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a, upsilon \" = m) transition: and the anharmonicities of the terminal bonds of the quencher molecules. In addition, the influence of the polarizability on the quenching rate constants is discussed. [publication_type] => J [keyword_plu] => SMALL POLYATOMIC-MOLECULES; RATE CONSTANTS; COLLISIONAL DEACTIVATION [author_in] => [Zou, SL; Liu, CP; Guo, JZ; Gu, YS; Chu, YN; Cao, DZ]Shandong Univ, Dept Chem, Jinan 250100, Peoples R China.@@@[Zou, SL; Liu, CP; Guo, JZ; Gu, YS; Chu, YN; Cao, DZ] Acad Sinica, Anhui Inst Opt & Fine Mech, Laser Spect Lab, Hefei 230031, Peoples R China. [publisher_city] => SHANGHAI [article_id] => 334499,239663,214925 [get_data] => 2018-08-29 [format_title_en_publication_en_pub_year] => ce4e6a3ea2e0691486b6f5a200f16ee51697963774 [begin_page] => 209 [cite_wos] => 0 [check_3Y] => 0 [cite_awos] => 0 [from_id] => 80,73 [cauthor_ad] => [Zou, SL]Shandong Univ, Dept Chem, Jinan 250100, Peoples R China. [hx_id] => 2371 [cauthor_order] => 1 [research_area] => Chemistry [sys_level_num] => 1_7 [publisher] => ACTA CHIMICA SINICA [sys_jg_type] => 9,5 [format_issn_issue_page_pub_year] => 6093452217357bf2fd58de975de434cc2010166786 [title_en] => Study on the quenching for PCl(b(1)Sigma(+)) by E-V model [publication_29] => ACTA CHIM SINICA [author_fn] => Zou, SL; Liu, CP; Guo, JZ; Gu, YS; Chu, YN; Cao, DZ [pub_year] => 1998 [publisher_ad] => SHANGHAI INST ORGANIC CHEM ACADEMIA SINICA 354 FENGLING LU, SHANGHAI; 200032, PEOPLES R CHINA [check_180] => 0 [keyword_en] => metastable molecule PCl(b(1)Sigma(+)); quenching rate constant; E-V; energy transfer [end_page] => 214 [cauthor_back] => Zou, SL [pages] => 6 [format_wos_No] => 7f8ff603597e95fff03452b96f1010f1-983549644 [hints] => 2 [volume] => 56 [language] => Japanese [source_type] => 351 [issue] => 3 [reference_No] => 6 [batch] => 3241,3252 [publication_en] => ACTA CHIMICA SINICA [school_id] => 117 [sys_update_time] => 2018-09-05 15:29:31 [format_title_en_issn_pub_year] => 7a13c5127696a15d5bff0afe01431a6736929600 [publication_iso] => Acta Chim. Sin. [wos_sub] => Chemistry, Multidisciplinary [SYS_TAG] => 3 [wos_No] => WOS:000072849300001 [page] => 209-214 [hb_type] => 2 [article_dt] => Article [jl_language] => japanese [jl_article_dt] => 期刊论文 [jl_publication_en] => actachimicasinica [jl_country] => 中国,中国 [jl_keyword_en] => ev,metastablemoleculepclb1sigma,energytransfer,quenchingrateconstant [jl_publisher] => actachimicasinica [author_jg] => 山东大学化学系 [keyword_cn] => 亚稳态分子;猝灭过程;E-V传能;PCl [format_title] => df29c2b455c4e6af055439c4c1171f011942024015 [clc] => O613.62 [title_cn] => 利用E―V传能模型研究亚稳态分子PC1(b^1Σ^+)的猝灭过程 [format_publication_cn] => 6918be3b26b1fa6ec0424f6071208a75331227575 [publication_cn] => 化学学报 [format_title_en] => a6bb28a462722bf647eeb6c8d4e9fa17-2026430942 [CSSN] => 31-1320/O6 [abstract_cn] => 亚稳态分子猝灭机理的研究一直受到人们的极大重视.本文利用E-V传能模型对亚稳态分子PCl(b1∑+)的猝灭过程进行了定量处理.结果表明PCl(b1∑+)的猝灭是PCl(b1∑+→a1△)跃迁和试剂分子端键X-Y振动能级近共振传能的结果,与PCl(b1∑+→a1△)跃迁的Franck-Condon因子及试剂分子端键X-Y振动的非谐性系数有关,而且也受猝灭试剂分子极化率的影响. [sys_priority_field] => 73 [author_cn] => 邹胜利;储焰南 [format_publication_en] => 169b60c7845c9e5f36906950b18f11111348184734 [jl_publication_cn] => 化学学报 [jl_keyword_cn] => 亚稳态分子,猝灭过程,pcl,ev传能 [jl_clc] => o61362 [company_id] => 43,169 [sys_subject_sort] => 0,0 [college_parent_id] => 43,169 [company_test] => Array,Array [author_id] => [author_test] => Array ( ) [sys_author_id_arr] => [jl_publication_cn_publication_en] => actachimicasinica,化学学报 [jl_keyword_cn_keyword_en] => quenchingrateconstant,energytransfer,猝灭过程,pcl,ev传能,亚稳态分子,ev,metastablemoleculepclb1sigma [sys_author_id] => [format_title_cn_publication_cn_pub_year] => c4ad408053007e2b0372ea2c45263112510450851 [format_title_cn_issn_pub_year] => b4d6727bbf40968b002d3228eea84f96-989245316 [id] => sgifvWUBFjIhTVEbUuIV [tags] => 0 ) [4] => Array ( [issn] => 0567-7351 [cite_wanfang] => 5 [batch2] => 1,2,5 [tag] => 0 [author_en] => Zhou, JH; Li, SL; Jiang, HH; Liu, DX; Yang, ZH [CSSN] => 31-1320/O6 [format_doi] => 3e29fa43dcd217b7aa6424b61e2290c6-187567212 [keyword_cn] => Schiff碱;锰配合物;晶体结构;热分解动力学; [article_id] => 181969,334501,239662,214232 [format_title_en_publication_en_pub_year] => ede874c97faea0ab4e597165143e7e2e1093931725 [abstract_cn] => X射线晶体结构分析结果表明,标题化合物晶体(C36H26MnN4O4)属单斜晶系,空间群为P21/α,α=0.9833(3),b=1.8646(3),c=0.9449(1)nm,Z2,最终因子Rw=0.057.利用热重分析对配合物晶体两步热分解过程进行了非等温热力学研究,探讨了反应的可能机理,得到其相应的动力学参数.第一步非等温动力学方程为:dα/dt=A·exp(-E/RT)·2(1-α)1/2,第二步:dα/dt=A·exp(-E/RT)·3/2(1-α)[-ln(1-α)]1/3. [author_jg] => [周建华;李淑兰;姜海辉;刘德信]山东大学化学系,济南,@@@[杨兆荷]山东大学晶体材料研究所,济南, [format_title_cn_publication_cn_pub_year] => 8b6b1f4d2542cd3babfd34e4efbc67c7611776090 [from_id] => 80,73 [issue] => 4 [sys_level_num] => 2_2 [sys_jg_type] => 0,5 [format_issn_issue_page_pub_year] => cfcb1d3c01bb090a7a76064e325a3fa0824388794 [title_en] => Synthesis, crystal structure and thermal decomposition of bis[2-(2 \'-phenoxyl)-benzoxazole]-di-pyridine manganese(II) [source_type] => 351,351 [pub_year] => 1998 [pub_date] => 2005-07-28 [pages] => 7 [hints] => 10 [author_cn] => 周建华@@@李淑兰@@@姜海辉@@@刘德信@@@杨兆荷 [doi] => 10.3321/j.issn:0567-7351.1998.04.010 [language] => Chinese [reference_No] => 9 [batch] => 0,3252,3241 [publication_en] => ACTA CHIMICA SINICA [format_title_en_issn_pub_year] => 76ab6f1d6649b5be9bf5fb5a1d5cd9fc-2091049058 [publication_cn] => 化学学报 [title_cn] => 双[2-(2'-苯氧基)苯并(口恶)唑]二吡啶合锰(Ⅱ)配合物的研究 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => 1c4325c913f0d46b021299e77aed3d70-1084310535 [page] => 371-377 [hb_type] => 2 [article_dt] => Article [hb_batch] => issn_issue_page_pub_year_2_3 [cite_wos] => 3 [check_3Y] => 0 [delivery_No] => ZQ821 [format_title] => f6c84a14b55c7ff59f18bc79c5086de41801557685 [cauthor_ad] => [Zhou, JH]Shandong Univ, Dept Chem, Jinan 250100, Peoples R China. [author_fn] => Zhou, JH; Li, SL; Jiang, HH; Liu, DX; Yang, ZH [publication_29] => ACTA CHIM SINICA [end_page] => 377 [abstract_en] => The title complex C36H26MnN4O4 was synthesized and its structure was determined by single crystal X-ray diffraction method. The crystal is monoclinic system, space group P2(1)/a, a=0.9833(3), b=1.8646(3), c=0.9449(1) nm, Z=2, final R-w =0.057 for 1217 observed reflections [I greater than or equal to 3 sigma(I)]. The kinetics of thermal decomposition reaction of the title complex was studied under non-isothermal condition by TG. The kinetic parameters were obtained from the analysis of TG, DTG curves by integral and differential methods. The kinetic expressions of thermal decomposition reaction are:; first step d alpha/dt = A.exp(-E/RT).2(1-alpha)(1/2); secondstep d alpha/dt=A.exp(-E/RT).3/2(1-alpha)[-ln(1-alpha)](1/3). [author_in] => [Zhou, JH; Li, SL; Jiang, HH; Liu, DX; Yang, ZH]Shandong Univ, Dept Chem, Jinan 250100, Peoples R China.@@@[Zhou, JH; Li, SL; Jiang, HH; Liu, DX; Yang, ZH] Shandong Univ, Inst Crystal Mat, Jinan 250100, Peoples R China. [publication_type] => J [begin_page] => 371 [volume] => 56 [get_data] => 2018-08-29 [publisher] => ACTA CHIMICA SINICA [keyword_en] => Schiff base; manganese complex; crystal structure; thermal decomposition; kinetics [format_publication_cn] => 6918be3b26b1fa6ec0424f6071208a75331227575 [publication_iso] => Acta Chim. Sin. [format_title_en] => 4c4de04dfd23c50cfdfeab5e67b478261618251167 [publisher_city] => SHANGHAI [hx_id] => 2380,2371 [cite_awos] => 3 [wos_No] => WOS:000073906300010 [sys_priority_field] => 73 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [check_180] => 0 [publisher_ad] => SHANGHAI INST ORGANIC CHEM ACADEMIA SINICA 354 FENGLING LU, SHANGHAI; 200032, PEOPLES R CHINA [format_publication_en] => 169b60c7845c9e5f36906950b18f11111348184734 [clc] => O614.711 [jl_language] => chinese [jl_publication_cn] => 化学学报 [jl_article_dt] => 期刊论文 [jl_publication_en] => actachimicasinica [jl_country] => 中国,中国 [jl_keyword_en] => crystalstructure,kinetics,manganesecomplex,schiffbase,thermaldecomposition [jl_keyword_cn] => schiff碱,热分解,水杨醛邻氨基酚,锰配合物,晶体 [jl_clc] => o614711 [jl_publisher] => actachimicasinica [company_id] => 24,0,151,43,169 [sys_subject_sort] => 0,0,0,0 [college_parent_id] => 24,151,43,169 [company_test] => Array,Array,Array,Array [author_id] => [author_test] => Array ( ) [sys_author_id_arr] => [jl_publication_cn_publication_en] => actachimicasinica,化学学报 [jl_keyword_cn_keyword_en] => 热分解,thermaldecomposition,水杨醛邻氨基酚,kinetics,manganesecomplex,锰配合物,晶体,schiffbase,crystalstructure,schiff碱 [imf_once] => 0.178 [author_first] => [jcr_wos] => [imf_5] => 0 [profession_stu] => [thesis_au] => [highly_article] => [student_No] => [grant_bulletin_No] => [dom_ranking] => [province] => [complete_time] => [bulletin_date] => [fund_amount] => [attachment_text] => [name_editor] => [subject_gb1] => [phone] => [book_alias] => [application_date] => [fund_type] => [isbn_10] => [classification_No] => [cssci_No] => [responsibility] => [uncontrolled_terms] => [controlled_terms] => [top_article] => [student_type] => [agency] => [classification_pub] => [format_wos_No] => ccf47e03114d2f295ed420c062543f79566704525 [uri] => http://d.g.wanfangdata.com.cn/Periodical_hxxb199804010.aspx [standard_in] => [country] => [open_time] => [institution_first] => [cauthor] => [ei_No] => [datebase] => [fund_CSSCI] => [school_stu] => [main_cword] => [create_time] => [degree] => [job_no] => [volume_label] => [main_eword] => [numerical_index] => [producer] => [awards_type] => [birthday] => [sponsor] => [imf] => 2.131 [bulletin_No] => [cite_scopus] => [institution_name] => [grant_bulletin_date] => [meet_code] => [department_tutor1] => [abstract_type] => [legal_status] => [email_c] => [discipline_name] => [institution_type] => [cscd_No] => [oral_time] => [name_tutor1] => [cauthor_back] => [scopus_No] => [positional_titles] => [sys_author_id] => [id] => 3ws5vmUBFjIhTVEbPO0E [tags] => 0 ) [5] => Array ( [batch2] => 1,2,6 [batch] => 3250,3243,3241,3254,3252 [tag] => 0 [abstract_cn] => 首次报道了1-苯基-3-甲基-4-苯甲酸吡唑啉酮-5(HPMBP)萃取镓的热力学和动力学,指出在体系中形成Ga(PMBP)_3(H_2O)_2萃合物,配体PMBP既有一次溶剂化作用,又有二次溶剂化作用,并得到红外光谱和核磁共振谱的证实.镓的萃取过程为水相化学反应控制,决速步骤为一次溶剂化过程:Ga~(3+)+HPMBP→Ga(PMBP)~(2+)+H~+.添加剂三辛基氧化膦(TOPO)不影响HPMBP萃取镓的分配比,但降低了HPMBP萃取镓的正向速率,表明动力学抑萃作用与热力学抑萃作用无对应关系. [keyword_cn] => HPMBP;镓;萃取热力学;萃取动力学 [article_id] => 334504,44190,237947,554751,498149 [clc] => O657.3 [author_jg] => [杨永会,孙思修,薛梅,刘萍]山东大学化学院,山东大学化学院,山东大学化学院,山东大学化学院 济南250100,济南250100,济南250100,济南250100 [format_title_cn_publication_cn_pub_year] => e2ca34822c05f20f678916560bb40081-1580571387 [hints] => 5 [issue] => 6 [sys_level_num] => 2_3 [sys_jg_type] => 0,5 [format_issn_issue_page_pub_year] => 4236dbc286e737f9e3a8a0d274f55093-354221067 [source_type] => 351 [pub_year] => 1998 [pub_date] => 1998-06-20 [pages] => 6 [from_id] => 76,80,78,73,85 [author_cn] => 杨永会,孙思修,薛梅,刘萍 [issn] => 0567-7351 [uri] => http://kns.cnki.net/kns/detail/detail.aspx?FileName=HXXB199806014&DbName=CJFQ1998 [publication_cn] => 化学学报 [title_cn] => 1-苯基-3-甲基-4-苯甲酰吡唑啉酮-5萃取镓的研究 [CSSN] => 31-1320/O6 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => 13f10c3345f748c30848f2a1ff694e65796344967 [page] => 606-611 [hb_type] => 2 [article_dt] => Article [hb_batch] => title_cn_publication_cn_pub_year_2_3 [format_title_en] => 49e59e7f12fc8fb95f17d3bd9187061d-1844975706 [format_title] => 36f5a72fb3f474c77e38976ad1cc9c9c-2112878130 [hx_id] => 2378,2371 [format_publication_cn] => 6918be3b26b1fa6ec0424f6071208a75331227575 [format_publication_en] => 169b60c7845c9e5f36906950b18f11111348184734 [jl_publication_cn] => 化学学报 [jl_article_dt] => 期刊论文 [jl_keyword_cn] => 萃取动力学,hpmbp,镓,萃取热力学 [jl_clc] => o6573 [author_in] => [Yang, Y.-H] Department of Chemistry, Shandong University, Jinan, 250100, China@@@[ Sun, S.-X] Department of Chemistry, Shandong University, Jinan, 250100, China@@@[ Xue, M] Department of Chemistry, Shandong University, Jinan, 250100, China@@@[ Liu, P] Department of Chemistry, Shandong University, Jinan, 250100, China [company_id] => 0,43,169 [sys_subject_sort] => 0,0 [college_parent_id] => 43,169 [company_test] => Array,Array [author_id] => [author_test] => Array ( ) [sys_author_id_arr] => [jl_publication_cn_publication_en] => 化学学报 [jl_keyword_cn_keyword_en] => 镓,hpmbp,萃取热力学,萃取动力学 [cite_wos] => 0 [publication_en] => ACTA CHIMICA SINICA [check_3Y] => 0 [language] => Chinese [delivery_No] => 104TR [cauthor_ad] => [Yang, YH]Shandong Univ, Dept Chem, Jinan 250100, Peoples R China. [author_fn] => Yang, YH; Sun, SX; Xue, M; Liu, P [cite_wanfang] => 6 [format_title_en_issn_pub_year] => 1385093e21e981f8ea2ce977cbea016d500697136 [datebase] => Scopus [format_scopus_No] => c4146302fd9349e49de59893eb76d57c1950601997 [publication_29] => ACTA CHIM SINICA [end_page] => 611 [abstract_en] => The extraction equilibrium and kinetics of gallium(III) from hydrochloric acid solutions with 1 - phenyl - 3 - methyl - 4 - benzoyl - pyrazolone - 5(HPMBP) in carbon tetrachloride have been investigated. The composition of the extracted species was found to be Ga(PMBP)(3) . 2H(2)O via the method of slopes, IR and NMR spectra. The values of K-ex, Delta H degrees, Delta G degrees and Delta s degrees at 298K were calculated. The extraction kinetics of Ga(III) was studied with the growing drop method. The extraction rate equation can be expressed as R-f = k(f)[Ga3+][HL]((o)). The activation energy of the reaction was calculated to be 15. 9kJ . mol(-1). The rate determining step was deduced to take place in water phase:Ga3+ + HL --> GaL2+ + H+,which is an immediate coordination process. [publication_type] => J [begin_page] => 606 [author_en] => Yang, YH; Sun, SX; Xue, M; Liu, P [volume] => 56 [publisher] => ACTA CHIMICA SINICA [get_data] => 2018-08-29 [keyword_en] => 1-phenyl-3-methyl-4-benzoyl-pyrazolone-5; gallium; extraction; equilibrium; extraction kinetics [publication_iso] => Acta Chim. Sin. [format_title_en_publication_en_pub_year] => ada8d8d5baf57bc6c32ef2fea04e1516-428949017 [publisher_city] => SHANGHAI [cauthor_order] => 1 [reference_No] => 17 [cite_awos] => 0 [wos_No] => WOS:000075031900015 [format_wos_No] => 2b159157ad2b61146e0b243650181dc9446894357 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [cauthor_back] => Yang, YH [check_180] => 0 [publisher_ad] => SHANGHAI INST ORGANIC CHEM ACADEMIA SINICA 354 FENGLING LU, SHANGHAI; 200032, PEOPLES R CHINA [standard_in] => Department of Chemistry, Shandong University, Jinan, 250100, China [scopus_No] => 2-s2.0-33748668790 [title_en] => Extraction of gallium(III) with HPMBP [jl_language] => chinese [jl_publication_en] => actachimicasinica [sys_author_jg_last_arr] => 济南250100 [jl_company_test] => uircu0,unameuu5316u5b66u4e0eu5316u5de5u5b66u9662,uparentidu43,uorgidu43,ulevelu1 [jl_country] => 中国 [jl_keyword_en] => extraction,equilibrium,gallium,extractionkinetics,1phenyl3methyl4benzoylpyrazolone5 [sys_author_in_last_arr] => china [jl_publisher] => actachimicasinica [sys_author_id] => [id] => jw5JvmUBFjIhTVEbudND [tags] => 0 ) [6] => Array ( [batch2] => 1,2,6 [batch] => 3250,3243,3241,3254,3252 [tag] => 0 [abstract_cn] => 本文用RHF/6-31G^*解析梯度方法研究了单重态硅稀与甲醛环加成反应的机理,用二级微扰方法对各构型的能量进行了相关校正,并用统计热力学方法和过渡态理论计算了该反应在不同温度下的热力学函数的变化和动力学性质。结果表明,此反应历程由两步组成:1)硅烯与甲醛生成一中间配合物,是一无势垒的放热反应,2)中间配合物异构化为产物,此步势垒经零点能校正后只有51.4kJ·mol^-1(MP2/6-31G^* [keyword_cn] => 硅烯;环加成反应;从头算;甲醛;硅杂环氧甲烷; [clc] => O627.41 O623.511 [author_jg] => [卢秀慧;王沂轩;刘成卜;邓从豪]济南大学化学系@@@[卢秀慧;王沂轩;刘成卜;邓从豪]山东大学化学院@@@[卢秀慧;王沂轩;刘成卜;邓从豪]山东大学化学院@@@[卢秀慧;王沂轩;刘成卜;邓从豪]山东大学化学院 济南250002@@@[卢秀慧;王沂轩;刘成卜;邓从豪]济南250100@@@[卢秀慧;王沂轩;刘成卜;邓从豪]济南250100@@@[卢秀慧;王沂轩;刘成卜;邓从豪]济南250100 [format_title_cn_publication_cn_pub_year] => a0373cc8e91cdc360ab6a1a006bac8c81348669744 [from_id] => 76,80,85,73,78 [issue] => 11 [sys_level_num] => 2_1 [sys_jg_type] => 9,5 [source_type] => 351 [pub_year] => 1998 [article_id] => 239386,539389,106129,498012,334511 [pages] => 6 [hints] => 18 [author_cn] => 卢秀慧[1];王沂轩[2] [issn] => 0567-7351 [uri] => https://www.scopus.com/inward/record.uri?eid=2-s2.0-33748660658&partnerID=40&md5=f1c32790e3d36f00e8007c287fcae7ee [publication_cn] => 化学学报 [title_cn] => 硅烯与甲醛环加成反应的理论研究 [CSSN] => 31-1320/O6 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => 22819116163ce257066cb1e49b90f381727906712 [hb_type] => 2 [hb_batch] => title_cn_publication_cn_pub_year_2_3 [publication_en] => ACTA CHIMICA SINICA [cite_wos] => 14 [fund_No] => 国家自然科学基金(29703003) [check_3Y] => 1 [language] => Chinese [delivery_No] => 145LH [format_title] => ec4924bb93aaf868843462db99888e871417011897 [cauthor_ad] => [Lu, XH]Jinan Univ, Dept Chem, Jinan 250002, Peoples R China. [author_fn] => Lu, XH; Wang, YX; Liu, CB; Deng, CH [publication_29] => ACTA CHIM SINICA [end_page] => 1080 [abstract_en] => The mechanism of the cycloaddition reaction of singlet silylene with formaldehyde has been studied by RHF/6 - 31G* gradient method. The electron correlation energies of all the structures are calculated by using second - order Moller - Plesset perturbation theory(MP2). We have also calculated the changes of thermodynamic functions and the quality of kinetic properties for this reaction at different temperatures by using statistical thermodynamics method and transition - state theory. The results show that this reaction proceeds in two steps: 1) silylene and formaldehyde form an intermediate complex, which is a kind of exothermal reaction with no barrier; 2) the intermediate complex isomerizes to sive the product. The barrier for the second step is 51.4kJ.mol(-1) at MP2/6 - 31G*//6 - 31G* level (with zero - point energies correction). In view of dynamics and thermodynamics, it is between 300 similar to 400K that the reaction will have not only larger;spontaneous tendency and equilibrium constant but also quicker reaction rate. [author_in] => [Lu, X.-H] Department of Chemistry, Jinan University, Jinan, 250002, China@@@[ Wang, Y.-X] Institute of Chemistry, Shandong University, Jinan, 250100, China@@@[ Liu, C.-B] Institute of Chemistry, Shandong University, Jinan, 250100, China@@@[ Deng, C.-H] Institute of Chemistry, Shandong University, Jinan, 250100, China [publication_type] => J [begin_page] => 1075 [article_dt] => Article [author_en] => Lu, XH; Wang, YX; Liu, CB; Deng, CH [volume] => 56 [get_data] => 2018-08-29 [publisher] => ACTA CHIMICA SINICA [keyword_en] => silylene; cycloaddition reaction; ab initio calculation; thermodynamic; and kinetic properties [format_publication_cn] => 6918be3b26b1fa6ec0424f6071208a75331227575 [publication_iso] => Acta Chim. Sin. [format_title_en] => b83f6c843db267f997604bb18adca7e5-1616947772 [publisher_city] => SHANGHAI [pub_date] => 1998-11-20 [hx_id] => 2378,2371 [reference_No] => 14 [cite_awos] => 14 [wos_No] => WOS:000077372200006 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [check_180] => 0 [publisher_ad] => SHANGHAI INST ORGANIC CHEM ACADEMIA SINICA 354 FENGLING LU, SHANGHAI; 200032, PEOPLES R CHINA [title_en] => Theoretical study on the cycloaddition reaction of silylene and formaldehyde [format_publication_en] => 169b60c7845c9e5f36906950b18f11111348184734 [jl_language] => chinese [jl_publication_cn] => 化学学报 [jl_article_dt] => 期刊论文 [jl_publication_en] => actachimicasinica [jl_country] => 中国,中国 [jl_keyword_en] => andkineticproperties,thermodynamic,silylene,cycloadditionreaction,abinitiocalculation [jl_keyword_cn] => ,从头算,甲醛,硅杂环氧甲烷,环加成反应,硅烯 [jl_clc] => o62741o623511 [jl_publisher] => actachimicasinica [company_id] => 43,169 [sys_subject_sort] => 0,0 [college_parent_id] => 43,169 [company_test] => Array,Array [author_id] => [author_test] => Array ( ) [sys_author_id_arr] => [jl_publication_cn_publication_en] => actachimicasinica,化学学报 [jl_keyword_cn_keyword_en] => 硅烯,silylene,环加成反应,andkineticproperties,cycloadditionreaction,从头算,甲醛,abinitiocalculation,thermodynamic,硅杂环氧甲烷 [sys_author_id] => [format_title_en_publication_en_pub_year] => f2dd77af0e3f081263c0aefcaa287dc01239372809 [format_wos_No] => 4484ca633d280ab56b1032ea052316692024569266 [format_title_en_issn_pub_year] => cb6296f0620e2e5d0ee6a493506c2412-43707729 [datebase] => Scopus [format_scopus_No] => 0803d757fde73f0454795766c35f0335307975915 [page] => 1079-1080 [format_issn_issue_page_pub_year] => ac7bebf96c406fe43c51ab44d114cad11910207873 [sys_priority_field] => 76 [standard_in] => Department of Chemistry, Jinan University, Jinan, 250002, China; Institute of Chemistry, Shandong University, Jinan, 250100, China [scopus_No] => 2-s2.0-33748660658 [id] => 1wkvvmUBFjIhTVEbW1o7 [tags] => 0 ) [7] => Array ( [batch2] => 1,2,6 [uri] => http://kns.cnki.net/kns/detail/detail.aspx?FileName=HXXB199804000&DbName=CJFQ1998 [tag] => 0 [abstract_cn] => 全氟辛酸钠(OBS)/十六烷基三甲基溴化铵(CTAB)-正丁醇/正丙醇-油-盐水体系能形成多相微乳液,本文应用正交试验设计寻找了最佳中相微乳液体系组成,然后系统地研究了含盐量、表面活性剂总浓度,醇总浓度,油的种类对该体系中相微乳液的形成,相态和其特性参数的影响.并且应用红外光谱对微乳液的微观结构进行了测定.最后还对碳氢表面活性剂和碳氢/碳氟表面活性剂复配体系进行了比较.本文结果对三次采油和日用化工等领域的应用以及对理论研究都具有重要的意义. [keyword_cn] => 碳氟表面活性剂;;正交试验;;中相微乳液;;红外光谱 [fund_No] => 国家自然科学基金(29373110)资助项目 [article_id] => 13368,498058,620587,334500,239661 [clc] => O657.1 [author_jg] => [李干佐;马成松;沈强;郝京诚;汪汉卿]山东大学国家教委胶体和界面化学开放实验室@@@[李干佐;马成松;沈强;郝京诚;汪汉卿]山东大学国家教委胶体和界面化学开放实验室@@@[李干佐;马成松;沈强;郝京诚;汪汉卿]山东大学国家教委胶体和界面化学开放实验室@@@[李干佐;马成松;沈强;郝京诚;汪汉卿]中国科学院兰州化学物理所@@@[李干佐;马成松;沈强;郝京诚;汪汉卿]中国科学院兰州化学物理所 济南250100@@@[李干佐;马成松;沈强;郝京诚;汪汉卿]济南250100 中国科学院兰州化学物理所@@@[李干佐;马成松;沈强;郝京诚;汪汉卿]兰州730000@@@[李干佐;马成松;沈强;郝京诚;汪汉卿]济南250100@@@[李干佐;马成松;沈强;郝京诚;汪汉卿]兰州730000@@@[李干佐;马成松;沈强;郝京诚;汪汉卿]兰州730000 [format_title_cn_publication_cn_pub_year] => 199072d0c5f14098af762fe7596279d2566163968 [hints] => 5 [issue] => 4 [author_first] => 李干佐 [sys_level_num] => 2_3 [sys_jg_type] => 3,5 [format_issn_issue_page_pub_year] => 4694845071964a370858b47cb8fb97da1769279281 [source_type] => 351 [pub_year] => 1998 [pub_date] => 1998-04-20 [pages] => 7 [from_id] => 76,80,78,73,85 [author_cn] => 李干佐;马成松;沈强;郝京诚;汪汉卿 [issn] => 0567-7351 [batch] => 3250,3243,3241,3254,3252 [publication_cn] => 化学学报 [title_cn] => 碳氟表面活性剂复配体系的中相微乳液研究 [CSSN] => 31-1320/O6 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => ac5b3e24c12bcd548d0333d4c9e95969-450074295 [page] => 313-319 [hb_type] => 2 [article_dt] => Article [hb_batch] => title_cn_publication_cn_pub_year_2_3 [format_title_en] => 5dd4b36bd6e71b4ff148dc210692dd03-1098145532 [format_title] => edfb9c862df8aa830f368ac0e22f254a539723536 [hx_id] => 2378,2371 [format_publication_cn] => 6918be3b26b1fa6ec0424f6071208a75331227575 [format_publication_en] => 169b60c7845c9e5f36906950b18f11111348184734 [jl_publication_cn] => 化学学报 [jl_article_dt] => 期刊论文 [jl_country] => 中国 [jl_keyword_cn] => ,红外光谱,中相微乳液,碳氟表面活性剂,正交试验 [jl_clc] => o6571 [author_in] => [Li, G.-Z] Department of Chemistry, Shandong University, Jinan, 250100, China@@@[ Ma, C.-S] Department of Chemistry, Shandong University, Jinan, 250100, China, Institute of Lanzhou Chemical Physics, Lanzhou, 730000, China@@@[ Shen, Q] Department of Chemistry, Shandong University, Jinan, 250100, China@@@[ Hao, J.-C] Institute of Lanzhou Chemical Physics, Lanzhou, 730000, China@@@[ Wang, H.-Q] Institute of Lanzhou Chemical Physics, Lanzhou, 730000, China [company_id] => 0,43,169 [author_id] => 21081,23247 [author_test] => Array ( [0] => Array ( [sure] => 0 [irmagnum] => 0 [u_index] => 4 [name] => 郝京诚 [irtag] => 7 [t_index] => 0 [person_id] => 21081 ) [1] => Array ( [sure] => 0 [irmagnum] => 0 [u_index] => 3 [name] => 沈强 [irtag] => 7 [t_index] => 0 [person_id] => 23247 ) ) [sys_author_id_arr] => [jl_publication_cn_publication_en] => 化学学报 [jl_keyword_cn_keyword_en] => 中相微乳液,碳氟表面活性剂,正交试验,红外光谱 [cite_wos] => 0 [publication_en] => ACTA CHIMICA SINICA [check_3Y] => 1 [language] => Chinese [delivery_No] => ZQ821 [cauthor_ad] => [Li, GZ]Shandong Univ, Dept Chem, Jinan 250100, Peoples R China. [author_fn] => Li, GZ; Ma, CS; Shen, Q; Hao, JC; Wang, HQ [cite_wanfang] => 8 [format_title_en_issn_pub_year] => cfc55ceb784369c35e497b4a63adb2be789866787 [datebase] => Scopus [format_scopus_No] => 5fdaa703ad9c05480b6174cb22f68e971818741439 [publication_29] => ACTA CHIM SINICA [end_page] => 319 [abstract_en] => Sodium perfluorooctanoate/cetyltrimethylammonium bromide, n-propyl alcohol/butyl alcohol, octane and brine can form middle phase microemulsion. Its optimum components were found by using perpendicular experiment. The effect of salinity, concentration of surfactants and alcohol, kinds of hydrocarbon to the formation and characteristics of the middle phase microemulsion have also been investigated. Microstructure of the microemulsion was determined by infrared spectrum. The OBS/CTAB system was compared with CTAB land AOT/CTAB systems. The results are of importance to practical and theoretical research. [researcherID] => Shen, Qiang/D-8622-2013 [orcID] => Shen, Qiang/0000-0001-5579-036X [publication_type] => J [begin_page] => 313 [author_en] => Li, GZ; Ma, CS; Shen, Q; Hao, JC; Wang, HQ [volume] => 56 [publisher] => ACTA CHIMICA SINICA [get_data] => 2018-08-29 [keyword_en] => fluorocarbon/hydrocarbon surfactants; perpendicular experiment; middle; phase microemulsion; infrared spectrum [keyword_plu] => HYDROCARBON SURFACTANTS; MICELLES; MIXTURES; SYSTEM [publication_iso] => Acta Chim. Sin. [format_title_en_publication_en_pub_year] => fe8ce5716d814b55215e9e56b16093c5762137647 [publisher_city] => SHANGHAI [cauthor_order] => 1 [reference_No] => 14 [cite_awos] => 0 [wos_No] => WOS:000073906300001 [format_wos_No] => e890e39c777c2d4facd91303dbeb41f81339766874 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [cauthor_back] => Li, GZ [check_180] => 0 [publisher_ad] => SHANGHAI INST ORGANIC CHEM ACADEMIA SINICA 354 FENGLING LU, SHANGHAI; 200032, PEOPLES R CHINA [standard_in] => Department of Chemistry, Shandong University, Jinan, 250100, China; Institute of Lanzhou Chemical Physics, Lanzhou, 730000, China [scopus_No] => 2-s2.0-33749862228 [title_en] => Studies of middle phase microemulsion formed by mixed fluorocarbon/hydrocarbon surfactants [jl_language] => chinese [jl_author_test] => uirtypical3,uirtstag0,upersonid21081,unameuu6c88u5f3a,uuindex3,usureu0,uuindex4,utindex0,uirtag6,uirinspecttag0,upersonid23247,uirauthortype0,unameuu90ddu4eacu8bda [jl_publication_en] => actachimicasinica [sys_author_jg_last_arr] => 山东大学国家教委胶体和界面化学开放实验室,山东大学国家教委胶体和界面化学开放实验室,山东大学国家教委胶体和界面化学开放实验室,中国科学院兰州化学物理所,中国科学院兰州化学物理所济南250100,济南250100中国科学院兰州化学物理所,兰州730000,济南250100,兰州730000,兰州730000 [jl_keyword_en] => middle,phasemicroemulsion,infraredspectrum,perpendicularexperiment,fluorocarbonhydrocarbonsurfactants [sys_author_in_last_arr] => china [jl_publisher] => actachimicasinica [sys_author_id] => [sys_subject_sort] => 0,0 [college_parent_id] => 43,169 [company_test] => Array,Array [id] => tg1GvmUBFjIhTVEbGdA3 [tags] => 0 ) [8] => Array ( [batch2] => 1,2,6 [batch] => 3250,3243,3241,3254,3252 [tag] => 0 [abstract_cn] => 用量子化学理论方法研究了硅杂环丙烯单重态的异构化反应。结果表明:该异构化反应的过渡态为三元环结构,该反应为氢迁移反应;反应的势垒高度为276.67kJ·mol^-1[MP2/6-31G(d)]。通过内禀反应坐标(IRC)计算,获得了沿反应途径的势能剖面。 [keyword_cn] => 硅甲基乙炔;硅杂环丙烯;异构化;氢迁移;势能剖面; [clc] => O627.41 [author_jg] => [胡海泉;刘成卜]聊城师范学院物理系@@@[胡海泉;刘成卜]山东大学化学院 聊城252059@@@[胡海泉;刘成卜]济南250100 [format_title_cn_publication_cn_pub_year] => 131ffbef3f8362bb6e915f6b1dc79d83-370120769 [from_id] => 76,80,85,73,78 [issue] => 12 [sys_level_num] => 2_1 [sys_jg_type] => 9,5 [source_type] => 351 [pub_year] => 1998 [article_id] => 239535,44191,648251,334512,498071 [pages] => 4 [hints] => 8 [author_cn] => 胡海泉[1];刘成卜[2] [issn] => 0567-7351 [uri] => https://www.scopus.com/inward/record.uri?eid=2-s2.0-33749853777&partnerID=40&md5=f22db637fc815659bdb52b7ff9ccd09b [publication_cn] => 化学学报 [title_cn] => 硅杂环丙烯异构化反应的理论研究 [CSSN] => 31-1320/O6 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => 4cdb1e8207f1a42d2bb1e5883a175563-308202710 [hb_type] => 2 [hb_batch] => title_cn_publication_cn_pub_year_2_3 [publication_en] => ACTA CHIMICA SINICA [cite_wos] => 0 [fund_No] => 国家自然科学基金资助课题(29473106) [check_3Y] => 0 [language] => Chinese [delivery_No] => 153CA [format_title] => 8c8229766ba6150210d58bed6c23c2f9-921122288 [cauthor_ad] => [Hu, HQ]Liaocheng Teachers Univ, Dept Phys, Liaocheng 252059, Peoples R China. [author_fn] => Hu, HQ; Liu, CB [publication_29] => ACTA CHIM SINICA [end_page] => 1183 [abstract_en] => The isomerization of singlet silacyclopropene has been studied by using MP2 method of quantum chemistry with 6 - 31G(d) basis set. The transition state for this reaction has been found to be a 3- membered ring, and the intrinsic reaction coordinate(IRC) calculation has been performed. The barrier height is 276.67kJ . mol(-1) and the released energy is 41.40kJ . mol(-1). The relative-structure data of the reactant,the transition state and the product are given. [author_in] => [Hu, H.-Q] Department of Physics, Liaocheng Teachers University, Liaocheng, 252059, China@@@[ Liu, C.-B] College of Chemistry, Shandong University, Jinan, 250100, China [publication_type] => J [begin_page] => 1180 [article_dt] => Article [author_en] => Hu, HQ; Liu, CB [volume] => 56 [get_data] => 2018-08-29 [publisher] => ACTA CHIMICA SINICA [keyword_en] => silacyclopropene; isomerization; hydrogen migration; potential curve [format_publication_cn] => 6918be3b26b1fa6ec0424f6071208a75331227575 [keyword_plu] => INSERTION [publication_iso] => Acta Chim. Sin. [format_title_en] => 377a193ce5b7cbfab626b6d035869d0d-1468578729 [publisher_city] => SHANGHAI [pub_date] => 1998-12-20 [hx_id] => 2378,2371 [reference_No] => 6 [cite_awos] => 0 [wos_No] => WOS:000077814300006 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [check_180] => 0 [publisher_ad] => SHANGHAI INST ORGANIC CHEM ACADEMIA SINICA 354 FENGLING LU, SHANGHAI; 200032, PEOPLES R CHINA [title_en] => Mechanism of the isomerization of silacyclopropene [format_publication_en] => 169b60c7845c9e5f36906950b18f11111348184734 [jl_language] => chinese [jl_publication_cn] => 化学学报 [jl_article_dt] => 期刊论文 [jl_publication_en] => actachimicasinica [jl_country] => 中国,中国 [jl_keyword_en] => hydrogenmigration,isomerization,potentialcurve,silacyclopropene [jl_keyword_cn] => ,氢迁移,硅杂环丙烯,硅甲基乙炔,势能剖面,异构化 [jl_clc] => o62741 [jl_publisher] => actachimicasinica [company_id] => 43,169 [sys_subject_sort] => 0,0 [college_parent_id] => 43,169 [company_test] => Array,Array [author_id] => [author_test] => Array ( ) [sys_author_id_arr] => [jl_publication_cn_publication_en] => actachimicasinica,化学学报 [jl_keyword_cn_keyword_en] => 势能剖面,potentialcurve,silacyclopropene,硅杂环丙烯,硅甲基乙炔,氢迁移,hydrogenmigration,异构化,isomerization [sys_author_id] => [format_title_en_publication_en_pub_year] => e479c8c3de56b8d196f438a2d19d97a9-1530890141 [format_wos_No] => f1fb40c6118a099d2a2676e462b305a9-1810233225 [format_title_en_issn_pub_year] => 801483e5e49ce05da87e951a68c5485c-415647274 [datebase] => Scopus [format_scopus_No] => fb7b73043835676dfc6733747895eb972021194805 [page] => 1182-1183 [format_issn_issue_page_pub_year] => 40eb658cff2b6a3c139607493dd4cabe-1625918789 [sys_priority_field] => 76 [standard_in] => Department of Physics, Liaocheng Teachers University, Liaocheng, 252059, China; College of Chemistry, Shandong University, Jinan, 250100, China [scopus_No] => 2-s2.0-33749853777 [id] => hgoyvmUBFjIhTVEbdE2G [tags] => 0 ) [9] => Array ( [batch2] => 1,2,6 [batch] => 3250,3243,3241,3254,3252 [tag] => 0 [abstract_cn] => 合成了两种新的钴(Ⅱ)schiff碱配合物水杨醛L-甲硫氨酸-水合钴(Ⅱ)(1),邻香兰素L-甲硫氨酸-水合钴(Ⅱ)(2)通过元素分析、红外光谱、热分析等测试手段研究了配合物的性质,并确定了配合物的组成。用气体吸收装置测定配合物在乙腈溶液中不同温度下的饱和吸氧量,求得氧合反应的平衡常数及热力学参数,同时探讨了温度和配体结构对配合物氧合性能的影响.用TG-DTG法研究了配合物的热稳定性及非等温热分解动力学,并采用积分法和微分法相结合的方法,推断了两种配合物的第一步热分解反应机理,得到了热分解反应动力学参数及其动力学方程. [keyword_cn] => 钴(Ⅱ)配合物;schiff碱;氧合反应热力学;热分解反应动力学 [article_id] => 498158,239397,648259,44189,334502 [clc] => O644 [author_jg] => [李淑兰,孟凡芹,刘德信,杨兆荷]山东大学化学系,山东大学化学系,山东大学化学系,山东大学晶体材料研究所 济南250100,济南250100,济南250100,济南250100 [format_title_cn_publication_cn_pub_year] => 25006f53046e2f1153643449e9a8ba6a888282343 [hints] => 11 [issue] => 5 [sys_level_num] => 2_3 [sys_jg_type] => 0,5 [format_issn_issue_page_pub_year] => dfb9a7d4c6369c0d069efa651b23db35-867182157 [source_type] => 351 [pub_year] => 1998 [pub_date] => 1998-05-20 [pages] => 6 [from_id] => 76,80,78,73,85 [author_cn] => 李淑兰,孟凡芹,刘德信,杨兆荷 [issn] => 0567-7351 [uri] => http://kns.cnki.net/kns/detail/detail.aspx?FileName=HXXB199805010&DbName=CJFQ1998 [publication_cn] => 化学学报 [title_cn] => Co(Ⅱ)Schiff碱配合物的合成、氧合反应热力学及热分解动力学的研究 [CSSN] => 31-1320/O6 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => 0ab8ed80068169953b3ae11641715b2b1923491053 [page] => 478-483 [hb_type] => 2 [article_dt] => Article [hb_batch] => title_cn_publication_cn_pub_year_2_3 [format_title_en] => e686fc2d51d09a197f3c76796e56f8f61779492906 [format_title] => ce0a2c9f1d94383c4a9827cb078715bb-386826545 [hx_id] => 2378,2371 [format_publication_cn] => 6918be3b26b1fa6ec0424f6071208a75331227575 [format_publication_en] => 169b60c7845c9e5f36906950b18f11111348184734 [jl_publication_cn] => 化学学报 [jl_article_dt] => 期刊论文 [jl_keyword_cn] => schiff碱,钴Ⅱ配合物,热分解反应动力学,氧合反应热力学 [jl_clc] => o644 [author_in] => [Li, S.-L] Department of Chemistry, Shandong University, Jinan, 250100, China@@@[ Meng, F.-Q] Department of Chemistry, Shandong University, Jinan, 250100, China@@@[ Liu, D.-X] Department of Chemistry, Shandong University, Jinan, 250100, China@@@[ Yang, Z.-H] Institute of Crystal Material, Shandong University, Jinan, 250100, China [company_id] => 24,0,151,43,169 [sys_subject_sort] => 0,0,0,0 [college_parent_id] => 24,151,43,169 [company_test] => Array,Array,Array,Array [author_id] => [author_test] => Array ( ) [sys_author_id_arr] => [jl_publication_cn_publication_en] => 化学学报 [jl_keyword_cn_keyword_en] => schiff碱,钴Ⅱ配合物,热分解反应动力学,氧合反应热力学 [cite_wos] => 7 [publication_en] => ACTA CHIMICA SINICA [check_3Y] => 1 [language] => Chinese [delivery_No] => ZT693 [cauthor_ad] => [Li, SL]Shandong Univ, Dept Chem, Jinan 250100, Peoples R China. [author_fn] => Li, SL; Meng, FQ; Liu, DX; Yang, ZH [cite_wanfang] => 21 [format_title_en_issn_pub_year] => eaa6947e7c8b8f85eccedba0e0950ebe61941124 [datebase] => Scopus [format_scopus_No] => 3e390a70551a9c81f1b0e310af94bb2c-10496174 [publication_29] => ACTA CHIM SINICA [end_page] => 483 [abstract_en] => Two new cobalt( II) schiff base complexes were prepared and characterized by elemental analyses, IR spectra and thermal analyses. The compositions of the complexes were also determined. Saturated oxygen uptake of the complexes in CH3CN solvent at different temperatures was obtained by manometric oxygen-uptake measurements. Oxygenation equilibrium constants and its thermodynamic parameters Delta H degrees, Delta S degrees were calculated from the above measurements. The effects of temperature and ligand structure on oxygenation were discussed. The thermal stability and non-isothermal kinetics of thermal decomposition reaction were also investigated by TG-DTG technique. The possible reaction mechanisms of their first step of thermodecomposition were deduced by means of integral and differential equations. [publication_type] => J [begin_page] => 478 [author_en] => Li, SL; Meng, FQ; Liu, DX; Yang, ZH [volume] => 56 [publisher] => ACTA CHIMICA SINICA [get_data] => 2018-08-29 [keyword_en] => cobalt( II ) complexes; schiff base; oxygenation thermodynamics;; kinetics of thermal decomposition [publication_iso] => Acta Chim. Sin. [format_title_en_publication_en_pub_year] => 976f75cebec3273b1e4c5afaffd8349a-1234744020 [publisher_city] => SHANGHAI [cauthor_order] => 1 [reference_No] => 21 [cite_awos] => 7 [wos_No] => WOS:000074115200011 [format_wos_No] => f7b80624378e3734d05c894b8cc0d6a9970619356 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [cauthor_back] => Li, SL [check_180] => 0 [publisher_ad] => SHANGHAI INST ORGANIC CHEM ACADEMIA SINICA 354 FENGLING LU, SHANGHAI; 200032, PEOPLES R CHINA [standard_in] => Department of Chemistry, Shandong University, Jinan, 250100, China; Institute of Crystal Material, Shandong University, Jinan, 250100, China [scopus_No] => 2-s2.0-33750422658 [title_en] => Studies on synthesis, oxygenation thermodynamics and kinetics of thermal decomposition of cobalt(II) Schiff base complexes [jl_language] => chinese [jl_publication_en] => actachimicasinica [sys_author_jg_last_arr] => 济南250100 [jl_company_test] => uircu0,uorgidu24,uparentidu24,unameuu6676u4f53u6750u6599u7814u7a76u6240,ulevelu1 [jl_country] => 中国 [jl_keyword_en] => ,oxygenationthermodynamics,cobaltiicomplexes,schiffbase,kineticsofthermaldecomposition [sys_author_in_last_arr] => china [jl_publisher] => actachimicasinica [sys_author_id] => [id] => iQ1EvmUBFjIhTVEbKmEG [tags] => 0 ) [10] => Array ( [issn] => 0567-7351 [delivery_No] => 145LH [batch2] => 1,2,6 [hb_batch] => 3241 [tag] => 0 [author_en] => Lu, TX; Li, GZ; Li, XZ; Sun, WB; Wu, Q [abstract_en] => Effects of the photolytically generated naphthoquinone radicals in the solutions containing different surfactants were studied by using the time - resolved ESR spectroscopy. In the ethylene glycol solvent the CIDEP effects of the naphthosemiquinone radical and ethylene glycol ketyl radical after irradiation at 308nm were observed due to triplet mechanism (TRI). In the TX - 100 micelle solution, the signals of the spin polarization of the naphthoquinone anion were observed, which was attributed to the electron transition between the polarized triplet of the naphthoquinone and TX - 100 micelle. [publication_type] => J [keyword_plu] => LASER-PHOTOLYSIS [author_in] => [Lu, T.-X] Department of Physics, Anhui Normal University, Wuhu, 241000, China@@@[ Li, G.-Z] College of Chemistry, Laboratory of Colloid and Interface Chemistry, Shandong University, Jinan, 250100, China@@@[ Li, X.-Z] College of Chemistry, Laboratory of Colloid and Interface Chemistry, Shandong University, Jinan, 250100, China@@@[ Sun, W.-B] Department of Physics, Anhui Normal University, Wuhu, 241000, China@@@[ Wu, Q] Department of Chemistry, Chinese University, Hongkong, Hong Kong [publisher_city] => SHANGHAI [article_id] => 554934,239385,498009,334510 [get_data] => 2018-08-29 [format_title_en_publication_en_pub_year] => 27b11967cd68fc35ab043c6ce3d9eab927895775 [begin_page] => 1041 [cite_wos] => 4 [check_3Y] => 0 [cite_awos] => 4 [from_id] => 76,80,73,78 [cauthor_ad] => [Lu, TX]Anhui Normal Univ, Dept Phys, Wuhu 241000, Peoples R China. [hx_id] => 2378,2371 [cauthor_order] => 1 [research_area] => Chemistry [sys_level_num] => 1_7 [publisher] => ACTA CHIMICA SINICA [sys_jg_type] => 0,5 [format_issn_issue_page_pub_year] => e4cd3beadbda423fe155605c49d9aed4-455708431 [title_en] => The TRESR study of the naphthoquinone radicals photolytically generated in TX-100 micelle [publication_29] => ACTA CHIM SINICA [author_fn] => Lu, TX; Li, GZ; Li, XZ; Sun, WB; Wu, Q [pub_year] => 1998 [publisher_ad] => SHANGHAI INST ORGANIC CHEM ACADEMIA SINICA 354 FENGLING LU, SHANGHAI; 200032, PEOPLES R CHINA [check_180] => 0 [keyword_en] => CIDEP; naphthoquinone; micelle; electron transition [end_page] => 1047 [cauthor_back] => Lu, TX [pages] => 7 [format_wos_No] => a1602250ad23c400f044bb13a15e8046-423039983 [hints] => 28 [volume] => 56 [language] => Chinese [source_type] => 351 [issue] => 11 [reference_No] => 8 [batch] => 3250,3243,3241,3252 [publication_en] => ACTA CHIMICA SINICA [school_id] => 117 [sys_update_time] => 2018-09-05 15:29:31 [format_title_en_issn_pub_year] => 5f6a4e15ae1bd3cb422ed01acf4e6a07961194360 [publication_iso] => Acta Chim. Sin. [wos_sub] => Chemistry, Multidisciplinary [SYS_TAG] => 3 [wos_No] => WOS:000077372200001 [page] => 1041-1047 [hb_type] => 2 [article_dt] => Article [jl_language] => chinese [jl_article_dt] => 期刊论文 [jl_publication_en] => actachimicasinica [jl_country] => 中国 [jl_keyword_en] => micelle,naphthoquinone,electrontransition,cidep [jl_publisher] => actachimicasinica [author_jg] => [陆同兴,李干佐,李锡忠,孙文斌,吴奇]安徽师范大学物理系,山东大学国家教委胶体和界面化学开放室,山东大学国家教委胶体和界面化学开放室,安徽师范大学物理系,香港中文大学化学系 芜湖241000,济南250100,济南250100,芜湖241000,香港 [keyword_cn] => CIDEP;萘醌;胶束;电子转移 [format_title] => 7eeef8ce2600cfdaadd569ebe8a781be-841825613 [cite_wanfang] => 6 [clc] => Z89 [title_cn] => TX—100胶束中光解萘醌自由基的电子自旋极化研究 [format_publication_cn] => 6918be3b26b1fa6ec0424f6071208a75331227575 [publication_cn] => 化学学报 [format_title_en] => f06cff995b270084aafe1275ece9d8161005524936 [CSSN] => 31-1320/O6 [abstract_cn] => 利用高时间分辨的电子自旋共振波谱仪(TRESR),研究了含有不同表面活性剂溶液中光解萘醌自由基CIDEP.在乙二醇溶剂中,在308nm的紫外激光照射下得到三重态机理极化的中性萘半醌自由基和以碳为中心的自由基R(OH)_2的信号,在表面活性剂TX-100的胶束中,得到萘醌阴离子自由基信号,并用萘醌分子与TX-100胶束间的电子转移进行解释. [sys_priority_field] => 76 [author_cn] => 陆同兴,李干佐,李锡忠,孙文斌,吴奇 [format_publication_en] => 169b60c7845c9e5f36906950b18f11111348184734 [uri] => https://www.scopus.com/inward/record.uri?eid=2-s2.0-33748664173&partnerID=40&md5=d95577d162b33908f100c3a2d89d4881 [jl_publication_cn] => 化学学报 [jl_keyword_cn] => 电子转移,萘醌,cidep,胶束 [jl_clc] => z89 [company_id] => 133,0,5,43,169 [sys_subject_sort] => 0,0,0,0 [college_parent_id] => 133,5,43,169 [company_test] => Array,Array,Array,Array [author_id] => [author_test] => Array ( ) [sys_author_id_arr] => [jl_publication_cn_publication_en] => actachimicasinica,化学学报 [jl_keyword_cn_keyword_en] => 萘醌,micelle,cidep,electrontransition,naphthoquinone,电子转移,胶束 [datebase] => Scopus [format_scopus_No] => bc2c392e1ac673488e469db6d112b3fa1033006131 [cite_scopus] => 1 [standard_in] => Department of Physics, Anhui Normal University, Wuhu, 241000, China; College of Chemistry, Laboratory of Colloid and Interface Chemistry, Shandong University, Jinan, 250100, China; Department of Chemistry, Chinese University, Hongkong, Hong Kong [scopus_No] => 2-s2.0-33748664173 [format_title_cn_publication_cn_pub_year] => 169a5bae9f210dd48a0cce08ac65e1ad-1808326307 [format_title_cn_issn_pub_year] => 395662b1268074a54b61579858e9bcfe1786477539 [sys_author_jg_last_arr] => 香港 [jl_company_test] => unameuu5316u5b66u4e0eu5316u5de5u5b66u9662,uorgidu5,uparentidu43,unameuu7269u7406u5b66u9662,uircu0,uorgidu43,ulevelu1,uparentidu5 [sys_author_in_last_arr] => china [sys_author_id] => [id] => vQifvWUBFjIhTVEbUuIW [tags] => 0 ) [11] => Array ( [issn] => 0567-7351 [delivery_No] => XD340 [batch2] => 1,2 [hb_batch] => 3241 [tag] => 0 [author_en] => Hao, JC; Li, GZ; Wang, HQ; Liu, WM [abstract_en] => The equilibrium phase diagram for the system dioctadecyldimethylammonium chloride (DODMAC)/n-decanol/n-decane/water was determined at 50 degrees C. The hyperfine structures of the liquid crystal phase were studied by H-2 NMR, X-ray low-angle diffraction,and polarizing microscopy. All results showed that there was a reversed hexagonal liquid crystalline phase. The connection between crystalline face distance(d(1)) and the content of water [f(w)/(1-f(w))] was obtained and the diameter of the cylindrical assemble was getted to be 4.035nm. [publication_type] => J [keyword_plu] => WATER [author_in] => [Hao, JC; Li, GZ; Wang, HQ; Liu, WM]SHANDONG UNIV,DEPT CHEM,JINAN 250100,PEOPLES R CHINA.@@@[Hao, JC; Li, GZ; Wang, HQ; Liu, WM] CHINESE ACAD SCI,LANZHOU INST CHEM PHYS,LAB SOLID LUBRICAT,LANZHOU 730000,PEOPLES R CHINA. [publisher_city] => SHANGHAI [article_id] => 334863,167949,84566,620586,213696 [get_data] => 2018-08-29 [format_title_en_publication_en_pub_year] => 406dc61bc98a9f1ce186fcc2c6f31011 [pages] => 7 [cite_wos] => 0 [check_3Y] => 2 [cite_awos] => 0 [from_id] => 80,78,73,85 [cauthor_ad] => [Hao, JC]SHANDONG NORMAL UNIV,DEPT CHEM,JINAN 250014,PEOPLES R CHINA. [school_id] => 117 [cauthor_order] => 1 [research_area] => Chemistry [sys_level_num] => 1_7 [publisher] => ACTA CHIMICA SINICA [sys_jg_type] => 10,5 [format_issn_issue_page_pub_year] => d0b5a157a05dd38df1ff7596f66ee7ad [title_en] => Studies on lyotropic liquid crystal in the system DODMAC/n-C10H21OH/n-C10H22/H2O with H-2 NMR and SAXS [publication_29] => ACTA CHIM SINICA [author_fn] => Hao, JC; Li, GZ; Wang, HQ; Liu, WM [pub_year] => 1997 [publisher_ad] => SHANGHAI INST ORGANIC CHEM ACADEMIA SINICA 345 LINGLING LU, SHANGHAI,; PEOPLES R CHINA [check_180] => 0 [end_page] => 497 [cauthor_back] => Hao, JC [begin_page] => 491 [format_wos_No] => 80cad16c3b21d8270f4a2d75dbf98122 [hints] => 7 [volume] => 55 [language] => Chinese [source_type] => 351 [issue] => 5 [reference_No] => 13 [batch] => 3250,3241,3254,3252 [publication_en] => ACTA CHIMICA SINICA [hx_id] => 2371 [sys_update_time] => 2018-09-05 15:29:31 [format_title_en_issn_pub_year] => 7ba39349a385d3e3d3637c80fb89d5f7 [publication_iso] => Acta Chim. Sin. [wos_sub] => Chemistry, Multidisciplinary [SYS_TAG] => 3 [wos_No] => WOS:A1997XD34000013 [page] => 491-497 [hb_type] => 2 [article_dt] => Article [jl_language] => chinese [jl_publication_en] => actachimicasinica [jl_article_dt] => 期刊论文 [jl_country] => 纳米比亚,瑞士,印度,苏里南,中国,西班牙,波兰,秘鲁 [jl_publisher] => actachimicasinica [author_jg] => [郝京诚,李干佐,汪汉卿,刘维民]山东师范大学化学系,山东大学化学系,中国科学院兰州化学物理研究所固体润滑开放实验室,中国科学院兰州化学物理研究所固体润滑开放实验室 济南250014,济南250100,兰州730000,兰州730000 [keyword_cn] => DODMAC;溶致液晶;~2HNMR;SAXS [format_title] => 4d6ccb31c54021046b1955bb69c5db631137774441 [clc] => O646 [title_cn] => DODMAC/n-C_(10)H_(21)OH/10% n-C_(10)H_(22)/H_2O体系溶致液晶的~2H NMR和SAXS研究 [format_publication_cn] => 6918be3b26b1fa6ec0424f6071208a75331227575 [publication_cn] => 化学学报 [format_title_en] => 380a6367179598ccab7bfe473edb7a7f-569989861 [sys_priority_field] => 73 [author_cn] => 郝京诚,李干佐,汪汉卿,刘维民 [format_publication_en] => 169b60c7845c9e5f36906950b18f11111348184734 [jl_publication_cn] => 化学学报 [jl_keyword_cn] => dodmac,溶致液晶,2hnmr,saxs [jl_clc] => o646 [company_id] => 0,43,169 [sys_subject_sort] => 0,0 [college_parent_id] => 43,169 [company_test] => Array,Array [author_id] => 23902,22443,21081 [author_test] => Array ( [0] => Array ( [sure] => 0 [irmagnum] => 0 [u_index] => 0 [name] => 王海庆 [irtag] => 7 [t_index] => 0 [person_id] => 23902 ) [1] => Array ( [sure] => 0 [irmagnum] => 0 [u_index] => 0 [name] => 刘维民 [irtag] => 7 [t_index] => 0 [person_id] => 22443 ) [2] => Array ( [sure] => 0 [irmagnum] => 0 [u_index] => 0 [name] => 郝京诚 [irtag] => 2 [t_index] => 0 [person_id] => 21081 ) ) [sys_author_id_arr] => 21081郝京诚 [jl_publication_cn_publication_en] => 化学学报,actachimicasinica [jl_keyword_cn_keyword_en] => dodmac,溶致液晶,2hnmr,saxs [sys_author_id] => 21081 [format_title_cn_publication_cn_pub_year] => 26cf91202fb7056150dc02946fcc95a2 [format_title_cn_issn_pub_year] => 3ada6a2c2ac64de5e755d2ee7e958a7c [CSSN] => 31-1320/O6 [abstract_cn] => 50℃下,测定了双十八烷基二甲基氯化铵(DODMAC)/n-C_(10)H_(21)OH/10%n-C_(10)H_(22)/H_2O四元体系相图,确定了液晶区域范围,用~2H NMR方法,并辅以偏光显微镜照片,确定了液晶为反相六角状,用SAXS求出了液晶晶面间距,确定了晶面间距d_1与含水量f_w/(1-f_w)之间的线性关系,并求得圆柱形聚集体的直径d_s=4.035nm. [uri] => http://kns.cnki.net/kns/detail/detail.aspx?FileName=HXXB199705012&DbName=CJFQ1997 [jl_pub_year] => 1997 [jl_author_test] => uirtagu7,upersonidu23902,usureu0,usureu1,uirtagu2,uirtypicalu,uirtstagu,uuindexu4,unameuu738bu6d77u5e86,uuindexu1,upersonidu22443,uuindexu3,uirauthortypeu,upersonidu21081,utindexu1,uirinspecttagu,unameuu90ddu4eacu8bda,unameuu5218u7ef4u6c11,utindexu0 [sys_author_jg_last_arr] => 兰州730000 [jl_company_test] => uircu0,unameuu5316u5b66u4e0eu5316u5de5u5b66u9662,uparentidu43,uorgidu43,ulevelu1 [sys_author_in_last_arr] => peoplesrchina [id] => fgifvWUBFjIhTVEbF9T9 [tags] => 0 ) [12] => Array ( [batch2] => 1,2,6 [batch] => 3250,3243,3241,3254,3252 [tag] => 0 [abstract_cn] => 用滴体积法研究了HDEHP在不同稀释剂-0.05mol·dm~(-3)(H_2,Na_2)SO_4(pH=2.40)体系中的界面性质,认为吸附于液-液界面的是单体HDEHP分子,得到了各体系中HDEHP的C_(min),Г_(max),A_i以及ΔG_(ad)等界面吸附参数.HDEHP在不同稀释剂体系中的界面活性顺序为:脂肪烃>芳香烃>氯仿>甲基异丁基酮,这种变化主要是在体相中和界面上稀释剂与萃取剂、界面上的萃取剂及稀释剂与界面层水之间分子间相互作用的结果.同时讨论了HDEHP在不同稀释剂中的萃取动力学机理. [keyword_cn] => HDEHP;稀释剂;界面性质;萃取动力学 [article_id] => 170615,498348,334856,539403,70236 [clc] => O643.3 [author_jg] => [杨永会,宋其圣,杨延钊,崔玉,孙国新,孙思修]山东大学化学系,山东大学化学系,山东大学化学系,山东建筑材料工业学院应用化学系,中国科学院上海原子核所 济南250100,济南250100,济南250100,济南250022,博士生 [format_title_cn_publication_cn_pub_year] => 75e3abb27e7cca19533fff5019f977a51853809872 [hints] => 7 [issue] => 1 [sys_level_num] => 2_3 [sys_jg_type] => 0,5 [format_issn_issue_page_pub_year] => 0ed5de6f2f35a63ce4d0dac9e1a2b3c2738798064 [source_type] => 351 [pub_year] => 1997 [pub_date] => 1997-01-20 [pages] => 5 [from_id] => 76,80,78,73,85 [author_cn] => 杨永会,宋其圣,杨延钊,崔玉,孙国新,孙思修 [issn] => 0567-7351 [uri] => http://kns.cnki.net/kns/detail/detail.aspx?FileName=HXXB199701010&DbName=CJFQ1997 [publication_cn] => 化学学报 [title_cn] => 不同稀释剂中HDEHP的界面性质研究 [CSSN] => 31-1320/O6 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => a8bd8111647dc8120e28e917671878ce-1876569061 [page] => 64-68 [hb_type] => 2 [article_dt] => Article [hb_batch] => title_cn_publication_cn_pub_year_2_3 [format_title_en] => 7f8920fc3c85b5d9d0acc277f75eecdf1213015277 [format_title] => c4b83cd5764557862c84942bf1aa1228320737426 [hx_id] => 2378,2371 [format_publication_cn] => 6918be3b26b1fa6ec0424f6071208a75331227575 [format_publication_en] => 169b60c7845c9e5f36906950b18f11111348184734 [jl_publication_cn] => 化学学报 [jl_article_dt] => 期刊论文 [jl_keyword_cn] => 稀释剂,hdehp,萃取动力学,界面性质 [jl_clc] => o6433 [author_in] => [Xiu, S.S] Department of ChemisLry, Shandong University, Jinan,250100, China@@@[ Xin, S.G] Department of ChemisLry, Shandong University, Jinan,250100, China@@@[ Yu, C.U.I] Department of ChemisLry, Shandong University, Jinan,250100, China [company_id] => 0,43,169 [author_id] => [author_test] => Array ( ) [sys_author_id_arr] => [jl_publication_cn_publication_en] => 化学学报 [jl_keyword_cn_keyword_en] => 稀释剂,界面性质,hdehp,萃取动力学 [publication_en] => ACTA CHIMICA SINICA [cite_wos] => 2 [check_3Y] => 2 [language] => Chinese [delivery_No] => WR736 [cauthor_ad] => [Sun, SX]SHANDONG UNIV,DEPT CHEM,JINAN 250100,PEOPLES R CHINA. [author_fn] => Sun, SX; Sun, GX; Cui, Y; Yang, YH; Song, QS; Yang, YZ [format_title_en_issn_pub_year] => 5d4df392efc52ccf6b92e2a18fe33d32-60026656 [datebase] => Scopus [format_scopus_No] => a0c3dc67d990750a8315a29b53d17ca81199074733 [publication_29] => ACTA CHIM SINICA [end_page] => 68 [abstract_en] => The interfacial properties of HDEHP in different diluent - 0.05mol/L (H-2, Na-2) SO4 (pH = 2.40) systems have been studied with the Drop Method. The interfacial parameters, c(min), Gamma(max), A(i) and Delta G(ad), of HDEHP have been obtained. It was suggested that the monomeric HDEHP molecule was the species adsorbed on the interface. The interfacial activity of HDEHP in different system decreased as follows: aliphatic hydrocarbon, aromatic hydrocarbon, carbon tetrachloride, chloroform, MIBK. This might be attributed to the molecular interaction between diluent and extractant or (and) diluent and water immediately adjacent to the interface. The extraction kinetics with HDEHP in different diluents has also been discussed. [publication_type] => J [begin_page] => 64 [author_en] => Sun, SX; Sun, GX; Cui, Y; Yang, YH; Song, QS; Yang, YZ [volume] => 55 [get_data] => 2018-08-29 [publisher] => ACTA CHIMICA SINICA [keyword_plu] => SOLVENT-EXTRACTION; COPPER-EXTRACTION; SURFACE EXCESS; HYDROXYOXIMES; MECHANISM; KINETICS; LIQUID; ACID [publication_iso] => Acta Chim. Sin. [format_title_en_publication_en_pub_year] => 8fb1717c1e912145372daea237162d2b899764168 [publisher_city] => SHANGHAI [cauthor_order] => 1 [reference_No] => 11 [cite_awos] => 2 [wos_No] => WOS:A1997WR73600011 [format_wos_No] => 868c673d98e23d6e7ce6a97f14d0f920624388803 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [cauthor_back] => Sun, SX [check_180] => 0 [publisher_ad] => SHANGHAI INST ORGANIC CHEM ACADEMIA SINICA 345 LINGLING LU, SHANGHAI,; PEOPLES R CHINA [standard_in] => Department of ChemisLry, Shandong University, Jinan,250100, China [scopus_No] => 2-s2.0-33751130599 [title_en] => Effect of diluents on the interfacial properties of HDEHP [jl_language] => chinese [jl_publication_en] => actachimicasinica [sys_author_jg_last_arr] => 博士生 [jl_country] => 中国 [sys_author_in_last_arr] => china [jl_publisher] => actachimicasinica [sys_author_id] => [sys_subject_sort] => 0,0 [college_parent_id] => 43,169 [company_test] => Array,Array [id] => 9w9KvmUBFjIhTVEbYAQa [tags] => 0 ) [13] => Array ( [batch2] => 1,2,6 [uri] => http://kns.cnki.net/kns/detail/detail.aspx?FileName=HXXB199709015&DbName=CJFQ1997 [tag] => 0 [abstract_cn] => 本文研究了对十一烯酰胺基偶氮苯及其硅氧烷均聚、共聚的梳状聚合物在溶液或薄膜状态下的光致变色性和热回复性.它们的反、顺异构体组分比随光照时间趋於某稳定值,该稳定的组分比与照射光波长有关.光异构反应是可逆的.比较了异构反应速率和异构转换率,以聚硅氧烷共聚物PSll_3A[侧基比(M_1/M_2)=1/9,M_是对十一烯酰胺基偶氮苯,M_2是对十一烯酰氧对甲氧基苯酯]为最佳.升高温度能增进热回复异构. [keyword_cn] => 聚硅氧烷;;梳状聚合物;;光致变色;;光异构 [fund_No] => 国家自然科学基金资助课题 [article_id] => 155188,334869,498405,554939,3222 [clc] => O643.3 [author_jg] => [张静智;张其震]山东大学化学系@@@[张静智;张其震]山东大学化学系 济南250100@@@[张静智;张其震]济南250100 [format_title_cn_publication_cn_pub_year] => da6f3ce37a160e9372cfcd366595595a-1261608474 [hints] => 11 [issue] => 9 [author_first] => 张静智 [sys_level_num] => 2_3 [sys_jg_type] => 0,5 [format_issn_issue_page_pub_year] => 44ecd1ffdc55228f4a7ef6c1c15cdd7e-286422625 [source_type] => 351 [pub_year] => 1997 [pub_date] => 1997-09-20 [pages] => 7 [from_id] => 76,80,78,73,85 [author_cn] => 张静智;张其震 [issn] => 0567-7351 [batch] => 3250,3243,3241,3254,3252 [publication_cn] => 化学学报 [title_cn] => 侧基含偶氮基的硅氧烷梳状聚合物的光致变色性 [CSSN] => 31-1320/O6 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => bddb54f64ed5ea13ce88c3b738b59d861511813962 [page] => 930-936 [hb_type] => 2 [article_dt] => Article [hb_batch] => title_cn_publication_cn_pub_year_2_3 [format_title_en] => 0cf7937aa0f02c2de93cb6e7c2b2298c1725843164 [format_title] => 51fccc8a9d8deeab20f79192d2b278c2-1843156150 [hx_id] => 2378,2371 [format_publication_cn] => 6918be3b26b1fa6ec0424f6071208a75331227575 [format_publication_en] => 169b60c7845c9e5f36906950b18f11111348184734 [jl_publication_cn] => 化学学报 [jl_article_dt] => 期刊论文 [jl_keyword_cn] => ,光致变色,梳状聚合物,光异构,聚硅氧烷 [jl_clc] => o6433 [author_in] => [Zhang, J.-Z] Department of Chemistry, Shandong University, Jinan, 250100, China@@@[ Zhang, Q.-Z] Department of Chemistry, Shandong University, Jinan, 250100, China [company_id] => 0,43,169 [author_id] => [author_test] => Array ( ) [sys_author_id_arr] => [jl_publication_cn_publication_en] => 化学学报 [jl_keyword_cn_keyword_en] => 聚硅氧烷,梳状聚合物,光异构,光致变色 [publication_en] => ACTA CHIMICA SINICA [cite_wos] => 14 [check_3Y] => 2 [language] => Chinese [delivery_No] => YB058 [cauthor_ad] => [Zhang, JZ]SHANDONG UNIV,DEPT CHEM,JINAN 250100,PEOPLES R CHINA. [author_fn] => Zhang, JZ; Zhang, QZ [format_title_en_issn_pub_year] => a2e133f3f07d7612354e9bc6d57bd382469184425 [datebase] => Scopus [format_scopus_No] => 4d55f296c18170143d70092b0cc5b00f10285318 [publication_29] => ACTA CHIM SINICA [end_page] => 936 [abstract_en] => This paper describes the photochromism and thermal back - isomerization of 4 - undecylen - [10] - amidoazobenzene and its homo - and copolysiloxanes in solution and solid film. The composition ratio of cis/tran isomers tends to be constant in with irradiation time. The photostationary stale composition is only related to irradiation wave length. The photoisomerization reaction is reversible. The copolysiloxane PSII(3)A [the ratio of fed monomers (M-1/M-2) = 1/9, M-1 is 4 - undecylen - [10] - amidoazobenzene, M-2 is methyl 4 - undecylenoylbenzoate] is the best in regard to photoisomerization reaction rate and photoisomerization conversion percentage. The thermal back - isomerization can be enhanced when temperature is elevated. [publication_type] => J [begin_page] => 930 [author_en] => Zhang, JZ; Zhang, QZ [volume] => 55 [get_data] => 2018-08-29 [publisher] => ACTA CHIMICA SINICA [publication_iso] => Acta Chim. Sin. [format_title_en_publication_en_pub_year] => c1f9505d4fe38520f14d15f9273011c7-34360647 [publisher_city] => SHANGHAI [cauthor_order] => 1 [reference_No] => 4 [cite_awos] => 14 [wos_No] => WOS:A1997YB05800016 [format_wos_No] => 7582e70cfe3fba4e6e5a1cc29e48ea441514524913 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [cauthor_back] => Zhang, JZ [check_180] => 0 [publisher_ad] => SHANGHAI INST ORGANIC CHEM ACADEMIA SINICA 345 LINGLING LU, SHANGHAI,; PEOPLES R CHINA [standard_in] => Department of Chemistry, Shandong University, Jinan, 250100, China [scopus_No] => 2-s2.0-33750187291 [title_en] => Photochromism of comb-like polysiloxane polymers containing azobenzene side groups [jl_language] => chinese [jl_publication_en] => actachimicasinica [sys_author_jg_last_arr] => 山东大学化学系,山东大学化学系济南250100,济南250100 [jl_country] => 中国 [sys_author_in_last_arr] => china [jl_publisher] => actachimicasinica [sys_author_id] => [sys_subject_sort] => 0,0 [college_parent_id] => 43,169 [company_test] => Array,Array [id] => rA5JvmUBFjIhTVEbmsTS [tags] => 0 ) [14] => Array ( [batch2] => 1,2,6 [batch] => 3250,3243,3241,3254,3252 [tag] => 0 [abstract_cn] => 本文研究了三种羧酸取代的四苯基叶啉衍生物在空气/Cd~(2+)水溶液界面上所形成的单层膜及LB膜.这三种卟啉衍生物中,一种没有脂链,另外两种具有不同长度的脂链.由π-A等温线得到的平均表观分子面积相差很大.紫外-可见光谱表明,LB膜中叶啉的Soret吸收带相对于溶液的吸收均红移,但红移程度不同LB膜的偏振紫外-可见光谱表明,LB膜中三种卟啉衍生物的卟啉环具有基本一致的取向.运用亚相降低法得到了三种卟啉衍生物单层LB膜,其紫外-可见光谱与用垂直提拉法得到的LB膜的紫外一可见光谱具有一致的特征.这些结果表明:卟啉衍生物有无取代链及取代链长的不同对平均表观分子面积的大小和膜中环间的距离有影响,但对环... [keyword_cn] => LB膜;卟啉;取向;结构 [article_id] => 334857,167948,539401,498672,13367 [clc] => O643.1 [author_jg] => [刘洪国,冯绪胜,杨孔章,梁维安]山东大学胶体与界面化学研究所,山东大学胶体与界面化学研究所,山东大学胶体与界面化学研究所,山东大学化学系 济南250100,济南250100,济南250100,济南250100 [format_title_cn_publication_cn_pub_year] => 4f43f69b304d55b6cfa279dfaa1c43b1-1218445284 [hints] => 6 [issue] => 2 [sys_level_num] => 2_3 [sys_jg_type] => 3,5 [format_issn_issue_page_pub_year] => 0e986843283d54e848cdeab8cd5db7ad-149203790 [source_type] => 351 [pub_year] => 1997 [pub_date] => 1997-02-20 [pages] => 6 [from_id] => 76,80,78,73,85 [author_cn] => 刘洪国,冯绪胜,杨孔章,梁维安 [issn] => 0567-7351 [uri] => http://kns.cnki.net/kns/detail/detail.aspx?FileName=HXXB199702002&DbName=CJFQ1997 [publication_cn] => 化学学报 [title_cn] => 具有不同取代链长的卟啉衍生物LB膜的结构研究 [CSSN] => 31-1320/O6 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => 6f2e1b753c5021d268ab9e91f2494aff-1993983755 [page] => 117-122 [hb_type] => 2 [article_dt] => Article [hb_batch] => title_cn_publication_cn_pub_year_2_3 [format_title_en] => 73e086e5dfc61421bab693666d5f56a7-1775415125 [format_title] => 0eeb8894bf09c72cee5b59d33479b312-241599263 [hx_id] => 2378,2371 [format_publication_cn] => 6918be3b26b1fa6ec0424f6071208a75331227575 [format_publication_en] => 169b60c7845c9e5f36906950b18f11111348184734 [jl_publication_cn] => 化学学报 [jl_article_dt] => 期刊论文 [jl_keyword_cn] => 取向,lb膜,卟啉,结构 [jl_clc] => o6431 [author_in] => [Liu, H.-G] Institute of Colloid and Interface Chemistry, Shandong University, Jinan, 250100, China@@@[ Feng, X.-S] Institute of Colloid and Interface Chemistry, Shandong University, Jinan, 250100, China@@@[ Yang, K.-Z] Institute of Colloid and Interface Chemistry, Shandong University, Jinan, 250100, China@@@[ Liang, W.-A] Department of Chemistry, Shandong University, Jinan, 250100, China [company_id] => 0,43,169 [author_id] => [author_test] => Array ( ) [sys_author_id_arr] => [jl_publication_cn_publication_en] => 化学学报 [jl_keyword_cn_keyword_en] => 取向,lb膜,卟啉,结构 [publication_en] => ACTA CHIMICA SINICA [cite_wos] => 7 [check_3Y] => 3 [language] => Chinese [delivery_No] => WM087 [cauthor_ad] => [Liu, HG]SHANDONG UNIV,INST COLLOID & INTERFACE CHEM,JINAN 250100,PEOPLES R CHINA. [author_fn] => Liu, HG; Feng, XS; Yang, KZ; Liang, WA [format_title_en_issn_pub_year] => dc79f0ce646b3e075b74d3adcefba7061626062170 [datebase] => Scopus [format_scopus_No] => 3ef1d3450bdc9b9cdb9db351b7cc3f04958903511 [publication_29] => ACTA CHIM SINICA [end_page] => 122 [abstract_en] => Monolayers and LB films of three kinds of carboxylic acid substituted porphyrins without alkyl chain or with alkyl chains of different length have been studied in this paper. Mean molecular areas were measured and found to increase as the alkyl chain length increased. UV - Vis spectrashow that Soret absorption bands of porphyrins in LB films have different red - shift compared with solution spectra. The polarized UV - Vis spectra show that the three kinds of porphyrins have the same orientation in LB films. The LB monolayers were obtained by using subphase lowing method, their UV - Vis spectra show the same characteristics as those in LB films obtained by using vertical dipping method. These results indicate that substituted alkyl chains have great influence on mean molecular areas and the distance between porphyrin rings in monolayers or LB films, but have no influence on porphyrin ring orientation. The porphyrin ring orientation is determined by porphyrin and the substituted hydrophilic groups. The three kinds of porphyrins have the same orientation in monolayers at Cd2+ aqueous solution interface, too, and the orientation preserved during the transfer. [publication_type] => J [begin_page] => 117 [author_en] => Liu, HG; Feng, XS; Yang, KZ; Liang, WA [volume] => 55 [get_data] => 2018-08-29 [publisher] => ACTA CHIMICA SINICA [keyword_plu] => LANGMUIR-BLODGETT-FILMS; AIR-WATER-INTERFACE; AMPHIPHILIC PORPHYRINS; DYE MONOLAYERS; ORIENTATION; REFLECTION; LIGHT [publication_iso] => Acta Chim. Sin. [format_title_en_publication_en_pub_year] => cf990fd0efa50afdaa3594ba2589ac84-21563950 [cite_scopus] => 1 [publisher_city] => SHANGHAI [cauthor_order] => 1 [reference_No] => 22 [cite_awos] => 7 [wos_No] => WOS:A1997WM08700003 [format_wos_No] => c63876364555580670f4a187a5b3c16e1657092424 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [cauthor_back] => Liu, HG [check_180] => 0 [publisher_ad] => SHANGHAI INST ORGANIC CHEM ACADEMIA SINICA 345 LINGLING LU, SHANGHAI,; PEOPLES R CHINA [standard_in] => Institute of Colloid and Interface Chemistry, Shandong University, Jinan, 250100, China; Department of Chemistry, Shandong University, Jinan, 250100, China [scopus_No] => 2-s2.0-33749823182 [title_en] => Studies on the structure of LB films of porphyrin derivatives containing different substituted alkyl chains [jl_language] => chinese [jl_publication_en] => actachimicasinica [sys_author_jg_last_arr] => 济南250100 [jl_country] => 中国 [sys_author_in_last_arr] => china [jl_publisher] => actachimicasinica [sys_author_id] => [sys_subject_sort] => 0,0 [college_parent_id] => 43,169 [company_test] => Array,Array [id] => 9Q9KvmUBFjIhTVEbYAQa [tags] => 0 ) [15] => Array ( [batch2] => 1,2,6 [batch] => 3250,3243,3241,3254,3252 [tag] => 0 [abstract_cn] => 应用表面张力法、NMR法和ESR法研究了全氟辛酸钠(SPFO)-十二烷基三甲基溴化铵(DTAB)混合体系水溶液胶束形成及混合胶束的微环境性质(微观粘度、微观极性等).结果表明,碳氟表面活性剂碳氟链和碳氢表面活性剂碳氢链之间具有强烈的相互作用,DTAB与SPFO在水溶液中形成混合胶束.DTAB与SPFO混合体系的表面活性高于单一的DTAB或SPFO,混合体系cmc较单一的DTAB和SPFO低.DTAB与SPFO混合胶束的微观粘度较DTAB胶束的大,而微观极性较DTAB的小. [keyword_cn] => 全氟辛酸钠;十二烷基三甲基溴化铵;胶束微环境;NMR;ESR [article_id] => 334862,597879,61142,498519,167946 [clc] => O643.3 [author_jg] => [郝京诚,汪汉卿,刘维民,李干佐]山东师范大学化学系,中国科学院兰州化学物理研究所固体润滑开放实验室,中国科学院兰州化学物理研究所固体润滑开放实验室,山东大学化学系 济南250014,兰州730000,兰州730000,济南250100 [format_title_cn_publication_cn_pub_year] => 9adfc35e7a1f59d9a60c3d510655b967837471251 [hints] => 4 [issue] => 4 [sys_level_num] => 2_3 [sys_jg_type] => 3,5 [format_issn_issue_page_pub_year] => ccdacf2d4206bb3c8859c35ecbeec424894034484 [source_type] => 351 [pub_year] => 1997 [pub_date] => 1997-04-20 [pages] => 6 [from_id] => 76,80,78,73,85 [author_cn] => 郝京诚,汪汉卿,刘维民,李干佐 [issn] => 0567-7351 [uri] => http://kns.cnki.net/kns/detail/detail.aspx?FileName=HXXB199704001&DbName=CJFQ1997 [publication_cn] => 化学学报 [title_cn] => 全氟辛酸钠与十二烷基三甲基溴化铵混合胶束微环境性质的NMR,ESR研究 [CSSN] => 31-1320/O6 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => dbc0d1cb85fc1c6790a342a69f94570c2013962017 [page] => 322-327 [hb_type] => 2 [article_dt] => Article [hb_batch] => title_cn_publication_cn_pub_year_2_3 [format_title_en] => a5d15d4d2cec5714efea728d8f4dad3e709759833 [format_title] => 6ba738a2af1c14772b3bdd349dc4cdaa-593642869 [hx_id] => 2378,2371 [format_publication_cn] => 6918be3b26b1fa6ec0424f6071208a75331227575 [format_publication_en] => 169b60c7845c9e5f36906950b18f11111348184734 [jl_publication_cn] => 化学学报 [jl_article_dt] => 期刊论文 [jl_keyword_cn] => nmr,胶束微环境,十二烷基三甲基溴化铵,esr,全氟辛酸钠 [jl_clc] => o6433 [author_in] => [Hao, J.-C] Department of Chemistry, Shandong Normal University, Jinan, 250014, China@@@[ Wang, H.-Q] Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, 730000, China@@@[ Liu, W.-M] Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, 730000, China@@@[ Li, G.-Z] Department of Chemistry, Shandong University, Jinan, 250100, China [company_id] => 0,43,169 [author_id] => [author_test] => Array ( ) [sys_author_id_arr] => [jl_publication_cn_publication_en] => 化学学报 [publication_en] => ACTA CHIMICA SINICA [cite_wos] => 6 [check_3Y] => 1 [language] => Chinese [delivery_No] => WX145 [cauthor_ad] => [Hao, JC]SHANDONG NORMAL UNIV,DEPT CHEM,JINAN 250014,PEOPLES R CHINA. [author_fn] => Hao, JC; Wang, HQ; Liu, WM; Li, GZ [format_title_en_issn_pub_year] => 83098b63a2cd68e14d07c13c8541c4f9326581957 [datebase] => Scopus [format_scopus_No] => 00a8119039e5f2c9d853e5ae44e55d1f333178154 [publication_29] => ACTA CHIM SINICA [end_page] => 327 [abstract_en] => The sodium perfluorooctanoate(SPFO)-dodecyltrimethylammonium bromide(DTAB) mixed micelles and the mixed micellar microenvironments (microviscosity and micropolarity) were studied by using NMR, ESR and surface tension. The results showed that SPFO and DTAB were capable of forming a mixed micelle in aqueous solution and the fluorocarbon chain of SPFO bad strong interaction with the hydrocarbon chain of DTAB. The surface activity of SPFO-DTAB is much higher than SPFO or DTAB itself. The ESR spectra revealed a low polarity and a high viscosity in SPFO-DTAB mixed micellar core, indicating that a number of SPFO fluorocarbon chain had penetrated into the interior of DTAB micelles. [publication_type] => J [begin_page] => 322 [author_en] => Hao, JC; Wang, HQ; Liu, WM; Li, GZ [volume] => 55 [get_data] => 2018-08-29 [publisher] => ACTA CHIMICA SINICA [keyword_plu] => AEROSOL OT; FLUOROCARBON [publication_iso] => Acta Chim. Sin. [format_title_en_publication_en_pub_year] => 4f1c64c82833c634a51906e50c05844c-1812948701 [cite_scopus] => 2 [publisher_city] => SHANGHAI [cauthor_order] => 1 [reference_No] => 10 [cite_awos] => 6 [wos_No] => WOS:A1997WX14500002 [format_wos_No] => ea501d994fa73286af02a0d865226feb-1252539135 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [cauthor_back] => Hao, JC [check_180] => 0 [publisher_ad] => SHANGHAI INST ORGANIC CHEM ACADEMIA SINICA 345 LINGLING LU, SHANGHAI,; PEOPLES R CHINA [standard_in] => Department of Chemistry, Shandong Normal University, Jinan, 250014, China; Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, 730000, China; Department of Chemistry, Shandong University, Jinan, 250100, China [scopus_No] => 2-s2.0-8744220146 [title_en] => Studies on the microenvironment properties of the mixed micelles of SPFO-DTAB by NMR and ESR [jl_language] => chinese [jl_publication_en] => actachimicasinica [sys_author_jg_last_arr] => 济南250100 [jl_country] => 中国 [sys_author_in_last_arr] => china [jl_publisher] => actachimicasinica [sys_author_id] => [sys_subject_sort] => 0,0 [college_parent_id] => 43,169 [company_test] => Array,Array [id] => Iw5HvmUBFjIhTVEbZSTq [tags] => 0 ) [16] => Array ( [batch2] => 1,2,6 [batch] => 3250,3243,3241,3252 [tag] => 0 [abstract_cn] => 以Cu~(2+)和Na~+同时作为模板,用2,6-二甲酰基对甲苯酚直接与一定比例的乙二胺,二-1,2-亚乙基-三胺发生[2+2]型 Schiff碱缩合,合成了含两个不同隔室Schiff碱大环配体(L~2-)的铜钠异双核配合物[CuNaL(ClO_4)].并对它进行了元素分析,UV-Vis,IR,1H NMR,摩尔电导和ESR谱等项表征.ESR谱显示三个g值峰,对应的gx,gy,gz值分别为1.987,2.168,2.233.单晶X射线四圆衍射分析表明,该配合物为单斜晶系,空间群P2_1/n,晶胞参数a=0.9255(3)b=1.7689(2),c=1.6055(2)nm,β=101.69(2)... [keyword_cn] => 铜钠异双核配合物;大环Schiff碱;晶体结构 [article_id] => 498537,581854,334864,155185 [clc] => O643.3 [author_jg] => [马长勤,张文兴,王绪宁,蒋德华]山东大学化学学院,山东大学化学学院,山东大学化学学院,山东大学化学学院 济南250100,济南250100,济南250100,济南250100 [format_title_cn_publication_cn_pub_year] => c07d5465ad0134b9c783ed7c3df91c811195527924 [hints] => 4 [issue] => 6 [sys_level_num] => 2_3 [sys_jg_type] => 0,5 [format_issn_issue_page_pub_year] => 1d368b4fedd52bd5385cf4a4832f49e3-670855344 [source_type] => 351 [pub_year] => 1997 [pub_date] => 1997-06-20 [pages] => 6 [from_id] => 76,80,73,78 [author_cn] => 马长勤,张文兴,王绪宁,蒋德华 [issn] => 0567-7351 [uri] => http://kns.cnki.net/kns/detail/detail.aspx?FileName=HXXB199706003&DbName=CJFQ1997 [publication_cn] => 化学学报 [title_cn] => 具有两种不同配位隔室的含酚桥基‘N_5O_2’Schiff碱大环铜钠异双核配合物的合成及结构 [CSSN] => 31-1320/O6 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => e90f1d0c661cfecfdf3d85b2f3e77bb6-1568855294 [page] => 539-544 [hb_type] => 2 [article_dt] => Article [jl_publication_cn] => 化学学报 [jl_article_dt] => 期刊论文 [jl_keyword_cn] => 大环schiff碱,铜钠异双核配合物,晶体结构 [jl_clc] => o6433 [author_in] => [Ma, C.-Q] College of Chemistry, Shandong University, Jinan, 250100, China@@@[ Zhang, W.-X] College of Chemistry, Shandong University, Jinan, 250100, China@@@[ Wang, X.-N] College of Chemistry, Shandong University, Jinan, 250100, China@@@[ Jiang, D.-H] College of Chemistry, Shandong University, Jinan, 250100, China [company_id] => 0,43,169 [sys_subject_sort] => 0,0 [college_parent_id] => 43,169 [company_test] => Array,Array [author_id] => [author_test] => Array ( ) [sys_author_id_arr] => [jl_publication_cn_publication_en] => 化学学报 [hb_batch] => grant_no [cite_wos] => 3 [publication_en] => ACTA CHIMICA SINICA [check_3Y] => 0 [language] => Chinese [delivery_No] => YD106 [cauthor_ad] => [Ma, CQ]SHANDONG UNIV,COLL CHEM,JINAN 250100,PEOPLES R CHINA. [format_title] => a1ce9c7c37551d3799f366c7a20f08c7-1958437909 [author_fn] => Ma, CQ; Zhang, WX; Wang, XN; Jiang, DH [format_title_en_issn_pub_year] => c9353972a7563099356137a36b61cb10-1045589801 [datebase] => Scopus [format_scopus_No] => b08fe5ba3a7727d51ec267fd547950921174921276 [publication_29] => ACTA CHIM SINICA [end_page] => 544 [abstract_en] => The title complex [CuNaL(ClO4)] of a Robson macrocycle with two different coordination compartments H2L, derived from Schiff base condensation of 4-methyl-2,6-diformylphenol and two kinds of diamine, has been synthesized in one template reaction. The complex has been characterized by UV-Vis, IR, H-1 NMR and ESR spectra. The ESR spectrum shows three peaks at g(x) = 1.987, g(y) = 2.168 and g(x) = 2.233, respectively. The complex crystallizes in the monoclinic crystal system, space group P2(1)/n, with Z = 4, a = 0.9255(3); b =1.7689(2), c = 1.6055(2)nm, beta = 101.69(2)degrees, and V = 2.574(9) nm(3). The refinement converges with R = 0.053 and R-W = 0.065 for 2640 reflections with I greater than or equal to 3 sigma(I). The Cu(II) and Na(I) ions reside at the 4- and 5-coordination compartments of the macrocycle, respectively. The coordination geometry around the copper atom is regarded as a planar square. But the sodium atom is also coordinated with one oxygen atom of a perchlorate anion on the axis. This geometry of six-coordinate sodium may be considered as a pentagonal pyramid. The distance between Cu and Na bridged by two phenolic oxygens is 0.3227(3)nm. [publication_type] => J [begin_page] => 539 [author_en] => Ma, CQ; Zhang, WX; Wang, XN; Jiang, DH [volume] => 55 [publisher] => ACTA CHIMICA SINICA [get_data] => 2018-08-29 [keyword_plu] => DISSIMILAR 4-COORDINATION; 5-COORDINATION SITES; ZN COMPLEXES; CU; MACROCYCLES; MN; FE; CO; NI [format_publication_cn] => 6918be3b26b1fa6ec0424f6071208a75331227575 [publication_iso] => Acta Chim. Sin. [format_title_en_publication_en_pub_year] => 37359fb8ab81c23667691d19a0722e3e-29038779 [cite_scopus] => 1 [format_title_en] => a829f7822e5b8e79ee815c286360dbf11692562330 [publisher_city] => SHANGHAI [cauthor_order] => 1 [hx_id] => 2378,2371 [reference_No] => 11 [cite_awos] => 3 [wos_No] => WOS:A1997YD10600004 [format_wos_No] => a840484ab5b8c8d4f88356d4b7f1cb892060629855 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [cauthor_back] => Ma, CQ [check_180] => 0 [publisher_ad] => SHANGHAI INST ORGANIC CHEM ACADEMIA SINICA 345 LINGLING LU, SHANGHAI,; PEOPLES R CHINA [standard_in] => College of Chemistry, Shandong University, Jinan, 250100, China [scopus_No] => 2-s2.0-33749617123 [title_en] => Synthesis and structure of Cu(II) and Na(I) heterodinuclear complex of phenol-bridged \'N5O2\' Schiff base ligand with two different coordination compartments [format_publication_en] => 169b60c7845c9e5f36906950b18f11111348184734 [jl_language] => chinese [jl_publication_en] => actachimicasinica [sys_author_jg_last_arr] => 济南250100 [jl_company_test] => uircu0,unameuu5316u5b66u4e0eu5316u5de5u5b66u9662,uparentidu43,uorgidu43,ulevelu1 [jl_country] => 中国 [sys_author_in_last_arr] => china [jl_publisher] => actachimicasinica [sys_author_id] => [id] => qw5IvmUBFjIhTVEbRWIm [tags] => 0 ) [17] => Array ( [batch2] => 1,2,6 [batch] => 3250,3243,3241,3254,3252 [tag] => 0 [abstract_cn] => 用高时间分辨电子自旋共振(TRESR)波谱仪,研究对苯醌(PBQ)在不同的介质中光解苯半醌自由基的化学诱导动态电子自旋极化(CIDEP).实验结果指出,在乙二醇溶液中得到苯半醌自由基(PBQH)和以碳为中心的自由基(R)(OH)_2.在乙二醇/水溶液中,得到以PBQH的六条峰为主的谱线图,然后在该体系中随着加入表面活性剂TX-100,AOT的浓度增加,苯半醌负离子基(PBQ~-)的谱线强度增加,而PBQH的谱线减弱直至消失.本文从自由基所处微环境性质出发,讨论其极化传递机理和有关物理化学性质 [keyword_cn] => 化学诱导动态电子自旋极化;时间分辨电子自旋共振;光解苯半醌自由基;胶束 [article_id] => 581860,498463,334858,155184,84756 [clc] => O641 [author_jg] => [陆同兴,汤开元,李干佐,苏红梅]安徽师范大学物理系,安徽师范大学物理系,山东大学化学院胶体和界面化学开放实验室,山东大学化学院胶体和界面化学开放实验室 芜湖241000,芜湖241000,济南250100,济南250100 [format_title_cn_publication_cn_pub_year] => d56c5215e9454edf5151416510fc6b8a-21432064 [hints] => 12 [issue] => 3 [sys_level_num] => 2_3 [sys_jg_type] => 3,5 [format_issn_issue_page_pub_year] => 6b7eeb0af4d95e3fe4f2b21c743bac23-726696207 [source_type] => 351 [pub_year] => 1997 [pub_date] => 1997-03-20 [pages] => 6 [from_id] => 76,80,78,73,85 [author_cn] => 陆同兴,汤开元,李干佐,苏红梅 [issn] => 0567-7351 [uri] => http://kns.cnki.net/kns/detail/detail.aspx?FileName=HXXB199703001&DbName=CJFQ1997 [publication_cn] => 化学学报 [title_cn] => 胶束微环境下光解苯半醌负离子基的CIDEP研究 [CSSN] => 31-1320/O6 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => c316b22ecfd54006e1c2085bd521f92d1503624487 [page] => 215-220 [hb_type] => 2 [article_dt] => Article [hb_batch] => title_cn_publication_cn_pub_year_2_3 [format_title_en] => 20c1ab2f18bfc0b76fed009047cd84cd-2046608474 [format_title] => 22a5e3612ce823f9848593af9ddabfa6-1749114302 [hx_id] => 2378,2371 [format_publication_cn] => 6918be3b26b1fa6ec0424f6071208a75331227575 [format_publication_en] => 169b60c7845c9e5f36906950b18f11111348184734 [jl_publication_cn] => 化学学报 [jl_article_dt] => 期刊论文 [jl_keyword_cn] => 光解苯半醌自由基,胶束,化学诱导动态电子自旋极化,时间分辨电子自旋共振 [jl_clc] => o641 [author_in] => [Lu, T.-X] Department of Physics, Anhui Normal University, Wuhu, 241000, China@@@[ Li, G.-Z] College of Chemistry, Laboratory of Colloid and Interface Chemistry, Shandong University, Jinan, 250100, China@@@[ Su, H.-M] College of Chemistry, Laboratory of Colloid and Interface Chemistry, Shandong University, Jinan, 250100, China@@@[ Tang, K.-Y] Department of Physics, Anhui Normal University, Wuhu, 241000, China [company_id] => 133,0,5,43,169 [sys_subject_sort] => 0,0,0,0 [college_parent_id] => 133,5,43,169 [company_test] => Array,Array,Array,Array [author_id] => [author_test] => Array ( ) [sys_author_id_arr] => [jl_publication_cn_publication_en] => 化学学报 [jl_keyword_cn_keyword_en] => 时间分辨电子自旋共振,化学诱导动态电子自旋极化,光解苯半醌自由基,胶束 [cite_wos] => 3 [publication_en] => ACTA CHIMICA SINICA [check_3Y] => 0 [language] => Chinese [delivery_No] => WT408 [cauthor_ad] => [Lu, TX]ANHUI UNIV,DEPT PHYS,WUHU 241000,PEOPLES R CHINA. [author_fn] => Lu, TX; Li, GZ; Su, HM; Tang, KY [format_title_en_issn_pub_year] => 632f5ecd44487947353ae87a52c09d1b1894112474 [datebase] => Scopus [format_scopus_No] => 885aac28068b0bd9763dda9c014558de1965065192 [publication_29] => ACTA CHIM SINICA [end_page] => 220 [abstract_en] => The CIDEP spectra of photolyzed p-benzosemiquinone radical in different media have teen studied experimentally with the highly time resolved ESR spectrometer. in p-benzoquinone solution with ethylene glycol as solvent, emission lines from PBQH(.) (R)over dot(OH)(2) were obtained. With ethylene glycol and water mixture as solvent, the spectrum mainly contained six lines from PBQH(.). With the addition of some surfactants (TX-100 and AOT)and increase of their concentration, the strength of PBQH(.) lines decreased gradually to such an extent as to disappear at last. At the same time, lines from PBQ(.-) appeared in the spectrum and increased gradually. On the basis of special properties of the microenvironment in which radicals lied, a polarization transference mechanism and some related physical chemical properties were discussed to explain these experimental results. [researcherID] => Su, Hongmei/S-6093-2016 [orcID] => Su, Hongmei/0000-0001-7384-6523 [publication_type] => J [begin_page] => 215 [author_en] => Lu, TX; Li, GZ; Su, HM; Tang, KY [volume] => 55 [publisher] => ACTA CHIMICA SINICA [get_data] => 2018-08-29 [keyword_plu] => POLARIZATION [publication_iso] => Acta Chim. Sin. [format_title_en_publication_en_pub_year] => e08db66641e8bd286f856c957325d4ca-682939266 [cite_scopus] => 1 [publisher_city] => SHANGHAI [cauthor_order] => 1 [reference_No] => 7 [cite_awos] => 4 [wos_No] => WOS:A1997WT40800002 [format_wos_No] => 575771273184a76bd27d6baa218230ec1397886908 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [cauthor_back] => Lu, TX [check_180] => 0 [publisher_ad] => SHANGHAI INST ORGANIC CHEM ACADEMIA SINICA 345 LINGLING LU, SHANGHAI,; PEOPLES R CHINA [standard_in] => Department of Physics, Anhui Normal University, Wuhu, 241000, China; College of Chemistry, Laboratory of Colloid and Interface Chemistry, Shandong University, Jinan, 250100, China [scopus_No] => 2-s2.0-33748618419 [title_en] => The CIDEP study of photolyzed p-benzosemiquinone anion-radical in micellar microenvironment [jl_language] => chinese [jl_publication_en] => actachimicasinica [sys_author_jg_last_arr] => 济南250100 [jl_company_test] => unameuu5316u5b66u4e0eu5316u5de5u5b66u9662,uorgidu5,uparentidu43,unameuu7269u7406u5b66u9662,uircu0,uorgidu43,ulevelu1,uparentidu5 [jl_country] => 中国 [sys_author_in_last_arr] => china [jl_publisher] => actachimicasinica [sys_author_id] => [id] => sQ5IvmUBFjIhTVEbRWIm [tags] => 0 ) [18] => Array ( [batch2] => 1,2,6 [uri] => http://kns.cnki.net/kns/detail/detail.aspx?FileName=HXXB199602011&DbName=CJFQ1996 [tag] => 0 [abstract_cn] => 本文以 n/n~+-Si半导体为基底,通过碱溶液刻蚀处理和Ni/Pt双层金属膜表面修饰后作为光阳极,用于1.0mol·dm~(-3)KOH溶液中光助电解水析氧.在恒电势1.0V(相对HgO/Hg电极)和90mW·cm~(-2)光照射下,最佳电极的析氧电流达到65.2mA·cm~(-2),稳定性实验表明,连续光照不超过200小时,光电极具有良好的抗腐蚀性.对电极表面进行了X-光电子能谱(ESCA)分析. [keyword_cn] => 光电化学;;半导体硅电极;;光电解析氧;;光电子能谱分析 [fund_No] => 厦门大学固体表面物理化学国家重点实验室资助的课题 [article_id] => 498908,84755,648067,335584,170603 [clc] => O642 [author_jg] => [李怀祥;李国铮;王士勋]山东师范大学化学系@@@[李怀祥;李国铮;王士勋]山东大学化学系@@@[李怀祥;李国铮;王士勋]山东大学化学系 济南250014@@@[李怀祥;李国铮;王士勋]济南250100@@@[李怀祥;李国铮;王士勋]济南250100 [format_title_cn_publication_cn_pub_year] => 9ae07702e446275be7c009c079784b2e-993358455 [hints] => 5 [issue] => 2 [author_first] => 李怀祥 [sys_level_num] => 2_3 [sys_jg_type] => 3,5 [format_issn_issue_page_pub_year] => 38d900d95d11235e2cc91ed8a7eb4340809785789 [source_type] => 351 [pub_year] => 1996 [pub_date] => 1996-02-20 [pages] => 5 [from_id] => 76,80,78,73,85 [author_cn] => 李怀祥;李国铮;王士勋 [issn] => 0567-7351 [batch] => 3250,3243,3241,3254,3252 [publication_cn] => 化学学报 [title_cn] => 镍铂修饰n型硅电极光电解析氧 [CSSN] => 31-1320/O6 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => ae9005f6948786fdc788c6fc8074bbff-224334930 [page] => 182-186 [hb_type] => 2 [article_dt] => Article [hb_batch] => title_cn_publication_cn_pub_year_2_3 [format_title_en] => 1584f97cfec18c0cd0a3391adbbd36d0-1746292061 [format_title] => 1154479a194b06b8f5e098dd939e0893-601426618 [hx_id] => 2378,2371 [format_publication_cn] => 6918be3b26b1fa6ec0424f6071208a75331227575 [format_publication_en] => 169b60c7845c9e5f36906950b18f11111348184734 [jl_publication_cn] => 化学学报 [jl_article_dt] => 期刊论文 [jl_keyword_cn] => ,光电解析氧,光电化学,半导体硅电极,光电子能谱分析 [jl_clc] => o642 [author_in] => [Li, H.-X] Department of Chemistry, Shangdong Teacher\'s University, Jinan, 250014, China@@@[ Li, G.-Z] Department of Chemistry, Shandong University, Jinan, 250100, China@@@[ Wang, S.-X] Department of Chemistry, Shandong University, Jinan, 250100, China [company_id] => 0,43,169 [author_id] => [author_test] => Array ( ) [sys_author_id_arr] => [jl_publication_cn_publication_en] => 化学学报 [cite_wos] => 3 [publication_en] => ACTA CHIMICA SINICA [check_3Y] => 1 [language] => Chinese [delivery_No] => UA979 [cauthor_ad] => [Li, HX]SHANDONG TEACHERS UNIV,DEPT CHEM,JINAN 250014,PEOPLES R CHINA. [author_fn] => Li, HX [format_title_en_issn_pub_year] => 686901a81e26590a869fbc85f96b38a0144071628 [datebase] => Scopus [format_scopus_No] => de5844ffc74a097602d0fda9d42c1839-1113356843 [publication_29] => ACTA CHIM SINICA [end_page] => 186 [abstract_en] => The splitting of water in a solution containing 1. 0 mol . dm(-3)KOH is studied based on the semiconductor photoanodes, n/n(+) - Si, by alkali - etching and modifying with Ni/Pt dual metal layer. The optimization photocurrent of 65. 2 mA . cm(-2) for oxygen evolution is observed at 1. 0V (vs. HgO/Hg electrode) with a light intensity of 90mW . cm(-2). The photoanodes are stable during oxygen continuous evolution for 200 hours. Electrode surface analysis is carried out by using Electron Spectroscopy for Chemical Analysis (ESCA) system. [publication_type] => J [begin_page] => 182 [author_en] => Li, HX [volume] => 54 [publisher] => ACTA CHIMICA SINICA [get_data] => 2018-08-29 [keyword_plu] => ENERGY-CONVERSION; OXYGEN [publication_iso] => Acta Chim. Sin. [format_title_en_publication_en_pub_year] => 7fe57a76c6f10482368e6b6bde456c05-212105740 [cite_scopus] => 1 [publisher_city] => SHANGHAI [cauthor_order] => 1 [reference_No] => 4 [cite_awos] => 3 [wos_No] => WOS:A1996UA97900012 [format_wos_No] => 01cb67267d125b5811cf2bd520ca34d7-56897852 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [cauthor_back] => Li, HX [check_180] => 0 [publisher_ad] => SHANGHAI INST ORGANIC CHEM ACADEMIA SINICA 345 LINGLING LU, SHANGHAI,; PEOPLES R CHINA [standard_in] => Department of Chemistry, Shangdong Teacher\'s University, Jinan, 250014, China; Department of Chemistry, Shandong University, Jinan, 250100, China [scopus_No] => 2-s2.0-33750277941 [title_en] => A study on water splitting of photoelectrolysis based on n/n(+)-Si electrodes [jl_language] => chinese [jl_publication_en] => actachimicasinica [sys_author_jg_last_arr] => 山东师范大学化学系,山东大学化学系,山东大学化学系济南250014,济南250100,济南250100 [jl_country] => 中国 [sys_author_in_last_arr] => china [jl_publisher] => actachimicasinica [sys_author_id] => [sys_subject_sort] => 0,0 [college_parent_id] => 43,169 [company_test] => Array,Array [id] => yg1EvmUBFjIhTVEbKGBy [tags] => 0 ) [19] => Array ( [batch2] => 1,2 [batch] => 3250,3241,3254,3252 [tag] => 0 [abstract_cn] => 本文合成了具有隔室构造的Schiff碱配体H_3L(L~(3-)=C_(11)H_(11)N_6OS_2~(3-)),并对其进行了元素分析,IR,~1H NMR和MS等项表征.制备了该配体的分别由醋酸根和吡啶分子协配的两种锌的双核配合物,对后者进行了X射线单晶结构分析.[Zn_2L(OH)(py)_2](Py)_2,P2_1/c,a=0.9195(1),b=2.3334(6),c=1.6111(3)nm,β=93.99(1)°,Z=4.结构用直接法解得,最终的R=0.066.测定的结果表明,两锌原子间存在酚氧和羟基的两μ_2-O-桥,每个五配位的锌均具有四方锥型的配位构型. [keyword_cn] => Schiff碱配体;双核锌配合物;晶体结构 [article_id] => 170606,335581,539395,106122 [clc] => O641.4 [author_jg] => [马长勤,王绪宁,张文兴,于正刚,蒋德华,董士利]山东大学化学院,山东大学化学院,山东大学化学院,山东大学化学院,山东大学化学院,淄博市公安局 济南250100,济南250100,济南250100,济南250100,济南250100,淄博255039 [format_title_cn_publication_cn_pub_year] => d0bfd133d1197a8f0072fe547c29e8791048131311 [hints] => 8 [issue] => 6 [sys_level_num] => 2_3 [sys_jg_type] => 5 [format_issn_issue_page_pub_year] => 541eb4e0ecfe7d2c817d83d9d34432aa-1299104508 [source_type] => 351 [pub_year] => 1996 [pub_date] => 1996-06-20 [pages] => 6 [from_id] => 80,78,73,85 [author_cn] => 马长勤,王绪宁,张文兴,于正刚,蒋德华,董士利 [issn] => 0567-7351 [uri] => http://kns.cnki.net/kns/detail/detail.aspx?FileName=HXXB199606006&DbName=CJFQ1996 [publication_cn] => 化学学报 [title_cn] => 含N,O和S的Schiff碱配体的双核锌配合物的合成与晶体结构 [CSSN] => 31-1320/O6 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => 830e4c0795d107904455dd94896af91b-1399008932 [page] => 562-567 [hb_type] => 2 [article_dt] => Article [hb_batch] => title_cn_publication_cn_pub_year_2_3 [format_title_en] => 4cb6957559cd6e825d32254ba816292b-818012582 [format_title] => b42d7eb077b76b7d2178d0e929283e43-286254877 [hx_id] => 2371 [format_publication_cn] => 6918be3b26b1fa6ec0424f6071208a75331227575 [format_publication_en] => 169b60c7845c9e5f36906950b18f11111348184734 [jl_publication_cn] => 化学学报 [jl_article_dt] => 期刊论文 [jl_keyword_cn] => schiff碱配体,晶体结构,双核锌配合物 [jl_clc] => o6414 [author_in] => [company_id] => 0,43,169 [sys_subject_sort] => 0,0 [college_parent_id] => 43,169 [company_test] => Array,Array [author_id] => [author_test] => Array ( ) [sys_author_id_arr] => [jl_publication_cn_publication_en] => 化学学报 [jl_keyword_cn_keyword_en] => 晶体结构,双核锌配合物,schiff碱配体 [sys_author_id] => [cite_wos] => 10 [publication_en] => ACTA CHIMICA SINICA [check_3Y] => 0 [language] => Chinese [delivery_No] => UY132 [cauthor_ad] => [Ma, CQ]SHANDONG UNIV,COLL CHEM,JINAN 250100,PEOPLES R CHINA. [author_fn] => Ma, CQ; Wang, XN; Zhang, WX; Yu, ZG; Jiang, DH; Dong, SL [format_title_en_issn_pub_year] => 616f0d6a37643129464f444a89d65e811586679960 [publication_29] => ACTA CHIM SINICA [end_page] => 567 [abstract_en] => A compartmental Schiff base ligand H(3)L(L(3-) = C11H11N6OS23-) has been synthesized and characterized by elemental analyses, H-1 NMR, IR and MS as well as etc.. Its dinuclear zinc complex, which are co-coordinated by acetate radicals and pyridine molecules respectively, have been prepared. For the later the single crystal structure has been determinated by X-ray diffraction. [Zn(2)L(OH)(py)(2)](py)(2), P2(1)/c, a = 0.9195(1), b = 2.3334(6), c = 1.6111(3), beta = 93.99(1)degrees, Z = 4. The structure was solved by direct method. The refinement converges with R = 0.066 and R(w) = 0.070 based on 2028 reflections with I greater than or equal to 3 sigma(I). The results indicate that between two zinc atoms exist two mu(2) - O- bridges formed by a phenolic oxygen atom and a hydroxy group in the lattice, respectively; and every five-coordinate zinc atom possesses a square pyramidal construction. [publication_type] => J [begin_page] => 562 [author_en] => Ma, CQ; Wang, XN; Zhang, WX; Yu, ZG; Jiang, DH; Dong, SL [volume] => 54 [get_data] => 2018-08-29 [publisher] => ACTA CHIMICA SINICA [keyword_plu] => METAL [publication_iso] => Acta Chim. Sin. [format_title_en_publication_en_pub_year] => 6f2ce8815607540212db0ef04639c663-64175109 [publisher_city] => SHANGHAI [cauthor_order] => 1 [reference_No] => 6 [cite_awos] => 10 [wos_No] => WOS:A1996UY13200007 [format_wos_No] => 9a9b5ba9621c953e1101135ffa159b27-811654138 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [cauthor_back] => Ma, CQ [check_180] => 0 [publisher_ad] => SHANGHAI INST ORGANIC CHEM ACADEMIA SINICA 345 LINGLING LU, SHANGHAI,; PEOPLES R CHINA [title_en] => Syntheses and crystal structure of dinuclear zinc complex with Schiff base ligand containing N, O and S dornors [id] => 7w9KvmUBFjIhTVEbYAQa [tags] => 0 ) ) 1-->
81. 单重态CCl_2与O_3反应机理的理论研究 SCOPUS SCIE

作者:胡海泉,刘成卜

作者机构:[胡海泉,刘成卜]聊城师范学院物理系,山东大学化学院 聊城252059,济南250100

来源:化学学报,ACTA CHIMICA SINICA,1999,Vol.57,Issue.1,29-33

WOS被引数:4

资源类型:期刊论文

WOS:000078453300006

82. 混杂[2,3,9,10,16,17,23,24-八(庚基)酞菁][四(4-吡啶基)卟啉]合钇(Ⅲ)二层配合物的合成及其谱学和电化学性质 SCIE

作者:姜建壮,于慧,边永忠

作者机构:[姜建壮,于慧,边永忠]山东大学化学系,环境工程系,山东大学化学系 北京大学稀土材料化学及应用国家重点实验室 北京100871,济南250100

来源:化学学报,ACTA CHIMICA SINICA,1999,Vol.57,Issue.12,1285-1290

WOS被引数:3

资源类型:期刊论文

WOS:000084781100001

83. 伯胺N_(1923)萃取硫酸铀酰的机理研究 SCOPUS SCIE

作者:杨永会,孙思修,薛淑云,马建华,孙国新,包伯荣

作者机构:[杨永会,孙思修,薛淑云,马建华,孙国新,包伯荣]山东大学化学学院,山东大学化学学院,青岛大学师范学院化学系,中国科学院上海原子核研究所,中国科学院上海原子核研究所,中国科学院上海原子核研究所 济南250100,济南250100,青岛266071,上海201800,上海201800,上海201800

来源:化学学报,ACTA CHIMICA SINICA,1998,Vol.56,Issue.9,848-853

WOS被引数:3

资源类型:期刊论文

WOS:000076266300003

84. 利用E―V传能模型研究亚稳态分子PC1(b^1Σ^+)的猝灭过程 SCIE

作者:邹胜利;储焰南

作者机构:山东大学化学系

来源:化学学报,ACTA CHIMICA SINICA,1998,Vol.56,Issue.3,209-214

资源类型:期刊论文

WOS:000072849300001

85. 双[2-(2'-苯氧基)苯并(口恶)唑]二吡啶合锰(Ⅱ)配合物的研究 万方 SCIE

作者:周建华;李淑兰;姜海辉;刘德信;杨兆荷

作者机构:[周建华;李淑兰;姜海辉;刘德信]山东大学化学系,济南,;[杨兆荷]山东大学晶体材料研究所,济南,

来源:化学学报,ACTA CHIMICA SINICA,1998,Vol.56,Issue.4,371-377

最新影响因子:2.131

当年影响因子:0.178

WOS被引数:3

资源类型:期刊论文;期刊论文

WOS:000073906300010

86. 1-苯基-3-甲基-4-苯甲酰吡唑啉酮-5萃取镓的研究 SCOPUS SCIE

作者:杨永会,孙思修,薛梅,刘萍

作者机构:[杨永会,孙思修,薛梅,刘萍]山东大学化学院,山东大学化学院,山东大学化学院,山东大学化学院 济南250100,济南250100,济南250100,济南250100

来源:化学学报,ACTA CHIMICA SINICA,1998,Vol.56,Issue.6,606-611

资源类型:期刊论文

WOS:000075031900015

87. 硅烯与甲醛环加成反应的理论研究 SCOPUS SCIE

作者:卢秀慧[1];王沂轩[2]

作者机构:[卢秀慧;王沂轩;刘成卜;邓从豪]济南大学化学系;[卢秀慧;王沂轩;刘成卜;邓从豪]山东大学化学院;[卢秀慧;王沂轩;刘成卜;邓从豪]山东大学化学院;[卢秀慧;王沂轩;刘成卜;邓从豪]山东大学化学院 济南250002;[卢秀慧;王沂轩;刘成卜;邓从豪]济南250100;[卢秀慧;王沂轩;刘成卜;邓从豪]济南250100;[卢秀慧;王沂轩;刘成卜;邓从豪]济南250100

来源:化学学报,ACTA CHIMICA SINICA,1998,Vol.56,Issue.11,1079-1080

WOS被引数:14

资源类型:期刊论文

WOS:000077372200006

88. 碳氟表面活性剂复配体系的中相微乳液研究 SCOPUS SCIE

作者:李干佐;马成松;沈强;郝京诚;汪汉卿

作者机构:[李干佐;马成松;沈强;郝京诚;汪汉卿]山东大学国家教委胶体和界面化学开放实验室;[李干佐;马成松;沈强;郝京诚;汪汉卿]山东大学国家教委胶体和界面化学开放实验室;[李干佐;马成松;沈强;郝京诚;汪汉卿]山东大学国家教委胶体和界面化学开放实验室;[李干佐;马成松;沈强;郝京诚;汪汉卿]中国科学院兰州化学物理所;[李干佐;马成松;沈强;郝京诚;汪汉卿]中国科学院兰州化学物理所 济南250100;[李干佐;马成松;沈强;郝京诚;汪汉卿]济南250100 中国科学院兰州化学物理所;[李干佐;马成松;沈强;郝京诚;汪汉卿]兰州730000;[李干佐;马成松;沈强;郝京诚;汪汉卿]济南250100;[李干佐;马成松;沈强;郝京诚;汪汉卿]兰州730000;[李干佐;马成松;沈强;郝京诚;汪汉卿]兰州730000

来源:化学学报,ACTA CHIMICA SINICA,1998,Vol.56,Issue.4,313-319

资源类型:期刊论文

WOS:000073906300001

89. 硅杂环丙烯异构化反应的理论研究 SCOPUS SCIE

作者:胡海泉[1];刘成卜[2]

作者机构:[胡海泉;刘成卜]聊城师范学院物理系;[胡海泉;刘成卜]山东大学化学院 聊城252059;[胡海泉;刘成卜]济南250100

来源:化学学报,ACTA CHIMICA SINICA,1998,Vol.56,Issue.12,1182-1183

资源类型:期刊论文

WOS:000077814300006

90. Co(Ⅱ)Schiff碱配合物的合成、氧合反应热力学及热分解动力学的研究 SCOPUS SCIE

作者:李淑兰,孟凡芹,刘德信,杨兆荷

作者机构:[李淑兰,孟凡芹,刘德信,杨兆荷]山东大学化学系,山东大学化学系,山东大学化学系,山东大学晶体材料研究所 济南250100,济南250100,济南250100,济南250100

来源:化学学报,ACTA CHIMICA SINICA,1998,Vol.56,Issue.5,478-483

WOS被引数:7

资源类型:期刊论文

WOS:000074115200011

91. TX—100胶束中光解萘醌自由基的电子自旋极化研究 SCOPUS SCIE

作者:陆同兴,李干佐,李锡忠,孙文斌,吴奇

作者机构:[陆同兴,李干佐,李锡忠,孙文斌,吴奇]安徽师范大学物理系,山东大学国家教委胶体和界面化学开放室,山东大学国家教委胶体和界面化学开放室,安徽师范大学物理系,香港中文大学化学系 芜湖241000,济南250100,济南250100,芜湖241000,香港

来源:化学学报,ACTA CHIMICA SINICA,1998,Vol.56,Issue.11,1041-1047

WOS被引数:4

资源类型:期刊论文

WOS:000077372200001

92. DODMAC/n-C_(10)H_(21)OH/10% n-C_(10)H_(22)/H_2O体系溶致液晶的~2H NMR和SAXS研究 SCIE

作者:郝京诚,李干佐,汪汉卿,刘维民

作者机构:[郝京诚,李干佐,汪汉卿,刘维民]山东师范大学化学系,山东大学化学系,中国科学院兰州化学物理研究所固体润滑开放实验室,中国科学院兰州化学物理研究所固体润滑开放实验室 济南250014,济南250100,兰州730000,兰州730000

来源:化学学报,ACTA CHIMICA SINICA,1997,Vol.55,Issue.5,491-497

资源类型:期刊论文

WOS:A1997XD34000013

93. 不同稀释剂中HDEHP的界面性质研究 SCOPUS SCIE

作者:杨永会,宋其圣,杨延钊,崔玉,孙国新,孙思修

作者机构:[杨永会,宋其圣,杨延钊,崔玉,孙国新,孙思修]山东大学化学系,山东大学化学系,山东大学化学系,山东建筑材料工业学院应用化学系,中国科学院上海原子核所 济南250100,济南250100,济南250100,济南250022,博士生

来源:化学学报,ACTA CHIMICA SINICA,1997,Vol.55,Issue.1,64-68

WOS被引数:2

资源类型:期刊论文

WOS:A1997WR73600011

94. 侧基含偶氮基的硅氧烷梳状聚合物的光致变色性 SCOPUS SCIE

作者:张静智;张其震

作者机构:[张静智;张其震]山东大学化学系;[张静智;张其震]山东大学化学系 济南250100;[张静智;张其震]济南250100

来源:化学学报,ACTA CHIMICA SINICA,1997,Vol.55,Issue.9,930-936

WOS被引数:14

资源类型:期刊论文

WOS:A1997YB05800016

95. 具有不同取代链长的卟啉衍生物LB膜的结构研究 SCOPUS SCIE

作者:刘洪国,冯绪胜,杨孔章,梁维安

作者机构:[刘洪国,冯绪胜,杨孔章,梁维安]山东大学胶体与界面化学研究所,山东大学胶体与界面化学研究所,山东大学胶体与界面化学研究所,山东大学化学系 济南250100,济南250100,济南250100,济南250100

来源:化学学报,ACTA CHIMICA SINICA,1997,Vol.55,Issue.2,117-122

WOS被引数:7

资源类型:期刊论文

WOS:A1997WM08700003

96. 全氟辛酸钠与十二烷基三甲基溴化铵混合胶束微环境性质的NMR,ESR研究 SCOPUS SCIE

作者:郝京诚,汪汉卿,刘维民,李干佐

作者机构:[郝京诚,汪汉卿,刘维民,李干佐]山东师范大学化学系,中国科学院兰州化学物理研究所固体润滑开放实验室,中国科学院兰州化学物理研究所固体润滑开放实验室,山东大学化学系 济南250014,兰州730000,兰州730000,济南250100

来源:化学学报,ACTA CHIMICA SINICA,1997,Vol.55,Issue.4,322-327

WOS被引数:6

资源类型:期刊论文

WOS:A1997WX14500002

97. 具有两种不同配位隔室的含酚桥基‘N_5O_2’Schiff碱大环铜钠异双核配合物的合成及结构 SCOPUS SCIE

作者:马长勤,张文兴,王绪宁,蒋德华

作者机构:[马长勤,张文兴,王绪宁,蒋德华]山东大学化学学院,山东大学化学学院,山东大学化学学院,山东大学化学学院 济南250100,济南250100,济南250100,济南250100

来源:化学学报,ACTA CHIMICA SINICA,1997,Vol.55,Issue.6,539-544

WOS被引数:3

资源类型:期刊论文

WOS:A1997YD10600004

98. 胶束微环境下光解苯半醌负离子基的CIDEP研究 SCOPUS SCIE

作者:陆同兴,汤开元,李干佐,苏红梅

作者机构:[陆同兴,汤开元,李干佐,苏红梅]安徽师范大学物理系,安徽师范大学物理系,山东大学化学院胶体和界面化学开放实验室,山东大学化学院胶体和界面化学开放实验室 芜湖241000,芜湖241000,济南250100,济南250100

来源:化学学报,ACTA CHIMICA SINICA,1997,Vol.55,Issue.3,215-220

WOS被引数:3

资源类型:期刊论文

WOS:A1997WT40800002

99. 镍铂修饰n型硅电极光电解析氧 SCOPUS SCIE

作者:李怀祥;李国铮;王士勋

作者机构:[李怀祥;李国铮;王士勋]山东师范大学化学系;[李怀祥;李国铮;王士勋]山东大学化学系;[李怀祥;李国铮;王士勋]山东大学化学系 济南250014;[李怀祥;李国铮;王士勋]济南250100;[李怀祥;李国铮;王士勋]济南250100

来源:化学学报,ACTA CHIMICA SINICA,1996,Vol.54,Issue.2,182-186

WOS被引数:3

资源类型:期刊论文

WOS:A1996UA97900012

100. 含N,O和S的Schiff碱配体的双核锌配合物的合成与晶体结构 SCIE

作者:马长勤,王绪宁,张文兴,于正刚,蒋德华,董士利

作者机构:[马长勤,王绪宁,张文兴,于正刚,蒋德华,董士利]山东大学化学院,山东大学化学院,山东大学化学院,山东大学化学院,山东大学化学院,淄博市公安局 济南250100,济南250100,济南250100,济南250100,济南250100,淄博255039

来源:化学学报,ACTA CHIMICA SINICA,1996,Vol.54,Issue.6,562-567

WOS被引数:10

资源类型:期刊论文

WOS:A1996UY13200007

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