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M+ + X-2(-) reaction system involves two potential energy surfaces, i.e., the covalence state(M+X-2) and the ionic state(M++X-2(-)) and their crossing effect, The working equations for calculating state-to-state probability have been derived based on the above two-state model, The selected-state reaction probabilities of collinear ion-pair formation process M+I-2 --> M+ +I-2(-) (M = Na, K, Cs) on Aten-Lanting-Los two-state potential energy surface have been calculated. The results show that the reaction probabilities are of resonance effect. [author_in] => [Ma, W.-Y] Institute of Theoretical Chemistry, Shandong University, Jinan, 250100, China, Department of Chemical Engineering, Shandong Institute of Light Industry, Jinan, 250100, China@@@[ Cai, Z.-T] Institute of Theoretical Chemistry, Shandong University, Jinan, 250100, China@@@[ Feng, D.-C] Institute of Theoretical Chemistry, Shandong University, Jinan, 250100, China@@@[ Deng, C.-H] Institute of Theoretical Chemistry, Shandong University, Jinan, 250100, China [pub_date] => MAY [format_title_en_publication_en_pub_year] => 01150d99dcf7cc7e89eb21937e27aa54-831692535 [from_id] => 76,74,73,80,78,85 [issue] => 5 [hx_id] => 2376,2378,2371 [classification_pub] => KTHPD [datebase] => Scopus [sys_level_num] => 1_4 [sys_jg_type] => 0,5 [format_issn_issue_page_pub_year] => dc1b6525eed0b9e672cd8ed3072b19f74238320 [title_en] => The quantum scattering study for ion-pair formation reaction with LCAC-SW method [volume] => 20 [author_fn] => Ma, WY; Cai, ZT; Feng, DC; Deng, CH [pub_year] => 1999 [article_id] => 213702,583486,3363,400978,497596,334140 [hints] => 39 [publisher] => HIGHER EDUCATION PRESS [language] => Chinese [source_type] => 351 [reference_No] => 6 [batch] => 3250,3241,3254,3246,3243,3252 [publication_en] => CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE [school_id] => 117 [sys_update_time] => 2018-09-05 15:28:36 [format_title_en_issn_pub_year] => 2e0aba09b12d8be864572c7482b7b742280124234 [format_ei_No] => 2b51d7438b637f14acc15d630ed12ea41321052191 [SYS_TAG] => 3 [page] => 138-140 [hb_type] => 2 [article_dt] => Letter [cite_wos] => 2 [check_3Y] => 0 [delivery_No] => 198MU [format_title] => 138d019b6bc006c5016ad404c9a3b481-798020738 [cauthor_ad] => [Ma, WY]Shandong Univ, Inst Theoret Chem, Jinan 250100, Peoples R China. [pages] => 3 [publication_29] => CHEM J CHINESE U [end_page] => 799 [publication_type] => J [begin_page] => 797 [get_data] => 2018-08-29 [keyword_en] => ion-pair formation; reaction probabilities; LCAC-SW method [format_publication_cn] => 112be9cb2f30361719ed2bc572ba4a22192440272 [publication_iso] => Chem. J. Chin. Univ.-Chin. [format_title_en] => 38f6d8c2b26a00e6f3b3e221e22baccb-1404889632 [publisher_city] => BEIJING [cite_awos] => 2 [wos_No] => WOS:000080428600031 [sys_priority_field] => 76 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [check_180] => 0 [publisher_ad] => SHATANHOU ST 55, BEIJING 100009, PEOPLES R CHINA [format_publication_en] => 4eabdd9afe3fe566a165b6e1c3e0dbbd-130083487 [jl_language] => chinese [jl_article_dt] => letter [jl_publication_en] => chemicaljournalofchineseuniversitieschinese [jl_country] => 中国 [jl_keyword_en] => reactionprobabilities,lcacswmethod,ionpairformation [jl_publisher] => highereducationpress [author_jg] => [马万勇,蔡政亭,冯大成,邓从豪]山东大学理论化学研究所,山东轻工业学院化工系 [keyword_cn] => 离子对生成;反应几率;LCAC-SW方法 [clc] => O643 [title_cn] => 离子对生成反应的LCAC-SW量子散射理论研究 [publication_cn] => 高等学校化学学报 [CSSN] => 22-1131/O6 [abstract_cn] => 离子对生成反应微观动力学的理论和实验研究有助于从本质上揭示气相、液相及上层空间大气化学反应机理.实验上已经发展到用激光-交叉分子束技术研究其态-态过程;理论上则主要是采用准经典轨迹法.由于这类反应是电子非绝热过程,涉及到共价态和离子态两个势能面及其耦... [author_cn] => 马万勇,蔡政亭,冯大成,邓从豪 [uri] => https://www.scopus.com/inward/record.uri?eid=2-s2.0-0345880689&partnerID=40&md5=01f341cefcc5e038e11305ccb0b90775 [jl_publication_cn] => 高等学校化学学报 [jl_keyword_cn] => 离子对生成,反应几率,lcacsw方法 [jl_clc] => o643 [company_id] => 0,0,0,0,0,0,0,0 [author_id] => [author_test] => Array ( ) [sys_author_id_arr] => [jl_publication_cn_publication_en] => chemicaljournalofchineseuniversitieschinese,高等学校化学学报 [jl_keyword_cn_keyword_en] => 离子对生成,反应几率,ionpairformation,lcacswmethod,lcacsw方法,reactionprobabilities [format_scopus_No] => 93d9b5bf09ce2cc5d06e2e952c4e33a2704217273 [format_wos_No] => 3c598c78e5a06731e00e41b30636c14a-1348391272 [standard_in] => Institute of Theoretical Chemistry, Shandong University, Jinan, 250100, China; Department of Chemical Engineering, Shandong Institute of Light Industry, Jinan, 250100, China [scopus_No] => 2-s2.0-0345880689 [format_title_cn_publication_cn_pub_year] => 74a93d03bed4819950721b59eff0b01893759334 [format_title_cn_issn_pub_year] => a72e6c26481cf94b5a1c0f3d26dff73a-1397311027 [sys_author_jg_last_arr] => 山东轻工业学院化工系 [sys_author_in_last_arr] => china [sys_author_id] => [id] => lQd5vWUBFjIhTVEbiEgl [tags] => 0 ) [1] => Array ( [cauthor] => Zhang, Huaijin [issn] => 0022-0248 [controlled_terms] => Absorption spectroscopy - Calcium compounds - Doping (additives) - Fluorescence - Laser applications - Luminescence - Optical pumping - Semiconductor lasers - Spectrum analysis - Ytterbium [batch2] => 1,6 [hb_batch] => 3246 [ei_No] => 1999314701728 [tag] => 0 [author_en] => Zhang, HJ; Meng, XL; Zhu, L; Wang, P; Liu, XS; Cheng, RP; Dawes, J; Dekker, P; Zhang, SJ; Sun, L [sys_level_num] => 1_4 [abstract_en] => Yb : Ca4YO(BO3)(3) (Yb :YCOB) crystal has been grown by the Czochralski method. The absorption and fluorescence spectra have been measured. The green luminescence is also observed. The output laser at 1032 nm has been demonstrated pumped by laser diode (LD) at 976.4 nm. (C) 1999 Elsevier Science B.V. All rights reserved. [format_doi] => e62d573626a11066858616ae33b2831459016627 [author_in] => [Zhang, HJ; Meng, XL; Zhu, L; Wang, P; Liu, XS; Cheng, RP; Dawes, J; Dekker, P; Zhang, SJ; Sun, L]Shandong Univ, Natl Lab Crystal Mat, Jinan 250100, Peoples R China.@@@[Zhang, HJ; Meng, XL; Zhu, L; Wang, P; Liu, XS; Cheng, RP; Dawes, J; Dekker, P; Zhang, SJ; Sun, L] Shandong Univ, Inst Crystal Mat, Jinan 250100, Peoples R China.@@@[Zhang, HJ; Meng, XL; Zhu, L; Wang, P; Liu, XS; Cheng, RP; Dawes, J; Dekker, P; Zhang, SJ; Sun, L] Macquarie Univ, Ctr Lasers & Applicat, N Ryde, NSW 2109, Australia. 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1. 离子对生成反应的LCAC-SW量子散射理论研究 EI SCOPUS SCIE

作者:马万勇,蔡政亭,冯大成,邓从豪

作者机构:[马万勇,蔡政亭,冯大成,邓从豪]山东大学理论化学研究所,山东轻工业学院化工系

来源:高等学校化学学报,CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,1999,Vol.20,Issue.5,138-140

WOS被引数:2

资源类型:期刊论文

WOS:000080428600031

2. Growth and laser properties of Yb : Ca4YO(BO3)(3) crystal EI SCOPUS SCIE

作者:Zhang, HJ; Meng, XL; Zhu, L; Wang, P; Liu, XS; Cheng, RP; Dawes, J; Dekker, P; Zhang, SJ; Sun, L

作者机构:[Zhang, HJ; Meng, XL; Zhu, L; Wang, P; Liu, XS; Cheng, RP; Dawes, J; Dekker, P; Zhang, SJ; Sun, L]Shandong Univ, Natl Lab Crystal Mat, Jinan 250100, Peoples R China.;[Zhang, HJ; Meng, XL; Zhu, L; Wang, P; Liu, XS; Cheng, RP; Dawes, J; Dekker, P; Zhang, SJ; Sun, L] Shandong Univ, Inst Crystal Mat, Jinan 250100, Peoples R China.;[Zhang, HJ; Meng, XL; Zhu, L; Wang, P; Liu, XS; Cheng, RP; Dawes, J; Dekker, P; Zhang, SJ; Sun, L] Macquarie Univ, Ctr Lasers & Applicat, N Ryde, NSW 2109, Australia.

来源:JOURNAL OF CRYSTAL GROWTH,1999,Vol.200,Issue.1-2,335-338

WOS被引数:3

资源类型:期刊论文

WOS:000079840600044

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