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X) and PS(C-->X) have been observed. Based on the spectra of excited fragments we estimated the formation rate constants and vibratonal population, of PS(B) and PS(C). The reaction mechanism were discussed. [publication_type] => J [begin_page] => 18 [author_en] => WANG, HQ; GU, YS; LIU, CP; YIN, YJ; CAO, DZ; LI, ST [volume] => 51 [get_data] => 2018-08-29 [publisher] => SCIENCE PRESS [publication_iso] => Acta Chim. Sin. [format_title_en_publication_en_pub_year] => 9d0c492e871d6390f2d1880561cc5e1b2081095590 [publisher_city] => BEIJING [cauthor_order] => 1 [reference_No] => 12 [cite_awos] => 1 [wos_No] => WOS:A1993KN62600004 [format_wos_No] => 49ed880a29639d78ce11d1b97b0bebed-517732442 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [cauthor_back] => WANG, HQ [check_180] => 2 [publisher_ad] => 16 DONGHUANGCHENGGEN NORTH ST, BEIJING 100717, PEOPLES R CHINA [title_en] => FORMATION OF EXCITED PS FRAGMENTS AND ITS KINETIC-STUDY [sys_subject_sort] => 0,0 [college_parent_id] => 43,169 [company_test] => Array,Array [id] => qg5IvmUBFjIhTVEbRWIm [tags] => 0 ) [3] => Array ( [batch2] => 1,2 [batch] => 3250,3241,3254,3252 [tag] => 0 [CSSN] => 31-1320/O6 [keyword_cn] => 萃取动力学;协同作用;金;三苯基氧化膦;伯胺N1923 [article_id] => 336073,597873,30758,155163 [abstract_cn] => 用恒界面池法研究了伯胺N1923和三苯基氧化膦(TPPO)二元萃取剂体系从盐酸介质中萃取AuCl_4~-的动力学,提出了界面化学反应控制机理。认为在界面区域内同时进行着N1923、TPPO以及二者的缔合物萃取AuCl_4~-的三个平行反应,三者的共同作用使Au(Ⅲ)向有机相的传质较N1923或TPPO的一元萃取剂体系明显加速。文中对这种动力学加速现象和动力学协同效应以及它们与热力学协同萃取的关系进行了讨论。 [author_jg] => [孙思修;高自立;沈静兰;柴金岭]山东大学化学系,山东大学化学系,山东大学化学系,山东师范大学化学系 济南 250100,济南 250100,济南 250100,济南 250014 [format_title_cn_publication_cn_pub_year] => a8e590c31d60a2f2e2b7e07ed4e04fc1688571620 [hints] => 3 [issue] => 1 [sys_level_num] => 2_3 [sys_jg_type] => 5 [format_issn_issue_page_pub_year] => ee1bb88086ec062c9f183b3c7ccc5fb31066832540 [source_type] => 351 [pub_year] => 1993 [pub_date] => 1993-01-31 [pages] => 6 [from_id] => 80,78,73,85 [author_cn] => 孙思修;高自立;沈静兰;柴金岭; [issn] => 0567-7351 [uri] => http://kns.cnki.net/kns/detail/detail.aspx?FileName=HXXB199301005&DbName=CJFQ1993 [publication_cn] => 化学学报 [title_cn] => 伯胺N1923和三苯基氧化膦萃取金(Ⅲ)的动力学——Ⅱ.二元萃取剂体系萃取AuCl_4~- [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => f048b9e031f34181d9cf392d71181475277011155 [page] => 30-35 [hb_type] => 2 [article_dt] => Article [hb_batch] => title_cn_publication_cn_pub_year_2_3 [format_title_en] => 05b4d672df776c9a36d4a861d53143a4-1721848806 [format_title] => 8eace363aab10f20b5adb001900114e5751184313 [hx_id] => 2371 [format_publication_cn] => 6918be3b26b1fa6ec0424f6071208a75331227575 [format_publication_en] => 169b60c7845c9e5f36906950b18f11111348184734 [jl_publication_cn] => 化学学报 [jl_article_dt] => 期刊论文 [jl_keyword_cn] => 协同作用,萃取动力学,伯胺n1923,金,三苯基氧化膦 [author_in] => [SUN, SX; GAO, ZL; SHEN, JL; CHAI, JL]SHANDONG NORMAL UNIV, DEPT CHEM, JINAN 250014, PEOPLES R CHINA. [company_id] => 0,43,169 [author_id] => [author_test] => Array ( ) [sys_author_id_arr] => [jl_publication_cn_publication_en] => 化学学报 [jl_keyword_cn_keyword_en] => 金,协同作用,三苯基氧化膦,萃取动力学,伯胺n1923 [sys_author_id] => [publication_en] => ACTA CHIMICA SINICA [cite_wos] => 0 [check_3Y] => 0 [language] => Chinese [delivery_No] => KN626 [cauthor_ad] => [SUN, SX]SHANDONG UNIV, DEPT CHEM, JINAN 250100, PEOPLES R CHINA. [author_fn] => SUN, SX; GAO, ZL; SHEN, JL; CHAI, JL [format_title_en_issn_pub_year] => 59fcdcd018052bf4f0033b3ee85aadd9-908892119 [publication_29] => ACTA CHIM SINICA [end_page] => 35 [abstract_en] => The extraction kinetics of gold (III) by the binary-extractant system of primary amine N1923 and tri-phenylphosphine oxide (TPPO) in chloroform from hydrochloric acid has been studied using stirred Lewis\' cell at 298K. The mechanism was reported that there are three parallel reactions at the interface, i.e. extraction of gold(III) by N1923, TPPO and their associated molecule respectively, which accelerate the mass transfer of gold(III) from aqueous into organic phase obviously. A deterministic concept of kinetic synergism was presented and the relation between kinetic and thermodynamic synergism was discussed. [publication_type] => J [begin_page] => 30 [author_en] => SUN, SX; GAO, ZL; SHEN, JL; CHAI, JL [volume] => 51 [get_data] => 2018-08-29 [publisher] => SCIENCE PRESS [publication_iso] => Acta Chim. Sin. [format_title_en_publication_en_pub_year] => 9d13f1ad7d7288f811b98f662b204165-763576886 [publisher_city] => BEIJING [cauthor_order] => 1 [reference_No] => 1 [cite_awos] => 0 [wos_No] => WOS:A1993KN62600006 [format_wos_No] => 0d591493cfcf528558bfed377aed9308254437002 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [cauthor_back] => SUN, SX [check_180] => 0 [publisher_ad] => 16 DONGHUANGCHENGGEN NORTH ST, BEIJING 100717, PEOPLES R CHINA [title_en] => THE EXTRACTION KINETICS OF GOLD(III) BY PRIMARYAMINE N1923 AND TRIPHENYLPHOSPINE OXIDE .2. THE EXTRACTION OF AUCL4- IN A SYSTEM OF BINARY-EXTRACTANT [sys_subject_sort] => 0,0 [college_parent_id] => 43,169 [company_test] => Array,Array [id] => HQ5HvmUBFjIhTVEbZSTq [tags] => 0 ) [4] => Array ( [batch2] => 1,2 [uri] => http://kns.cnki.net/kns/detail/detail.aspx?FileName=HXXB199308000&DbName=CJFQ1993 [tag] => 0 [CSSN] => 31-1320/O6 [keyword_cn] => 阴离子型表面活性剂;;微乳液;;异常流变性 [fund_No] => 国家自然科学基金 [article_id] => 167940,336078,14629,539384 [abstract_cn] => 对以正十六烷、油酸钾、正己醇和水所组成的微乳液进行研究,对其流变性和机理作了探讨.微乳液粘度和水油比变化的关系可用相转化来说明.层形结构区显示出有高粘度特征,并具有明显的负触变性现象.对此进行了讨论,并研究了pH值和盐类的影响. [author_jg] => [伍世英;陈宗淇;王世权;李莹;袁云龙;张传胜]青岛化工学院应用化学系@@@[伍世英;陈宗淇;王世权;李莹;袁云龙;张传胜]青岛化工学院应用化学系@@@[伍世英;陈宗淇;王世权;李莹;袁云龙;张传胜]青岛化工学院应用化学系@@@[伍世英;陈宗淇;王世权;李莹;袁云龙;张传胜]青岛化工学院应用化学系@@@[伍世英;陈宗淇;王世权;李莹;袁云龙;张传胜]山东大学化学系@@@[伍世英;陈宗淇;王世权;李莹;袁云龙;张传胜]山东大学化学系 青岛 266042@@@[伍世英;陈宗淇;王世权;李莹;袁云龙;张传胜]青岛 266042@@@[伍世英;陈宗淇;王世权;李莹;袁云龙;张传胜]青岛 266042@@@[伍世英;陈宗淇;王世权;李莹;袁云龙;张传胜]青岛 266042@@@[伍世英;陈宗淇;王世权;李莹;袁云龙;张传胜]济南 250100@@@[伍世英;陈宗淇;王世权;李莹;袁云龙;张传胜]济南 250100 [format_title_cn_publication_cn_pub_year] => 67b98bb06a545af1fe60cf09ead38e05-1439901088 [hints] => 3 [issue] => 8 [author_first] => 伍世英; [sys_level_num] => 2_3 [sys_jg_type] => 10,5 [format_issn_issue_page_pub_year] => 6f83f9a9372c093d2b46eb468fa73dd5694987792 [source_type] => 351 [pub_year] => 1993 [pub_date] => 1993-08-29 [pages] => 7 [from_id] => 80,78,73,85 [author_cn] => 伍世英;陈宗淇;王世权;李莹;袁云龙;张传胜; [issn] => 0567-7351 [batch] => 3250,3241,3254,3252 [publication_cn] => 化学学报 [title_cn] => 阴离子型表面活性剂所组成微乳液的异常流变性 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => b435edce75c2c934bc83d36331b33f78140132699 [page] => 729-735 [hb_type] => 2 [article_dt] => Article [hb_batch] => title_cn_publication_cn_pub_year_2_3 [format_title_en] => 5c5b6e9b39f327ee38ca92944d4154391702613417 [format_title] => 399982a561958466420fa7ec178ef8771597015962 [hx_id] => 2371 [format_publication_cn] => 6918be3b26b1fa6ec0424f6071208a75331227575 [format_publication_en] => 169b60c7845c9e5f36906950b18f11111348184734 [jl_publication_cn] => 化学学报 [jl_article_dt] => 期刊论文 [jl_keyword_cn] => ,微乳液,阴离子型表面活性剂,异常流变性 [author_in] => [WU, SY; CHEN, ZQ; WANG, SQ; LI, Y; YUAN, YL; ZHANG, CS]SHANGDONG UNIV,DEPT CHEM,JINAN 250100,PEOPLES R CHINA. [company_id] => 0,43,169 [author_id] => 22000,24171,21999 [author_test] => Array ( [0] => Array ( [sure] => 0 [irmagnum] => 0 [u_index] => 4 [name] => 李莹 [irtag] => 7 [t_index] => 0 [person_id] => 21999 ) [1] => Array ( [sure] => 0 [irmagnum] => 0 [u_index] => 4 [name] => 李莹 [irtag] => 7 [t_index] => 0 [person_id] => 22000 ) [2] => Array ( [sure] => 0 [irmagnum] => 0 [u_index] => 3 [name] => 王世权 [irtag] => 7 [t_index] => 0 [person_id] => 24171 ) ) [sys_author_id_arr] => [jl_publication_cn_publication_en] => 化学学报 [jl_keyword_cn_keyword_en] => 异常流变性,微乳液,阴离子型表面活性剂 [sys_author_id] => [publication_en] => ACTA CHIMICA SINICA [cite_wos] => 5 [check_3Y] => 0 [language] => Chinese [delivery_No] => LX882 [cauthor_ad] => [WU, SY]QINGDAO INST CHEM TECHNOL,DEPT APPL CHEM,QINGDAO 266042,PEOPLES R CHINA. [author_fn] => WU, SY; CHEN, ZQ; WANG, SQ; LI, Y; YUAN, YL; ZHANG, CS [format_title_en_issn_pub_year] => 95d323095c5aefd8a6eb0aa2fb62d626648217811 [publication_29] => ACTA CHIM SINICA [end_page] => 735 [abstract_en] => Microemulsion, which are optically transparent oil-water dispersion were spontaneously produced upon mixing hexadecane, hexanol, potassium oleate, and water in specific proportions. The viscosity of microemulsions was measured for several water/oil ratios. The striking optical and viscosity changes observed at specific water/oil ratios were in agreement with the proposed mechanism of phase inversion, namely, water spheres --> water cyclinder --> water lamellae --> continuous water phase, for this system. In the lamellae region, the dispersion exhibited negative thixotropic and shear thicken properties. The bizarre rheological properties exhibited by the dispersion with water/oil ratios of 1 were explained in terms of ion-dipole association between oleate and hexanol molecules on adjacent dropletes, which was investigated as a function of pH, ratios of water and added salts. [publication_type] => J [begin_page] => 729 [author_en] => WU, SY; CHEN, ZQ; WANG, SQ; LI, Y; YUAN, YL; ZHANG, CS [volume] => 51 [get_data] => 2018-08-29 [publisher] => ACTA CHIMICA SINICA [keyword_plu] => LIQUID-CRYSTALS; RATIO [publication_iso] => Acta Chim. Sin. [format_title_en_publication_en_pub_year] => c69b0a84942cb0221948f672b11a7a001570388038 [publisher_city] => SHANGHAI [cauthor_order] => 1 [reference_No] => 14 [cite_awos] => 5 [wos_No] => WOS:A1993LX88200001 [format_wos_No] => 33929a6ec1b2a969b71d49ec06ec876a-2044470079 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [cauthor_back] => WU, SY [check_180] => 0 [publisher_ad] => SHANGHAI INST ORGANIC CHEM ACADEMIA SINICA 345 LINGLING LU, SHANGHAI,; PEOPLES R CHINA [title_en] => THE BIZARRE RHEOLOGICAL PROPERTIES OF MICROEMULSION WITH ANIONIC SURFACTANT [sys_subject_sort] => 0,0 [college_parent_id] => 43,169 [company_test] => Array,Array [id] => 5A9KvmUBFjIhTVEbYAQa [tags] => 0 ) [5] => Array ( [batch2] => 1,2 [batch] => 3250,3241,3252 [tag] => 0 [CSSN] => 31-1320/O6 [keyword_cn] => 邻香兰素;甘氨酸;镍配合物;晶体结构;热分解动力学 [article_id] => 554937,336076,187245 [abstract_cn] => 本文报道了邻香兰素甘氨酸三吡啶合Ni(Ⅱ)的合成、性质、晶体结构及热分解动力学.晶体的X射线分析结果表明,该晶体为单斜晶系,空间群为C2/c,a=3.3549(6),b=1.1396(4),c=1.4555(5)nm,β=113.96(3)°,V=5.086nm~3,M_r=526.21,Z=8,D_o=1.37g·cm~(-3),μ=8.060m~(-1),F(000)=2200.对配合物第一步热分解过程进行了非等温动力学研究,其机理为球对称的三维扩散,动力学方程为:da/dt=A·e~(-E/(RT))·3/2(1-a)~(2/3)[1-(1-A)~(1/3)]~(-1). [author_jg] => [崔学桂;孙宏建;刘德信;李晓燕;李淑兰]山东大学应用化学系,山东大学应用化学系,山东大学应用化学系,山东大学应用化学系,山东大学应用化学系 济南 250100,济南 250100,济南 250100,济南 250100,济南 250100 [format_title_cn_publication_cn_pub_year] => 5067161e2e276e236ee31926380f69d7954241786 [hints] => 7 [issue] => 4 [sys_level_num] => 2_3 [sys_jg_type] => 5 [format_issn_issue_page_pub_year] => dc1de2ed295bcc2a9729e9c2bcf9c3311462867013 [source_type] => 351 [pub_year] => 1993 [pub_date] => 1993-05-01 [pages] => 6 [from_id] => 80,73,78 [author_cn] => 崔学桂;孙宏建;刘德信;李晓燕;李淑兰; [issn] => 0567-7351 [uri] => http://kns.cnki.net/kns/detail/detail.aspx?FileName=HXXB199304006&DbName=CJFQ1993 [publication_cn] => 化学学报 [title_cn] => 邻香兰素甘氨酸三吡啶合Ni(Ⅱ)的合成、性质、晶体结构及热分解动力学 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => d9f404459982effef612ac38271ae0a0-1327522648 [page] => 346-351 [hb_type] => 2 [article_dt] => Article [jl_publication_cn] => 化学学报 [jl_article_dt] => 期刊论文 [jl_keyword_cn] => 镍配合物,甘氨酸,热分解动力学,晶体结构,邻香兰素 [author_in] => [company_id] => 0,43,169 [author_id] => 23476,21933 [author_test] => Array ( [0] => Array ( [sure] => 0 [irmagnum] => 0 [u_index] => 4 [name] => 李晓燕 [irtag] => 7 [t_index] => 0 [person_id] => 21933 ) [1] => Array ( [sure] => 0 [irmagnum] => 0 [u_index] => 2 [name] => 孙宏建 [irtag] => 7 [t_index] => 0 [person_id] => 23476 ) ) [sys_author_id_arr] => [jl_publication_cn_publication_en] => 化学学报 [jl_keyword_cn_keyword_en] => 晶体结构,热分解动力学,甘氨酸,邻香兰素,镍配合物 [sys_author_id] => [hb_batch] => grant_no [publication_en] => ACTA CHIMICA SINICA [cite_wos] => 12 [check_3Y] => 4 [language] => Chinese [delivery_No] => LF790 [format_title] => 6d4fcf8f84ea1168bedda901ad9b5e931145391663 [cauthor_ad] => [CUI, XG]SHANDONG UNIV,DEPT CHEM,JINAN 250100,PEOPLES R CHINA. [author_fn] => CUI, XG; SUN, HJ; LIU, DX; LI, XY; LI, SL [format_title_en_issn_pub_year] => ee4feec40aa53f4946e3fe0ac0aa94df-614986267 [publication_29] => ACTA CHIM SINICA [end_page] => 351 [abstract_en] => In this paper, the synthesis, crystal structure, properties and thermoanalysis of o-vanillin glycine tripyridine Nickel(II) were reported. The complex is monoclinic system, space group is C2/c, with cell parameters a = 3.3549(6), b = 1.1396(4), c = 1.4555(5) nm, beta = 113.96(3)-degrees, V = 5.086 nm3, M(r) = 526.21, Z = 8, D(c) = 1.37 g/cm3, mu = 8.06 cm-1, F(000) = 2200. The kinetics of thermal decomposition of the complex was studied also under non-isothermal condition by TG, DTG curves. The mechanism is three-dimension diffusion, 3D (sphere symmetry). The kinetic equation is expressed as: dalpha/dt = A . e(-E/RT) . 3/2 . (1-(1-alpha)1/3]-1. [publication_type] => J [begin_page] => 346 [author_en] => CUI, XG; SUN, HJ; LIU, DX; LI, XY; LI, SL [volume] => 51 [get_data] => 2018-08-29 [publisher] => ACTA CHIMICA SINICA [format_publication_cn] => 6918be3b26b1fa6ec0424f6071208a75331227575 [publication_iso] => Acta Chim. Sin. [format_title_en_publication_en_pub_year] => ee261629aec1b96e5d7aba85e5b16eb9-796131631 [format_title_en] => 894e78d693e4b4c21f8acbbac12abb7e680362614 [publisher_city] => SHANGHAI [cauthor_order] => 1 [hx_id] => 2371 [reference_No] => 8 [cite_awos] => 12 [wos_No] => WOS:A1993LF79000007 [format_wos_No] => 63b9a9a0008c41785c47a5253f59e3a0970807300 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [cauthor_back] => CUI, XG [check_180] => 1 [publisher_ad] => SHANGHAI INST ORGANIC CHEM ACADEMIA SINICA 345 LINGLING LU, SHANGHAI,; PEOPLES R CHINA [title_en] => THE SYNTHESIS, CRYSTAL-STRUCTURE, PROPERTIES AND THERMOANALYSIS OF O-VANILLIN GLYCINE TRIPYRIDINE NICKEL(II) [format_publication_en] => 169b60c7845c9e5f36906950b18f11111348184734 [sys_subject_sort] => 0,0 [college_parent_id] => 43,169 [company_test] => Array,Array [id] => qg5JvmUBFjIhTVEbmsTS [tags] => 0 ) [6] => Array ( [issn] => 0567-7351 [delivery_No] => KH222 [batch2] => 1,2 [hb_batch] => 3241 [tag] => 0 [author_en] => JIANG, DH; YANG, YH; GAO, ZL; SUN, SX; SHEN, JL [abstract_en] => This paper reports the preparation of tiltle compounds and determination of their composition, IR spee-tra and the solubility behaviour of the compounds in some organic solvents.; The structures of title compounds were determined by single crystal X-ray diffraction analysis. The first compound is monoclinic system and space group C2/c, two (C6H5)3PO forms a dimer, [(C6H5)3PO-H-OP(C6H5)3]+, in which a symmetric hydrogen bond exists. The second compound is triclinic system, and space group P1BAR, four (C6H5)3PO are connected with three hydrogens in protoned water. One of the three hydrogen bonds is branch-hydrogen bond [GRAPHICS],(~)the other two are normal (O-H/O). [publication_type] => J [publisher_city] => SHANGHAI [article_id] => 643644,336510,155158 [get_data] => 2018-08-29 [format_title_en_publication_en_pub_year] => 581bc1db90661ad20d5ec2748bcf745f1165645860 [pages] => 7 [cite_wos] => 2 [check_3Y] => 0 [cite_awos] => 2 [from_id] => 80,73,78 [cauthor_ad] => [JIANG, DH]SHANDONG UNIV,DEPT CHEM,JINAN 250100,PEOPLES R CHINA. [school_id] => 117 [cauthor_order] => 1 [research_area] => Chemistry [sys_level_num] => 1_7 [publisher] => ACTA CHIMICA SINICA [sys_jg_type] => 0,5 [format_issn_issue_page_pub_year] => 4248971c90a7fd6e11fbaf1f6a0edc381298334081 [title_en] => STUDIES ON SYNTHESIS, CHARACTERIZATION AND STRUCTURE OF THE EXTRACTION COMPOUNDS, HAUCL4.2(C6H5)3PO AND HAUCL4.H2O.4(C6H5)3PO [publication_29] => ACTA CHIM SINICA [author_fn] => JIANG, DH; YANG, YH; GAO, ZL; SUN, SX; SHEN, JL [pub_year] => 1992 [publisher_ad] => SHANGHAI INST ORGANIC CHEM ACADEMIA SINICA 345 LINGLING LU, SHANGHAI,; PEOPLES R CHINA [check_180] => 0 [end_page] => 1097 [cauthor_back] => JIANG, DH [begin_page] => 1091 [format_wos_No] => ea3a33917dda19d7207fd92288528186853184957 [hints] => 0 [volume] => 50 [language] => Chinese [source_type] => 351 [issue] => 11 [reference_No] => 0 [batch] => 3250,3241,3252 [publication_en] => ACTA CHIMICA SINICA [hx_id] => 2371 [sys_update_time] => 2018-09-05 15:29:33 [format_title_en_issn_pub_year] => e267f8a79fed90cce7c16a96b3195391124294311 [publication_iso] => Acta Chim. Sin. [wos_sub] => Chemistry, Multidisciplinary [SYS_TAG] => 3 [wos_No] => WOS:A1992KH22200009 [page] => 1091-1097 [hb_type] => 2 [article_dt] => Article [jl_language] => chinese [jl_publication_en] => actachimicasinica [jl_article_dt] => 期刊论文 [jl_publisher] => actachimicasinica [author_jg] => [蒋德华;杨永会;高自立;孙思修;沈静兰]山东大学化学系,山东大学化学系,山东大学化学系,山东大学化学系,山东大学化学系 济南 250100,济南 250100,济南 250100,济南 250100,济南 250100 [keyword_cn] => 金;三苯基氧化膦;萃合物;晶体结构 [format_title] => fc6276c77c6bc6119c913e408aa1f3932081210139 [title_cn] => 三苯基氧化膦与氯金酸形成的萃合物晶体的合成、特性和结构 [format_publication_cn] => 6918be3b26b1fa6ec0424f6071208a75331227575 [publication_cn] => 化学学报 [format_title_en] => 8dfe8bc0094d4b64fb7a6e44e7537b44-644366952 [sys_priority_field] => 73 [author_cn] => 蒋德华;杨永会;高自立;孙思修;沈静兰; [format_publication_en] => 169b60c7845c9e5f36906950b18f11111348184734 [CSSN] => 31-1320/O6 [abstract_cn] => 本文报道了三苯基氧化膦与氯金酸形成的两种配合物晶体的合成、特性和结构.由元素分析及谱学特性确定了萃合物的组成分别为HAuCl_4·2(C_6H_5)_3PO(1)和HAuCl_4·H_2O·4(C_6H_5)_3PO(2).X射线结构分析确定了两种单晶的结构.晶体(1)属于单斜晶系,空间群为C2/c,组成化学式为[(Ph_3PO)_2H]·AuCl_4,其中存在有对称氢键.晶体(2)属于三斜晶系,空间群为PI,组成化学式为(H_3O)·[AuCl_4]·4Ph_3PO,其中存在有分叉氢键. [uri] => http://kns.cnki.net/kns/detail/detail.aspx?FileName=HXXB199211008&DbName=CJFQ1992 [jl_publication_cn] => 化学学报 [jl_keyword_cn] => 萃合物,三苯基氧化膦,晶体结构,金 [author_in] => [company_id] => 43,169 [sys_subject_sort] => 0,0 [college_parent_id] => 43,169 [company_test] => Array,Array [author_id] => [author_test] => Array ( ) [sys_author_id_arr] => [jl_publication_cn_publication_en] => actachimicasinica,化学学报 [sys_author_id] => [format_title_cn_publication_cn_pub_year] => 0eb6832a14cd1a1bd6755ddb85016919-1559819929 [format_title_cn_issn_pub_year] => 6142b03ada8a944e51bf250dd5f91003-551213877 [id] => 7QifvWUBFjIhTVEbIto4 [tags] => 0 ) [7] => Array ( [batch2] => 1,2 [batch] => 3250,3241,3252 [tag] => 0 [CSSN] => 31-1320/O6 [keyword_cn] => 萃取;钼;二-(2-乙基己基)磷酸;稀释剂效应 [article_id] => 539382,336507,155159 [abstract_cn] => 考察了Mo(VI)在盐酸水相与二-(2-乙基己基)磷酸的不同稀释剂有机相间的分配平衡,观察到萃取平衡常数按正辛烷、四氯化碳、苯、氯仿、1,2-二氯乙烷、甲苯、甲基异丁基酮的次序递减,萃合物的组成也按这一顺序呈现规律性变化.文中将这些结果与稀释剂极性进行了关联,得到萃取平衡常数与稀释剂的极性参数E_T间良好的线性关系.此外,本文还提出了H_2MoO_4的酸、碱式解离常数分别为0.158和1.21×10(-13). [author_jg] => [孙思修;高自立;刘源;沈静兰]山东大学化学系,山东大学化学系,山东大学化学系,山东大学化学系 济南 250100,济南 250100,济南 250100,济南 250100 [format_title_cn_publication_cn_pub_year] => 9deccd26d2bab4b51655f67266a814a22036365568 [hints] => 0 [issue] => 9 [sys_level_num] => 2_3 [sys_jg_type] => 5 [format_issn_issue_page_pub_year] => 489a487c4a6571848323742cc029e421526128012 [source_type] => 351 [pub_year] => 1992 [pub_date] => 1992-09-27 [pages] => 6 [from_id] => 80,73,78 [author_cn] => 孙思修;高自立;刘源;沈静兰; [issn] => 0567-7351 [uri] => http://kns.cnki.net/kns/detail/detail.aspx?FileName=HXXB199209007&DbName=CJFQ1992 [publication_cn] => 化学学报 [title_cn] => 二-(2-乙基己基)磷酸在不同稀释剂中对钼(Ⅵ)的萃取 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => 712e587939ac67acad4eddb3a6b675ab-990730302 [page] => 877-882 [hb_type] => 2 [article_dt] => Article [jl_publication_cn] => 化学学报 [jl_article_dt] => 期刊论文 [jl_keyword_cn] => 萃取,稀释剂效应,钼,二2乙基己基磷酸 [author_in] => [company_id] => 0,43,169 [author_id] => [author_test] => Array ( ) [sys_author_id_arr] => [jl_publication_cn_publication_en] => 化学学报 [sys_author_id] => [hb_batch] => grant_no [publication_en] => ACTA CHIMICA SINICA [cite_wos] => 3 [check_3Y] => 0 [language] => Japanese [delivery_No] => JV027 [format_title] => f0e9876f0cd8c10266d1d785b2a906f51164950595 [cauthor_ad] => [SUN, SX]SHANDONG UNIV, DEPT CHEM, JINAN 250100, PEOPLES R CHINA. [author_fn] => SUN, SX; GAO, ZL; LIU, Y; SHEN, JL [format_title_en_issn_pub_year] => 381daf5ade27f715dc453985cdbdc68a1666075954 [publication_29] => ACTA CHIM SINICA [end_page] => 882 [abstract_en] => The distrabution equilibria of molybdenum(VI) between hydrochloric acid media and various diluent solution of di-(2-ethylhexyl)phosphate were investigated at 298K. The extraction equilibrium constants decrease in order of octane, carbon tetrachloride, bezene, chloroform, 1, 2-dichloroethane, toluene and methylisobutylketone. Effect of diluent polarity on the composition of extracted species were also observed. [publication_type] => J [begin_page] => 877 [author_en] => SUN, SX; GAO, ZL; LIU, Y; SHEN, JL [volume] => 50 [get_data] => 2018-08-29 [publisher] => SCIENCE PRESS [keyword_plu] => SOLVENT-EXTRACTION [format_publication_cn] => 6918be3b26b1fa6ec0424f6071208a75331227575 [publication_iso] => Acta Chim. Sin. [format_title_en_publication_en_pub_year] => 1d97da72820fd06f503502d65fc79821-484281464 [format_title_en] => d223d3e1032fc06d089319f2fac9f6e6-464651640 [publisher_city] => BEIJING [cauthor_order] => 1 [hx_id] => 2371 [reference_No] => 11 [cite_awos] => 3 [wos_No] => WOS:A1992JV02700008 [format_wos_No] => 7638178ec64312c991dcd52e7f8e1f94-587872968 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [cauthor_back] => SUN, SX [check_180] => 0 [publisher_ad] => 16 DONGHUANGCHENGGEN NORTH ST, BEIJING 100717, PEOPLES R CHINA [title_en] => EXTRACTION EQUILIBRIA OF MOLYBDENUM (VI) FROM HYDROCHLORIC-ACID BY DI-(2-ETHYLHEXYL) PHOSPHATE IN VARIOUS DILUENT SOLUTIONS [format_publication_en] => 169b60c7845c9e5f36906950b18f11111348184734 [sys_subject_sort] => 0,0 [college_parent_id] => 43,169 [company_test] => Array,Array [id] => 4g9KvmUBFjIhTVEbYAQa [tags] => 0 ) [8] => Array ( [batch2] => 1,2 [batch] => 3250,3241,3252 [tag] => 0 [CSSN] => 31-1320/O6 [keyword_cn] => 交换反应;Cl+HCl;始终;势能面;振动量子数;跃迁几率;氢原子;动力学共振;共线; [article_id] => 597872,168112,336505 [abstract_cn] => 本文用一维量子散射方法,计算了氢原子交换反应Cl+HCl(v≤3)→ClH(v′≤3)+Cl。得到了各振动态间反应和非反应非弹性几率。结果表明反应和非反应非弹性几率均呈振荡变化。反应与非反应去激几率相差不大,预期在Cl原子与HCl(v=1,2,3)碰撞去激过程中,反应和非反应散射都是一种有效的机理;此与Wilkins的轨迹结果相符。去激几率与始终态振动量子数密切相关,我们归纳出公式:P_(vv′)≈10~(v+v′-2(v″+1))P_(vv″),(v>v′>v″)。与Moor的实验结果符合较好。 [author_jg] => [陈德展;居冠之]山东师范大学化学系,山东大学化学院 济南 250014,济南 250100 [format_title_cn_publication_cn_pub_year] => 2f34cb638854a8b2658187319efe83e8545015772 [hints] => 1 [issue] => 1 [sys_level_num] => 2_3 [sys_jg_type] => 5 [format_issn_issue_page_pub_year] => 2984f2092c608dd0d31882f5df6dc08f1821715717 [source_type] => 351 [pub_year] => 1992 [pub_date] => 1992-01-31 [pages] => 4 [from_id] => 80,73,78 [author_cn] => 陈德展;居冠之; [issn] => 0567-7351 [uri] => http://kns.cnki.net/kns/detail/detail.aspx?FileName=HXXB199201000&DbName=CJFQ1992 [publication_cn] => 化学学报 [title_cn] => 氢原子共线交换反应的动力学计算 Ⅱ.在反应势能面上Cl+HCl(v)碰撞对的振动去激 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => 6cdfe6934805c09ca534e9cb230e7b54-1102356200 [page] => 1-4 [hb_type] => 2 [article_dt] => Article [jl_publication_cn] => 化学学报 [jl_article_dt] => 期刊论文 [jl_keyword_cn] => ,振动量子数,共线,clhcl,跃迁几率,始终,动力学共振,势能面,交换反应,氢原子 [author_in] => [CHEN, DZ; JU, GZ]SHANDONG UNIV,THEORET CHEM LAB,JINAN 250100,PEOPLES R CHINA. [company_id] => 0,43,169 [sys_subject_sort] => 0,0 [college_parent_id] => 43,169 [company_test] => Array,Array [author_id] => [author_test] => Array ( ) [sys_author_id_arr] => [jl_publication_cn_publication_en] => 化学学报 [sys_author_id] => [hb_batch] => grant_no [publication_en] => ACTA CHIMICA SINICA [cite_wos] => 1 [check_3Y] => 0 [language] => Chinese [delivery_No] => HJ438 [format_title] => 89cbc120ac9e21a9ff7048bf448acec3880012250 [cauthor_ad] => [CHEN, DZ]SHANDONG NORMAL UNIV,DEPT CHEM,JINAN 250014,PEOPLES R CHINA. [author_fn] => CHEN, DZ; JU, GZ [format_title_en_issn_pub_year] => 01df085a54a65a78733e72746316be802034980152 [publication_29] => ACTA CHIM SINICA [end_page] => 4 [abstract_en] => The reactive and nonreactive inelastic probabilities are calculated for the collisional deexcitation of vibrationally excited HCl (v = 1, 2, 3) molecules by Cl atoms using collinear exact quantum method. The results indicate that the reactive and nonreactive inelastic probabilities oscillate with energy; according to the probability of channels of the reaction and nonreaction it is expected that both reactive and nonreactive inelastic collisions are all equally effective in the deexcitation of HCl (v = 1, 2, 3) by Cl atoms, which is good agreement with the results obtained by Wilkins; the probability has a close relation with the quantum number v of the vibrational states of the HCl, we found P(vv\') almost-equal-to 10(v+v\'-2(v\"+1))P(vv\"), (v > v\' > v\"). This is in good accord with Moor\'s experimental results. [publication_type] => J [begin_page] => 1 [author_en] => CHEN, DZ; JU, GZ [volume] => 50 [get_data] => 2018-08-29 [publisher] => ACTA CHIMICA SINICA [keyword_plu] => CROSS-SECTIONS [format_publication_cn] => 6918be3b26b1fa6ec0424f6071208a75331227575 [publication_iso] => Acta Chim. Sin. [format_title_en_publication_en_pub_year] => 3e216fed2d94e385d609fa5506818fca690478546 [format_title_en] => 2e7c41aa341a07afdbb87636c6c107d5-175292678 [publisher_city] => SHANGHAI [cauthor_order] => 1 [hx_id] => 2371 [reference_No] => 8 [cite_awos] => 1 [wos_No] => WOS:A1992HJ43800001 [format_wos_No] => 8859155b0545c9f6ef95fa2cef2a550a943958879 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [cauthor_back] => CHEN, DZ [check_180] => 0 [publisher_ad] => SHANGHAI INST ORGANIC CHEM ACADEMIA SINICA 345 LINGLING LU, SHANGHAI,; PEOPLES R CHINA [title_en] => DYNAMIC CALCULATIONS ON THE COLLINEAR HYDROGEN-ATOM TRANSFER-REACTION .2. VIBRATIONAL DEEXCITATION OF HCL(UPSILON=1, 2, 3) BY CL ATOMS ON A REACTIVE POTENTIAL-ENERGY SURFACE [format_publication_en] => 169b60c7845c9e5f36906950b18f11111348184734 [id] => HA5HvmUBFjIhTVEbZSTq [tags] => 0 ) [9] => Array ( [issn] => 0567-7351 [delivery_No] => KA500 [batch2] => 1,2 [hb_batch] => 3241 [tag] => 0 [author_en] => SUN, SX; GAO, ZL; SHEN, JL; CHAI, JL [abstract_en] => The kinetics and mechanism of the extraction of gold(III) by primaryamine N1923 or triphenylphosphine oxide (TPPO) in chloroform from hydrochloric acid have been studied in a stirred Lewis\' cell. The experimental results showed that the chemical reactions at the interface are rate-determining steps. The rate constants and activation energies of the reactions were calculated. [publication_type] => J [author_in] => [SUN, SX; GAO, ZL; SHEN, JL; CHAI, JL]SHANDONG NORMAL UNIV,DEPT CHEM,JINAN 250014,PEOPLES R CHINA. [publisher_city] => SHANGHAI [article_id] => 336508,554927,167933 [get_data] => 2018-08-29 [format_title_en_publication_en_pub_year] => 8e91a8811a4e1da508cb19ddda24f541-83957884 [pages] => 6 [cite_wos] => 0 [check_3Y] => 0 [cite_awos] => 0 [from_id] => 80,73,78 [cauthor_ad] => [SUN, SX]SHANDONG UNIV,DEPT CHEM,JINAN 250100,PEOPLES R CHINA. [school_id] => 117 [cauthor_order] => 1 [research_area] => Chemistry [sys_level_num] => 1_7 [publisher] => ACTA CHIMICA SINICA [sys_jg_type] => 0,5 [format_issn_issue_page_pub_year] => 2e926cf835df4e094c567ac7bb92ba2e1841414257 [title_en] => THE EXTRACTION KINETICS OF GOLD(III) BY PRIMARYAMINE N1923 AND TRIPHENYLPHOSPHINE OXIDE .1. THE EXTRACTION OF AUCL4- IN A SYSTEM OF SINGLE EXTRACTANT [publication_29] => ACTA CHIM SINICA [author_fn] => SUN, SX; GAO, ZL; SHEN, JL; CHAI, JL [pub_year] => 1992 [publisher_ad] => SHANGHAI INST ORGANIC CHEM ACADEMIA SINICA 345 LINGLING LU, SHANGHAI,; PEOPLES R CHINA [check_180] => 0 [end_page] => 994 [cauthor_back] => SUN, SX [begin_page] => 989 [format_wos_No] => 90f7402a3c5b2d6c1c85bc01162c0b1d774641464 [hints] => 2 [volume] => 50 [language] => Chinese [source_type] => 351 [issue] => 10 [reference_No] => 1 [batch] => 3250,3241,3252 [publication_en] => ACTA CHIMICA SINICA [hx_id] => 2371 [sys_update_time] => 2018-09-05 15:29:33 [format_title_en_issn_pub_year] => a5e5bf4f5de61141c5c837bc40e10175-916195429 [publication_iso] => Acta Chim. Sin. [wos_sub] => Chemistry, Multidisciplinary [SYS_TAG] => 3 [wos_No] => WOS:A1992KA50000010 [page] => 989-994 [hb_type] => 2 [article_dt] => Article [jl_language] => chinese [jl_publication_en] => actachimicasinica [jl_article_dt] => 期刊论文 [jl_country] => 中国,中国 [jl_publisher] => actachimicasinica [author_jg] => [孙思修;高自立;沈静兰;柴金岭]山东大学化学系,山东大学化学系,山东大学化学系,山东师范大学化学系 济南 250100,济南 250100,济南 250100,济南 250014 [keyword_cn] => 金;溶剂萃取;动力学;伯胺N1923;三苯基氧化膦 [format_title] => f958efa7bde4bef41ea50269bc859c12-837879095 [title_cn] => 伯胺N1923和三苯基氧化膦萃取金(Ⅲ)的动力学 Ⅰ.一元萃取剂体系萃取AuCl_4~- [format_publication_cn] => 6918be3b26b1fa6ec0424f6071208a75331227575 [publication_cn] => 化学学报 [format_title_en] => 14314e6652d792d415e335101f65478f-1964753623 [CSSN] => 31-1320/O6 [abstract_cn] => 研究了伯胺N1923和三苯基氧化膦(TPPO)两个一元萃取剂体系从盐酸介质中萃取AuCl_4~-的动力学.认为两体系的萃取速率均受界面化学反应控制;得到298K时两体系萃取反应的速率常数;计算出萃取反应的活化能. [sys_priority_field] => 73 [author_cn] => 孙思修;高自立;沈静兰;柴金岭; [uri] => http://kns.cnki.net/kns/detail/detail.aspx?FileName=HXXB199210009&DbName=CJFQ1992 [format_publication_en] => 169b60c7845c9e5f36906950b18f11111348184734 [jl_publication_cn] => 化学学报 [jl_keyword_cn] => 伯胺n1923,三苯基氧化膦,动力学,溶剂萃取,金 [company_id] => 43,169 [sys_subject_sort] => 0,0 [college_parent_id] => 43,169 [company_test] => Array,Array [author_id] => [author_test] => Array ( ) [sys_author_id_arr] => [jl_publication_cn_publication_en] => actachimicasinica,化学学报 [jl_keyword_cn_keyword_en] => 金,三苯基氧化膦,动力学,溶剂萃取,伯胺n1923 [sys_author_id] => [format_title_cn_publication_cn_pub_year] => 3aafc05be41a32cfe6cc8c91322688891868461500 [format_title_cn_issn_pub_year] => 6e0ff19a6ca0f7bbce1c2031de6c530e-1428553165 [id] => 6wifvWUBFjIhTVEbIto4 [tags] => 0 ) [10] => Array ( [batch2] => 2 [tag] => 0 [author_en] => CHEN RONGLI~*;WANG LIZENG;LIU PING;LU MAOSUN;YIN PEIYU [keyword_cn] => 三阶导数卷积极谱法;;顺丁烯二酸;;微量分析 [article_id] => 280897,95509,584880 [format_title_en_publication_en_pub_year] => 1ca0581afe1d9d0cb236b4647bf0d6ba954812369 [author_jg] => [陈荣礼;王丽增;刘萍;陆懋荪;尹佩玉]山东大学化学院应化系@@@[陈荣礼;王丽增;刘萍;陆懋荪;尹佩玉]山东大学化学院应化系@@@[陈荣礼;王丽增;刘萍;陆懋荪;尹佩玉]山东大学化学院应化系@@@[陈荣礼;王丽增;刘萍;陆懋荪;尹佩玉]山东大学化学院应化系@@@[陈荣礼;王丽增;刘萍;陆懋荪;尹佩玉]山东大学化学院应化系 济南 250100@@@[陈荣礼;王丽增;刘萍;陆懋荪;尹佩玉]济南 250100@@@[陈荣礼;王丽增;刘萍;陆懋荪;尹佩玉]济南 250100@@@[陈荣礼;王丽增;刘萍;陆懋荪;尹佩玉]济南 250100@@@[陈荣礼;王丽增;刘萍;陆懋荪;尹佩玉]济南 250100 [format_title_cn_publication_cn_pub_year] => da54f618a454abcf7015b4f8a8d193ff1175817345 [hints] => 0 [issue] => 06 [sys_level_num] => 2_2 [sys_jg_type] => 0,5 [format_issn_issue_page_pub_year] => 862ade10659aa04f8debc00d73fffeba-333077758 [title_en] => DETERMINATION OF MALEIC ACID IN FUMARIC ACID BY THIRD DERIVATIVE CONVOLUTED POLAROGRAPHIC WAVE [source_type] => 351 [pub_year] => 1991 [keyword_en] => MALEIC ACID;MICRO ANALYSIS;DERIVATIVE CONVOLUTED;POLAROGRAHY [pub_date] => 1991-06-30 [pages] => 673-676 [from_id] => 80,85,78 [author_cn] => 陈荣礼;王丽增;刘萍;陆懋荪;尹佩玉; [language] => chi [issn] => 1872-2040 [batch] => 3250,3252,3254 [publication_en] => CHINESE JOURNAL OF ANALYTICAL CHEMISTRY [format_title_en_issn_pub_year] => aec8b2066c438327ddde9caa0de360e5-2062434730 [publication_cn] => 分析化学 [title_cn] => 三阶导数卷积极谱法测定反丁烯二酸中的微量顺丁烯二酸 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => b4f2c2d24eed41d2642c419bfaf23b60-122720453 [page] => 673-676 [hb_type] => 2 [article_dt] => 期刊论文 [hb_batch] => title_cn_publication_cn_pub_year_2_3 [author_first] => 陈荣礼; [format_title_en] => 29809b1133650a2b31c8c7315e33c2f7812316039 [format_title] => 28cb8ba914f6f846700e59508c9ac836-1163185337 [CSSN] => 22-1125/O6 [hx_id] => [abstract_cn] => 本文研究了反丁烯二酸试样中微量顺丁烯二酸的测定方法。在pH=6 含8%乙醇0.2mol/L NH_3/NH_4Cl底液中,顺丁烯二酸三阶导数卷积极谱波的峰电位为-1.36V(vs.SCE),浓度线性范围0.07~50μg/ml。允许共存顺式与反式丁烯二酸的浓度比为1∶250。20次测量的相对标准偏差为1.1%。标准回收率在96~103%以内。分析测定结果与气相色谱法一致。总反应电子转移数为2,电极反应不可逆,电极过程有氢离子参与反应。 [uri] => http://kns.cnki.net/kns/detail/detail.aspx?FileName=FXHX199106011&DbName=CJFQ1991 [format_publication_cn] => e7234b1e691affb2eaa0746a4c5ba31a817203325 [format_publication_en] => 5ab27f8faa83b55beffa8c446710d971-1363561487 [jl_language] => chinese [jl_publication_cn] => 分析化学 [jl_article_dt] => 期刊论文 [jl_publication_en] => chinesejournalofanalyticalchemistry [jl_keyword_en] => maleicacid,polarograhy,derivativeconvoluted,microanalysis [jl_keyword_cn] => ,三阶导数卷积极谱法,顺丁烯二酸,微量分析 [author_in] => [company_id] => 43,169 [sys_subject_sort] => 0,0 [college_parent_id] => 43,169 [company_test] => Array,Array [author_id] => [author_test] => Array ( [0] => Array ( [sure] => 0 [irInspect_tag] => 0 [irmagnum] => 0 [irAuthorType] => 0 [name] => 刘萍 [u_index] => 3 [irtag] => 6 [t_index] => 0 [irTsTag] => 0 [irTypical] => 3 [person_id] => 22376 ) [1] => Array ( [sure] => 0 [irInspect_tag] => 0 [irmagnum] => 0 [irAuthorType] => 0 [name] => 刘萍 [u_index] => 3 [irtag] => 6 [t_index] => 0 [irTsTag] => 0 [irTypical] => 3 [person_id] => 22377 ) ) [sys_author_id_arr] => [jl_publication_cn_publication_en] => 分析化学,chinesejournalofanalyticalchemistry [jl_keyword_cn_keyword_en] => 顺丁烯二酸,microanalysis,maleicacid,polarograhy,微量分析,derivativeconvoluted,三阶导数卷积极谱法 [sys_author_id] => [id] => _gs2vmUBFjIhTVEbf1Xa [tags] => 0 ) [11] => Array ( [batch2] => 1,2 [batch] => 3250,3241,3254,3252 [tag] => 0 [abstract_cn] => 本文以 n/n+-Si 和 p/n+-Si 为基底,通过铂、镍等金属膜表面修饰后组成光电化学电池,探讨了金属/n-Si 间的 Schottky 势垒对电池开路光电压的影响.研究了铂膜修饰电极的光电化学性能.用 p/n+-Si 电极,在65mW·cm-2的光照射下,最佳电池的输出参数是:开路光电压0.530 V,短路光电流47.6mA·cm-2,填充因子0.35,光电转换效率13.6%.连续照光75小时,电池性能基本稳定。更多还原 [keyword_cn] => 电化学电池;半导体硅;金属修饰; [clc] => TM914.41 [author_jg] => [李怀祥;王士勋;李国铮]山东大学化学系,中国.@@@[李怀祥]山东师范大学化学系,中国 [format_title_cn_publication_cn_pub_year] => 6cfb181122f478fd3b21d1dad74162551056153470 [from_id] => 80,78,73,85 [issue] => 10 [sys_level_num] => 2_1 [sys_jg_type] => 5 [source_type] => 351 [pub_year] => 1991 [article_id] => 167938,336438,113790,581840 [pages] => 5 [hints] => 2 [author_cn] => 李怀祥[1,2];王士勋[1];李国铮[1]; [issn] => 0567-7351 [uri] => http://lib.cqvip.com/qk/91047X/199110/526687.html [publication_cn] => 化学学报 [title_cn] => 金属修饰半导体硅组成光电化学电池的研究 [CSSN] => 31-1320/O6 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => 9fc99a7a72fd32205b182527c03a0a471881266441 [hb_type] => 2 [jl_publication_cn] => 化学学报 [jl_country] => 中国 [jl_keyword_cn] => 金属修饰,,电化学电池,半导体硅 [jl_clc] => tm91441 [author_in] => [company_id] => 43,169 [author_id] => [author_test] => Array ( ) [sys_author_id_arr] => [jl_publication_cn_publication_en] => 化学学报 [sys_author_id] => [hb_batch] => grant_no [author_first] => 李怀祥; [publication_en] => ACTA CHIMICA SINICA [cite_wos] => 3 [check_3Y] => 0 [language] => Chinese [delivery_No] => GR218 [format_title] => ac2b6f512f15f9f6c3a08fca4bcbd095-105289205 [cauthor_ad] => [LI, HX]SHANDONG UNIV, DEPT CHEM, JINAN 250100, PEOPLES R CHINA. [author_fn] => LI, HX; WANG, SX; LI, GZ [format_title_en_issn_pub_year] => 056e4a677dcf941886162d0bace4fe51-412620524 [publication_29] => ACTA CHIM SINICA [end_page] => 1002 [abstract_en] => Photoelectrochemical cells based n/n+-Si or p/n+-Si are described. The effect of Schottky barrier on the open-circuit photovoltage was studied. Under the irradiation with the light intensity of 65 mW.cm-2, optimized output parameters of p/n+-Si cell were found to be as follows, V(oc), 0.530 V; I(sc), 47.6 mA.cm-2; fill factor, 0.35; light-electric energy converscion efficiency, 13.6% and some of the photoelectrochemical cells ware still stable while the irradiation continued for 75 hours. [publication_type] => J [begin_page] => 998 [article_dt] => Article [author_en] => LI, HX; WANG, SX; LI, GZ [volume] => 49 [get_data] => 2018-08-29 [publisher] => SCIENCE PRESS [page] => 998-1002 [keyword_plu] => SEMICONDUCTOR ELECTRODES; ENERGY-CONVERSION; SI; PHOTOVOLTAGES; PHOTOANODES [format_publication_cn] => 6918be3b26b1fa6ec0424f6071208a75331227575 [publication_iso] => Acta Chim. Sin. [format_title_en_publication_en_pub_year] => 9593faee26c09e67759ce97b232277e3-1846238737 [format_title_en] => 96e06825c3471c1ba211c30ce873bfca-1665035059 [publisher_city] => BEIJING [cauthor_order] => 1 [hx_id] => 2371 [reference_No] => 10 [format_issn_issue_page_pub_year] => 82649f0defaf738cbfc53a3c595edc72-536443100 [cite_awos] => 4 [wos_No] => WOS:A1991GR21800011 [format_wos_No] => a24005413dafd21951f1f072f327b8f7257515349 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [cauthor_back] => LI, HX [check_180] => 0 [publisher_ad] => 16 DONGHUANGCHENGGEN NORTH ST, BEIJING 100717, PEOPLES R CHINA [title_en] => A STUDY ON PHOTOELECTROCHEMICAL CELLS BASED ON SILICON MODIFIED BY METAL-FILMS [format_publication_en] => 169b60c7845c9e5f36906950b18f11111348184734 [jl_article_dt] => 期刊论文 [sys_subject_sort] => 0,0 [college_parent_id] => 43,169 [company_test] => Array,Array [id] => xQkvvmUBFjIhTVEbDEno [tags] => 0 ) [12] => Array ( [batch2] => 1,2 [batch] => 3250,3241,3254,3252 [tag] => 0 [CSSN] => 31-1320/O6 [keyword_cn] => 萃合物;硫氰酸盐;水相;SCN;硫氰化物;硫化合物;摩尔浓度;克分子浓度;N1923;胺盐;初始浓度;Ni;伯胺;一级胺; [article_id] => 336433,620582,68845,187228 [abstract_cn] => 298±1K下考察了伯胺N1923(B)与其硫氰酸盐共存,用煤油作稀释剂时,从1.00mol·dm~(-3)(Na,H)SCN水相中萃取Co(Ⅱ)或Ni(Ⅱ)的平衡.萃合物组成为(BH)_2M(SCN)_4·xB,x最大为4. [author_jg] => [高自立;孙思修;施新超;朱靖江;阮红;沈静兰]山东大学化学系,山东大学化学系,山东大学化学系,山东大学化学系,山东大学化学系,山东大学化学系 济南 250100,济南 250100,济南 250100 上海水产大学加工系,济南 250100 南通师专,济南 250100,济南 250100 [format_title_cn_publication_cn_pub_year] => 1d0c0c0d078d7897d35badb10ed57c79-105210867 [hints] => 3 [issue] => 3 [sys_level_num] => 2_3 [sys_jg_type] => 5 [format_issn_issue_page_pub_year] => 50f37224e7b2134dba6c8f7f9f3d668c1574450889 [source_type] => 351 [pub_year] => 1991 [pub_date] => 1991-04-01 [pages] => 5 [from_id] => 80,78,73,85 [author_cn] => 高自立;孙思修;施新超;朱靖江;阮红;沈静兰; [issn] => 0567-7351 [uri] => http://kns.cnki.net/kns/detail/detail.aspx?FileName=HXXB199103006&DbName=CJFQ1991 [publication_cn] => 化学学报 [title_cn] => 伯胺N1923萃取Co(Ⅱ)Ni(Ⅱ)的平衡 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => e3519ff0afe2df3372b9b73c86e33659-2056528818 [page] => 244-248 [hb_type] => 2 [article_dt] => Article [hb_batch] => title_cn_publication_cn_pub_year_2_3 [format_title_en] => 3d6cbb8afec82e13bbf150420d9092e3-677145877 [format_title] => 7845cee5e2992e89291daa5ecabccde5-1083214040 [hx_id] => 2371 [format_publication_cn] => 6918be3b26b1fa6ec0424f6071208a75331227575 [format_publication_en] => 169b60c7845c9e5f36906950b18f11111348184734 [jl_publication_cn] => 化学学报 [jl_article_dt] => 期刊论文 [jl_keyword_cn] => 萃合物,ni,克分子浓度,硫氰酸盐,水相,硫氰化物,n1923,一级胺,胺盐,初始浓度,伯胺,scn,摩尔浓度,硫化合物, [author_in] => [company_id] => 0,43,169 [author_id] => [author_test] => Array ( ) [sys_author_id_arr] => [jl_publication_cn_publication_en] => 化学学报 [jl_keyword_cn_keyword_en] => ni,硫氰化物,scn,水相,n1923,萃合物,硫化合物,克分子浓度,一级胺,硫氰酸盐,初始浓度,摩尔浓度,胺盐,伯胺 [sys_author_id] => [publication_en] => ACTA CHIMICA SINICA [cite_wos] => 3 [check_3Y] => 0 [language] => Chinese [delivery_No] => FW890 [cauthor_ad] => [GAO, ZL]SHANDONG UNIV,DEPT CHEM,JINAN 250100,PEOPLES R CHINA. [author_fn] => GAO, ZL; SUN, SX; SHI, XC; ZHU, JJ; RUAN, H; SHEN, JL [format_title_en_issn_pub_year] => e4f4369c6b4d6a1f9556dedf788f4c761896551640 [publication_29] => ACTA CHIM SINICA [end_page] => 248 [abstract_en] => The extraction of the systems M2+/1.00 mol.dm-3 (H, Na) SCN-N1923 (B)-kerosene has been studied at 298 +/- 1 K. When both B and BHSCN are present in organic phase, the reaction is as follows: M2+ + 4SCN- + 2H+ + (x + 2)B(o) reversible (BH) 2M (SCN)4.x(B)(o) where x = 0 - 4. When only BHSCN is present in organic phase, the extraction of Co(II) is poor and Ni(II) can not be extracted. The extraction of Co(II) by BHSCN is as follows: Co2+ + 2SCN- + 2BHSCN(o) reversible (BH)2Co(SCN)4(o). The lack of free amine N1923(B) in organic phase is the reason of poor extractability of Co(II) in this case. And the nonextractability of Ni(II) by BHSCN is due to the presence of Ni(SCN)4.2H2O2- in the aqueous phase. When two coordination water molecules of the species Ni(SCN)4.2H2O2- are replaced by amine N1923 molecules, the extractability of Ni(II) will be enhanced. This can be observed from the result of Ni(II) extraction in the presence of B and BHSCN in organic phase. [publication_type] => J [begin_page] => 244 [author_en] => GAO, ZL; SUN, SX; SHI, XC; ZHU, JJ; RUAN, H; SHEN, JL [volume] => 49 [get_data] => 2018-08-29 [publisher] => ACTA CHIMICA SINICA [publication_iso] => Acta Chim. Sin. [format_title_en_publication_en_pub_year] => d7a9b7375ebfad8dfe470b321075153c742425575 [publisher_city] => SHANGHAI [cauthor_order] => 1 [reference_No] => 2 [cite_awos] => 3 [wos_No] => WOS:A1991FW89000007 [format_wos_No] => ff37739c53ded93f412e490609813581336082322 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [cauthor_back] => GAO, ZL [check_180] => 0 [publisher_ad] => SHANGHAI INST ORGANIC CHEM ACADEMIA SINICA 345 LINGLING LU, SHANGHAI,; PEOPLES R CHINA [title_en] => THE EXTRACTION EQUILIBRIA OF COBALT(II) AND NICKEL(II) WITH PRIMARY AMINE N1923 [sys_subject_sort] => 0,0 [college_parent_id] => 43,169 [company_test] => Array,Array [id] => sQ1GvmUBFjIhTVEbGdA3 [tags] => 0 ) [13] => Array ( [batch2] => 1,2 [batch] => 3250,3241,3252 [tag] => 0 [CSSN] => 31-1320/O6 [keyword_cn] => 配位反应;生成常数;冠醚;环醚;热力学性质;物理性能;镧系;二苯并;高氯酸盐; [article_id] => 167937,336435,648252 [abstract_cn] => 用滴定量热计于298.15 K测定了除钷、镥以外的全部十三种镧系(Ⅲ)高氯酸盐与二苯并-18-冠-6在无水乙腈中的配位作用.借助计算机用自编程序算出了配位反应的生成常数和焓变,进而算出了配位反应的自由能变化和熵变化.探讨了镧系(Ⅲ)阳离子对配位反应的影响.此外,还比较了几种不同冠醚与高氯酸镧在无水乙腈中配位反应的热力学性质. [author_jg] => [黄锡荣;蒋本杲;尹敬执;阎海科]山东大学化学系,山东大学化学系,山东大学化学系,中国科学院化学研究所 济南 250100,济南 250100,济南 250100,北京 100080 [format_title_cn_publication_cn_pub_year] => 864c17cc49b65f36ea369d021ec61b571317171837 [hints] => 4 [issue] => 4 [sys_level_num] => 2_3 [sys_jg_type] => 5 [format_issn_issue_page_pub_year] => 5c68f3ed77e12a2d13429a8c988bbd40957353560 [source_type] => 351 [pub_year] => 1991 [pub_date] => 1991-05-01 [pages] => 6 [from_id] => 80,73,78 [author_cn] => 黄锡荣;蒋本杲;尹敬执;阎海科; [issn] => 0567-7351 [uri] => http://kns.cnki.net/kns/detail/detail.aspx?FileName=HXXB199104008&DbName=CJFQ1991 [publication_cn] => 化学学报 [title_cn] => 稀土(Ⅲ)-冠醚配位反应的热力学性质 Ⅱ. 镧系(Ⅲ)高氯酸盐与二苯并18-冠-6在无水乙腈中配位反应的量热滴定研究 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => 261ef99a237c0aad71e939dfc8ce05b4764849422 [page] => 359-364 [hb_type] => 2 [article_dt] => Article [jl_publication_cn] => 化学学报 [jl_article_dt] => 期刊论文 [jl_keyword_cn] => ,环醚,镧系,物理性能,配位反应,高氯酸盐,生成常数,二苯并,冠醚,热力学性质 [author_in] => [HUANG, XR; JIANG, BG; YIN, JZ; YAN, HK]ACAD SINICA,INST CHEM,BEIJING 100080,PEOPLES R CHINA. [company_id] => 0,43,169 [author_id] => 21289 [author_test] => Array ( [0] => Array ( [sure] => 0 [irmagnum] => 0 [u_index] => 1 [name] => 黄锡荣 [irtag] => 7 [t_index] => 0 [person_id] => 21289 ) ) [sys_author_id_arr] => [jl_publication_cn_publication_en] => 化学学报 [jl_keyword_cn_keyword_en] => 配位反应,镧系,物理性能,高氯酸盐,二苯并,环醚,生成常数,冠醚,热力学性质 [sys_author_id] => [hb_batch] => grant_no [publication_en] => ACTA CHIMICA SINICA [cite_wos] => 6 [check_3Y] => 2 [language] => Chinese [delivery_No] => FV356 [format_title] => f0ea57b7feb70828ecb0cfd63d3b245e-549700517 [cauthor_ad] => [HUANG, XR]SHANDONG UNIV,DEPT CHEM,JINAN 250100,PEOPLES R CHINA. [author_fn] => HUANG, XR; JIANG, BG; YIN, JZ; YAN, HK [format_title_en_issn_pub_year] => 1d747f70791907c9cb7816af829f9028158479968 [publication_29] => ACTA CHIM SINICA [end_page] => 364 [abstract_en] => The coordination reactions of dibenzo-18-crown-6 with lanthanide perchlorates except Pm, Lu in anhydrous acetonitrile were investigated at 298.15 K by titration calorimeter. The formation constants and enthalpies of coordination reactions were calculated using computer program made by ourselves. The changes of free energy and entropy of every coordination reaction were obtained. The influences of lanthanide cations (III) on the coordination reactions were discussed. Comparisons were also made on the thermodynamic properties for coordination reaction of lanthanum perchlorate with dibenzo-18-crown-6 and with other crowns in anhydrous acetonitrile, respectively. [publication_type] => J [begin_page] => 359 [author_en] => HUANG, XR; JIANG, BG; YIN, JZ; YAN, HK [volume] => 49 [get_data] => 2018-08-29 [publisher] => ACTA CHIMICA SINICA [keyword_plu] => MACROCYCLIC LIGANDS; COMPLEXES; 15-CROWN-5; 18-CROWN-6; POLYETHERS; CATIONS [format_publication_cn] => 6918be3b26b1fa6ec0424f6071208a75331227575 [publication_iso] => Acta Chim. Sin. [format_title_en_publication_en_pub_year] => 56933f5cfe87fb6c0f5d9d340eb52ff5-97608163 [format_title_en] => 2247946979f800c6f518db961a4b531a68710459 [publisher_city] => SHANGHAI [cauthor_order] => 1 [hx_id] => 2371 [reference_No] => 13 [cite_awos] => 8 [wos_No] => WOS:A1991FV35600009 [format_wos_No] => 95dc7dd5e57c41057811e522888265c4-1470588439 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [cauthor_back] => HUANG, XR [check_180] => 0 [publisher_ad] => SHANGHAI INST ORGANIC CHEM ACADEMIA SINICA 345 LINGLING LU, SHANGHAI,; PEOPLES R CHINA [title_en] => THERMODYNAMIC PROPERTIES OF RARE EARTH(III)-CROWNETHER COORDINATION REACTIONS .2. CALORIMETRIC TITRATION STUDIES ON COORDINATION REACTIONS OF LANTHANIDE PERCHLORATES WITH DIBENZO-18-CROWN-6 IN ANHYDROUS ACETONITRILE [format_publication_en] => 169b60c7845c9e5f36906950b18f11111348184734 [sys_subject_sort] => 0,0 [college_parent_id] => 43,169 [company_test] => Array,Array [id] => gg1EvmUBFjIhTVEbKmEG [tags] => 0 ) [14] => Array ( [batch2] => 1,2 [batch] => 3250,3241,3252 [tag] => 0 [CSSN] => 31-1320/O6 [keyword_cn] => 亚稳态;传能;相对分布;激发态;产物;光谱图;He;CH_3l;解离;分子;反应;激发过程;碎片;Br; [article_id] => 539388,336436,167939 [abstract_cn] => 本文利用流动余辉技术研究了亚稳态He(2~3S)与CH_3I和CH_3Br传能时分子的解离激发过程.实验中测定了产物的相对分布、CH(A,υ′=O)的转动布居和主要碎片的形成速率常数. [author_jg] => [郭敬忠;顾月姝;刘传朴;李保中;印永嘉;曹德兆;蔡继业]山东大学化学系,山东大学化学系,山东大学化学系,山东大学化学系,山东大学化学系,中国科学院安徽光学精密机械研究所,中国科学院安徽光学精密机械研究所 济南 250100,济南 250100,济南 250100,济南 250100,济南 250100,合肥 230031,合肥 230031 [format_title_cn_publication_cn_pub_year] => 03b64ccc0119974fb8ceaa5352c7d26a29207751 [hints] => 3 [issue] => 5 [sys_level_num] => 2_3 [sys_jg_type] => 5 [format_issn_issue_page_pub_year] => b89815e20ab0296bc78fb7e67b83f6b3-836408909 [source_type] => 351 [pub_year] => 1991 [pub_date] => 1991-05-31 [pages] => 6 [from_id] => 80,73,78 [author_cn] => 郭敬忠;顾月姝;刘传朴;李保中;印永嘉;曹德兆;蔡继业; [issn] => 0567-7351 [uri] => http://kns.cnki.net/kns/detail/detail.aspx?FileName=HXXB199105007&DbName=CJFQ1991 [publication_cn] => 化学学报 [title_cn] => He(2~3S)与CH_3l和CH_3Br在流动余辉中传能的解离激发反应 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => ed7dafc4e6cf955ee1940f1e82e5984a-229228999 [page] => 456-461 [hb_type] => 2 [article_dt] => Article [jl_publication_cn] => 化学学报 [jl_article_dt] => 期刊论文 [jl_keyword_cn] => ,相对分布,反应,光谱图,亚稳态,解离,分子,碎片,激发过程,br,ch3l,传能,产物,激发态,he [author_in] => [GUO, JZ; GU, YZ; LIU, CP; LI, BZ; YIN, YJ; CAO, DZ; CAI, JY]ACAD SINICA,ANHUI INST OPT & FINE MECH,HEFEI 230031,PEOPLES R CHINA. [company_id] => 0,43,169 [author_id] => [author_test] => Array ( ) [sys_author_id_arr] => [jl_publication_cn_publication_en] => 化学学报 [sys_author_id] => [hb_batch] => grant_no [publication_en] => ACTA CHIMICA SINICA [cite_wos] => 0 [check_3Y] => 0 [language] => Chinese [delivery_No] => FV412 [format_title] => c6810c39614fbdc103d4d62b6a8e9a35-1458391458 [cauthor_ad] => [GUO, JZ]SHANDONG UNIV,DEPT CHEM,JINAN 250100,PEOPLES R CHINA. [author_fn] => GUO, JZ; GU, YZ; LIU, CP; LI, BZ; YIN, YJ; CAO, DZ; CAI, JY [format_title_en_issn_pub_year] => ebc2df52d339f28eef71871cde06694b-2023471705 [publication_29] => ACTA CHIM SINICA [end_page] => 461 [abstract_en] => The dissociative excitation of CH3I and CH3Br is investigated by Helium flowing afterglow technique. We estimated the relative populations of various electronically excited products. The formation rate constants of CH(A), CH(B) and CH(C) are obtained from reaction He(2(3)S) + CH3I. The rotational populations of CH(A2-DELTA, upsilon\' = 0) can be represented in terms of a Boltzmann distribution. [publication_type] => J [begin_page] => 456 [author_en] => GUO, JZ; GU, YZ; LIU, CP; LI, BZ; YIN, YJ; CAO, DZ; CAI, JY [volume] => 49 [get_data] => 2018-08-29 [publisher] => ACTA CHIMICA SINICA [keyword_plu] => PENNING IONIZATION; ATOMS [format_publication_cn] => 6918be3b26b1fa6ec0424f6071208a75331227575 [publication_iso] => Acta Chim. Sin. [format_title_en_publication_en_pub_year] => 456075cbf6ceb1b7950239ba8af12492618904243 [format_title_en] => ed712d915dbfa1a7be5c5d3f480ac29c1068675767 [publisher_city] => SHANGHAI [cauthor_order] => 1 [hx_id] => 2371 [reference_No] => 15 [cite_awos] => 0 [wos_No] => WOS:A1991FV41200008 [format_wos_No] => a584c6d77e8de9873000b7da01de2178-1169897885 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [cauthor_back] => GUO, JZ [check_180] => 0 [publisher_ad] => SHANGHAI INST ORGANIC CHEM ACADEMIA SINICA 345 LINGLING LU, SHANGHAI,; PEOPLES R CHINA [title_en] => THE DISSOCIATION EXCITATION REACTION OF CH3I AND CH3BR IN HELIUM FLOWING AFTERGLOW [format_publication_en] => 169b60c7845c9e5f36906950b18f11111348184734 [sys_subject_sort] => 0,0 [college_parent_id] => 43,169 [company_test] => Array,Array [id] => 6A9KvmUBFjIhTVEbYAQa [tags] => 0 ) [15] => Array ( [batch2] => 2 [tag] => 0 [author_en] => TIAN YUJIN LIU GUOQING ZHANG KECONG [keyword_cn] => Study on the Laser Crystal of ZnWO_4;nm; [article_id] => 174058,637444 [format_title_en_publication_en_pub_year] => 070bdc58bd021c46435ce800fcefd9201037770809 [author_jg] => [田玉金,刘国庆,张克从,刘明果,陆宝生]Department of Chemistry, Beijing Polytechnic University, 100022,Department of Chemistry, Beijing Polytechnic University, 100022,Department of Chemistry, Beijing Polytechnic University, 100022,Institute of Crystal Materials, Shandong University, Jinan, 250 [format_title_cn_publication_cn_pub_year] => 2a5a656987d8c95f3bab2b699e364af8-1772370650 [hints] => 2 [issue] => Z1 [sys_level_num] => 2_2 [sys_jg_type] => 0,5 [format_issn_issue_page_pub_year] => b9b24357ea25558393fed5493adfcd37-838436468 [title_en] => STUDY ON THE LASER CRYSTAL OF ZNWO_4:ER [source_type] => 351 [pub_year] => 1991 [pub_date] => 1991-12-31 [pages] => 1 [from_id] => 80,78 [author_cn] => 田玉金,刘国庆,张克从,刘明果,陆宝生 [language] => chi [issn] => 1000-985X [batch] => 3250,3252 [publication_en] => JOURNAL OF SYNTHETIC CRYSTALS [format_title_en_issn_pub_year] => 94e5037b1371de4ff32f32fcba65e7ff451456938 [publication_cn] => 人工晶体学报 [title_cn] => Study on the Laser Crystal of ZnWO_4:Er [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => 94e5037b1371de4ff32f32fcba65e7ff451456938 [page] => 239 [hb_type] => 2 [article_dt] => 期刊论文 [hb_batch] => title_cn_publication_cn_pub_year_2_3 [format_title_en] => 0e7af488e4a887d63db44568fb7dd608-1176454266 [format_title] => 0e7af488e4a887d63db44568fb7dd608-1176454266 [CSSN] => 11-2637/O7 [hx_id] => [abstract_cn] => The laset of Er~(3+) ion has had people\\\'s attention because of its excellent properties and application. So we grew out crystal of ZnWO_4:Er and measured its absorption, excitation and emission spectra. We can see from the absorption spectrum that the absorption of Er~(3+) ion in ZnWO_4 crystal ... [uri] => http://kns.cnki.net/kns/detail/detail.aspx?FileName=RGJT1991Z1067&DbName=CJFQ1991 [format_publication_cn] => abcb79b40b4f4a7f3e815c680ccb863d-1343701553 [format_publication_en] => 2b9e316eb570c7d953f4358bb1d50569818691304 [jl_language] => chinese [jl_publication_cn] => 人工晶体学报 [jl_publication_en] => journalofsyntheticcrystals [jl_article_dt] => 期刊论文 [jl_keyword_cn] => ,studyonthelasercrystalofznwo4,nm [author_in] => [company_id] => 24,151,43,169 [sys_subject_sort] => 0,0,0,0 [college_parent_id] => 24,151,43,169 [company_test] => Array,Array,Array,Array [author_id] => [author_test] => Array ( ) [sys_author_id_arr] => [jl_publication_cn_publication_en] => journalofsyntheticcrystals,人工晶体学报 [sys_author_id] => [id] => WAw9vmUBFjIhTVEbSfG8 [tags] => 0 ) [16] => Array ( [batch2] => 1,2 [batch] => 3250,3241,3252 [tag] => 0 [CSSN] => 31-1320/O6 [keyword_cn] => 配合物;第一个;积分法;微分法;计算方法;Ln;热分解反应机理;热分解反应动力学;非等温动力学;函数;NCS;热分解动力学;吸热峰;DSC;NH;CH; [article_id] => 336437,187224,598064 [abstract_cn] => 本文利用非等温DSC曲线对十二种镧系元素异硫氰酸盐与苄胺形成的配合物Ln(NCS)_2.4C_6H_5CH_2NH_2(Ln=La、Pr、Nd、Sm、Eu、Gd、Tb、Dy、Ho、Er、Tm、Yb)进行了非等温动力学研究,并运用积分法和微分法进行了分析,推断了它们的热分解反应机理函数,当Ln=La、Pr、Nd、Sm、Eu、Gd时,配合物的热分解动力学方程式da/dt=A·e~(-E/RT·3)(1-α)~(2/3);当Ln=Tb、Dy、Ho、Er、Tm、Yb时,则为dα/dt=A·e~(-E/RT·)(1-α),呈现“钆断”现象.此外还得到了该系列配合物的热分解反应动力学补偿效应表达式. [author_jg] => [杨淑荣;张建华;蒋本杲;杨兆荷]山东大学化学院,山东大学化学院,山东大学化学院,山东大学晶体材料研究所 济南 250100,济南 250100,济南 250100,济南 250100 [format_title_cn_publication_cn_pub_year] => 6fbec1a5b71ac6832caad0684a19a6ed-687723202 [hints] => 4 [issue] => 6 [sys_level_num] => 2_3 [sys_jg_type] => 5 [format_issn_issue_page_pub_year] => 7baa7313ad7ac433c3bcdb396e129d51-430494833 [source_type] => 351 [pub_year] => 1991 [pub_date] => 1991-06-30 [pages] => 8 [from_id] => 80,73,78 [author_cn] => 杨淑荣;张建华;蒋本杲;杨兆荷; [issn] => 0567-7351 [uri] => http://kns.cnki.net/kns/detail/detail.aspx?FileName=HXXB199106000&DbName=CJFQ1991 [publication_cn] => 化学学报 [title_cn] => 用非等温DSC曲线确定Ln(NCS)_3·4C_6H_5CH_2NH_2的热分解反应机理函数及热分解反应动力学参数 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => b9369a8696db6628954266c29f4d13de-769064542 [page] => 521-528 [hb_type] => 2 [article_dt] => Article [jl_publication_cn] => 化学学报 [jl_article_dt] => 期刊论文 [jl_keyword_cn] => nh,,ch,第一个,热分解动力学,ln,ncs,配合物,dsc,微分法,吸热峰,热分解反应机理,计算方法,热分解反应动力学,函数,非等温动力学,积分法 [author_in] => [YANG, SR; ZHANG, JH; JIANG, BG; YANG, ZH]SHANDONG UNIV,INST CRYSTAL MAT,JINAN 250100,PEOPLES R CHINA. [company_id] => 24,0,151,43,169 [sys_subject_sort] => 0,0,0,0 [college_parent_id] => 24,151,43,169 [company_test] => Array,Array,Array,Array [author_id] => [author_test] => Array ( [0] => Array ( [sure] => 0 [irInspect_tag] => 0 [irmagnum] => 0 [irAuthorType] => 0 [name] => 张建华 [u_index] => 2 [irtag] => 6 [t_index] => 0 [irTsTag] => 0 [irTypical] => 3 [person_id] => 25450 ) ) [sys_author_id_arr] => [jl_publication_cn_publication_en] => 化学学报 [sys_author_id] => [hb_batch] => grant_no [publication_en] => ACTA CHIMICA SINICA [cite_wos] => 0 [check_3Y] => 0 [language] => Chinese [delivery_No] => FX904 [format_title] => 0d18605accdc96c95fb194f5fd9e226d-623337836 [cauthor_ad] => [YANG, SR]SHANDONG UNIV,SCH CHEM,JINAN 250100,PEOPLES R CHINA. [author_fn] => YANG, SR; ZHANG, JH; JIANG, BG; YANG, ZH [format_title_en_issn_pub_year] => 718b03c65938a07f0147dbb6980d16281741218760 [publication_29] => ACTA CHIM SINICA [end_page] => 528 [abstract_en] => In this paper, the kinetics of thermal decomposition of the complexes Ln(NCS)3. 4C6H5CH2NH2 (Ln = La, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb) were studied under non-isothermal condition by DSC curves. Kinetic parameters were obtained from analysis of the DSC curves by integral\'s method and differential\'s method. The possible reaction mechanisms were suggested by comparison of the kinetic parameters. Their kinetic equations may be expressed as: da/dt = Ae(-E/RT).3(1 - alpha)2/3 when Ln = La, Pr, Nd, Sm, Eu, Gd. da/dt = Ae(-E/RT).(1 - alpha) when Ln = Tb, Dy, Ho, Er, Tm, Yb. The \"Gadolinium-block\" is observed. The mathematical expression of the kinetic compensation effects of these thermal decomposition reactions had been obtained. [publication_type] => J [begin_page] => 521 [author_en] => YANG, SR; ZHANG, JH; JIANG, BG; YANG, ZH [volume] => 49 [get_data] => 2018-08-29 [publisher] => ACTA CHIMICA SINICA [keyword_plu] => COMPENSATION [format_publication_cn] => 6918be3b26b1fa6ec0424f6071208a75331227575 [publication_iso] => Acta Chim. Sin. [format_title_en_publication_en_pub_year] => 52493bb8f355abfaa41595d69ad46a651565833301 [format_title_en] => 67b8f5ff3880e21cd33185b1556401dc535320029 [publisher_city] => SHANGHAI [cauthor_order] => 1 [hx_id] => 2371 [reference_No] => 6 [cite_awos] => 0 [wos_No] => WOS:A1991FX90400001 [format_wos_No] => 90441051c278fbda1084515622020740-529442771 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [cauthor_back] => YANG, SR [check_180] => 0 [publisher_ad] => SHANGHAI INST ORGANIC CHEM ACADEMIA SINICA 345 LINGLING LU, SHANGHAI,; PEOPLES R CHINA [title_en] => THE DETERMINATION OF THE MOST PROBABLE MECHANISM FUNCTIONS AND KINETIC-PARAMETERS OF THE THERMAL-DECOMPOSITION REACTION OF COMPLEXES OF RARE-EARTH ISOTHIOCYANATES WITH ENZYLAMINE BY NONISOTHERMAL DSC CURVES [format_publication_en] => 169b60c7845c9e5f36906950b18f11111348184734 [id] => 3A5HvmUBFjIhTVEbZySy [tags] => 0 ) [17] => Array ( [batch2] => 2 [tag] => 0 [author_en] => WANG LAIFENG [keyword_cn] => 钛白代用品;;填料改性;;高岭土 [article_id] => 244122,68967,525625 [format_title_en_publication_en_pub_year] => cd0ef5fc8e27ae66ad1aa7c474a31d1f-500985199 [author_jg] => [王来锋]山东省分析测试中心@@@[王果庭]山东大学化学院 [format_title_cn_publication_cn_pub_year] => e576ea9f33e984ac18747fdf294712ab-108992554 [hints] => 0 [issue] => 04 [sys_level_num] => 2_2 [sys_jg_type] => 0,5 [format_issn_issue_page_pub_year] => a4a863e5a62655e37de9b4efc4ccca15-1958413638 [title_en] => THE STUDIES OF A TITANIA EXTENDER [source_type] => 351 [pub_year] => 1990 [keyword_en] => TITANIN SUBSTITUTE;FILLER MODIFICATION;KAOLIN [pub_date] => 1990-12-31 [pages] => 9-12 [from_id] => 80,85,78 [author_cn] => 王来锋;王果庭; [language] => chi [issn] => 1002-4026 [batch] => 3250,3252,3254 [publication_en] => SHANDONG SCIENCE [format_title_en_issn_pub_year] => d793d4fab478249af2f4a848cf46f098-70205928 [publication_cn] => 山东科学 [title_cn] => 钛白增量剂的研究 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => 81b8161e88f9af031375e91e201aae97551512952 [page] => 9-12 [hb_type] => 2 [article_dt] => 期刊论文 [hb_batch] => title_cn_publication_cn_pub_year_2_3 [author_first] => 王来锋; [format_title_en] => d445ebd9d774710ca20bd0b5e96b0f5d1419985362 [format_title] => c58b44c2a030f912f64d32f596b3528d1098242075 [CSSN] => 37-1188/N [hx_id] => [abstract_cn] => 本文研究了一种钛白增量剂的制备方法。高岭土经筛选、超细粉碎、二氧化钛包膜处理,使之具有相当的颜料性能,在造纸、塑料、橡胶中可代替钛白。本文对填料的功能化技术进行了初步的尝试。 [uri] => http://kns.cnki.net/kns/detail/detail.aspx?FileName=SDKX199004002&DbName=CJFQ1990 [format_publication_cn] => 8f8e51434bec8777ef2f59b823ac5bd61509739041 [format_publication_en] => c7ca146fbf33c26e09b074967501534c426064357 [jl_language] => chinese [jl_publication_cn] => 山东科学 [jl_article_dt] => 期刊论文 [jl_publication_en] => shandongscience [jl_keyword_en] => titaninsubstitute,fillermodification,kaolin [jl_keyword_cn] => ,高岭土,钛白代用品,填料改性 [author_in] => [company_id] => 43,169 [sys_subject_sort] => 0,0 [college_parent_id] => 43,169 [company_test] => Array,Array [author_id] => [author_test] => Array ( ) [sys_author_id_arr] => [jl_publication_cn_publication_en] => shandongscience,山东科学 [jl_keyword_cn_keyword_en] => fillermodification,titaninsubstitute,填料改性,钛白代用品,高岭土,kaolin [sys_author_id] => [id] => CAs4vmUBFjIhTVEb-eDV [tags] => 0 ) [18] => Array ( [batch2] => 2 [tag] => 0 [keyword_cn] => 热分解;分解反应;非等温动力学;DSC;配合物;曲线研究;异硫氰酸;氢酸; [article_id] => 239668,552372 [author_jg] => [杨淑荣;蒋本杲;杨兆荷]山东大学化学院,山东大学化学院,山东大学晶体材料研究所 济南 250100,济南 250100,济南 [format_title_cn_publication_cn_pub_year] => d2d311156b2262574ddeda89ac935e1f1154037440 [hints] => 0 [issue] => 09 [sys_level_num] => 2_2 [sys_jg_type] => 0,5 [format_issn_issue_page_pub_year] => 508e6929193ea78787b4548b30e9b2991916631032 [source_type] => 351 [pub_year] => 1990 [pub_date] => 1990-09-28 [pages] => 4 [from_id] => 80,78 [author_cn] => 杨淑荣;蒋本杲;杨兆荷; [language] => chi [issn] => 0441-3776 [batch] => 3250,3252 [publication_en] => CHEMISTRY [publication_cn] => 化学通报 [title_cn] => 用非等温DSC曲线研究异硫氰酸钇苄胺配合物的热分解非等温反应动力学 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => 44c3bce51e23b611ed4dd70056fa2218-512642016 [page] => 40-43 [hb_type] => 2 [article_dt] => 期刊论文 [hb_batch] => title_cn_publication_cn_pub_year_2_3 [format_title_en] => [format_title] => cd237887f7479c0b1eb37cf21dd3a1481033644542 [CSSN] => 11-1804/O6 [hx_id] => [abstract_cn] => 利用DSC曲线研究热分解反应动力学的报道还不多。本文利用一条非等温DSC曲线,将积分法和微分法相结合,对异硫氰酸钇与苄胺形成的配合物的热分解进行了非等温动力学 [uri] => http://kns.cnki.net/kns/detail/detail.aspx?FileName=HXTB199009011&DbName=CJFQ1990 [format_publication_cn] => 90c6a717a719c47d3b45b2cb7357db17-405779104 [format_publication_en] => dce09f281c35f49c2f58ea7580b530b71737319721 [jl_language] => chinese [jl_publication_cn] => 化学通报 [jl_publication_en] => chemistry [jl_article_dt] => 期刊论文 [jl_keyword_cn] => 氢酸,热分解,,配合物,异硫氰酸,dsc,曲线研究,分解反应,非等温动力学 [author_in] => [company_id] => 24,151,43,169 [sys_subject_sort] => 0,0,0,0 [college_parent_id] => 24,151,43,169 [company_test] => Array,Array,Array,Array [author_id] => [author_test] => Array ( ) [sys_author_id_arr] => [jl_publication_cn_publication_en] => 化学通报,chemistry [jl_keyword_cn_keyword_en] => 热分解,配合物,分解反应,异硫氰酸,非等温动力学,氢酸,dsc,曲线研究 [sys_author_id] => [id] => 5Qs5vmUBFjIhTVEbPO0E [tags] => 0 ) [19] => Array ( [batch2] => 2 [tag] => 0 [author_en] => CAI ZHENG-TING GUAN DA-REN FAN YUE-PENG [keyword_cn] => 配合物;C-6;H_2O;晶体;NCS;Mn;电子;轻子; [fund_No] => 国家教委科学基金 [article_id] => 527018,167930 [format_title_en_publication_en_pub_year] => ef92d414574e91c6735d11c3eb8a9e2f636698875 [author_jg] => [蔡政亭,关大任,樊悦朋,张瑞勤]山东大学化学学院,山东大学化学学院,山东大学化学学院,山东大学物理系 济南,济南,济南 [format_title_cn_publication_cn_pub_year] => 7d7946b0e84bb37e7484008819a1bf36-1656653624 [hints] => 1 [issue] => 04 [sys_level_num] => 2_2 [sys_jg_type] => 0,5 [format_issn_issue_page_pub_year] => 15d689e1be462f02aed5398fd18c62d2685106695 [title_en] => STUDIES ON ELECTRONIC STRUCTURE AND CHEMICAL BOND FEATURES OF THE COORDINATE COMPOUND CRYSTAL [MN(H_2O)_4(NCS)_2]·(18-C-6) [source_type] => 351 [pub_year] => 1990 [pub_date] => 1990-08-29 [pages] => 6 [from_id] => 80,78 [author_cn] => 蔡政亭,关大任,樊悦朋,张瑞勤 [language] => chi [issn] => 0254-5861 [batch] => 3250,3252 [publication_en] => CHINESE JOURNAL OF STRUCTURAL CHEMISTRY [format_title_en_issn_pub_year] => 2cf847bbaf6f096746ffc62d7f010b5f385644979 [publication_cn] => 结构化学 [title_cn] => [Mn(H_2O)_4(NCS)_2]·(18-C-6)配合物晶体的电子结构与成键特性理论研究 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => 00e8af529bba41804ccdbb379429f1d2-903750868 [page] => 322-327 [hb_type] => 2 [article_dt] => 期刊论文 [hb_batch] => title_cn_publication_cn_pub_year_2_3 [format_title_en] => dfbe544edb6bb0b258913793abbbd6641358209877 [format_title] => 5963e993b74df3114abadf7006d4a3cf-577413951 [CSSN] => 35-1112/TQ [hx_id] => [abstract_cn] => 本文取配合物晶体[Mn(H_2O)_4(NCS)_2]·(18-C-6)的一个分子片断进行CNDO/2半经验分子轨道理论计算,给出Mulliken键级、电荷分布和电子态密度等,探讨了其成键特性。结果表明,过渡金属配合单元[Mn(H_2O)_4(NCS)_2]与18-C-6冠醚环之间的主要结合方式是定域化程度相当高的氢键,与来自实验测量的推测相一致。 [uri] => http://kns.cnki.net/kns/detail/detail.aspx?FileName=JGHX199004013&DbName=CJFQ1990 [format_publication_cn] => 63269391a61c5d1ed19167c77c7995b71058064782 [format_publication_en] => a27e2e5b5839299d0c9ab0d30fb9c00d278116815 [jl_language] => chinese [jl_publication_cn] => 结构化学 [jl_publication_en] => chinesejournalofstructuralchemistry [jl_article_dt] => 期刊论文 [jl_keyword_cn] => ,ncs,轻子,mn,配合物,晶体,h2o,c6,电子 [author_in] => [company_id] => 133,5,43,169 [sys_subject_sort] => 0,0,0,0 [college_parent_id] => 133,5,43,169 [company_test] => Array,Array,Array,Array [author_id] => [author_test] => Array ( ) [sys_author_id_arr] => [jl_publication_cn_publication_en] => 结构化学,chinesejournalofstructuralchemistry [jl_keyword_cn_keyword_en] => ncs,配合物,mn,电子,h2o,晶体,c6,轻子 [sys_author_id] => [id] => Rg09vmUBFjIhTVEbpggJ [tags] => 0 ) ) 1-->
10461. 中相微乳液的形成和特性——Ⅳ.表面活性剂复配及醇和油的影响

作者:李干佐;郑立强;徐桂英;王弘立;毛宏志;

作者机构:[李干佐;郑立强;徐桂英;王弘立;毛宏志]山东大学化学院,中国科学院兰州化学物理研究所,山东大学化学院,中国科学院兰州化学物理研究所,山东大学化学院 济南250100,兰州730000,济南250100,兰州730000,济南250100

来源:科学通报,CINESE SCIENCE BULLETIN,1993,Issue.22,2042-2044

资源类型:期刊论文

10462. 导数光度法同时测定五种食用合成色素

作者:冯素萍[1];王淑仁[2];陈荣礼[3];李高兰[4];王丽增[5]

作者机构:[冯素萍]山东大学实验中心,中国.;[王淑仁]山东大学化学院,中国.;[陈荣礼]山东大学化学院 济南 250100,中国.;[李高兰]济南 250100,中国.;[王丽增]济南 250100,中国

来源:分析化学,CHINESE JOURNAL OF ANALYTICAL CHEMISTRY,1993,Issue.03,294-298

资源类型:期刊论文

10463. PS自由基的形成及动力学研究 SCIE

作者:郭敬忠;王海庆;顾月姝;刘传朴;印永嘉;曹德兆;李书涛;

作者机构:[郭敬忠;王海庆;顾月姝;刘传朴;印永嘉;曹德兆;李书涛]山东大学化学系,山东大学化学系,山东大学化学系,山东大学化学系,山东大学化学系,中国科学院安徽光学精密机械研究所,中国科学院安徽光学精密机械研究所 济南 250100,济南 250100,济南 250100,济南 250100,济南 250100,合肥 230031,合肥 230031

来源:化学学报,ACTA CHIMICA SINICA,1993,Vol.51,Issue.1,18-22

WOS被引数:1

资源类型:期刊论文

WOS:A1993KN62600004

10464. 伯胺N1923和三苯基氧化膦萃取金(Ⅲ)的动力学——Ⅱ.二元萃取剂体系萃取AuCl_4~- SCIE

作者:孙思修;高自立;沈静兰;柴金岭;

作者机构:[孙思修;高自立;沈静兰;柴金岭]山东大学化学系,山东大学化学系,山东大学化学系,山东师范大学化学系 济南 250100,济南 250100,济南 250100,济南 250014

来源:化学学报,ACTA CHIMICA SINICA,1993,Vol.51,Issue.1,30-35

资源类型:期刊论文

WOS:A1993KN62600006

10465. 阴离子型表面活性剂所组成微乳液的异常流变性 SCIE

作者:伍世英;陈宗淇;王世权;李莹;袁云龙;张传胜;

作者机构:[伍世英;陈宗淇;王世权;李莹;袁云龙;张传胜]青岛化工学院应用化学系;[伍世英;陈宗淇;王世权;李莹;袁云龙;张传胜]青岛化工学院应用化学系;[伍世英;陈宗淇;王世权;李莹;袁云龙;张传胜]青岛化工学院应用化学系;[伍世英;陈宗淇;王世权;李莹;袁云龙;张传胜]青岛化工学院应用化学系;[伍世英;陈宗淇;王世权;李莹;袁云龙;张传胜]山东大学化学系;[伍世英;陈宗淇;王世权;李莹;袁云龙;张传胜]山东大学化学系 青岛 266042;[伍世英;陈宗淇;王世权;李莹;袁云龙;张传胜]青岛 266042;[伍世英;陈宗淇;王世权;李莹;袁云龙;张传胜]青岛 266042;[伍世英;陈宗淇;王世权;李莹;袁云龙;张传胜]青岛 266042;[伍世英;陈宗淇;王世权;李莹;袁云龙;张传胜]济南 250100;[伍世英;陈宗淇;王世权;李莹;袁云龙;张传胜]济南 250100

来源:化学学报,ACTA CHIMICA SINICA,1993,Vol.51,Issue.8,729-735

WOS被引数:5

资源类型:期刊论文

WOS:A1993LX88200001

10466. 邻香兰素甘氨酸三吡啶合Ni(Ⅱ)的合成、性质、晶体结构及热分解动力学 SCIE

作者:崔学桂;孙宏建;刘德信;李晓燕;李淑兰;

作者机构:[崔学桂;孙宏建;刘德信;李晓燕;李淑兰]山东大学应用化学系,山东大学应用化学系,山东大学应用化学系,山东大学应用化学系,山东大学应用化学系 济南 250100,济南 250100,济南 250100,济南 250100,济南 250100

来源:化学学报,ACTA CHIMICA SINICA,1993,Vol.51,Issue.4,346-351

WOS被引数:12

资源类型:期刊论文

WOS:A1993LF79000007

10467. 三苯基氧化膦与氯金酸形成的萃合物晶体的合成、特性和结构 SCIE

作者:蒋德华;杨永会;高自立;孙思修;沈静兰;

作者机构:[蒋德华;杨永会;高自立;孙思修;沈静兰]山东大学化学系,山东大学化学系,山东大学化学系,山东大学化学系,山东大学化学系 济南 250100,济南 250100,济南 250100,济南 250100,济南 250100

来源:化学学报,ACTA CHIMICA SINICA,1992,Vol.50,Issue.11,1091-1097

WOS被引数:2

资源类型:期刊论文

WOS:A1992KH22200009

10468. 二-(2-乙基己基)磷酸在不同稀释剂中对钼(Ⅵ)的萃取 SCIE

作者:孙思修;高自立;刘源;沈静兰;

作者机构:[孙思修;高自立;刘源;沈静兰]山东大学化学系,山东大学化学系,山东大学化学系,山东大学化学系 济南 250100,济南 250100,济南 250100,济南 250100

来源:化学学报,ACTA CHIMICA SINICA,1992,Vol.50,Issue.9,877-882

WOS被引数:3

资源类型:期刊论文

WOS:A1992JV02700008

10469. 氢原子共线交换反应的动力学计算 Ⅱ.在反应势能面上Cl+HCl(v)碰撞对的振动去激 SCIE

作者:陈德展;居冠之;

作者机构:[陈德展;居冠之]山东师范大学化学系,山东大学化学院 济南 250014,济南 250100

来源:化学学报,ACTA CHIMICA SINICA,1992,Vol.50,Issue.1,1-4

WOS被引数:1

资源类型:期刊论文

WOS:A1992HJ43800001

10470. 伯胺N1923和三苯基氧化膦萃取金(Ⅲ)的动力学 Ⅰ.一元萃取剂体系萃取AuCl_4~- SCIE

作者:孙思修;高自立;沈静兰;柴金岭;

作者机构:[孙思修;高自立;沈静兰;柴金岭]山东大学化学系,山东大学化学系,山东大学化学系,山东师范大学化学系 济南 250100,济南 250100,济南 250100,济南 250014

来源:化学学报,ACTA CHIMICA SINICA,1992,Vol.50,Issue.10,989-994

资源类型:期刊论文

WOS:A1992KA50000010

10471. 三阶导数卷积极谱法测定反丁烯二酸中的微量顺丁烯二酸

作者:陈荣礼;王丽增;刘萍;陆懋荪;尹佩玉;

作者机构:[陈荣礼;王丽增;刘萍;陆懋荪;尹佩玉]山东大学化学院应化系;[陈荣礼;王丽增;刘萍;陆懋荪;尹佩玉]山东大学化学院应化系;[陈荣礼;王丽增;刘萍;陆懋荪;尹佩玉]山东大学化学院应化系;[陈荣礼;王丽增;刘萍;陆懋荪;尹佩玉]山东大学化学院应化系;[陈荣礼;王丽增;刘萍;陆懋荪;尹佩玉]山东大学化学院应化系 济南 250100;[陈荣礼;王丽增;刘萍;陆懋荪;尹佩玉]济南 250100;[陈荣礼;王丽增;刘萍;陆懋荪;尹佩玉]济南 250100;[陈荣礼;王丽增;刘萍;陆懋荪;尹佩玉]济南 250100;[陈荣礼;王丽增;刘萍;陆懋荪;尹佩玉]济南 250100

来源:分析化学,CHINESE JOURNAL OF ANALYTICAL CHEMISTRY,1991,Issue.06,673-676

资源类型:期刊论文

10472. 金属修饰半导体硅组成光电化学电池的研究 SCIE

作者:李怀祥[1,2];王士勋[1];李国铮[1];

作者机构:[李怀祥;王士勋;李国铮]山东大学化学系,中国.;[李怀祥]山东师范大学化学系,中国

来源:化学学报,ACTA CHIMICA SINICA,1991,Vol.49,Issue.10,998-1002

WOS被引数:3

资源类型:期刊论文

WOS:A1991GR21800011

10473. 伯胺N1923萃取Co(Ⅱ)Ni(Ⅱ)的平衡 SCIE

作者:高自立;孙思修;施新超;朱靖江;阮红;沈静兰;

作者机构:[高自立;孙思修;施新超;朱靖江;阮红;沈静兰]山东大学化学系,山东大学化学系,山东大学化学系,山东大学化学系,山东大学化学系,山东大学化学系 济南 250100,济南 250100,济南 250100 上海水产大学加工系,济南 250100 南通师专,济南 250100,济南 250100

来源:化学学报,ACTA CHIMICA SINICA,1991,Vol.49,Issue.3,244-248

WOS被引数:3

资源类型:期刊论文

WOS:A1991FW89000007

10474. 稀土(Ⅲ)-冠醚配位反应的热力学性质 Ⅱ. 镧系(Ⅲ)高氯酸盐与二苯并18-冠-6在无水乙腈中配位反应的量热滴定研究 SCIE

作者:黄锡荣;蒋本杲;尹敬执;阎海科;

作者机构:[黄锡荣;蒋本杲;尹敬执;阎海科]山东大学化学系,山东大学化学系,山东大学化学系,中国科学院化学研究所 济南 250100,济南 250100,济南 250100,北京 100080

来源:化学学报,ACTA CHIMICA SINICA,1991,Vol.49,Issue.4,359-364

WOS被引数:6

资源类型:期刊论文

WOS:A1991FV35600009

10475. He(2~3S)与CH_3l和CH_3Br在流动余辉中传能的解离激发反应 SCIE

作者:郭敬忠;顾月姝;刘传朴;李保中;印永嘉;曹德兆;蔡继业;

作者机构:[郭敬忠;顾月姝;刘传朴;李保中;印永嘉;曹德兆;蔡继业]山东大学化学系,山东大学化学系,山东大学化学系,山东大学化学系,山东大学化学系,中国科学院安徽光学精密机械研究所,中国科学院安徽光学精密机械研究所 济南 250100,济南 250100,济南 250100,济南 250100,济南 250100,合肥 230031,合肥 230031

来源:化学学报,ACTA CHIMICA SINICA,1991,Vol.49,Issue.5,456-461

资源类型:期刊论文

WOS:A1991FV41200008

10476. Study on the Laser Crystal of ZnWO_4:Er

作者:田玉金,刘国庆,张克从,刘明果,陆宝生

作者机构:[田玉金,刘国庆,张克从,刘明果,陆宝生]Department of Chemistry, Beijing Polytechnic University, 100022,Department of Chemistry, Beijing Polytechnic University, 100022,Department of Chemistry, Beijing Polytechnic University, 100022,Institute of Crystal Materials, Shandong University, Jinan, 250

来源:人工晶体学报,JOURNAL OF SYNTHETIC CRYSTALS,1991,Issue.Z1,239

资源类型:期刊论文

10477. 用非等温DSC曲线确定Ln(NCS)_3·4C_6H_5CH_2NH_2的热分解反应机理函数及热分解反应动力学参数 SCIE

作者:杨淑荣;张建华;蒋本杲;杨兆荷;

作者机构:[杨淑荣;张建华;蒋本杲;杨兆荷]山东大学化学院,山东大学化学院,山东大学化学院,山东大学晶体材料研究所 济南 250100,济南 250100,济南 250100,济南 250100

来源:化学学报,ACTA CHIMICA SINICA,1991,Vol.49,Issue.6,521-528

资源类型:期刊论文

WOS:A1991FX90400001

10478. 钛白增量剂的研究

作者:王来锋;王果庭;

作者机构:[王来锋]山东省分析测试中心;[王果庭]山东大学化学院

来源:山东科学,SHANDONG SCIENCE,1990,Issue.04,9-12

资源类型:期刊论文

10479. 用非等温DSC曲线研究异硫氰酸钇苄胺配合物的热分解非等温反应动力学

作者:杨淑荣;蒋本杲;杨兆荷;

作者机构:[杨淑荣;蒋本杲;杨兆荷]山东大学化学院,山东大学化学院,山东大学晶体材料研究所 济南 250100,济南 250100,济南

来源:化学通报,CHEMISTRY,1990,Issue.09,40-43

资源类型:期刊论文

10480. [Mn(H_2O)_4(NCS)_2]·(18-C-6)配合物晶体的电子结构与成键特性理论研究

作者:蔡政亭,关大任,樊悦朋,张瑞勤

作者机构:[蔡政亭,关大任,樊悦朋,张瑞勤]山东大学化学学院,山东大学化学学院,山东大学化学学院,山东大学物理系 济南,济南,济南

来源:结构化学,CHINESE JOURNAL OF STRUCTURAL CHEMISTRY,1990,Issue.04,322-327

资源类型:期刊论文

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