule-responsive yellow-to-red color change indicator [country] => [cite_wos] => 0 [publication_en] => ACTA CHIMICA SINICA [check_3Y] => 4 [open_time] => [language] => Chinese [delivery_No] => 587LH [reference] => Gu LQ, 1999, NATURE, V398, P686@@@Hao A Y, 1999, Inclusion Phenomena and Macrocyclic Chemistry, V34, P445@@@Hao AY, 2000, SYNTHETIC COMMUN, V30, P3703, DOI@@@10.1080/00397910008086997@@@Kuwabara T, 1998, Org. Chem., V63, P8729@@@Matsushita A, 1997, Chem. Soc., Perkin. Trans 2, P1705@@@Schneider H J, 1990, Frontiers in Supramolecular Organic CHemistry and@@@Photochemistry, VCH, Weinheim@@@郝爱友, 1996, 化学通报, V4, P16@@@张希(译), 1995, 超分子化学@@@刘育, 1999, 中国科学(B辑), V29, P532 [cite_wanfang] => 1 [institution_first] => Shandong University [cauthor] => Hao, AY(haoay@sdu.edu.cn) [ei_No] => [datebase] => Scopus [fund_CSSCI] => [school_stu] => [main_cword] => [end_page] => 1535 [create_time] => [abstract_en] => Water-soluble hydroxypropyl beta-cyclodextrin was converted to acetonyl hydroxypropyl beta-cyclodextrin via selective oxidation. Ethylenediamine was used as a flexible chain as well as a connecter to get water-soluble methyl red-modified hydroxypropyl beta-cyclodextrin. When hydrophobic molecules such as cyclohexane were added in the diluted solution of the methyl red-modified hydroxypropyl beta-cyclodextrin (6 x 10(-8) to 2 x 10(-5) mol.dm(-3)), the methyl red moiety could be pressed out of the cavity of the beta-cyclodextrin. This variation would be accompanied with color changing from yellow to red in an acidic solution due to the diazenediyl protonation of the methyl red moiety. The color changing is influenced by the structure, bulkage, polarity etc. of the guest molecules, the methyl red-modified hydroxypropyl beta-cyclodextrin can thus be used as a water-soluble color changing molecular indicator. [degree] => [job_no] => [publication_type] => J [volume_label] => [volume] => 60 [main_eword] => [numerical_index] => [publisher] => SCIENCE CHINA PRESS [keyword_en] => methyl red-modified hydroxypropyl beta-CD via ethylenediamine;; water-solubility; color change; molecular indicator [awards_type] => [birthday] => [sponsor] => [imf] => 2.131 [bulletin_No] => [format_title_en_publication_en_pub_year] => cc53d9a80f71b6f9ac05d20be9fa1ef2215511741 [institution_name] => [grant_bulletin_date] => [department_tutor1] => [abstract_type] => [legal_status] => [email_c] => haoay@sdu.edu.cn [discipline_name] => [institution_type] => [cscd_No] => CSCD:1009217 [sys_priority_field] => 73 [research_area] => Chemistry [oral_time] => [name_tutor1] => [cauthor_back] => [check_180] => 1 [scopus_No] => 2-s2.0-0442265880 [positional_titles] => [jl_language] => chinese [jl_publication_en] => actachimicasinica [sys_author_jg_last_arr] => 博士生 [jl_company_test] => uircu0,unameuu5316u5b66u4e0eu5316u5de5u5b66u9662,uparentidu43,uorgidu43,ulevelu1 [jl_country] => 中国 [jl_keyword_en] => ,watersolubility,molecularindicator,methylredmodifiedhydroxypropylbetacdviaethylenediamine,colorchange [sys_author_in_last_arr] => china [jl_publisher] => sciencechinapress [sys_author_id] => [id] => uQ5IvmUBFjIhTVEbRWIm [tags] => 0 ) [19] => Array ( [batch2] => 1,2,6 [uri] => https://www.scopus.com/inward/record.uri?eid=2-s2.0-0442264863&partnerID=40&md5=34838cf55b63b319c59eb2cb6497a6ee [tag] => 0 [abstract_cn] => 在油酸钠保护下用NaBH4 还原AgNO3 ,制得了银纳米粒子胶体溶液 .利用相转移剂NaH2 PO4 等 ,使Ag纳米粒子在水 /有机相界面之间形成薄膜 .形成的Ag纳米粒子膜可以转移到玻璃等基质上 ,讨论了其转移机理 ;并用石英晶体微天平 (QCM)定量检测了银纳米粒子的相转移量 . [keyword_cn] => 银纳米粒子;;单层膜;;相转移;;QCM [fund_No] => 国家重点基础研究专项经费(No. G19990650); 国家自然科学基金(No. 20173033)资助项目 [article_id] => 26625,332384,597898,495415,664162,239553 [clc] => TQ153 [author_jg] => [李德刚] 山东大学化学系, 济南, 山东 250100, 中国.@@@[赵世勇] 山东大学化学系, 济南, 山东 250100, 中国.@@@[王春涛] 山东大学化学系, 济南, 山东 250100, 中国.@@@[陈慎豪] 山东大学化学系, 金属腐蚀与防护国家重点实验室, 济南, 山东 250100, 中国 [format_title_cn_publication_cn_pub_year] => 806afc7e177abe469f77b7c7c7314ba5-221230536 [hints] => 2 [issue] => 3 [author_first] => 李德刚 [sys_level_num] => 2_3 [sys_jg_type] => 5 [format_issn_issue_page_pub_year] => 476fe67b57e78cc02cd495e516ca25d0-1373531054 [source_type] => 351 [pub_year] => 2002 [pub_date] => MAR [pages] => 5 [from_id] => 76,75,73,80,78,85 [author_cn] => 李德刚;陈慎豪;赵世勇;王春涛 [issn] => 0567-7351 [batch] => 3249,3250,3252,3254,3243,3241 [publication_cn] => 化学学报 [title_cn] => 相转移方法制备银纳米粒子单层膜 [CSSN] => 31-1320/O6 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => 3a0a346c0949cff461e351ef3acdac44350353872 [page] => 408-412+378 [hb_type] => 2 [article_dt] => Article [hb_batch] => title_cn_publication_cn_pub_year_2_3 [publication_en] => ACTA CHIMICA SINICA [cite_wos] => 3 [check_3Y] => 1 [language] => Chinese [delivery_No] => 533UW [format_title] => f4b7aaa98e91ce45d070b427dba71fc3429840700 [cauthor_ad] => [Li, DG]Shandong Univ, Dept Chem, Jinan 250100, Peoples R China. [author_fn] => Li, DG; Chen, SH; Zhao, SY; Wang, CT [reference] => BRUCKENSTEIN S, 1985, ELECTROCHIM ACTA, V30, P1295, DOI@@@10.1016/0013-4686(85)85005-2@@@Christophe P., 1993, J PHYS CHEM, V97, P12974@@@HIRAI H, 1992, CHEM LETT, P1527, DOI 10.1246/cl.1992.1527@@@@@@OZIN GA, 1992, ADV MATER, V4, P612, DOI 10.1002/adma.19920041003@@@SCHUMACHER R, 1990, ANGEW CHEM INT EDIT, V29, P329, DOI@@@10.1002/anie.199003293@@@Wang W, 1998, LANGMUIR, V14, P602, DOI 10.1021/la9710177@@@WANG Y, 1991, J PHYS CHEM-US, V95, P525, DOI 10.1021/j100155a009@@@WANG Y, 1991, ACCOUNTS CHEM RES, V24, P133, DOI 10.1021/ar00005a002@@@史苏华, 1991, 吉林大学自然科学学报, V4, P78@@@曹茂盛, 2000, 化学通报, V2, P42 [publication_29] => ACTA CHIM SINICA [end_page] => 412 [abstract_en] => Ag nanoparticles were produced by the reduction of AgNO3 with the protecting of sodium oleate using NaBH4. After adding, the transferring regent NaH2PO4, a film of Ag nanoparticles was formed at the interface of water/organic phase. The film could be transferred to a substrate such as glass. The mechanism of the transfer of the film was discussed. Quartz Crystal Microbalance (QCM) was also used to measure the transferred colloidal quantity for Ag nanoparticles. [author_in] => [Li, D.-G] Department of Chemistry, Shandong University, Jinan 250100, China@@@[ Chen, S.-H] Department of Chemistry, Shandong University, Jinan 250100, China, State Key Laboratory for Corrosion and Protection of Metals, Shenyang 110015, China@@@[ Zhao, S.-Y] Department of Chemistry, Shandong University, Jinan 250100, China@@@[ Wang, C.-T] Department of Chemistry, Shandong University, Jinan 250100, China [publication_type] => J [begin_page] => 408 [author_en] => Li, DG; Chen, SH; Zhao, SY; Wang, CT [volume] => 60 [get_data] => 2018-08-29 [publisher] => SCIENCE CHINA PRESS [keyword_en] => Ag nanoparticles; monolayer film; phase transfer; QCM [format_publication_cn] => 6918be3b26b1fa6ec0424f6071208a75331227575 [keyword_plu] => SIZED SEMICONDUCTOR CLUSTERS; MICROBALANCE; SILVER [publication_iso] => Acta Chim. Sin. [format_title_en] => 068584ffbe0cb752f1268b3485ec592219354379 [publisher_city] => BEIJING [hx_id] => 2377,2378,2371 [reference_No] => 10 [email] => shchen@sdu.edu.cn [cite_awos] => 7 [wos_No] => WOS:000174549600006 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [check_180] => 0 [publisher_ad] => 16 DONGHUANGCHENGGEN NORTH ST, BEIJING 100717, PEOPLES R CHINA [title_en] => Production of the monolayer of Ag nanoparticles by phase transferring [format_publication_en] => 169b60c7845c9e5f36906950b18f11111348184734 [jl_language] => chinese [jl_publication_cn] => 化学学报 [jl_article_dt] => 期刊论文 [jl_publication_en] => actachimicasinica [jl_country] => 中国,中国 [jl_keyword_en] => agnanoparticles,phasetransfer,qcm,monolayerfilm [jl_keyword_cn] => ,银纳米粒子,单层膜,相转移,qcm [jl_clc] => tq153 [jl_publisher] => sciencechinapress [company_id] => 0,43,143,169,16 [sys_subject_sort] => 0,0,0,0 [college_parent_id] => 16,43,169,143 [company_test] => Array,Array,Array,Array [author_id] => 21630,25925 [author_test] => Array ( [0] => Array ( [sure] => 0 [irmagnum] => 0 [u_index] => 1 [name] => 李德广 [irtag] => 7 [t_index] => 1 [person_id] => 21630 ) [1] => Array ( [sure] => 0 [irmagnum] => 0 [u_index] => 3 [name] => 赵双宜 [irtag] => 7 [t_index] => 0 [person_id] => 25925 ) ) [sys_author_id_arr] => [cscd_No] => CSCD:1008369 [jl_publication_cn_publication_en] => actachimicasinica,化学学报 [jl_keyword_cn_keyword_en] => 银纳米粒子,单层膜,phasetransfer,monolayerfilm,相转移,agnanoparticles,qcm [sys_author_id] => [format_cscd_No] => 611ea1f2c000a7028bf7cf232d097fcc-530256039 [format_title_en_publication_en_pub_year] => b44d0928433dedace7a655be6dd2f54d1415278669 [format_wos_No] => 17bbecf9c787d51d927dae35a59397b61815995995 [format_title_en_issn_pub_year] => bf6e43b08d82ea72790e26dce9f77072-2065364006 [format_scopus_No] => abd2cebfd1f7489ecf90d33e9e320ef41832792116 [standard_in] => Department of Chemistry, Shandong University, Jinan 250100, China; State Key Laboratory for Corrosion and Protection of Metals, Shenyang 110015, China [datebase] => Scopus [cite_scopus] => 4 [sys_priority_field] => 76 [scopus_No] => 2-s2.0-0442264863 [id] => Ng5HvmUBFjIhTVEbZSTq [tags] => 0 ) ) 1-->
41. 端基含4个丁氧基苯介晶基元光致变色液晶树状物的合成、结构及液晶性研究 CSCD SCOPUS SCIE

作者:张其震,刘建强,李爱香,张静智

作者机构:[张其震] 山东大学化学与化工学院, 济南, 山东 250100, 中国.;[刘建强] 山东大学化学与化工学院, 济南, 山东 250100, 中国.;[李爱香] 山东大学化学与化工学院, 济南, 山东 250100, 中国.;[张静智] 山东大学化学与化工学院, 济南, 山东 250100, 中国

来源:化学学报,ACTA CHIMICA SINICA,2004,Vol.62,Issue.3,312-316

WOS被引数:4

资源类型:期刊论文

WOS:000188877700015

42. 利用水引发固相反应方法合成氮化铝纳米粉 CSCD SCIE

作者:李凯 [1];刘振刚 [2];于美燕 [2];董守义 [1];王琪珑 [2];郝霄鹏 [1];崔得良 [1]

作者机构:[李凯] 山东大学, 晶体材料国家重点实验室, 济南, 山东 250100, 中国.;[董守义] 山东大学, 晶体材料国家重点实验室, 济南, 山东 250100, 中国.;[郝霄鹏] 山东大学, 晶体材料国家重点实验室, 济南, 山东 250100, 中国.;[崔得良] 山东大学, 晶体材料国家重点实验室, 济南, 山东 250100, 中国.;[刘振刚] 山东大学化学与化工学院, 济南, 山东 250100, 中国.;[于美燕] 山东大学化学与化工学院, 济南, 山东 250100, 中国.;[王琪珑] 山东大学化学与化工学院, 济南, 山东 250100, 中国

来源:化学学报,ACTA CHIMICA SINICA,2004,Vol.62,Issue.12

WOS被引数:7

资源类型:期刊论文

WOS:000222218900010

43. ET类分子导体3d轨道对晶体能带及导电性的影响 CSCD SCOPUS SCIE

作者:刘国群,雷虹,方奇

作者机构:[刘国群] 山东大学, 晶体材料国家重点实验室, 济南, 山东 250100, 中国.;[方奇] 山东大学, 晶体材料国家重点实验室, 济南, 山东 250100, 中国.;[雷虹] 山东大学信息科学与工程学院, 济南, 山东 250100, 中国

来源:化学学报,ACTA CHIMICA SINICA,2004,Vol.62,Issue.1,10-15

资源类型:期刊论文

WOS:000187998100003

44. 氮硼为电子授受中心的D--π-A化合物的合成与上转换荧光 CSCD SCOPUS SCIE

作者:刘志强,曹笃霞,方奇,刘国群,许贵宝

作者机构:[刘志强] 山东大学, 晶体材料国家重点实验室, 济南, 山东 250100, 中国.;[曹笃霞] 山东大学, 晶体材料国家重点实验室, 济南, 山东 250100, 中国.;[方奇] 山东大学, 晶体材料国家重点实验室, 济南, 山东 250100, 中国.;[刘国群] 山东大学, 晶体材料国家重点实验室, 济南, 山东 250100, 中国.;[许贵宝] 山东大学, 晶体材料国家重点实验室, 济南, 山东 250100, 中国

来源:化学学报,ACTA CHIMICA SINICA,2004,Vol.62,Issue.20,2103-2108

WOS被引数:7

资源类型:期刊论文

WOS:000224840200025

45. 分子导体(Py Me)[Ni(dmit)_2]_2的合成、结构与导电性 CSCD SCOPUS SCIE

作者:许文,方奇,薛刚,于文涛,刘国群,雷虹

作者机构:[许文] 山东大学, 晶体材料国家重点实验室, 济南, 山东 250100, 中国.;[方奇] 山东大学, 晶体材料国家重点实验室, 济南, 山东 250100, 中国.;[薛刚] 山东大学, 晶体材料国家重点实验室, 济南, 山东 250100, 中国.;[于文涛] 山东大学, 晶体材料国家重点实验室, 济南, 山东 250100, 中国.;[刘国群] 山东大学, 晶体材料国家重点实验室, 济南, 山东 250100, 中国.;[雷虹] 山东大学信息科学与工程学院, 济南, 山东 250100, 中国

来源:化学学报,ACTA CHIMICA SINICA,2004,Vol.62,Issue.6,587-592+533

资源类型:期刊论文

WOS:000220437300011

46. 混合碳链烷基聚葡糖苷中相微乳液的研究 CSCD SCOPUS SCIE

作者:柴金岭;李东祥;李干佐;梁芳珍;张高勇山东大学胶体与界面化学教育部重点实验室;夏瑞

作者机构:[柴金岭] 山东大学, 胶体与界面化学教育部重点实验室, 济南, 山东 250100, 中国.;[李东祥] 山东大学, 胶体与界面化学教育部重点实验室, 济南, 山东 250100, 中国.;[李干佐] 山东大学, 胶体与界面化学教育部重点实验室, 济南, 山东 250100, 中国.;[张高勇] 山东大学, 胶体与界面化学教育部重点实验室, 济南, 山东 250100, 中国.;[梁芳珍] 山东师范大学化学系, 济南, 山东 250014, 中国.;[夏瑞] 北京药品检验所, 北京 100035, 中国

来源:化学学报,ACTA CHIMICA SINICA,2004,Vol.62,Issue.1,47-52

WOS被引数:11

资源类型:期刊论文

WOS:000187998100010

47. 烷基聚葡糖苷微乳液中脂肪酶催化的酯合成反应动力学 CSCD SCOPUS SCIE

作者:柴金岭 [1];高延红 [2];王金山 [2];李干佐 [3];张高勇 [3];徐清 [4]

作者机构:[柴金岭] 山东师范大学化学系, 济南, 山东 250014, 中国.;[高延红] 山东师范大学化学系, 济南, 山东 250014, 中国.;[王金山] 山东师范大学化学系, 济南, 山东 250014, 中国.;[李干佐] 山东大学, 胶体与界面化学教育部重点实验室, 济南, 山东 250100, 中国.;[张高勇] 山东大学, 胶体与界面化学教育部重点实验室, 济南, 山东 250100, 中国.;[徐清] 诺维信(中国)有限公司, 北京 100085, 中国

来源:化学学报,ACTA CHIMICA SINICA,2004,Vol.62,Issue.19,1894-1900

WOS被引数:1

资源类型:期刊论文

WOS:000224536500008

48. 二代光致变色液晶树枝状碳硅烷的光化学研究——端基含36个丁氧基偶氮苯介晶基元 CSCD SCOPUS SCIE

作者:张其震,刘建强,张静智

作者机构:[张其震] 山东大学化学化工学院, 济南, 山东 250100, 中国.;[刘建强] 山东大学化学化工学院, 济南, 山东 250100, 中国.;[张静智] 山东大学化学化工学院, 济南, 山东 250100, 中国

来源:化学学报,ACTA CHIMICA SINICA,2004,Vol.62,Issue.3,317-323

WOS被引数:9

资源类型:期刊论文

WOS:000188877700016

49. 端基含4个丁氧基偶氮苯介晶基元光致变色液晶树状物的光化学研究 CSCD SCOPUS SCIE

作者:张其震;刘建强;唐新德;张静智

作者机构:[张其震] 山东大学化学与化工学院, 济南, 山东 250100, 中国.;[刘建强] 山东大学化学与化工学院, 济南, 山东 250100, 中国.;[唐新德] 山东大学化学与化工学院, 济南, 山东 250100, 中国.;[张静智] 山东大学化学与化工学院, 济南, 山东 250100, 中国

来源:化学学报,ACTA CHIMICA SINICA,2004,Vol.62,Issue.18,1822-1828

WOS被引数:6

资源类型:期刊论文

WOS:000224063500028

50. CH_3S与NO基态反应的机理及动力学 CSCD SCOPUS SCIE

作者:王少坤,张庆竹,周建华,顾月姝

作者机构:[王少坤] 山东大学化学与化工学院, 济南, 山东 250100, 中国.;[张庆竹] 山东大学化学与化工学院, 济南, 山东 250100, 中国.;[顾月姝] 山东大学化学与化工学院, 济南, 山东 250100, 中国.;[周建华] 山东轻工业学院化工系, 济南, 山东 250100, 中国

来源:化学学报,ACTA CHIMICA SINICA,2004,Vol.62,Issue.6,550-555+531

WOS被引数:20

资源类型:期刊论文

WOS:000220437300004

51. 三代树状碳硅烷液晶研究——端基含丁氧基偶氮苯介晶基元 CSCD SCOPUS SCIE

作者:张其震[1];殷晓颖[1];王大庆[2];李光[3];季怡萍[3];赵晓光[3]

作者机构:[张其震] 山东大学化学化工学院, 济南, 山东 201000, 中国.;[殷晓颖] 山东大学化学化工学院, 济南, 山东 201000, 中国.;[王大庆] 山东师范大学测试中心, 济南, 山东 250014, 中国.;[李光] 中国科学院长春应用化学研究所, 长春, 吉林 130022, 中国.;[季怡萍] 中国科学院长春应用化学研究所, 长春, 吉林 130022, 中国.;[赵晓光] 中国科学院长春应用化学研究所, 长春, 吉林 130022, 中国

来源:化学学报,ACTA CHIMICA SINICA,2003,Vol.61,Issue.4,619-624

WOS被引数:11

资源类型:期刊论文

WOS:000187533500030

52. 四原子分子振转相互作用的Lie代数方法 CSCD SCIE

作者:冯东太,丁世良,王美山

作者机构:[冯东太] 山东大学物理与微电子学院/化学院, 济南, 山东 250100, 中国.;[丁世良] 山东大学物理与微电子学院/化学院, 济南, 山东 250100, 中国.;[王美山] 山东大学物理与微电子学院/化学院, 济南, 山东 250100, 中国

来源:化学学报,ACTA CHIMICA SINICA,2003,Vol.61,Issue.11,1729-1733+1692

资源类型:期刊论文

WOS:000188245800007

53. 二代树状碳硅烷液晶研究Ⅰ.端基含36个丁氧基偶氮苯介晶基元 CSCD SCIE

作者:张其震,刘建强,殷晓颖,张静智,季怡萍,赵晓光,李光

作者机构:[张其震,刘建强,殷晓颖,张静智,季怡萍,赵晓光,李光]山东大学化学化工学院,山东大学化学化工学院,山东大学化学化工学院,山东大学化学化工学院,中国科学院长春应用化学研究所,中国科学院长春应用化学研究所,中国科学院长春应用化学研究所 济南250100,济南250100,济南250100,济南250100,长春130022,长春130022,长春130022

来源:化学学报,ACTA CHIMICA SINICA,2003,Vol.61,Issue.3,416-421

WOS被引数:13

资源类型:期刊论文

WOS:000182279800022

54. 一代树状碳硅烷液晶研究——端基含12个4-硝基偶氮苯介晶基元 CSCD SCOPUS SCIE

作者:张其震,盛昕,殷晓颖,季怡萍,李光,赵晓光

作者机构:[张其震] 山东大学化学化工学院, 济南, 山东 250100, 中国.;[盛昕] 山东大学化学化工学院, 济南, 山东 250100, 中国.;[殷晓颖] 山东大学化学化工学院, 济南, 山东 250100, 中国.;[季怡萍] 中国科学院长春应用化学研究所, 长春, 吉林 130022, 中国.;[李光] 中国科学院长春应用化学研究所, 长春, 吉林 130022, 中国.;[赵晓光] 中国科学院长春应用化学研究所, 长春, 吉林 130022, 中国

来源:化学学报,ACTA CHIMICA SINICA,2003,Vol.61,Issue.9,1478-1483

WOS被引数:10

资源类型:期刊论文

WOS:000188245700026

55. 烯丙基硫脲和十二烷基硫醇对铜的缓蚀作用 CSCD SCOPUS SCIE

作者:王春涛;陈慎豪;赵世勇;李德刚

作者机构:[王春涛] 山东大学化学与化工学院, 济南, 山东 250100, 中国.;[陈慎豪] 山东大学化学与化工学院, 济南, 山东 250100, 中国.;[赵世勇] 山东大学化学与化工学院, 济南, 山东 250100, 中国.;[李德刚] 山东大学化学与化工学院, 济南, 山东 250100, 中国

来源:化学学报,ACTA CHIMICA SINICA,2003,Vol.61,Issue.2,151-155

WOS被引数:10

资源类型:期刊论文

WOS:000181172200001

56. 一代树状碳硅烷液晶的光化学研究——端基含12个4-丁氧基偶氮苯介晶基元 CSCD SCOPUS SCIE

作者:张其震,刘建强,殷晓颖,张静智

作者机构:[张其震,刘建强,殷晓颖,张静智]山东大学化学化工学院,山东大学化学化工学院物理与微电子学院,山东大学化学化工学院,山东大学化学化工学院 济南 250100, 济南 250100, 济南 250100, 济南 250100

来源:化学学报,ACTA CHIMICA SINICA,2003,Vol.61,Issue.7,1108-1113

WOS被引数:11

资源类型:期刊论文

WOS:000184988400026

57. 用环糊精合成楔筒状主体分子新模型 CSCD SCIE

作者:郝爱友;王金山

作者机构:[郝爱友] 山东大学化学与化工学院, 济南, 山东 250100, 中国.;[王金山] 山东师范大学化学系, 济南, 山东 250014, 中国

来源:化学学报,ACTA CHIMICA SINICA,2002,Vol.60,Issue.8,1536-1538+1356

WOS被引数:5

资源类型:期刊论文

WOS:000177641800033

58. 以N—N基团为单桥的双核Cu(Ⅱ)体系磁-结构关联的理论研究 CSCD SCOPUS SCIE

作者:毕思玮,刘成卜

作者机构:[毕思玮,刘成卜]山东大学理论化学研究所,山东大学理论化学研究所 济南250100曲阜师范大学化学系曲阜273165,济南250100

来源:化学学报,ACTA CHIMICA SINICA,2002,Vol.60,Issue.8,1390-1395+1348

资源类型:期刊论文

WOS:000177641800007

59. 水溶性显色型分子识别器——甲基红基乙二胺基羟丙基-β-环糊精 SCOPUS CSCD SCOPUS SCIE

作者:郝爱友,王金山,辛志荣

作者机构:[郝爱友,王金山,辛志荣]山东大学化学与化工学院,山东师范大学化学系,长春应用化学研究所 济南250100,济南250014,博士生

来源:化学学报,ACTA CHIMICA SINICA,2002,Vol.60,Issue.8,1531-1535+1355

JCR分区(WOS):Q3

最新影响因子:2.131

当年影响因子:0.536

资源类型:期刊论文

WOS:000177641800032

60. 相转移方法制备银纳米粒子单层膜 CSCD SCOPUS SCIE

作者:李德刚;陈慎豪;赵世勇;王春涛

作者机构:[李德刚] 山东大学化学系, 济南, 山东 250100, 中国.;[赵世勇] 山东大学化学系, 济南, 山东 250100, 中国.;[王春涛] 山东大学化学系, 济南, 山东 250100, 中国.;[陈慎豪] 山东大学化学系, 金属腐蚀与防护国家重点实验室, 济南, 山东 250100, 中国

来源:化学学报,ACTA CHIMICA SINICA,2002,Vol.60,Issue.3,408-412+378

WOS被引数:3

资源类型:期刊论文

WOS:000174549600006

共 4 页, 63 条记录

TOP