按条件检索“168”条记录

已选条件: 出版物中文: 高等学校化学学报 ×
导出
  • 排序
  • 显示
IH(v\'=0)+I system. For H and I atom, 6-311+ +G** basis set and SDD basis set including the relativistic effect are used separately. The scattering resonance states are found for the title system and the six scattering resonance states are identified as the Feshbach type in the. collision energy range from 0 to 0.58 eV which are compared with the theoretical results of quantum. scattering and the experimental ones of threshold photodetachment spectroscopy. The partial potential energy surface can reveal effectively the mechanism of the scattering resonance states formation. [abstract_cn] => 在QCISD(T)//MP2水平下,分别采用6-311++G**基组和SDD基组对重-轻-重反应I+HI(v=0)→IH(v\\\'=0)+I中的H和I的偏分势能面进行了ab initio计算,指认出在0~0.58 eV碰撞能范围内所产生的6个散射共振态为Feshbach共振,并与文献报道的量子散射理论计算与高分辨阈值光分离光谱实验结果进行了比较. [keyword_cn] => 重-轻-重体系;偏分势能面;散射共振态;从头计算 [fund_No] => 国家自然科学基金 [format_title_en_publication_en_pub_year] => 89bf9a03daba39df5daf1cf0fbf659ef-201756336 [publication_type] => J [author_jg] => [孙孝敏] 山东大学理论化学研究所, 济南, 山东 250100, 中国.@@@[王华阳] 山东大学理论化学研究所, 济南, 山东 250100, 中国.@@@[蔡政亭] 山东大学理论化学研究所, 济南, 山东 250100, 中国.@@@[冯大诚] 山东大学理论化学研究所, 济南, 山东 250100, 中国.@@@[边文生] 中国科学院化学研究所, 分子反应动力学国家重点实验室, 北京 100080, 中国 [cite_cscd] => 4 [cite_awos] => 6 [from_id] => 75,73,80 [issue] => 9 [email] => zhtcai@sdu.edu.cn [email_c] => zhtcai@sdu.edu.cn [sys_level_num] => 1_1 [format_title_cn_publication_cn_pub_year] => d60e885185da18424beefa48f717ca441035525009 [sys_jg_type] => 9,5 [format_issn_issue_page_pub_year] => ee1af11c574fe7dbf02b309f2d90d2f0-1315876948 [title_en] => Theoretical study on the scattering resonance states for I+HI(v=0)-> IH(v \'=0)+I system [volume] => 25 [author_fn] => Sun, XM; Wang, HY; Cai, ZT; Feng, DC; Bian, WS [pub_year] => 2004 [check_180] => 0 [keyword_en] => heavy-light-heavy system; partial potential energy surface; scattering; resonance states; ab initio [end_page] => 1705 [article_id] => 329491,682449,213719 [pages] => 4 [hints] => 11 [author_cn] => 孙孝敏;王华阳;蔡政亭;冯大诚;边文生 [language] => Chinese [source_type] => 351 [reference_No] => 16 [cscd_No] => CSCD:1805753 [batch] => 3249,3252,3241 [publication_en] => CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE [hx_id] => 2377,2371 [author_in] => [Sun, XM; Wang, HY; Cai, ZT; Feng, DC; Bian, WS]Shandong Univ, Inst Theoret Chem, Jinan 250100, Peoples R China.@@@[Sun, XM; Wang, HY; Cai, ZT; Feng, DC; Bian, WS] Chinese Acad Sci, Inst Chem, State Key Lab Mol React Dynam, Beijing 100080, Peoples R China. [format_title_en_issn_pub_year] => b0d8624589ac5764cead0c5cea8932a6-1982191802 [check_3Y] => 4 [publication_cn] => 高等学校化学学报 [title_cn] => I+HI(υ=0)→IH(υ′=0)+I体系散射共振态的理论研究 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => 9505fe8307000c3e632f0d7c21bfb71798848941 [page] => 1702-1705 [hb_type] => 2 [article_dt] => Article [hb_batch] => issn_issue_page_pub_year_1_7 [cite_wos] => 5 [delivery_No] => 855ZY [format_title] => 5821e3cb4620c7f9236683380aa3a2752072963264 [cauthor_ad] => [Cai, ZT]Shandong Univ, Inst Theoret Chem, Jinan 250100, Peoples R China. [publication_29] => CHEM J CHINESE U [author_en] => Sun, XM; Wang, HY; Cai, ZT; Feng, DC; Bian, WS [get_data] => 2018-08-29 [publisher] => HIGHER EDUCATION PRESS [format_publication_cn] => 112be9cb2f30361719ed2bc572ba4a22192440272 [keyword_plu] => OSCILLATORY BEHAVIOR; SPECTROSCOPY; PROBABILITY; COLLISION; REGION; CL [publication_iso] => Chem. J. Chin. Univ.-Chin. [format_title_en] => d517286e73be1ac59275fff0693df7a5995822178 [publisher_city] => BEIJING [pub_date] => SEP [wos_No] => WOS:000224014600029 [sys_priority_field] => 73 [wos_sub] => Chemistry, Multidisciplinary [publisher_ad] => SHATANHOU ST 55, BEIJING 100009, PEOPLES R CHINA [format_publication_en] => 4eabdd9afe3fe566a165b6e1c3e0dbbd-130083487 [jl_language] => chinese [jl_publication_cn] => 高等学校化学学报 [jl_article_dt] => 期刊论文 [jl_publication_en] => chemicaljournalofchineseuniversitieschinese [jl_country] => 中国,中国 [jl_keyword_en] => resonancestates,heavylightheavysystem,abinitio,scattering,partialpotentialenergysurface [jl_keyword_cn] => 散射共振态,重轻重体系,从头计算,偏分势能面 [jl_publisher] => highereducationpress [cite_wanfang] => 3 [clc] => O641 [CSSN] => 22-1131/O6 [jl_clc] => o641 [company_id] => [author_id] => 23586 [author_test] => Array ( [0] => Array ( [sure] => 0 [irmagnum] => 0 [u_index] => 1 [name] => 孙孝敏 [irtag] => 7 [t_index] => 0 [person_id] => 23586 ) ) [sys_author_id_arr] => [jl_publication_cn_publication_en] => chemicaljournalofchineseuniversitieschinese,高等学校化学学报 [jl_keyword_cn_keyword_en] => 从头计算,散射共振态,partialpotentialenergysurface,resonancestates,heavylightheavysystem,偏分势能面,重轻重体系,abinitio,scattering [sys_author_id] => [format_wos_No] => 6f59315475258a48f82635b9512f443b-1411527407 [id] => 3QZzvWUBFjIhTVEbvjjw [tags] => 0 ) [1] => Array ( [batch2] => 1,2 [uri] => http://kns.cnki.net/kns/detail/detail.aspx?FileName=GDXH200404023&DbName=CJFQ2004 [tag] => 0 [CSSN] => 22-1131/O6 [keyword_cn] => 二氟亚烷基卡宾;;环加成反应;;二阶微扰理论;;势能面 [fund_No] => 山东省自然科学基金 [article_id] => 329745,213718,539184,682492 [abstract_cn] => 用二阶微扰理论研究单重态二氟亚烷基卡宾与甲醛发生的环加成反应机理 ,采用 MP2 /6-3 1 G*方法计算了势能面上各驻点的构型参数、振动频率和能量 .结果表明 ,单重态二氟亚烷基卡宾与甲醛的环加成反应主要有两种反应通道 ,通道 1中 ,两个反应物经 a,b和 c三条反应途径生成三元环构型的产物 P1 ,其中途径 c是主反应途径 ,该途径有两步组成 :( )二氟亚烷基卡宾与甲醛生成了 1个富能中间体 ( INT1 c) ,是无势垒放热反应 ,放出能量为 2 1 9.1 8k J/mol;( )中间体 ( INT1 c)异构化为产物二氟亚烷基环氧乙烷 ,其势垒为 1 3 4.71 k J/... [author_jg] => [卢秀慧] 济南大学化学化工学院, 济南, 山东 250002, 中国.@@@[武卫荣] 济南大学化学化工学院, 济南, 山东 250002, 中国.@@@[步宇翔] 山东大学理论化学研究所, 济南, 山东 250100, 中国.@@@[刘成卜] 山东大学理论化学研究所, 济南, 山东 250100, 中国 [format_title_cn_publication_cn_pub_year] => 71e3fdfaf842e468ce7ff2125cbdabdd-1395391406 [hints] => 7 [issue] => 4 [author_first] => 卢秀慧 [sys_level_num] => 2_3 [sys_jg_type] => 0,5 [format_issn_issue_page_pub_year] => 97c1ff5a9dc9b60cfe73a795e077dcb145104563 [source_type] => 351 [pub_year] => 2004 [pub_date] => APR 10 [pages] => 4 [from_id] => 75,73,80,78 [author_cn] => 卢秀慧;武卫荣;步宇翔;刘成卜 [issn] => 0251-0790 [batch] => 3250,3249,3241,3252 [publication_cn] => 高等学校化学学报 [title_cn] => 二氟亚烷基卡宾与甲醛环加成反应机理的理论研究 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => 13390054631f899e5a8450e9e77c9d89-2072222462 [page] => 681-684+5 [hb_type] => 2 [article_dt] => Article [hb_batch] => title_cn_publication_cn_pub_year_2_3 [publication_en] => CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE [cite_wos] => 2 [check_3Y] => 0 [language] => Chinese [delivery_No] => 811LX [format_title] => 55c2fa9ec98d2efebdb4c2b23c4a1dcf-1904705774 [cauthor_ad] => [Lu, XH]Jinan Univ, Sch Chem & Chem Engn, Jinan 250002, Peoples R China. [author_fn] => Lu, XH; Wu, WR; Bu, YX; Liu, CB [reference] => APELOIG Y, 1983, J AM CHEM SOC, V105, P4781, DOI 10.1021/ja00352a042@@@@@@FOX DP, 1986, J AM CHEM SOC, V108, P750, DOI 10.1021/ja00264a029@@@@@@FRISCH MJ, 1981, CHEM PHYS LETT, V81, P421, DOI@@@10.1016/0009-2614(81)85642-4@@@KRISHNAN R, 1981, CHEM PHYS LETT, V79, P408, DOI@@@10.1016/0009-2614(81)85003-8@@@[卢秀慧 Lu Xiuhui], 2002, [化学学报, Acta Chemical Sinica], V60, P769@@@Stang P, 1978, Chem. Rev., V784, P383@@@STANG PJ, 1982, ACCOUNTS CHEM RES, V15, P348, DOI 10.1021/ar00083a002@@@@@@谷文祥, 1997, 高等学校化学学报, V18, P238 [publication_29] => CHEM J CHINESE U [end_page] => 684 [abstract_en] => The mechanism of cycloaddition between singlet difluoro-vinylidene and formaldehyde was investigated with MP2/6-31G* method, including geometry optimization, vibrational analysis, and energetics for the involved stationary points on the potential energy surface. The results show that the title reaction has two major channels. The first one brings about a three-membered ring product(P1) via a, b and c paths, of which c is the leading path that consists of two steps: (1) an intermediate (INT1c) is formed between difluoro vinylidene and formaldehyde through a free barrier exothermic reaction of 219.18 kJ/ mol; (1) the intermediate then isomerizes to a products difluoro-methylene ethane oxide, with an energy barrier of 134.71 kJ/mol. The reaction path of channel 2 consists of three steps: (1) an energy-rich intermediate (INT1b) is firstly formed between difluoro-vinylidene and formaldehyde through a free barrier exothermic reaction of 142.77 kJ/mol; (1) the intermediate (INT1b) then isomerizes to the other one intermediate (INT2), with an energy barrier of 22.31 kJ/mol; the intermediate (INT2) isomerizes to one 4-membered ring products (P2), with an energy barrier of 11.98 kJ/mol. [author_in] => [Lu, XH; Wu, WR; Bu, YX; Liu, CB]Jinan Univ, Sch Chem & Chem Engn, Jinan 250002, Peoples R China.@@@[Lu, XH; Wu, WR; Bu, YX; Liu, CB] Shandong Univ, Inst Theoret Chem, Jinan 250100, Peoples R China. [publication_type] => J [begin_page] => 681 [author_en] => Lu, XH; Wu, WR; Bu, YX; Liu, CB [volume] => 25 [get_data] => 2018-08-29 [publisher] => HIGHER EDUCATION PRESS [keyword_en] => difluoro; vinylidene carbene; cycloaddition reaction; second-order; Moller-Plesset perturbation theory; potential energy surface [format_publication_cn] => 112be9cb2f30361719ed2bc572ba4a22192440272 [keyword_plu] => ALKYLIDENECARBENE ADDITION; STEREOSELECTIVITY; OLEFINS [publication_iso] => Chem. J. Chin. Univ.-Chin. [format_title_en] => ff9c7532d764841dbdb4130714a70dcd-1904151542 [publisher_city] => BEIJING [hx_id] => 2377,2371 [reference_No] => 8 [email] => lxh9853@Yahoo.com.cn [cite_awos] => 3 [wos_No] => WOS:000220774500023 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [check_180] => 0 [publisher_ad] => SHATANHOU ST 55, BEIJING 100009, PEOPLES R CHINA [title_en] => Theoretical study on mechanism of cycloaddition reaction between difluorovinylidene and formaldehyde [format_publication_en] => 4eabdd9afe3fe566a165b6e1c3e0dbbd-130083487 [jl_language] => chinese [jl_publication_cn] => 高等学校化学学报 [jl_article_dt] => 期刊论文 [jl_publication_en] => chemicaljournalofchineseuniversitieschinese [jl_country] => 中国,中国 [jl_keyword_en] => potentialenergysurface,mollerplessetperturbationtheory,secondorder,difluoro,cycloadditionreaction,vinylidenecarbene [jl_keyword_cn] => ,环加成反应,二氟亚烷基卡宾,二阶微扰理论,势能面 [jl_publisher] => highereducationpress [company_id] => [author_id] => 20105 [author_test] => Array ( [0] => Array ( [sure] => 0 [irmagnum] => 0 [u_index] => 3 [name] => 步宇翔 [irtag] => 7 [t_index] => 0 [person_id] => 20105 ) ) [sys_author_id_arr] => [cscd_No] => CSCD:1594913 [jl_publication_cn_publication_en] => chemicaljournalofchineseuniversitieschinese,高等学校化学学报 [jl_keyword_cn_keyword_en] => potentialenergysurface,二氟亚烷基卡宾,mollerplessetperturbationtheory,势能面,环加成反应,difluoro,secondorder,cycloadditionreaction,二阶微扰理论,vinylidenecarbene [sys_author_id] => [format_cscd_No] => 0819c429356f3581d80d0a5a1007c7d01433164076 [format_title_en_publication_en_pub_year] => 5f67d550196eee16e2405233cc29046a1692600379 [format_wos_No] => 02a016f0d2811cfa05fbfb842a2310f21719243413 [format_title_en_issn_pub_year] => b6ec1e16b746b5618b9bc5e34b67d5cf-650936138 [id] => Gw9KvmUBFjIhTVEbYAQa [tags] => 0 ) [2] => Array ( [batch2] => 1,2 [batch] => 3250,3249,3241,3252 [tag] => 0 [CSSN] => 22-1131/O6 [keyword_cn] => Enterococcus durans;EPS-Ⅰ;胞外多糖;分离纯化 [article_id] => 200869,682520,583491,329579 [abstract_cn] => The rough crystal of exopolysaccharide produced by Enterococcus durans, a strain of lactic acid bacteria screened from the intestine of a cock in our laboratory, was purified by CM-cellulose column chromatography, DEAE-Sephadex A-25 ionexchange and Sephadex G-100 gel chromatography to give EPS-Ⅰ. ... [author_jg] => [顾笑梅] 山东大学生命科学院, 微生物技术国家重点实验室, 济南, 山东 250100, 中国.@@@[马桂荣] 山东大学生命科学院, 微生物技术国家重点实验室, 济南, 山东 250100, 中国.@@@[吴厚铭] 中国科学院上海有机化学研究所, 生命有机化学国家重点实验室, 上海 200032, 中国 [format_title_cn_publication_cn_pub_year] => 8a8000949edb6484f39bdbca1cd0e4c3-191097856 [hints] => 9 [issue] => 7 [sys_level_num] => 2_3 [sys_jg_type] => 0,5 [format_issn_issue_page_pub_year] => ae16577cffe80c85abef1de3b206ee5817749035 [source_type] => 351 [pub_year] => 2004 [pub_date] => JUL [pages] => 3 [from_id] => 75,73,80,78 [author_cn] => 顾笑梅,吴厚铭,马桂荣 [issn] => 0251-0790 [uri] => http://kns.cnki.net/kns/detail/detail.aspx?FileName=GDXH200407026&DbName=CJFQ2004 [publication_cn] => 高等学校化学学报 [title_cn] => Enterococcus durans产胞外多糖EPS-Ⅰ的分离纯化和结构分析 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => 2b859622d7c7ad6fe0b42516edc60ad4-929418072 [page] => 1288-1290 [hb_type] => 2 [article_dt] => Article [hb_batch] => title_cn_publication_cn_pub_year_2_3 [publication_en] => CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE [cite_wos] => 4 [check_3Y] => 4 [language] => Chinese [delivery_No] => 841CG [format_title] => aafce9d0a01db11f7736c0ed081ce51c-1297944149 [cauthor_ad] => [Ma, GR]Shandong Univ, State Key Lab Microbial Technol, Jinan 250100, Peoples R China. [author_fn] => Gu, XM; Wu, HM; Ma, GR [reference] => COREY EJ, 1962, J AM CHEM SOC, V84, P866, DOI 10.1021/ja00864a039@@@[顾笑梅 Gu Xiaomei], 2003, [中华微生物学和免疫学杂志, Chinese Journal of Microbiology@@@and Immunology], V23, P442@@@[顾笑梅 Gu Xiaomei], 2003, [微生物学报, Acta Microbiologica Sinica], V43, P251@@@HAKOMORI SI, 1964, J BIOCHEM-TOKYO, V55, P205@@@Luc De Vuyst, 1999, FEMS Microbiology Reviews, V23, P153@@@Marijke Gruter, 1994, Journal of Carbohydrate Chemistry, V13, P363@@@NAGAOKA M, 1994, BIOL PHARM BULL, V17, P1514@@@ODA M, 1983, AGR BIOL CHEM TOKYO, V47, P1623, DOI@@@10.1080/00021369.1983.10865826@@@张维杰, 1994, 糖复合生化研究技术(第二版), P41@@@杨洁彬, 1996, 乳酸菌生物学基础及应用, P179 [publication_29] => CHEM J CHINESE U [end_page] => 1290 [abstract_en] => The rough crystal of exopolysaccharide produced by Enterococcus durans, a strain of lactic acid bacteria screened from the intestine of a cock in our laboratory, was purified by CM-cellulose column chromatography, DEAE-Sephadex A-25 ionexchange and Sephadex G-100 gel chromatography to give EPS-I. The EPS-I was eluted as a single peak in HPLC analysis, indicating the homogeneity of EPS-I and free from low-molecular-weight polysaccharides. The molecular weight of the EPS-I was determined as 42 000 by the light scattering method. The result of its elemental analysis was C 41.08% and H 7.23% without the elements of N, P and S. Monosaccharide analysis showed that it was composed of Glc and Man in a molar ratio of 4:1. Sugar composition analysis, methylation analysis and H-1 and C-13 NMR spectroscopy revealed that the EPS-I was composed of pentasaccharide repeating units. The sequence of sugar residues was determined by using two-dimensional NMR, including heteronuclear multiple-bond correlation(HMBC) and nuclear overhauser effect spectroscopy (NOESY). The structure of the pentasaccharide repeating unit of EPS-I was given, a new excellular polysaccharide from lactic acid bacterium compared with other EPSs was reported. [author_in] => [Gu, XM; Wu, HM; Ma, GR]Shandong Univ, State Key Lab Microbial Technol, Jinan 250100, Peoples R China.@@@[Gu, XM; Wu, HM; Ma, GR] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Bioorgan & Nat Prod Chem, Shanghai 200032, Peoples R China. [publication_type] => J [begin_page] => 1288 [author_en] => Gu, XM; Wu, HM; Ma, GR [volume] => 25 [get_data] => 2018-08-29 [publisher] => HIGHER EDUCATION PRESS [keyword_en] => Enterococcus durans; EPS-I; extracellular polysaccharide; purification [format_publication_cn] => 112be9cb2f30361719ed2bc572ba4a22192440272 [publication_iso] => Chem. J. Chin. Univ.-Chin. [format_title_en] => d13b51b08c398057ee9155173fae0d96495829996 [publisher_city] => BEIJING [hx_id] => 2377,2371 [reference_No] => 10 [email] => grma@beelink.com [cite_awos] => 4 [wos_No] => WOS:000222906300025 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [check_180] => 0 [publisher_ad] => SHATANHOU ST 55, BEIJING 100009, PEOPLES R CHINA [title_en] => Isolation, purification and structural elucidation of EPS-I, an extracellular polysaccharide from Enterococcus durans [format_publication_en] => 4eabdd9afe3fe566a165b6e1c3e0dbbd-130083487 [jl_language] => chinese [jl_publication_cn] => 高等学校化学学报 [jl_article_dt] => 期刊论文 [jl_publication_en] => chemicaljournalofchineseuniversitieschinese [jl_country] => 中国,中国 [jl_keyword_en] => enterococcusdurans,extracellularpolysaccharide,purification,epsi [jl_keyword_cn] => enterococcusdurans,epsⅠ,分离纯化,胞外多糖 [jl_publisher] => highereducationpress [company_id] => 160,34 [sys_subject_sort] => 0,0 [college_parent_id] => 160,34 [company_test] => Array,Array [author_id] => [author_test] => Array ( ) [sys_author_id_arr] => [cscd_No] => CSCD:1811220 [jl_publication_cn_publication_en] => chemicaljournalofchineseuniversitieschinese,高等学校化学学报 [jl_keyword_cn_keyword_en] => enterococcusdurans,epsi,胞外多糖,epsⅠ,purification,分离纯化,extracellularpolysaccharide [sys_author_id] => [format_cscd_No] => 7121bb50c44a1e9f3132a9ac7b9c96781345133721 [format_title_en_publication_en_pub_year] => f6c254876414ce263c8ac9a047a05d12863879446 [format_wos_No] => 583a100b61a3d0a922eea08a30c5c691137283362 [format_title_en_issn_pub_year] => 61137aca03dbe1b4fb6004486281c02a2032962922 [id] => bg5IvmUBFjIhTVEbKVm1 [tags] => 0 ) [3] => Array ( [batch2] => 1,2 [uri] => http://kns.cnki.net/kns/detail/detail.aspx?FileName=GDXH200403028&DbName=CJFQ2004 [tag] => 0 [CSSN] => 22-1131/O6 [keyword_cn] => 介孔二氧化硅;;正戊醇;;正辛胺;;孔径 [article_id] => 213715,46203,597741,683776,329839 [abstract_cn] => 在十六烷基三甲基溴化铵 ( CTAB)与硝酸形成的胶束体系中 ,分别加入正戊醇与正辛胺作助表面活性剂 ,合成出介孔二氧化硅 .经小角 XRD和 N2 气体吸附与脱附实验证实 ,随着 CTAB与正戊醇摩尔比的增加 ,介孔二氧化硅的孔径增加 ;而随 CTAB与正辛胺摩尔比的增加 ,介孔二氧化硅的孔径减小 .主要原因是正戊醇增大了 CTAB胶束体积 ,从而导致介孔二氧化硅的孔径增加 .而在 CTAB与正辛胺的混合胶束中 ,正辛胺同硅酸盐作用力比 CTAB强 ,导致介孔二氧化硅的孔径减小 [author_jg] => [韩书华] 山东大学, 胶体与界面化学教育部重点实验室, 济南, 山东 250100, 中国.@@@[侯万国] 山东大学, 胶体与界面化学教育部重点实验室, 济南, 山东 250100, 中国.@@@[许军] 山东大学, 胶体与界面化学教育部重点实验室, 济南, 山东 250100, 中国.@@@[李正民] 山东大学化学学院, 济南, 山东 250100, 中国 [format_title_cn_publication_cn_pub_year] => 69b8c5c6538d042d5953b8f32ce86a32-848273746 [hints] => 17 [issue] => 3 [author_first] => 韩书华 [sys_level_num] => 2_3 [sys_jg_type] => 10,5 [format_issn_issue_page_pub_year] => e87a1fcbe51a7a4cbf6cbbb14f9dc0f2-631194124 [source_type] => 351 [pub_year] => 2004 [pub_date] => MAR 10 [pages] => 3 [from_id] => 75,78,73,80,85 [author_cn] => 韩书华;侯万国;许军;李正民 [issn] => 0251-0790 [batch] => 3250,3249,3241,3254,3252 [publication_cn] => 高等学校化学学报 [title_cn] => 助表面活性剂对介孔二氧化硅孔径的影响 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => 77df57feb7b74185c6a5534598937e50-262384010 [page] => 509-511+391 [hb_type] => 2 [article_dt] => Article [hb_batch] => title_cn_publication_cn_pub_year_2_3 [publication_en] => CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE [cite_wos] => 2 [check_3Y] => 1 [language] => Chinese [delivery_No] => 807UI [format_title] => 6f5ba7dcb1c3d14ed14e49a70f009082-629102237 [cauthor_ad] => [Hou, WG]Minist Educ, Key Lab Colloid & Interface Chem, Jinan 250100, Peoples R China. [author_fn] => Han, SH; Hou, WG; Xu, J; Li, ZM [reference] => BECK JS, 1992, J AM CHEM SOC, V114, P10834, DOI 10.1021/ja00053a020@@@KRESGE CT, 1992, NATURE, V359, P710, DOI 10.1038/359710a0@@@Mao M, 2002, J PHYS CHEM B, V106, P219, DOI 10.1021/jp0107255@@@Mao M, 2002, LANGMUIR, V18, P3380, DOI 10.1021/la011787p@@@Sayari A, 2000, ANGEW CHEM INT EDIT, V39, P2920, DOI@@@10.1002/1521-3773(20000818)39:16<2920::AID-ANIE2920>3.3.CO;2-V@@@Sayari A, 1998, ADV MATER, V10, P1376@@@Sun T, 1998, ANGEW CHEM INT EDIT, V37, P664, DOI@@@10.1002/(SICI)1521-3773(19980316)37:5<664::AID-ANIE664>3.0.CO;2-T@@@ZANA R, 1995, ADV COLLOID INTERFAC, V57, P1, DOI@@@10.1016/0001-8686(95)00235-I@@@Zhao DY, 1998, SCIENCE, V279, P548, DOI 10.1126/science.279.5350.548@@@孙锦玉, 2000, 高等学校化学学报, V21, P21@@@赵国玺, 1984, 表面活性物理化学, P184@@@沈绍典, 2000, 高等学校化学学报, V23, P358 [publication_29] => CHEM J CHINESE U [end_page] => 511 [abstract_en] => Mesoporous silica was synthesized and templated by mixed micelles of cetyltrimethylammonium. bromide(CTAB), n-pentanol or n-octylamine and nitric acid. The products were determined by small angle X-ray diffraction and N-2 gas adsorption-desoption. The results show that pore size of mesoporous silica increased with increase of the molar ratio of CTAB to pentanol, while the pore size decreased with increase of the molar ratio of CTAB to n-octylamine. The reason is that micelle volume increased by addition of pentanol, resulting in the increase of the pore size of mesoporous silica, templated by the mixed micelles of CTAB, pentanol and nitric acid. However, there is bigger interaction between n-octylamin and silicate than that between CTAB and silicate in the mixed micelles of CTAB, n-octylamine and nitric acid, resulting in the decrease of the pore size of mesoporous silica. [author_in] => [Han, SH; Hou, WG; Xu, J; Li, ZM]Minist Educ, Key Lab Colloid & Interface Chem, Jinan 250100, Peoples R China.@@@[Han, SH; Hou, WG; Xu, J; Li, ZM] Shandong Univ, Coll Chem, Jinan 250100, Peoples R China. [publication_type] => J [begin_page] => 509 [author_en] => Han, SH; Hou, WG; Xu, J; Li, ZM [volume] => 25 [get_data] => 2018-08-29 [publisher] => HIGHER EDUCATION PRESS [keyword_en] => mesoporous; silica; n-pentanol; n-octylamin; pore size [format_publication_cn] => 112be9cb2f30361719ed2bc572ba4a22192440272 [keyword_plu] => MOLECULAR-SIEVES; TRANSITION [publication_iso] => Chem. J. Chin. Univ.-Chin. [format_title_en] => 602858911e603fefa383d5a7c2750087338145648 [publisher_city] => BEIJING [hx_id] => 2377,2371 [reference_No] => 12 [email] => wghou@sdu.edu.cn [cite_awos] => 4 [wos_No] => WOS:000220526000029 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [check_180] => 0 [publisher_ad] => SHATANHOU ST 55, BEIJING 100009, PEOPLES R CHINA [title_en] => Effect of cosurfactants on pore size of mesoporous silica [format_publication_en] => 4eabdd9afe3fe566a165b6e1c3e0dbbd-130083487 [jl_language] => chinese [jl_publication_cn] => 高等学校化学学报 [jl_article_dt] => 期刊论文 [jl_publication_en] => chemicaljournalofchineseuniversitieschinese [jl_country] => 中国,中国 [jl_keyword_en] => mesoporous,npentanol,noctylamin,silica,poresize [jl_keyword_cn] => ,介孔二氧化硅,正戊醇,正辛胺,孔径 [jl_publisher] => highereducationpress [company_id] => 43,169 [sys_subject_sort] => 0,0 [college_parent_id] => 43,169 [company_test] => Array,Array [author_id] => 24832,21153,21055 [author_test] => Array ( [0] => Array ( [sure] => 0 [irmagnum] => 0 [u_index] => 1 [name] => 韩书华 [irtag] => 7 [t_index] => 0 [person_id] => 21055 ) [1] => Array ( [sure] => 0 [irmagnum] => 0 [u_index] => 2 [name] => 侯万国 [irtag] => 7 [t_index] => 0 [person_id] => 21153 ) [2] => Array ( [sure] => 0 [irmagnum] => 0 [u_index] => 3 [name] => 许军 [irtag] => 7 [t_index] => 0 [person_id] => 24832 ) ) [sys_author_id_arr] => 21153侯万国,21055韩书华,24739徐健 [cscd_No] => CSCD:1587810 [jl_publication_cn_publication_en] => chemicaljournalofchineseuniversitieschinese,高等学校化学学报 [jl_keyword_cn_keyword_en] => 介孔二氧化硅,poresize,正戊醇,正辛胺,mesoporous,npentanol,孔径,silica,noctylamin [sys_author_id] => 21153,21055,24739 [format_cscd_No] => ef928fd9e5ab6cd72063d1d349ac9952-495786753 [format_title_en_publication_en_pub_year] => 78dace89af6b1acfcc6db2d6e402a2f3-1166761635 [format_wos_No] => aba8e9ce331c89248992f2b44cedae97669572595 [format_title_en_issn_pub_year] => b932db2c484fc49d0b0f7d7c7c535010-1536260730 [id] => mA5HvmUBFjIhTVEbZSPq [tags] => 0 ) [4] => Array ( [batch2] => 1,2 [uri] => http://kns.cnki.net/kns/detail/detail.aspx?FileName=GDXH200407047&DbName=CJFQ2004 [tag] => 0 [CSSN] => 22-1131/O6 [keyword_cn] => 光致变色液晶树状物;;光电信息功能材料;;光异构化;;光回复异构;;热回复异构;;活化能 [fund_No] => 国家自然科学基金; 山东省自然科学基金; 中国科学院长春应用化学研究所高分子物理重点实验室基金 [article_id] => 539179,200871,329577,683785,106794 [abstract_cn] => 研究了端基含己氧基偶氮苯基元新的一代碳硅烷光致变色液晶树状物 G1及其偶氮基元化合物 M3在各种溶液中的反顺光异构化反应速率常数、光回复异构化反应速率常数、热回复异构化反应速率常数、量子产率、活化能和异构转换率 .G1和 M3的光致变色速率常数为 0 .1 s- 1 ,比对应的光致变色液晶聚硅氧烷的光响应速度快 1 0 7倍 [author_jg] => [张其震] 山东大学化学化工学院, 济南, 山东 250100, 中国.@@@[刘建强] 山东大学化学化工学院, 济南, 山东 250100, 中国.@@@[殷晓颖] 山东大学化学化工学院, 济南, 山东 250100, 中国.@@@[张静智] 山东大学化学化工学院, 济南, 山东 250100, 中国 [format_title_cn_publication_cn_pub_year] => fb447ce355b595156bd1add67d33f968 [hints] => 25 [issue] => 7 [author_first] => 张其震 [sys_level_num] => 2_3 [sys_jg_type] => 10,3,5 [format_issn_issue_page_pub_year] => 069af14cf2fc8063442e9bec0dc71c2b [source_type] => 351 [pub_year] => 2004 [pub_date] => JUL [pages] => 5 [from_id] => 75,78,73,80,85 [author_cn] => 张其震;刘建强;殷晓颖;张静智 [issn] => 0251-0790 [batch] => 3250,3249,3241,3254,3252 [publication_cn] => 高等学校化学学报 [title_cn] => 端基含己氧基偶氮苯基元的一代光致变色液晶碳硅烷树状物的光响应行为研究 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => 82224fdb4b5381d22ddd594c0d3c9e7d [page] => 1368-1372 [hb_type] => 2 [article_dt] => Article [hb_batch] => title_cn_publication_cn_pub_year_2_3 [publication_en] => CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE [cite_wos] => 11 [check_3Y] => 0 [language] => Chinese [delivery_No] => 841CG [format_title] => 98072de0137e929ee5608cf1859d16cf-1798499900 [cauthor_ad] => [Zhang, QZ]Shandong Univ, Sch Chem & Chem Engn, Jinan 250100, Peoples R China. [author_fn] => Zhang, QZ; Liu, JQ; Yin, XY; Zhang, JZ [reference] => Archut A, 1998, J AM CHEM SOC, V120, P12187, DOI 10.1021/ja9822409@@@@@@Chen X, 1998, SUPRAMOL SCI, V5, P591, DOI 10.1016/S0968-5677(98)00081-9@@@CHEN X, 1997, MOL CRYST LIQ CRYST, V295, P93@@@IKEDA T, 1995, SCIENCE, V268, P1873, DOI 10.1126/science.268.5219.1873@@@Junge DM, 1999, J AM CHEM SOC, V121, P4912, DOI 10.1021/ja990387+@@@Nagasaki T, 1997, CHEM LETT, P717, DOI 10.1246/cl.1997.717@@@[张其震 Zhang Qizhen], 2004, [高等学校化学学报, Chemical Journal of Chinese@@@Universities], V25, P170@@@[张其震 Zhang Qizhen], 2003, [高等学校化学学报, Chemical Journal of Chinese@@@Universities], V24, P1887@@@[张其震 Zhang Qizheng], 2003, [高等学校化学学报, Chemical Journal of Chinese@@@Universities], V24, P1704@@@张其震, 1997, 高等学校化学学报, V18, P158@@@张静智, 1997, 化学学报, V55, P930@@@张其震, 1996, 高分子学报, P121 [publication_29] => CHEM J CHINESE U [end_page] => 1372 [abstract_en] => Studies were made of on the absorbance at 360 nm A(360), difference of absorbance at 360 nm DeltaA(360), intensity of light I-0, absorption intensity of light I-a, molar extinction coefficient at 360 nm 6360, maximum absorption wavelength lambda(max), quantum yield Phi activation energy E, trans/cis isomer absorbance ratio A/A(0), trans/cis photo-isomerization reaction, rate constant k(p), photo back-isomerization positive/counter reaction rate constants k(t) and k(c), thermal back-isomerization reaction rate constant k(H) at different temperatures and photo back-isomerization reaction equilibrium value k(i)/k(c) of a new carbosilane photochromic liquid crystalline (LC) dendrimer of the first generation (G1) containing twelve 4-hexyloxyazobenzene moieties in its periphery and azobenzene unit M3 in solvents such as chloroform, tetrahydrofuran and so on. solvent were described. The photochromic rate constant of G1 and M3 are 10(-1) s(-1), their photoresponsive rate are 10(7) times larger than that of photochromic liquid crystalline polysiloxane. [author_in] => [Zhang, QZ; Liu, JQ; Yin, XY; Zhang, JZ]Shandong Univ, Sch Chem & Chem Engn, Jinan 250100, Peoples R China.@@@[Zhang, QZ; Liu, JQ; Yin, XY; Zhang, JZ] Shandong Univ, Sch Phys & Microelect, Jinan 250100, Peoples R China. [publication_type] => J [begin_page] => 1368 [author_en] => Zhang, QZ; Liu, JQ; Yin, XY; Zhang, JZ [volume] => 25 [get_data] => 2018-08-29 [publisher] => HIGHER EDUCATION PRESS [keyword_en] => photochromic liquid crystalline dendrimer; photoelectric informational; functional material; photoisomerization; photo back-isomerization;; thermal back-isomerization; activation energy [format_publication_cn] => 112be9cb2f30361719ed2bc572ba4a22192440272 [keyword_plu] => 4-HEXYLOXYAZOBENZENE MESOGENIC GROUPS; SIDE-GROUPS; AZOBENZENE [publication_iso] => Chem. J. Chin. Univ.-Chin. [format_title_en] => 5569daaa334fecc01d9e0821bb3792dc1496072326 [publisher_city] => BEIJING [hx_id] => 2377,2371 [reference_No] => 12 [email] => qzzhang@sdu.edu.cn [cite_awos] => 12 [wos_No] => WOS:000222906300045 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [check_180] => 0 [publisher_ad] => SHATANHOU ST 55, BEIJING 100009, PEOPLES R CHINA [title_en] => Photoresponse behaviour of a new photochromic liquid crystalline carbosilane dendrimer of the first generation containing hexyloxyazobenzene moieties groups in its periphery [format_publication_en] => 4eabdd9afe3fe566a165b6e1c3e0dbbd-130083487 [jl_language] => chinese [jl_publication_cn] => 高等学校化学学报 [jl_article_dt] => 期刊论文 [jl_publication_en] => chemicaljournalofchineseuniversitieschinese [jl_country] => 纳米比亚,瑞士,印度,苏里南,中国,西班牙,波兰,秘鲁 [jl_keyword_en] => activationenergy,photochromicliquidcrystallinedendrimer,functionalmaterial,photobackisomerization,thermalbackisomerization,photoisomerization,photoelectricinformational [jl_keyword_cn] => 活化能,光回复异构,热回复异构,光电信息功能材料,光致变色液晶树状物,光异构化 [jl_publisher] => highereducationpress [company_id] => 133,5,43,169 [sys_subject_sort] => 0,0,0,0 [college_parent_id] => 133,5,43,169 [company_test] => Array,Array,Array,Array [author_id] => [author_test] => Array ( [0] => Array ( [sure] => 0 [irmagnum] => 0 [u_index] => 2 [name] => 刘建强 [irtag] => 7 [t_index] => 0 [person_id] => 22294 ) ) [sys_author_id_arr] => 22294刘建强 [cscd_No] => CSCD:1811302 [jl_publication_cn_publication_en] => 高等学校化学学报,chemicaljournalofchineseuniversitieschinese [jl_keyword_cn_keyword_en] => photochromicliquidcrystallinedendrimer,photoelectricinformational,活化能,光回复异构,热回复异构,functionalmaterial,光电信息功能材料,photobackisomerization,thermalbackisomerization,光致变色液晶树状物,photoisomerization,activationenergy,光异构化 [sys_author_id] => [format_cscd_No] => bab9540df83f55709c9dbb61bf852bf3 [format_title_en_publication_en_pub_year] => 359c16bdedb9948182366ca4a537d048 [format_wos_No] => 2c24bd39e60fa4063a28b86610e0c12b [format_title_en_issn_pub_year] => 488ea69a5d29d357ad292da2595fd4f9 [jl_pub_year] => 2004 [jl_author_test] => upersonid22294,usureu0,uuindex2,utindex0,uirtag7,uirmagnum0,unameuu5218u5efau5f3a [sys_author_jg_last_arr] => 中国 [jl_company_test] => unameuu5316u5b66u4e0eu5316u5de5u5b66u9662,uorgidu5,uparentidu43,unameuu7269u7406u5b66u9662,uircu0,uorgidu43,ulevelu1,uparentidu5 [sys_author_in_last_arr] => peoplesrchina [id] => Fg9KvmUBFjIhTVEbYAQa [tags] => 0 ) [5] => Array ( [batch2] => 1,2 [batch] => 3250,3249,3241,3254,3252 [tag] => 0 [CSSN] => 22-1131/O6 [keyword_cn] => 水热合成;Co3O4;强迫水解;立方体 [article_id] => 106793,620490,329804,683767,220096 [abstract_cn] => 研究了原料浓度、溶液酸度、水热反应温度和时间以及陈化方式等条件对立方状 Co3O4 形貌和粒度的影响 ,采用 XRD,TEM和 IR等手段跟踪反应过程 ,并表征产物 ,对水热过程中的相转变和尖晶石相 Co3O4的水热形成机理进行了初步探讨 [author_jg] => [张卫民] 山东大学化学与化工学院, 济南, 山东 250100, 中国.@@@[宋新宇] 山东大学化学与化工学院, 济南, 山东 250100, 中国.@@@[李大枝] 山东大学化学与化工学院, 济南, 山东 250100, 中国.@@@[俞海云] 山东大学化学与化工学院, 济南, 山东 250100, 中国.@@@[孙思修] 山东大学化学与化工学院, 济南, 山东 250100, 中国 [format_title_cn_publication_cn_pub_year] => 1138746bf792775d38b55c581f9b7594-1774876360 [hints] => 39 [issue] => 5 [sys_level_num] => 2_3 [sys_jg_type] => 10,5 [format_issn_issue_page_pub_year] => 89b6eefa3d00bcf4f461fa6cd09b8d97-1070711195 [source_type] => 351 [pub_year] => 2004 [pub_date] => MAY [pages] => 5 [from_id] => 75,78,73,80,85 [author_cn] => 张卫民,宋新宇,李大枝,俞海云,孙思修 [issn] => 0251-0790 [uri] => http://kns.cnki.net/kns/detail/detail.aspx?FileName=GDXH200405001&DbName=CJFQ2004 [publication_cn] => 高等学校化学学报 [title_cn] => 水热条件对立方状Co_3O_4形貌的影响 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => 1721d6590ab23cb56e4a00e1e38ca729327993159 [page] => 797-801 [hb_type] => 2 [article_dt] => Article [hb_batch] => title_cn_publication_cn_pub_year_2_3 [publication_en] => CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE [cite_wos] => 14 [fund_No] => 国家自然科学基金 [check_3Y] => 7 [language] => Chinese [delivery_No] => 822DF [format_title] => dfc01a4b6a09d0102ef7f636c7a5df49425992570 [cauthor_ad] => [Sun, SX]Shandong Univ, Sch Chem & Chem Engn, Jinan 250100, Peoples R China. [author_fn] => Zhang, WM; Song, XY; Li, DZ; Yu, HY; Sun, SX [reference] => Baydi M.E., 1994, J SOLID STATE CHEM, V109, P281, DOI DOI@@@10.1006/JSSC.1994.1105@@@BOGGIO R, 1985, J APPL ELECTROCHEM, V15, P335, DOI 10.1007/BF00615986@@@@@@Feng J, 2003, CHEM MATER, V15, P2829, DOI 10.1021/cm020940d@@@IWAKURA C, 1981, ELECTROCHIM ACTA, V26, P1319, DOI@@@10.1016/0013-4686(81)85116-X@@@MARKOV L, 1990, SOLID STATE IONICS, V39, P187, DOI@@@10.1016/0167-2738(90)90397-A@@@@@@PIROVANO C, 1984, J ELECTROANAL CHEM, V180, P171, DOI@@@10.1016/0368-1874(84)83578-9@@@@@@RASIYAH P, 1983, J ELECTROCHEM SOC, V130, P365, DOI 10.1149/1.2119712@@@Sampanthar JT, 2001, CHEM MATER, V13, P4722, DOI 10.1021/cm010553o@@@SINGH RN, 1990, J ELECTROCHEM SOC, V137, P1408, DOI 10.1149/1.2086682@@@Spinolo G, 1997, J ELECTROANAL CHEM, V423, P49, DOI@@@10.1016/S0022-0728(96)04841-3@@@SUGIMOTO T, 1979, J INORG NUCL CHEM, V41, P165, DOI@@@10.1016/0022-1902(79)80506-0@@@Takada S, 2001, NANO LETT, V1, P379, DOI 10.1021/nl015538x@@@TRASATTI S, 1984, ELECTROCHIM ACTA, V29, P1503, DOI@@@10.1016/0013-4686(84)85004-5@@@Verelst M, 1999, CHEM MATER, V11, P2702, DOI 10.1021/cm991003h@@@Xu R, 2003, CHEM MATER, V15, P2040, DOI 10.1021/cm021732o@@@Xu R, 2003, J PHYS CHEM B, V107, P926, DOI 10.1021/jp021094x@@@Xu ZP, 2000, CHEM MATER, V12, P3459, DOI 10.1021/cm000371e@@@Xu ZP, 2000, INT J INORG MATER, V2, P187, DOI@@@10.1016/S1466-6049(00)00020-9@@@Xu ZP, 1999, CHEM MATER, V11, P67, DOI 10.1021/cm980420b@@@[张卫民 Zhang Weimin], 2003, [高等学校化学学报, Chemical Journal of Chinese@@@Universities], V24, P2151@@@Zhang YC, 1997, J ELECTROCHEM SOC, V144, P4345, DOI 10.1149/1.1838190@@@张卫民, 2000, 无机化学学报, V16, P873@@@陈代荣, 1998, 高等学校化学学报, V19, P1 [publication_29] => CHEM J CHINESE U [end_page] => 801 [abstract_en] => As a continued part of our research endeavor in the synthesis of Co3O4 with different morphologies by hydrothermal treatment followed by decomposition, the effects of hydrothermal synthetic conditions, such as the starting concentration of Co(NO3)(2) solution, pH of the suspension, hydrothermal temperature, holding time and the stocking mode, on the Co3O4 cubes were reported in this paper. The results of XRD, TEM and IR were used to monitor the procedures of hydrothermal treatment. The cube size increased with the increasing of the acidity of solution, but decreased at a higher temperature. Prolonging the treating time helped the growth of the Co3O4 cubes. Moreover, the phase transformation and mechanism of Co3O4 spinel formation during the hydrothermal synthetic process were also discussed. [author_in] => [Zhang, WM; Song, XY; Li, DZ; Yu, HY; Sun, SX]Shandong Univ, Sch Chem & Chem Engn, Jinan 250100, Peoples R China. [publication_type] => J [begin_page] => 797 [author_en] => Zhang, WM; Song, XY; Li, DZ; Yu, HY; Sun, SX [volume] => 25 [get_data] => 2018-08-29 [publisher] => HIGHER EDUCATION PRESS [keyword_en] => hydrothermal synthesis; cobalt oxide; forced hydrolysis; cube [format_publication_cn] => 112be9cb2f30361719ed2bc572ba4a22192440272 [keyword_plu] => OXYGEN EVOLUTION; ANODIC EVOLUTION; CO3O4 NANOCUBES; DECOMPOSITION; ELECTRODES [publication_iso] => Chem. J. Chin. Univ.-Chin. [format_title_en] => 3b368085a46205276a4522c5b0444ed7-521901216 [publisher_city] => BEIJING [hx_id] => 2377,2371 [reference_No] => 23 [email] => ssx@sdu.edu.cn [cite_awos] => 16 [wos_No] => WOS:000221514700002 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [check_180] => 0 [publisher_ad] => SHATANHOU ST 55, BEIJING 100009, PEOPLES R CHINA [title_en] => Effects of hydrothermal synthetic conditions onCo(3)O(4) cubes morphologies [format_publication_en] => 4eabdd9afe3fe566a165b6e1c3e0dbbd-130083487 [jl_language] => chinese [jl_publication_cn] => 高等学校化学学报 [jl_article_dt] => 期刊论文 [jl_publication_en] => chemicaljournalofchineseuniversitieschinese [jl_country] => 中国,中国 [jl_keyword_en] => forcedhydrolysis,hydrothermalsynthesis,cube,cobaltoxide [jl_keyword_cn] => 立方体,水热合成,co3o4,强迫水解 [jl_publisher] => highereducationpress [author_id] => 23399 [author_test] => Array ( [0] => Array ( [sure] => 1 [irmagnum] => 0 [u_index] => 0 [name] => 宋新宇 [sys_author_id] => Array ( [0] => 23399 ) [irtag] => 0 [t_index] => 0 [person_id] => 23399 ) ) [company_id] => 43,169 [sys_subject_sort] => 0,0 [college_parent_id] => 43,169 [company_test] => Array,Array [sys_author_id_arr] => 23399宋新宇 [cscd_No] => CSCD:1808877 [jl_publication_cn_publication_en] => chemicaljournalofchineseuniversitieschinese,高等学校化学学报 [jl_keyword_cn_keyword_en] => hydrothermalsynthesis,cube,水热合成,cobaltoxide,forcedhydrolysis,co3o4,强迫水解,立方体 [sys_author_id] => 23399 [format_cscd_No] => 47ac56e933e8a12261a5c33f76367b1a-20865389 [format_title_en_publication_en_pub_year] => 111e6e9d51d691a2c4ee33e9e1a2456a1870859094 [format_wos_No] => 38188f5e302d71f5a915d197eda33e481775971253 [format_title_en_issn_pub_year] => 7c31b08dcc56a965243c2611b8e5fb0f487915377 [id] => VQ1GvmUBFjIhTVEbF9Bq [tags] => 0 ) [6] => Array ( [batch2] => 1,2 [batch] => 3250,3249,3252,3254,3241 [tag] => 0 [abstract_cn] => 自从1970年报道第一个波导光栅之后[1],人们又很快发现了它在集成光学上的应用潜力.目前,对廉价、可靠和高效的集成光学器件的需求使研究者们开始注意聚合物材料.因此有关各种聚合物型的波导光栅的制备和光学性能的研究备受注意[2].现在,紫外光漂白[3]、激光切除[4]和光致二色型[5]等一系列方法已经被用于聚合物波导光栅的制备,同时,聚合物波导光栅的光控光开关[6]、光子禁带效应[7]和谐振光栅[8]等各种光学性质也有广泛的研究. [keyword_cn] => 双光子聚合技术;聚合物;光栅光波导;耦合光栅;集成光学器件; [clc] => TN256 [author_jg] => [于晓强] 山东大学, 晶体材料国家重点实验室,中国.@@@[张献] 山东大学, 晶体材料国家重点实验室,中国.@@@[许贵宝] 山东大学, 晶体材料国家重点实验室,中国.@@@[赵华平] 山东大学, 晶体材料国家重点实验室,中国.@@@[何畏] 山东大学, 晶体材料国家重点实验室,中国.@@@[邵宗书] 山东大学, 晶体材料国家重点实验室,中国.@@@[蒋民华] 山东大学, 晶体材料国家重点实验室,中国.@@@[孙渝明] 山东大学信息科学与工程学院, 济南, 山东 250100, 中国.@@@[刘恩泉] 山东大学信息科学与工程学院, 济南, 山东 250100, 中国 [format_title_cn_publication_cn_pub_year] => 2a7a1201256a317ce54aecacdebc25a9543788397 [from_id] => 75,78,73,80,85 [issue] => 10 [sys_level_num] => 2_1 [sys_jg_type] => 9,10,5 [source_type] => 351 [pub_year] => 2004 [article_id] => 329292,682636,202451,106796,539176 [pages] => 3 [hints] => 88 [author_cn] => 于晓强 [1];张献 [1];许贵宝 [1];赵华平 [1];何畏 [1];邵宗书 [1];蒋民华 [1];孙渝明 [2];刘恩泉 [2] [issn] => 0251-0790 [uri] => http://lib.cqvip.com/qk/90335X/200410/10524264.html [publication_cn] => 高等学校化学学报 [title_cn] => 利用双光子聚合技术制备的聚合物型光栅光波导和耦合光栅 [CSSN] => 22-1131/06 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => 561c8dfd77457060bd31f4bd397ae947-863247876 [hb_type] => 2 [hb_batch] => title_cn_publication_cn_pub_year_2_3 [publication_en] => CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE [cite_wos] => 3 [fund_No] => 国家重点基础研究项目; 国家自然科学基金; NSFC/RGC资助 [check_3Y] => 0 [language] => Chinese [delivery_No] => 864IU [format_title] => 79bfe02e297a7dc333d5cf2e2094f9fe742814449 [cauthor_ad] => [Yu, XQ]Shandong Univ, Natl Key Lab Crystal Mat, Jinan 250100, Peoples R China. [author_fn] => Yu, XQ; Zhang, X; Xu, GB; Zhao, HP; He, W; Shao, ZS; Jiang, MH; Sun, YM; Liu, EQ [reference] => AhnS, 2001, Commun, V194, P309@@@Bader M, 1998, Mater, V9, P334@@@Bader MA, 2001, SYNTHETIC MET, V124, P141, DOI@@@10.1016/S0379-6779(01)00452-0@@@Brian H C, 1999, NATURE, V398, P51@@@DakssM, 1970, Appl. Phys. Lett, V16, P523@@@Donvala, 2001, Synth. Met, V124, P19@@@Klein-Wiele JH, 2002, SYNTHETIC MET, V127, P53, DOI@@@10.1016/S0379-6779(01)00590-2@@@Lee JM, 2004, OPT COMMUN, V232, P139, DOI 10.1016/joptcom.2003.12.046@@@Ren Y, 2002, J MATER CHEM, V12, P3431, DOI 10.1039/b206578a@@@Toussaere E, 1999, Mater, V12, P357@@@于晓强, 2000, 高等学校化学学报, V21, P1953 [publication_29] => CHEM J CHINESE U [end_page] => 1933 [abstract_en] => Two ternary materials systems, which comprise two-photon initiators, oligomer and poly(methyl methacrylate), were prepared. A polymeric waveguide film was manufactured by spinning the materials on ITO, and the two-photon initiated photopolymerization(TPIP) was carried out successfully in the waveguide film. Consequently, an approach using TPIP is demonstrated for fabrication of grating in a thin polymeric film possessing waveguide properties. The results show that the resulted grating can manipulate and couple light. [researcherID] => Xu, Guibao/F-3461-2010 [author_in] => [Yu, XQ; Zhang, X; Xu, GB; Zhao, HP; He, W; Shao, ZS; Jiang, MH; Sun, YM; Liu, EQ]Shandong Univ, Natl Key Lab Crystal Mat, Jinan 250100, Peoples R China.@@@[Yu, XQ; Zhang, X; Xu, GB; Zhao, HP; He, W; Shao, ZS; Jiang, MH; Sun, YM; Liu, EQ] Shandong Univ, Coll Opt Informat Engn, Jinan 250100, Peoples R China. [publication_type] => J [begin_page] => 1931 [article_dt] => Letter [author_en] => Yu, XQ; Zhang, X; Xu, GB; Zhao, HP; He, W; Shao, ZS; Jiang, MH; Sun, YM; Liu, EQ [volume] => 25 [get_data] => 2018-08-29 [publisher] => HIGHER EDUCATION PRESS [keyword_en] => two-photon initiated photopolymerization; grating waveguide; coupling; grating [format_publication_cn] => 112be9cb2f30361719ed2bc572ba4a22192440272 [publication_iso] => Chem. J. Chin. Univ.-Chin. [format_title_en] => 3d220bc91853071f76871360b22d894e-463307761 [publisher_city] => BEIJING [pub_date] => OCT 10 [hx_id] => 2377,2371 [reference_No] => 11 [email] => yuxq@icm.sdu.edu.cn [cite_awos] => 3 [wos_No] => WOS:000224628000039 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [check_180] => 0 [publisher_ad] => SHATANHOU ST 55, BEIJING 100009, PEOPLES R CHINA [title_en] => Fabrication of grating waveguide and coupling grating using two-photon initiated photopolymerization [format_publication_en] => 4eabdd9afe3fe566a165b6e1c3e0dbbd-130083487 [jl_language] => chinese [jl_publication_cn] => 高等学校化学学报 [jl_article_dt] => letter [jl_publication_en] => chemicaljournalofchineseuniversitieschinese [jl_country] => 中国,中国 [jl_keyword_en] => twophotoninitiatedphotopolymerization,grating,gratingwaveguide,coupling [jl_keyword_cn] => ,耦合光栅,双光子聚合技术,集成光学器件,聚合物,光栅光波导 [jl_clc] => tn256 [jl_publisher] => highereducationpress [company_id] => 24,151,15,142 [sys_subject_sort] => 0,0,0,0 [college_parent_id] => 24,151,15,142 [company_test] => Array,Array,Array,Array [author_id] => 25201 [author_test] => Array ( [0] => Array ( [sure] => 0 [irmagnum] => 0 [u_index] => 0 [name] => 于晓强 [irtag] => 7 [t_index] => 0 [person_id] => 25201 ) ) [sys_author_id_arr] => 25201于晓强 [cscd_No] => CSCD:1810920 [jl_publication_cn_publication_en] => chemicaljournalofchineseuniversitieschinese,高等学校化学学报 [jl_keyword_cn_keyword_en] => coupling,光栅光波导,集成光学器件,twophotoninitiatedphotopolymerization,耦合光栅,双光子聚合技术,grating,聚合物,gratingwaveguide [sys_author_id] => 25201 [format_cscd_No] => 5f225d188b7f1cd0bc7a3c960f88a0b2-456879075 [format_title_en_publication_en_pub_year] => 116ccf962eb2874009e8c080b1d50b491712912615 [format_wos_No] => d1c3b4b21aba4ba3e5742a78fe2c13e71588202320 [format_title_en_issn_pub_year] => e53c9984c2bf122b94fb06898d1c2c311994978570 [id] => bgkvvmUBFjIhTVEbXF2q [tags] => 0 ) [7] => Array ( [batch2] => 1,2 [batch] => 3250,3249,3252,3254,3241 [tag] => 0 [abstract_cn] => 用发散法合成了周边含12个己氧基偶氮苯介晶基元(M3)端基的树状碳硅烷(D1), 并用元素分析、氢谱、激光质谱、红外光谱、紫外-可见光谱、偏光显微镜、 DSC和WAXD对产物进行表征. 结果表明, D1为向列相, 与M3相同, 树状物相态由介晶基元相态决定, D1的液晶态相行为: K92N126I124N78K, D1熔点比M3降低了24~30 ℃, D1清亮点比M3提高了6~8 ℃, D1液晶态温区比M3加宽30~38 ℃, 在树状物中观察到S=+2的高强向错. [keyword_cn] => 端基;己氧基偶氮苯介晶基元;树状化合物;碳硅烷;液晶;合成;向列相; [clc] => O634.41 TN104.3 [author_jg] => [张其震] 山东大学化学化工学院, 济南, 山东 250100, 中国.@@@[刘建强] 山东大学化学化工学院, 济南, 山东 250100, 中国.@@@[殷晓颖] 山东大学化学化工学院, 济南, 山东 250100, 中国.@@@[张静智] 山东大学化学化工学院, 济南, 山东 250100, 中国.@@@[李光] 中国科学院长春应用化学研究所, 长春, 吉林 130022, 中国.@@@[赵晓光] 中国科学院长春应用化学研究所, 长春, 吉林 130022, 中国.@@@[季怡萍] 中国科学院长春应用化学研究所, 长春, 吉林 130022, 中国 [format_title_cn_publication_cn_pub_year] => 11072b743637b645498c3258229ef76c [from_id] => 75,78,73,80,85 [issue] => 10 [sys_level_num] => 2_1 [sys_jg_type] => 0,5 [source_type] => 351 [pub_year] => 2003 [article_id] => 106792,202742,330911,683957,597475 [pages] => 5 [hints] => 21 [author_cn] => 张其震[1];刘建强[1];殷晓颖[1];张静智[1];李光[2];赵晓光[2];季怡萍[2] [issn] => 0251-0790 [uri] => http://lib.cqvip.com/qk/90335X/200310/8450014.html [publication_cn] => 高等学校化学学报 [title_cn] => 端基含12个己氧基偶氮苯介晶基元的树状碳硅烷液晶的合成 [CSSN] => 22-1131/06 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => 2f934f6f78055144812c4b007780fde9 [hb_type] => 2 [hb_batch] => title_cn_publication_cn_pub_year_2_3 [publication_en] => CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE [cite_wos] => 12 [fund_No] => 国家自然科学基金(批准号:29874020,59573029)资助 [check_3Y] => 1 [language] => Chinese [delivery_No] => 735VJ [format_title] => 1c804f52d50fc94b3ee267bc38c6dfb1-1287754529 [cauthor_ad] => [Zhang, QZ]Shandong Univ, Sch Chem & Chem Engn, Jinan 250100, Peoples R China. [author_fn] => Zhang, QZ; Liu, JQ; Yin, XY; Zhang, JZ; Li, G; Zhao, XG; Ji, YP [reference] => FICHTE B, 1997, ORGANIKM, P784@@@Fischwick M, 1970, J. Organomet. Chem., V25, P69@@@KANG SK, 1985, SYNTHESIS-STUTTGART, P1161@@@Karstedt B D, 1973, US Patent, 3775452@@@LECOIN D, 1975, MOL CRYST LIQ CRYST, V31, P233, DOI@@@10.1080/15421407508082875@@@Lorenz K, 1996, ADV MATER, V8, P414, DOI 10.1002/adma.19960080509@@@NEHRING J, 1972, J CHEM SOC FARAD T 2, V68, P1, DOI 10.1039/f29726800001@@@PERCEC V, 1995, J AM CHEM SOC, V117, P11441, DOI 10.1021/ja00151a008@@@Ponomarenko SA, 1996, LIQ CRYST, V21, P1, DOI 10.1080/02678299608033789@@@SONG WH, 1993, MAKROMOL CHEM-RAPID, V14, P605@@@WOOLEY KL, 1993, MACROMOLECULES, V26, P1514, DOI 10.1021/ma00059a006@@@张其震, 1996, 高等学校化学学报, V17, P1804@@@张其震, 1998, 高等学校化学学报, V19, P1175@@@张其震, 1998, 高等学校化学学报, V19, P827@@@张其震, 1997, 高等学校化学学报, V18, P158 [publication_29] => CHEM J CHINESE U [end_page] => 1891 [abstract_en] => The divergent synthesis of a new carbosilane liquid-crystalline(LC) dendrimer(D1) was described. Twelve 4-hexyloxyazobenzene groups (M3) were used as mesogenic fragments and-attached to its periphery. Structure and properties of D1 were characterized by means of elemental analysis, H-1 NMR, IR, UV, MALDI-TOF-MS, polarizing optical micrograph, DSC and WAXD. D1 is a nematic liquid crystal, which is the same as M3. The mesomorphic behaviour of the dendrimer depends on that of the mesogenic units. Phase behavior of D1 is K92N126I124N78K. m. p. of Ell is 24-30 degreesC lower than that of M3, its clearing temperature is 13-8 degreesC higher than that of M3 and its mesophase region is 30 similar to 38 degreesC wider than that of M3. The clearing enthalpy of D1 accords with the value that is commonly found for n-i phase transition in LC and LC polymers. This may be due to the deformation of branched dendrimer D1 which can be change to fit into the anisotropic LC phase structure. Eight extinguished brushes emanating from a stationary point are observed, corresponding to the high-strength disclination of S = + 2 of dendrimer. [author_in] => [Zhang, QZ; Liu, JQ; Yin, XY; Zhang, JZ; Li, G; Zhao, XG; Ji, YP]Shandong Univ, Sch Chem & Chem Engn, Jinan 250100, Peoples R China.@@@[Zhang, QZ; Liu, JQ; Yin, XY; Zhang, JZ; Li, G; Zhao, XG; Ji, YP] Chinese Acad Sci, Changchun Inst Appl Chem, Changchun 130022, Peoples R China. [publication_type] => J [begin_page] => 1887 [article_dt] => Article [author_en] => Zhang, QZ; Liu, JQ; Yin, XY; Zhang, JZ; Li, G; Zhao, XG; Ji, YP [volume] => 24 [get_data] => 2018-08-29 [publisher] => HIGHER EDUCATION PRESS [keyword_en] => dendrimer; liquid crystal; nematic phase; high-strength disclination;; carbosilane [format_publication_cn] => 112be9cb2f30361719ed2bc572ba4a22192440272 [keyword_plu] => SCHLIEREN TEXTURE; POLYMER [publication_iso] => Chem. J. Chin. Univ.-Chin. [format_title_en] => 11087b205dd42db11e43aac3a541dbfe89739025 [publisher_city] => BEIJING [pub_date] => OCT 10 [hx_id] => 2377,2371 [reference_No] => 15 [email] => qzzhang@sdu.edu.cn [cite_awos] => 12 [wos_No] => WOS:000186135000041 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [check_180] => 0 [publisher_ad] => SHATANHOU ST 55, BEIJING 100009, PEOPLES R CHINA [title_en] => Carbosilane liquid crystalline dendrimer containing twelve 4-hexyloxyazobenzene mesogenic groups [format_publication_en] => 4eabdd9afe3fe566a165b6e1c3e0dbbd-130083487 [jl_language] => chinese [jl_publication_cn] => 高等学校化学学报 [jl_article_dt] => 期刊论文 [jl_publication_en] => chemicaljournalofchineseuniversitieschinese [jl_country] => 纳米比亚,瑞士,印度,苏里南,中国,西班牙,波兰,秘鲁 [jl_keyword_en] => highstrengthdisclination,liquidcrystal,nematicphase,dendrimer,carbosilane [jl_keyword_cn] => 碳硅烷,液晶,树状化合物,合成,己氧基偶氮苯介晶基元,端基,向列相 [jl_clc] => o63441tn1043 [jl_publisher] => highereducationpress [company_id] => 43,169 [sys_subject_sort] => 0,0 [college_parent_id] => 43,169 [company_test] => Array,Array [author_id] => [author_test] => Array ( [0] => Array ( [sure] => 0 [irmagnum] => 0 [u_index] => 0 [name] => 刘建强 [irtag] => 7 [t_index] => 0 [person_id] => 22294 ) ) [sys_author_id_arr] => [cscd_No] => CSCD:1238505 [jl_publication_cn_publication_en] => 高等学校化学学报,chemicaljournalofchineseuniversitieschinese [jl_keyword_cn_keyword_en] => 碳硅烷,液晶,highstrengthdisclination,树状化合物,合成,己氧基偶氮苯介晶基元,端基,carbosilane,向列相,nematicphase,liquidcrystal,dendrimer [sys_author_id] => [format_cscd_No] => d65bb001c4a3731bd09d3a29a1d5a78e [format_title_en_publication_en_pub_year] => 62fbc7489696565d7053e7184affd085 [format_wos_No] => db29967c92daca699548265b0a2e218a [format_title_en_issn_pub_year] => 32dd377d8536fcc2b6ebc0814f858a2b [jl_pub_year] => 2003 [jl_author_test] => upersonid22294,usureu0,uuindex0,utindex0,uirtag7,uirmagnum0,unameuu5218u5efau5f3a [sys_author_jg_last_arr] => 中国 [jl_company_test] => uircu0,unameuu5316u5b66u4e0eu5316u5de5u5b66u9662,uparentidu43,uorgidu43,ulevelu1 [sys_author_in_last_arr] => peoplesrchina [id] => agkvvmUBFjIhTVEbXF2q [tags] => 0 ) [8] => Array ( [batch2] => 1,2,6 [batch] => 3249,3250,3252,3254,3246,3243,3241 [tag] => 0 [CSSN] => 22-1131/O6 [keyword_cn] => 树状化合物;液晶;向列相;碳硅烷 [article_id] => 202750,597499,681930,330988,399549,16032,492271 [abstract_cn] => 用发散法合成周边含36个己氧基偶氮苯介晶基元(M3)端基的新的二代树状碳硅烷液晶(D2),并用元素分析、氢谱、激光质谱、红外光谱、紫外-可见光谱、偏光显微镜,DSC和WAXD法进行表征。D2为向列相,与M3相同.D2液晶态相行为是K90N105I1l3N75K,D2熔点比M3降低26~33℃,D2清亮点比M3降低3~15℃,D2液晶态温区比M3加宽11~30℃。D2和一代树状物D1的相态由介晶基元相态决定。D2熔点比D1降低2~3℃。D2清亮点比D1降低11~21℃,D2液晶态温区比D1减少8~19℃。 [author_jg] => [张其震,刘建强,殷晓颖,张静智,赵晓光,李光,季怡萍]山东大学化学化工学院,山东大学化学化工学院,山东大学化学化工学院,山东大学化学化工学院,中国科学院长春应用化学研究所,中国科学院长春应用化学研究所,中国科学院长春应用化学研究所 济南 250100,济南 250100,济南 250100,济南 250100,长春 130022,长春 130022,长春 130022 [format_title_cn_publication_cn_pub_year] => f06096bfbbe825e728e64fda74fb60362054154770 [hints] => 21 [issue] => 9 [sys_level_num] => 2_3 [sys_jg_type] => 11,5 [format_issn_issue_page_pub_year] => 82bdb9b78ad7ab7a66542af558e3605c640676069 [source_type] => 351 [pub_year] => 2003 [pub_date] => SEP 10 [pages] => 4 [from_id] => 76,75,74,73,80,85,78 [author_cn] => 张其震,刘建强,殷晓颖,张静智,赵晓光,李光,季怡萍 [issn] => 0251-0790 [uri] => http://kns.cnki.net/kns/detail/detail.aspx?FileName=GDXH200309042&DbName=CJFQ2003 [publication_cn] => 高等学校化学学报 [title_cn] => 二代树状碳硅烷液晶研究——端基含36个己氧基偶氮苯介晶基元 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => 1631e363dc1b425e80253b0f6de26b60-948586974 [page] => 1704-1707 [hb_type] => 2 [article_dt] => Article [hb_batch] => title_cn_publication_cn_pub_year_2_3 [format_title_en] => 8a25aa5c57d3c6dc3d354a4c5263798f946299350 [format_title] => 0f2dd1a3e5d2e74518ae705cb4b1a628-1178165229 [hx_id] => 2376,2377,2378,2371 [format_publication_cn] => 112be9cb2f30361719ed2bc572ba4a22192440272 [format_publication_en] => 4eabdd9afe3fe566a165b6e1c3e0dbbd-130083487 [jl_publication_cn] => 高等学校化学学报 [jl_article_dt] => 期刊论文 [jl_keyword_cn] => 碳硅烷,树状化合物,向列相,液晶 [author_in] => [Zhang, Q.-Z] School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China@@@[ Liu, J.-Q] School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China@@@[ Yin, X.-Y] School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China@@@[ Zhang, J.-Z] School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China@@@[ Zhao, X.-G] Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China@@@[ Li, G] Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China@@@[ Ji, Y.-P] Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China [company_id] => 0,43,169 [sys_subject_sort] => 0,0 [college_parent_id] => 43,169 [company_test] => Array,Array [author_id] => [author_test] => Array ( ) [sys_author_id_arr] => [jl_publication_cn_publication_en] => 高等学校化学学报 [jl_keyword_cn_keyword_en] => 碳硅烷,液晶,树状化合物,向列相 [fund_No] => 国家自然科学基金(批准号:29874020,59573029); 中国科学院高分子化学和物理国家重点实验室基金资助 [index_keyword] => Carbosilanes; Divergent synthesis; Elementary analysis; Liquid crystalline; Liquid crystalline dendrimers; Nematic phase; Optical micrographs; Structure and properties; Liquid crystals; Melting point; Dendrimers [cauthor_ad] => [Zhang, QZ]Shandong Univ, Sch Chem & Chem Engn, Jinan 250100, Peoples R China. [author_fn] => Zhang, QZ; Liu, JQ; Yin, XY; Zhang, JZ; Zhao, XG; Li, G; Ji, YP [format_title_en_issn_pub_year] => 8d06ca39520e1e796f84946a08932ca91491181425 [format_scopus_No] => 278e3d85b82c92214ffe0137df734f68-1304874173 [publication_29] => CHEM J CHINESE U [begin_page] => 1704 [author_en] => Zhang, QZ; Liu, JQ; Yin, XY; Zhang, JZ; Zhao, XG; Li, G; Ji, YP [format_cscd_No] => 8a8d279d475492454642f37faaf39d69-1074385921 [get_data] => 2018-08-29 [publication_iso] => Chem. J. Chin. Univ.-Chin. [publisher_city] => BEIJING [cite_cscd] => 11 [classification_No] => 931.2 Physical Properties of Gases, Liquids and Solids [uncontrolled_terms] => Carbosilanes - Divergent synthesis - Elementary analysis - Liquid crystalline - Liquid crystalline dendrimers - Nematic phase - Optical micrographs - Structure and properties [publication_info] => 0251-0790(2003)24:9<1704:EDSZTG>2.0.TX;2-# [controlled_terms] => Liquid crystals - Melting point [format_ei_No] => 4df59ef89a14ece0cf1fdd37ce79b7361212479469 [email] => qzzhang@sdu.edu.cn [reference_No] => 8 [cite_awos] => 13 [wos_No] => WOS:000186134800041 [classification_pub] => KTHPD [format_wos_No] => 6c81daefc5f34a57f66756f106658a67231525026 [wos_sub] => Chemistry, Multidisciplinary [publisher_ad] => SHATANHOU ST 55, BEIJING 100009, PEOPLES R CHINA [standard_in] => School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China; Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China [title_en] => Studies on carbosilane liquid crystalline dendrimer of the second generation - Containing 36 4-hexyloxyazobenzene groups in its periphery [cite_wos] => 12 [publication_en] => CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE [check_3Y] => 0 [language] => Chinese [delivery_No] => 735VG [reference] => Lorenz K, 1996, ADV MATER, V8, P414, DOI 10.1002/adma.19960080509@@@PERCEC V, 1995, J AM CHEM SOC, V117, P11441, DOI 10.1021/ja00151a008@@@Ponomarenko SA, 1996, LIQ CRYST, V21, P1, DOI 10.1080/02678299608033789@@@WOOLEY KL, 1993, MACROMOLECULES, V26, P1514, DOI 10.1021/ma00059a006@@@张其震, 1998, 高等学校化学学报, V19, P1175@@@张其震, 1998, 高等学校化学学报, V19, P827@@@张其震, 1997, 高等学校化学学报, V18, P158@@@殷晓颖, 1999, Master Dissertation [cite_wanfang] => 17 [cauthor] => Zhang, Q.-Z.(qzzhang@sdu.edu.cn) [ei_No] => 20134416936733 [datebase] => Scopus [end_page] => 1707 [abstract_en] => The divergent synthesis of a new carbosilane liquid crystalline(LC) dendrimer of the second generation(D2) was described. Thirty-six 4-hexyloxyazobenzene groups (M3) were used as mesogenic fragments and attached to its periphery. The structure and properties of D2 were characterized by elementary analysis, H-1 NMR, MALDI-TOF-MS, IR, UV, polarizing optical micrograph, DSC and WAXD. It is argued that mesophase of nematic type is realized. It is shown that the mesophase type of the dendrimer D2 and D1 essentially depends on the chemical nature of the mesogenic groups and is the same as that of mesogenic unites. The phase behavior of D2 in LC state is K90N105H11N75K. The melting point of D2 decreases 26-33 degreesC than that of M3, the temperature at its clear point decreases 3-15 degreesC than that of M3 and its mesophase region is enlarged 11-30 degreesC than that of M3. The melting point of D2 decreases 2-3 degreesC than that of D1, the temperature at its clear point decreases 11-21 degreesC than that of D1 and its mesophase region decreases 8-19 degreesC than that of D1. [publication_type] => J [volume] => 24 [main_eword] => Dendrimers [numerical_index] => Temperature 2.75e+02K to 2.76e+02K, Temperature 2.76e+02K to 2.88e+02K, Temperature 2.81e+02K to 2.92e+02K, Temperature 2.84e+02K to 2.94e+02K, Temperature 2.84e+02K to 3.03e+02K, Temperature 2.99e+02K to 3.06e+02K [publisher] => HIGHER EDUCATION PRESS [keyword_en] => dendrimer; liquid crystal; nematic phase; carbosilane [format_title_en_publication_en_pub_year] => 62516b6637e8f984c39af75790a752f91893834053 [cite_scopus] => 9 [email_c] => qzzhang@sdu.edu.cn [cscd_No] => CSCD:1214074 [research_area] => Chemistry [check_180] => 0 [scopus_No] => 2-s2.0-12144270950 [jl_language] => chinese [jl_author_test] => upersonid22294,uirtstag0,uuindex2,usureu0,utindex0,uirtag7,uirtypical1,uirinspecttag0,uirauthortype0,unameuu5218u5efau5f3a [jl_publication_en] => chemicaljournalofchineseuniversitieschinese [sys_author_jg_last_arr] => 长春130022 [jl_company_test] => uircu0,unameuu5316u5b66u4e0eu5316u5de5u5b66u9662,uparentidu43,uorgidu43,ulevelu1 [jl_country] => 中国 [jl_keyword_en] => liquidcrystal,nematicphase,dendrimer,carbosilane [sys_author_in_last_arr] => china [jl_publisher] => highereducationpress [sys_author_id] => [id] => pA5HvmUBFjIhTVEbZSLp [tags] => 0 ) [9] => Array ( [batch2] => 1,2 [batch] => 3250,3249,3241,3252 [tag] => 0 [CSSN] => 22-1131/O6 [keyword_cn] => 耗散颗粒动力学模拟;聚合物;表面活性剂;相互作用 [article_id] => 597504,331212,202753,682048 [abstract_cn] => 用耗散颗粒动力学模拟 (DPD)方法研究了聚乙烯吡咯烷酮 (PVP)与 2 -乙基己基琥珀酸酯磺酸钠(AOT)之间的相互作用 .在三维模拟格子中 ,聚合物链均方末端距〈r2 〉随着表面活性剂浓度的增加呈现一种首先减小 ,接着增加 ,然后又减小的趋势 .构型和结构分析表明 ,AOT的加入能够引起聚合物链的二面角分布发生改变 ,这意味着 AOT与 PVP产生了相互作用 .同时表面活性剂 /聚合物体系的聚集形态也可以在 DPD三维模拟格子中直观显现出来 . [author_jg] => [苑世领] 山东大学理论化学研究所, 济南, 山东 250100, 中国.@@@[刘成卜] 山东大学理论化学研究所, 济南, 山东 250100, 中国.@@@[蔡政亭] 山东大学理论化学研究所, 济南, 山东 250100, 中国.@@@[徐桂英] 山东大学, 胶体与界面化学教育部重点实验室, 济南, 山东 250100, 中国 [format_title_cn_publication_cn_pub_year] => e8012f2bd3b4d8547fa92c03fa45574f1984653033 [hints] => 17 [issue] => 6 [sys_level_num] => 2_3 [sys_jg_type] => 0,5 [format_issn_issue_page_pub_year] => 3e4a3fa74b00e6b3e3f6a3344705ab35-577685088 [source_type] => 351 [pub_year] => 2003 [pub_date] => JUN [pages] => 4 [from_id] => 75,73,80,78 [author_cn] => 苑世领,刘成卜,徐桂英,蔡政亭 [issn] => 0251-0790 [uri] => http://kns.cnki.net/kns/detail/detail.aspx?FileName=GDXH200306028&DbName=CJFQ2003 [publication_cn] => 高等学校化学学报 [title_cn] => 聚合物PVP与表面活性剂AOT相互作用的介观模拟 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => 1110f925098e461e0087a356912bd8f1-2081731429 [page] => 1048-1051 [hb_type] => 2 [article_dt] => Article [hb_batch] => title_cn_publication_cn_pub_year_2_3 [publication_en] => CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE [cite_wos] => 11 [fund_No] => 国家自然科学基金(批准号:20173032); 山东大学特聘教授科研启动资金资助 [check_3Y] => 4 [language] => Chinese [delivery_No] => 696AU [format_title] => 551b502459e2c954bcec282bf5d63e221401661692 [cauthor_ad] => [Liu, CB]Shandong Univ, Inst Theoret Chem, Jinan 250100, Peoples R China. [author_fn] => Yuan, SL; Liu, CB; Xu, GY; Cai, ZT [reference] => Brackman J C, 1992, E. Langmuir, V8, P424@@@BRACKMAN JC, 1991, LANGMUIR, V7, P469, DOI 10.1021/la00051a009@@@@@@CHARI K, 1994, J CHEM PHYS, V100, P5294, DOI 10.1063/1.467194@@@Claesson PM, 1998, J PHYS CHEM B, V102, P1270, DOI 10.1021/jp9732165@@@@@@ESPANOL P, 1995, EUROPHYS LETT, V30, P191, DOI@@@10.1209/0295-5075/30/4/001@@@Farinato R S, 1999, Colloid-Polymer Interactions: From Fundamentals to@@@Practice@@@Groot RD, 1999, J CHEM PHYS, V110, P9739, DOI 10.1063/1.478939@@@Groot RD, 1997, J CHEM PHYS, V107, P4423, DOI 10.1063/1.474784@@@Groot RD, 2000, LANGMUIR, V16, P7493, DOI 10.1021/la000010d@@@Hoff E, 2001, LANGMUIR, V17, P28, DOI 10.1021/la001175p@@@HOOGERBRUGGE PJ, 1992, EUROPHYS LETT, V19, P155, DOI@@@10.1209/0295-5075/19/3/001@@@Kwak J C T, 1998, Polymer-surfactant systems@@@Lee LT, 1997, MACROMOLECULES, V30, P6559, DOI 10.1021/ma9704469@@@@@@Mears SJ, 1998, LANGMUIR, V14, P4997, DOI 10.1021/la970745r@@@[钱昌吉 Qian Changji], 2002, [高等学校化学学报, Chemical Journal of Chinese@@@Universities], V23, P2172@@@[苑世领 Yuan Shiling], 2002, [化学学报, Acta Chemical Sinica], V60, P241@@@[苑世领 Yuan Shiling], 2002, [化学学报, Acta Chemical Sinica], V60, P585 [publication_29] => CHEM J CHINESE U [end_page] => 1051 [abstract_en] => The interaction between polyvinylpyrrolidone (PVP) with sodium bis(2-ethylhexyl) sulfosuccinate (AOT) has been studied, by dissipative particles dynamics (DPD.) simulation. With the increase of surfactant concentration, the mean, square end-to-end distance of polymer chain firstly increased, then reduced, and increased again. The analysis of structure shows that the dihedral of polymer chain changed if AOT was added in the polymer system. It indicates that the interaction between polymer and surfactant occurs. And the aggregates of polymer and surfactant can be shown by using the DPD simulated cell. One conclusion is that molecular simulation can be considered as an adjunct to experiments. [author_in] => [Yuan, SL; Liu, CB; Xu, GY; Cai, ZT]Shandong Univ, Inst Theoret Chem, Jinan 250100, Peoples R China.@@@[Yuan, SL; Liu, CB; Xu, GY; Cai, ZT] Shandong Univ, Key Lab Colloid & Interface Chem, Jinan 250100, Peoples R China. [publication_type] => J [begin_page] => 1048 [author_en] => Yuan, SL; Liu, CB; Xu, GY; Cai, ZT [volume] => 24 [get_data] => 2018-08-29 [publisher] => HIGHER EDUCATION PRESS [keyword_en] => dissipative particle dynamics(DPD); polymer; surfactant; interaction [format_publication_cn] => 112be9cb2f30361719ed2bc572ba4a22192440272 [keyword_plu] => DISSIPATIVE PARTICLE DYNAMICS; MICELLE INTERACTION; ANIONIC SURFACTANT; AGGREGATION; VISCOSITY; MIXTURES [publication_iso] => Chem. J. Chin. Univ.-Chin. [format_title_en] => e2150568af3322c2c302a8424c958b242144674892 [publisher_city] => BEIJING [hx_id] => 2377,2371 [reference_No] => 17 [email] => cbliu@sdu.edu.cn [cite_awos] => 21 [wos_No] => WOS:000183863200027 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [check_180] => 0 [publisher_ad] => SHATANHOU ST 55, BEIJING 100009, PEOPLES R CHINA [title_en] => Mesoscopic. simulation on the interaction between polymer PVP and surfactant AOT [format_publication_en] => 4eabdd9afe3fe566a165b6e1c3e0dbbd-130083487 [jl_language] => chinese [jl_publication_cn] => 高等学校化学学报 [jl_article_dt] => 期刊论文 [jl_publication_en] => chemicaljournalofchineseuniversitieschinese [jl_country] => 中国,中国 [jl_keyword_en] => polymer,interaction,dissipativeparticledynamicsdpd,surfactant [jl_keyword_cn] => 耗散颗粒动力学模拟,聚合物,相互作用,表面活性剂 [jl_publisher] => highereducationpress [company_id] => [author_id] => 25263 [author_test] => Array ( [0] => Array ( [sure] => 0 [irmagnum] => 0 [u_index] => 0 [name] => 苑世领 [irtag] => 7 [t_index] => 0 [person_id] => 25263 ) ) [sys_author_id_arr] => [cscd_No] => CSCD:1204570 [jl_publication_cn_publication_en] => chemicaljournalofchineseuniversitieschinese,高等学校化学学报 [jl_keyword_cn_keyword_en] => 耗散颗粒动力学模拟,interaction,surfactant,polymer,表面活性剂,dissipativeparticledynamicsdpd,聚合物,相互作用 [sys_author_id] => 25263 [format_cscd_No] => abbe6c209c486d28724a5cfd21195d44-2094005059 [format_title_en_publication_en_pub_year] => 9f191430b8271d5aed829b1f0a62de0f1079999310 [format_wos_No] => ae414833c8c73d158b0e7a3d5040a01e-727472510 [format_title_en_issn_pub_year] => 1d3c8b05f685ae7679a8702fa0eba8f21239840107 [id] => qQ5HvmUBFjIhTVEbZSLp [tags] => 0 ) [10] => Array ( [batch2] => 1,2 [batch] => 3250,3249,3252,3254,3241 [tag] => 0 [abstract_cn] => 以氨水和氢氧化钾水溶液为沉淀剂, 利用沉淀-固相热解法和中压水热-固相热解法, 制备了不同形貌的Co3O4纳米微粉. 在水热条件下, 得到了立方和六角片状的Co3O4微粉, 采用XRD和TEM等手段跟踪反应过程并表征产物, 在此水热反应体系中影响产物Co3O4形貌的主要因素是pH值和NO-3. [keyword_cn] => 水热-固相热解法;制备;四氧化三钴;纳米微粉;Co2O4;表征;纳米材料; [clc] => O614.812 TB383 [author_jg] => [张卫民] 山东大学化学与化工学院, 济南, 山东 250100, 中国.@@@[孙思修] 山东大学化学与化工学院, 济南, 山东 250100, 中国.@@@[俞海云] 山东大学化学与化工学院, 济南, 山东 250100, 中国.@@@[宋新宇] 山东大学化学与化工学院, 济南, 山东 250100, 中国 [format_title_cn_publication_cn_pub_year] => 695386bcb6b81aed45c148c65f6e491b-1704719489 [from_id] => 75,78,73,80,85 [issue] => 12 [sys_level_num] => 2_1 [sys_jg_type] => 10,5 [source_type] => 351 [pub_year] => 2003 [article_id] => 214038,683888,620458,68603,330647 [pages] => 4 [hints] => 26 [author_cn] => 张卫民;孙思修;俞海云;宋新宇 [issn] => 0251-0790 [uri] => http://lib.cqvip.com/qk/90335X/200312/8780099.html [publication_cn] => 高等学校化学学报 [title_cn] => 水热-固相热解法制备不同形貌的四氧化三钴纳米微粉 [CSSN] => 22-1131/06 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => 2a252fdd3bbf935cc522a181c6d81d5a-1245898567 [hb_type] => 2 [hb_batch] => title_cn_publication_cn_pub_year_2_3 [publication_en] => CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE [cite_wos] => 7 [check_3Y] => 4 [language] => Chinese [delivery_No] => 758PZ [format_title] => 62f6e131e5633b5df29a9a9ba41af0a7-1511546858 [cauthor_ad] => [Sun, SX]Shandong Univ, Sch Chem & Chem Engn, Jinan 250100, Peoples R China. [author_fn] => Zhang, WM; Sun, SX; Yu, HY; Song, XY [reference] => Chiang YM, 1998, J ELECTROCHEM SOC, V145, P887, DOI 10.1149/1.1838362@@@GARAVAGLIA R, 1984, SURF TECHNOL, V23, P41, DOI@@@10.1016/0376-4583(84)90074-8@@@@@@GARAVAGLIA R, 1983, SURF TECHNOL, V19, P197, DOI@@@10.1016/0376-4583(83)90024-9@@@@@@JEYAGOWRY T, 2002, J AM CHEM SOC J, V124, P6668@@@[陈兴泉 Liu Xingquan], 2002, [高等学校化学学报, Chemical Journal of Chinese@@@Universities], V23, P179@@@MARKOV L, 1990, SOLID STATE IONICS, V39, P187, DOI@@@10.1016/0167-2738(90)90397-A@@@@@@PIROVANO C, 1984, J ELECTROANAL CHEM, V180, P171, DOI@@@10.1016/0368-1874(84)83578-9@@@@@@SINGH RN, 1991, J ELECTROANAL CHEM, V314, P241, DOI@@@10.1016/0022-0728(91)85440-Z@@@@@@Spinolo G, 1997, J ELECTROANAL CHEM, V423, P49, DOI@@@10.1016/S0022-0728(96)04841-3@@@史延慧, 1999, 高等学校化学学报, V20, P359@@@蔡少华, 1998, 高等学校化学学报, V19, P691@@@毛雅春, 1998, 高等学校化学学报, V19, P340@@@徐如人, 2001, 无机合成与制备化学, P128@@@曾庆新, 2002, 高等学校化学学报, V23, P2240 [publication_29] => CHEM J CHINESE U [end_page] => 2154 [abstract_en] => The powder of Co3O4 with a cubic structure and well-developed hexagonal platelets were synthesized hydrothermally, followed by decomposition of the precursors in the Co (NO3) (2)-NH3 or KOH system. The results of XRD and TEM which were used to monitor the processes of hydrothermal treatment and calcination showed that NO3- played a key role in the formation of Co3O4 with different morphologies. Co3O4, with a cubic structure could be directly prepared hydrothermally from the system with NO3-. After the NOT was rinsed from the system, a topotactic phenomena was observed. Well-developed hexagonal platelets of beta-Co(OH), were obtained from the hydrothermal system, and then, being baked at 300 degreesC in air, beta-Co(OH)(2) was transformed into Co3O4 with the same morphology as the precursor. [author_in] => [Zhang, WM; Sun, SX; Yu, HY; Song, XY]Shandong Univ, Sch Chem & Chem Engn, Jinan 250100, Peoples R China. [publication_type] => J [begin_page] => 2151 [article_dt] => Article [author_en] => Zhang, WM; Sun, SX; Yu, HY; Song, XY [volume] => 24 [get_data] => 2018-08-29 [publisher] => HIGHER EDUCATION PRESS [keyword_en] => hydrothermal synthesis; cobalt oxide; nano-powder [format_publication_cn] => 112be9cb2f30361719ed2bc572ba4a22192440272 [keyword_plu] => THERMAL-DECOMPOSITION; PHYSICOCHEMICAL CHARACTERIZATION; SPINELS [publication_iso] => Chem. J. Chin. Univ.-Chin. [format_title_en] => 7660fcbbf2984d159fc3ef0076dccc722066698643 [publisher_city] => BEIJING [pub_date] => DEC [hx_id] => 2377,2371 [reference_No] => 14 [email] => ssx@sdu.edu.cn [cite_awos] => 15 [wos_No] => WOS:000187660500004 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [check_180] => 1 [publisher_ad] => SHATANHOU ST 55, BEIJING 100009, PEOPLES R CHINA [title_en] => Synthesis of Co3O4 nanopowder with different morphologies by hydrothermal treatment followed by decomposition [format_publication_en] => 4eabdd9afe3fe566a165b6e1c3e0dbbd-130083487 [jl_language] => chinese [jl_publication_cn] => 高等学校化学学报 [jl_article_dt] => 期刊论文 [jl_publication_en] => chemicaljournalofchineseuniversitieschinese [jl_country] => 中国,中国 [jl_keyword_en] => hydrothermalsynthesis,nanopowder,cobaltoxide [jl_keyword_cn] => ,制备,四氧化三钴,表征,纳米材料,纳米微粉,co2o4,水热固相热解法 [jl_clc] => o614812tb383 [jl_publisher] => highereducationpress [author_id] => 23399 [author_test] => Array ( [0] => Array ( [sure] => 1 [irmagnum] => 0 [u_index] => 4 [name] => 宋新宇 [sys_author_id] => Array ( [0] => 23399 ) [irtag] => 0 [t_index] => 0 [person_id] => 23399 ) ) [company_id] => 43,169 [sys_subject_sort] => 0,0 [college_parent_id] => 43,169 [company_test] => Array,Array [sys_author_id_arr] => 23399宋新宇 [cscd_No] => CSCD:1197050 [jl_publication_cn_publication_en] => chemicaljournalofchineseuniversitieschinese,高等学校化学学报 [jl_keyword_cn_keyword_en] => hydrothermalsynthesis,制备,四氧化三钴,cobaltoxide,nanopowder,纳米材料,表征,co2o4,纳米微粉,水热固相热解法 [sys_author_id] => 23399 [format_cscd_No] => f9994e5467f97dd19dd7fa4e2ec40ed5788274149 [format_title_en_publication_en_pub_year] => 5c156fb064692e183b3fb1de764cca47-2080353141 [format_wos_No] => e31324c0e8028a77d4fcf9ba6d909f9b-1839676297 [format_title_en_issn_pub_year] => 5ba983ea6b1f6625e675b493330b4541-1304859621 [id] => bwkxvmUBFjIhTVEbTvGU [tags] => 0 ) [11] => Array ( [batch2] => 1,2 [uri] => http://kns.cnki.net/kns/detail/detail.aspx?FileName=GDXH200306029&DbName=CJFQ2003 [tag] => 0 [CSSN] => 22-1131/O6 [keyword_cn] => 粘土;;混合金属氢氧化物;;触变性;;流变学;;悬浮体 [fund_No] => 国家自然科学基金(批准号:20043002); 教育部科学技术研究重点项目(批准号:02128); 山东省自然科学基金(批准号:Y2001B01)资助 [article_id] => 220626,84130,683872,538712,331213 [abstract_cn] => 研究了带相反电荷的粘土颗粒和 MMH(铝、镁混合金属氢氧化物 )颗粒形成的混和悬浮体的流变学性能 ,考察了盐对混合体系流变学性能的影响 .结果表明 ,当粘土质量分数为 1 %时 ,悬浮体为牛顿型流体 ;当质量分数升至 2 %时 ,悬浮体表现出固体的弹性响应 ;特定粘土含量的悬浮体中 ,随着 MMH量的增加 ,混合体系的屈服值和弹性模量亦增加 ,表明凝胶结构增强 .向混合体系中加入 Na Cl,弹性模量、屈服值和粘度等流变参数均降低 .与单组分粘土悬浮体或 MMH悬浮体相比 ,双组分混合体系的结构恢复很快 . [author_jg] => [郭培志] 山东大学胶体与界面化学研究所, 胶体与界面化学教育部重点实验室, 济南, 山东 250100, 中国.@@@[孙德军] 山东大学胶体与界面化学研究所, 胶体与界面化学教育部重点实验室, 济南, 山东 250100, 中国.@@@[金志琳] 山东大学胶体与界面化学研究所, 胶体与界面化学教育部重点实验室, 济南, 山东 250100, 中国.@@@[张春光] 山东大学胶体与界面化学研究所, 胶体与界面化学教育部重点实验室, 济南, 山东 250100, 中国 [format_title_cn_publication_cn_pub_year] => ec2e4401f5cdabbf61e61fcc46d99b79-1885607538 [hints] => 7 [issue] => 6 [author_first] => 郭培志 [sys_level_num] => 2_3 [sys_jg_type] => 10,5 [format_issn_issue_page_pub_year] => f3bbad49a7e2b682e1a24c813585ed371392344768 [source_type] => 351 [pub_year] => 2003 [pub_date] => JUN [pages] => 4 [from_id] => 75,78,73,80,85 [author_cn] => 郭培志;孙德军;金志琳;张春光 [issn] => 0251-0790 [batch] => 3250,3249,3241,3254,3252 [publication_cn] => 高等学校化学学报 [title_cn] => 带相反电荷胶体颗粒混和悬浮体的流变学性能 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => a6461b1c27055b9a7dc0e96d8f632cb1-1832919801 [page] => 1052-1055 [hb_type] => 2 [article_dt] => Article [hb_batch] => title_cn_publication_cn_pub_year_2_3 [publication_en] => CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE [cite_wos] => 0 [check_3Y] => 4 [language] => Chinese [delivery_No] => 696AU [format_title] => e1d1fd63f8e5a7cb51c951e30de55e812147407946 [cauthor_ad] => [Sun, DJ]Shandong Univ, Key Lab Colloid & Interface Chem, Educ Minist, Jinan 250100, Peoples R China. [author_fn] => Guo, PZ; Sun, DJ; Jin, ZL; Zhang, CG [reference] => Abend S, 2000, APPL CLAY SCI, V16, P201, DOI@@@10.1016/S0169-1317(99)00040-X@@@Barnes HA, 1997, J NON-NEWTON FLUID, V70, P1, DOI@@@10.1016/S0377-0257(97)00004-9@@@Bonn D, 1999, EUROPHYS LETT, V45, P52, DOI 10.1209/epl/i1999-00130-3@@@Bonn D, 2002, PHYS REV LETT, V89, DOI 10.1103/PhysRevLett.89.015701@@@Buscall R J, 1991, Faraday Transactions, V87, P1365@@@Islam AM, 1995, ADV COLLOID INTERFAC, V62, P109, DOI@@@10.1016/0001-8686(95)00276-V@@@@@@Lagaly G, 2001, COLLOID POLYM SCI, V279, P1097, DOI@@@10.1007/s003960100526@@@Luckham PF, 1999, ADV COLLOID INTERFAC, V82, P43, DOI@@@10.1016/S0001-8686(99)00005-6@@@Nicolai T, 2000, LANGMUIR, V16, P8189, DOI 10.1021/la9915623@@@Pignon F, 1998, J RHEOL, V42, P1349, DOI 10.1122/1.550964@@@So JH, 2001, COLLOID SURFACE A, V190, P89, DOI@@@10.1016/S0927-7757(01)00668-9@@@Tombacz E, 2001, COLLOID POLYM SCI, V279, P484, DOI@@@10.1007/s003960100480@@@@@@Vaccari A, 1998, CATAL TODAY, V41, P53, DOI@@@10.1016/S0920-5861(98)00038-8@@@van OLPHEN H, 1977, An introduction to clay colloid chemistr@@@Wierenga A, 1998, LANGMUIR, V14, P55, DOI 10.1021/la970376z@@@@@@Willenbacher N, 1996, J COLLOID INTERF SCI, V182, P501, DOI@@@10.1006/jcis.1996.0494@@@Zhou ZW, 2001, CHEM ENG SCI, V56, P2901, DOI@@@10.1016/S0009-2509(00)00473-5@@@侯万国, 1998, 化学学报, V56, P514@@@孙德军, 2001, 高等学校化学学报, V22, P1002@@@孙德军, 1998, 高等学校化学学报, V19, P252@@@孙德军, 1996, 高等学校化学学报, V17, P1428@@@孙德军, 2001, 化学学报, V59, P163 [publication_29] => CHEM J CHINESE U [end_page] => 1055 [abstract_en] => The rheological properties of single-component clay dispersions and clay/MMH mixed-dispersions containing oppositely charged colloidal particles have been investigated As. the clay concentration is increased, the clay suspensions develop from the newtonian form of flow behavior to a yielding type of response. At w(clay) is between 2%-4%, upon addition of MMH to,clay dispersions, the magnitude of yield value and storage modulus increase monotonically, indicating enhanced gel strength. Adding NaCl to clay/MMH mixed suspensions causes the decrease of storage modulus, yield values and apparent viscosities. In the structural recovery measurements, the time dependence of viscoelastic properties of clay/MMH mixed dispersions shows only very small variations of the storage moduli over 3 h, in contrast to unusual thixotropic properties of aqueous single-component dispersions of laponite or MMH. The above results are interpreted based on attractive electrostatic, interactions between clay and MMH particles due to their opposite charges, similar to the edge(+)/face(-) interactions in single-component clay dispersions under a low pH value. [researcherID] => Guo, Peizhi/D-1362-2013; Guo, Peizhi/F-2876-2014 [author_in] => [Guo, PZ; Sun, DJ; Jin, ZL; Zhang, CG]Shandong Univ, Key Lab Colloid & Interface Chem, Educ Minist, Jinan 250100, Peoples R China. [orcID] => Guo, Peizhi/0000-0002-8773-2196; Guo, Peizhi/0000-0002-5158-1250 [publication_type] => J [begin_page] => 1052 [author_en] => Guo, PZ; Sun, DJ; Jin, ZL; Zhang, CG [volume] => 24 [get_data] => 2018-08-29 [publisher] => HIGHER EDUCATION PRESS [keyword_en] => clay; mixed metal hydroxides; thixotropy; rheology; suspension [format_publication_cn] => 112be9cb2f30361719ed2bc572ba4a22192440272 [keyword_plu] => AQUEOUS DISPERSIONS; SODIUM MONTMORILLONITE; THIXOTROPIC PROPERTIES; OXIDE SUSPENSIONS; HYDROXIDE; SCATTERING; BEHAVIOR; LAPONITE [publication_iso] => Chem. J. Chin. Univ.-Chin. [format_title_en] => 1b7cd88cdcb849bc2d2bdf5218e2965b812957166 [publisher_city] => BEIJING [hx_id] => 2377,2371 [reference_No] => 22 [email] => djsun@sdu.edu.cn [cite_awos] => 1 [wos_No] => WOS:000183863200028 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [check_180] => 0 [publisher_ad] => SHATANHOU ST 55, BEIJING 100009, PEOPLES R CHINA [title_en] => Rheological properties of mixed suspensions containing oppositely charged colloidal particles [format_publication_en] => 4eabdd9afe3fe566a165b6e1c3e0dbbd-130083487 [jl_language] => chinese [jl_publication_cn] => 高等学校化学学报 [jl_article_dt] => 期刊论文 [jl_publication_en] => chemicaljournalofchineseuniversitieschinese [jl_country] => 中国,中国 [jl_keyword_en] => thixotropy,suspension,mixedmetalhydroxides,rheology,clay [jl_keyword_cn] => ,触变性,悬浮体,粘土,流变学,混合金属氢氧化物 [jl_publisher] => highereducationpress [company_id] => [author_id] => 23456 [author_test] => Array ( [0] => Array ( [sure] => 0 [irmagnum] => 0 [u_index] => 2 [name] => 孙德军 [irtag] => 7 [t_index] => 0 [person_id] => 23456 ) ) [sys_author_id_arr] => 23456孙德军 [cscd_No] => CSCD:1204592 [jl_publication_cn_publication_en] => chemicaljournalofchineseuniversitieschinese,高等学校化学学报 [jl_keyword_cn_keyword_en] => 混合金属氢氧化物,悬浮体,thixotropy,mixedmetalhydroxides,流变学,粘土,clay,suspension,触变性,rheology [sys_author_id] => 23456 [format_cscd_No] => 4f31952de2ae739c076a9f9e8cd2d5b0-205699041 [format_title_en_publication_en_pub_year] => c743ffb3f397d9eb71b725b77aac2bf4-434589876 [format_wos_No] => a14fdc54e9e1d91a92ff467785ac05ce1142733587 [format_title_en_issn_pub_year] => 11645e0a0251385c4a3b234ea788c082952122628 [id] => 5A9KvmUBFjIhTVEbfhHC [tags] => 0 ) [12] => Array ( [batch2] => 1,2 [uri] => http://kns.cnki.net/kns/detail/detail.aspx?FileName=GDXH200308027&DbName=CJFQ2003 [tag] => 0 [CSSN] => 22-1131/O6 [keyword_cn] => 蜡油;;降凝剂;;焓;;熵 [article_id] => 202745,583489,681932,331112,46200 [abstract_cn] => 用 DSC热分析仪研究了合成蜡油的加热与冷却过程 ,测定了蜡油在不同蜡浓度下 ,添加降凝剂前后的平衡蜡溶点和析蜡点以及溶解度和饱和度 ,并进行了热力学分析 .结果表明 ,含蜡油的平衡蜡溶点高于平衡析蜡点 ,降凝剂使平衡蜡溶点进一步升高 ,析蜡点进一步降低 ,导致含蜡油凝点较大幅度降低 .在实验浓度和温度范围内 ,该过程符合 Van′t Hoff方程 ,降凝剂使蜡的溶解焓和溶解熵增大 ,析出焓和析出熵减少 .降凝剂提高了蜡晶析出的临界半径 ,增大了成核位垒 ,使蜡晶析出困难 . [author_jg] => [李传宪] 山东大学, 胶体与界面化学教育部重点实验室, 济南, 山东 250100, 中国.@@@[张春光] 山东大学, 胶体与界面化学教育部重点实验室, 济南, 山东 250100, 中国.@@@[孙德军] 山东大学, 胶体与界面化学教育部重点实验室, 济南, 山东 250100, 中国.@@@[孙洁] 石油大学(华东), 东营, 山东 257061, 中国 [format_title_cn_publication_cn_pub_year] => 8bee2b3016a8874696cbbd7cbe1530261834589239 [hints] => 11 [issue] => 8 [author_first] => 李传宪 [sys_level_num] => 2_3 [sys_jg_type] => 10,5 [format_issn_issue_page_pub_year] => 2d933b552bc1636e18b84c8501b17289-721413852 [source_type] => 351 [pub_year] => 2003 [pub_date] => AUG [pages] => 5 [from_id] => 75,78,73,80,85 [author_cn] => 李传宪;张春光;孙德军;孙洁 [issn] => 0251-0790 [batch] => 3250,3249,3241,3254,3252 [publication_cn] => 高等学校化学学报 [title_cn] => 降凝剂对蜡油中蜡析出与溶解影响的物理化学研究 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => 60d9bf14b0fa91be3f58e0bc8e35ee0b-47777132 [page] => 1451-1455 [hb_type] => 2 [article_dt] => Article [hb_batch] => title_cn_publication_cn_pub_year_2_3 [publication_en] => CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE [cite_wos] => 5 [check_3Y] => 1 [language] => Chinese [delivery_No] => 715WE [format_title] => cc0882eac4233ecfd9ef80ed0b401093-1143195568 [cauthor_ad] => [Zhang, CG]Shandong Univ, Key Lab Colloid & Interface Chem, State Educ Minist, Jinan 250100, Peoples R China. [author_fn] => Li, CX; Zhang, CG; Sun, DJ; Sun, J [reference] => ADHVARYU A, 2002, THERMOCHIMICA ACTA J, V7077, P1@@@BEINY DHM, 1987, J CHEM ENG DATA, V32, P9, DOI 10.1021/je00047a002@@@@@@BEINY DHM, 1990, J CRYST GROWTH, V102, P801, DOI@@@10.1016/0022-0248(90)90845-C@@@@@@El Gamal I M, 1998, Colloids and Surfaces A: Physicochemical and@@@Engineering Aspects, V135, P183@@@HANSEN AB, 1991, ENERG FUEL, V5, P914@@@HENNESSY AJ, 1999, J CRYST GROWTH, V199, P830@@@Machado ALC, 2001, J PETROL SCI ENG, V32, P159, DOI@@@10.1016/S0920-4105(01)00158-9@@@RONNINGSEN HP, 1991, ENERG FUEL, V5, P895@@@[施红伟 Shi Hongwei], 2002, [高等学校化学学报, Chemical Journal of Chinese@@@Universities], V23, P1610@@@Singh P, 1999, J RHEOL, V43, P1437, DOI 10.1122/1.551054@@@Young PH, 2001, THERMOCHIM ACTA, V367, P387, DOI@@@10.1016/S0040-6031(00)00658-4@@@张付生, 2001, 油田化学, V18, P79@@@王松, 2001, 高等学校化学学报, V22, P1938@@@李克华, 1993, 石油与天然气化工, V1, P44@@@印永嘉, 1998, 物理化学简明教程, P136@@@郑忠, 1989, 胶体科学导论, P24 [publication_29] => CHEM J CHINESE U [end_page] => 1455 [abstract_en] => The heating/cooling procedures were studied with differential scanning calorimeter. Equilibrium wax dissolution temperature (WDT), wax precipitation temperature (WPT) and solubility as well as saturation of undoping and doping pour point depressant were measured and analyzed thermodynamically. The results show that equilibrium WDT is higher than WPT, and pour point depressant(PPD) can make the WDT increase and the WPT decrease, resulting in large depression of pour point of waxy oil. The relationship between wax solubility/saturation and temperature accords to Van\'t Hoff equation. the dissolving enthalpy and entropy of the wax of pout point depressant doped oil increased, but the precipitation enthalpy and entropy of the wax of pour point depressant doped oil decreased. PPD makes, the critical radius and the potential barrier of nucleation of wax crystal increase, and makes the separation of wax from waxy oil difficult. [author_in] => [Li, CX; Zhang, CG; Sun, DJ; Sun, J]Shandong Univ, Key Lab Colloid & Interface Chem, State Educ Minist, Jinan 250100, Peoples R China.@@@[Li, CX; Zhang, CG; Sun, DJ; Sun, J] Univ Petr E China, Coll Oil Storage & Transportat, Dongying 257061, Peoples R China. [publication_type] => J [begin_page] => 1451 [author_en] => Li, CX; Zhang, CG; Sun, DJ; Sun, J [volume] => 24 [get_data] => 2018-08-29 [publisher] => HIGHER EDUCATION PRESS [keyword_en] => waxy oil; pour point depressant (PPD); enthalpy; entropy [format_publication_cn] => 112be9cb2f30361719ed2bc572ba4a22192440272 [keyword_plu] => DIFFERENTIAL SCANNING CALORIMETRY; SEA CRUDE OILS; CRYSTALLIZATION; NUCLEATION; PIPELINE; BEHAVIOR [publication_iso] => Chem. J. Chin. Univ.-Chin. [format_title_en] => 5bbe3d62fdbc89a85385601b6d83076b-1460527949 [publisher_city] => BEIJING [hx_id] => 2377,2371 [reference_No] => 16 [email] => cgzhang@sdu.edu.cn [cite_awos] => 13 [wos_No] => WOS:000184995100028 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [check_180] => 0 [publisher_ad] => SHATANHOU ST 55, BEIJING 100009, PEOPLES R CHINA [title_en] => Physicochemical research on effect of pour point depressant on wax precipitation and dissolution of waxy oil [format_publication_en] => 4eabdd9afe3fe566a165b6e1c3e0dbbd-130083487 [jl_language] => chinese [jl_publication_cn] => 高等学校化学学报 [jl_article_dt] => 期刊论文 [jl_publication_en] => chemicaljournalofchineseuniversitieschinese [jl_country] => 中国,中国 [jl_keyword_en] => waxyoil,pourpointdepressantppd,entropy,enthalpy [jl_keyword_cn] => ,焓,蜡油,降凝剂,熵 [jl_publisher] => highereducationpress [company_id] => [author_id] => 23456 [author_test] => Array ( [0] => Array ( [sure] => 0 [irmagnum] => 0 [u_index] => 3 [name] => 孙德军 [irtag] => 7 [t_index] => 0 [person_id] => 23456 ) ) [sys_author_id_arr] => 23456孙德军 [cscd_No] => CSCD:1232466 [jl_publication_cn_publication_en] => chemicaljournalofchineseuniversitieschinese,高等学校化学学报 [jl_keyword_cn_keyword_en] => 降凝剂,waxyoil,焓,熵,蜡油,pourpointdepressantppd,enthalpy,entropy [sys_author_id] => 23456 [format_cscd_No] => beea0013889a3bdf1b29cb323309a5e4272752626 [format_title_en_publication_en_pub_year] => 15f694283a0c7822f398a238ef2d8b50-1623798657 [format_wos_No] => ed09b6a86dcc695f5e0b8e42ea77dd2f-1914707695 [format_title_en_issn_pub_year] => 49863403fdc05b3e88f03334220998e5816945678 [id] => bA5IvmUBFjIhTVEbKVm1 [tags] => 0 ) [13] => Array ( [batch2] => 1,2 [batch] => 3250,3249,3241,3254,3252 [tag] => 0 [CSSN] => 22-1131/O6 [keyword_cn] => 高分子乳液;方解石;球方解石;晶型转变 [article_id] => 106790,683874,555653,331618,202748 [abstract_cn] => In this paper, polymer latices P(St-co-MAA) were used to control the crystallization of CaCO 3, and the influence of the lattices on the crystallization habit and morphology was studied by combination of XRD, FTIR and SEM. The mechanism of the morphology transformation of CaCO 3 from calcite to ... [author_jg] => [陈亚坤] 中国科学院化学研究所分子科学中心, 高分子物理与化学国家重点实验室, 北京 100080, 中国.@@@[赵莹] 中国科学院化学研究所分子科学中心, 高分子物理与化学国家重点实验室, 北京 100080, 中国.@@@[王笃金] 中国科学院化学研究所分子科学中心, 高分子物理与化学国家重点实验室, 北京 100080, 中国.@@@[王家君] 中国科学院化学研究所分子科学中心, 高分子物理与化学国家重点实验室, 北京 100080, 中国.@@@[郑爱国] 中国科学院化学研究所分子科学中心, 高分子物理与化学国家重点实验室, 北京 100080, 中国.@@@[徐端夫] 中国科学院化学研究所分子科学中心, 高分子物理与化学国家重点实验室, 北京 100080, 中国.@@@[徐怡庄] 北京大学化学与分子工程学院, 稀土材料化学及应用国家重点实验室, 北京 250100, 中国.@@@[吴瑾光] 北京大学化学与分子工程学院, 稀土材料化学及应用国家重点实验室, 北京 250100, 中国.@@@[沈强] 山东大学, 胶体界面化学教育部重点实验室, 济南, 山东 250100, 中国 [format_title_cn_publication_cn_pub_year] => 0ae8f134f6049f51bafed2e1f653b307-1295647810 [hints] => 10 [issue] => 2 [sys_level_num] => 2_3 [sys_jg_type] => 10,5 [format_issn_issue_page_pub_year] => 18fecb77fa48c896ea7a16be284d0824-282643487 [source_type] => 351 [pub_year] => 2003 [pub_date] => FEB [pages] => 3 [from_id] => 75,78,73,80,85 [author_cn] => 陈亚坤,赵莹,王笃金,徐怡庄,沈强,王家君,郑爱国,吴瑾光,徐端夫 [issn] => 0251-0790 [uri] => http://kns.cnki.net/kns/detail/detail.aspx?FileName=GDXH200302039&DbName=CJFQ2003 [publication_cn] => 高等学校化学学报 [title_cn] => P(St-co-MAA)乳液体系对CaCO_3结晶的调控 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => 363dc5083f76842a9bc79bf89925e4d2-1168324971 [page] => 332-334 [hb_type] => 2 [article_dt] => Article [hb_batch] => title_cn_publication_cn_pub_year_2_3 [publication_en] => CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE [cite_wos] => 1 [fund_No] => 国家自然科学基金(批准号:20151004); 高分子物理、化学国家重点实验基金(批准号:01-B-08)资助 [check_3Y] => 1 [language] => Chinese [delivery_No] => 672VE [format_title] => 505154546b0f72f0e302b471e3810226158385371 [cauthor_ad] => [Wang, DJ]Chinese Acad Sci, Inst Chem, State Key Lab Polymer Phys & Chem, Ctr Mol Sci, Beijing 100080, Peoples R China. [author_fn] => Chen, YK; Zhao, Y; Wang, DJ; Xu, YZ; Shen, Q; Wang, JJ; Zheng, AG; Wu, JG; Xu, DF [reference] => FLEMMING A, 1991, APPL SPECTROSC, V45, P1748@@@Kralj D, 1997, J CRYST GROWTH, V177, P248, DOI@@@10.1016/S0022-0248(96)01128-1@@@Rao S, 1973, J. Chem. Soc. Japan, V46, P1414@@@Wang PH, 2000, J APPL POLYM SCI, V75, P1693, DOI@@@10.1002/(SICI)1097-4628(20000401)75:14<1693::AID-APP2>3.0.CO;2-8@@@@@@杜满泉, 2001, 高等学校化学学报, V22, P2120 [publication_29] => CHEM J CHINESE U [end_page] => 334 [abstract_en] => In this paper, polymer latices P(St-co-MAA) were used to control the crystallization of CaCO3, and the influence of the lattices on the crystallization, habit and morphology was studied by combination of XRD, FTIR and SEM. The mechanism of the morphology transformation of CaCO3 from calcite to vaterite with the increase of polar group content in latex was investigated. The concentrating effect of calcium ions on the latex surface inhibited the transformation from vaterite to calcite. [researcherID] => Wang, Dujin/F-1075-2011; Shen, Qiang/D-8622-2013 [author_in] => [Chen, YK; Zhao, Y; Wang, DJ; Xu, YZ; Shen, Q; Wang, JJ; Zheng, AG; Wu, JG; Xu, DF]Chinese Acad Sci, Inst Chem, State Key Lab Polymer Phys & Chem, Ctr Mol Sci, Beijing 100080, Peoples R China.@@@[Chen, YK; Zhao, Y; Wang, DJ; Xu, YZ; Shen, Q; Wang, JJ; Zheng, AG; Wu, JG; Xu, DF] Peking Univ, State Key Lab Rare Earth Mat Chem & Applicat, Coll Chem & Mol Engn, Beijing 100871, Peoples R China.@@@[Chen, YK; Zhao, Y; Wang, DJ; Xu, YZ; Shen, Q; Wang, JJ; Zheng, AG; Wu, JG; Xu, DF] Shandong Univ, Key Lab Colloid & Interface Chem Minist Educ, Jinan 250100, Peoples R China. [orcID] => Shen, Qiang/0000-0001-5579-036X [publication_type] => J [begin_page] => 332 [author_en] => Chen, YK; Zhao, Y; Wang, DJ; Xu, YZ; Shen, Q; Wang, JJ; Zheng, AG; Wu, JG; Xu, DF [volume] => 24 [get_data] => 2018-08-29 [publisher] => HIGHER EDUCATION PRESS [keyword_en] => polymer latex; calcite; vaterite; crystal phase transformation [format_publication_cn] => 112be9cb2f30361719ed2bc572ba4a22192440272 [publication_iso] => Chem. J. Chin. Univ.-Chin. [format_title_en] => 09b4b16434caed5fc80d10a1e0de829c-1714904858 [publisher_city] => BEIJING [hx_id] => 2377,2371 [reference_No] => 5 [email] => djwang@pplas.icas.ac.cn [cite_awos] => 1 [wos_No] => WOS:000182543000034 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [check_180] => 0 [publisher_ad] => SHATANHOU ST 55, BEIJING 100009, PEOPLES R CHINA [title_en] => Investigation of the mechanism of CaCO3 crystallization controlled by polymer lattices P(St-co-MAA) [format_publication_en] => 4eabdd9afe3fe566a165b6e1c3e0dbbd-130083487 [jl_language] => chinese [jl_publication_cn] => 高等学校化学学报 [jl_article_dt] => 期刊论文 [jl_publication_en] => chemicaljournalofchineseuniversitieschinese [jl_country] => 中国,中国 [jl_keyword_en] => polymerlatex,vaterite,calcite,crystalphasetransformation [jl_keyword_cn] => 晶型转变,球方解石,高分子乳液,方解石 [jl_publisher] => highereducationpress [company_id] => [author_id] => 23247 [author_test] => Array ( [0] => Array ( [sure] => 0 [irmagnum] => 0 [u_index] => 0 [name] => 沈强 [irtag] => 7 [t_index] => 0 [person_id] => 23247 ) ) [sys_author_id_arr] => 23247沈强 [cscd_No] => CSCD:1282851 [jl_publication_cn_publication_en] => chemicaljournalofchineseuniversitieschinese,高等学校化学学报 [jl_keyword_cn_keyword_en] => 高分子乳液,crystalphasetransformation,方解石,polymerlatex,球方解石,晶型转变,calcite,vaterite [sys_author_id] => 23247 [format_cscd_No] => 33b06accc1a8dfd9fa48e05bf1be95be-607989273 [format_title_en_publication_en_pub_year] => b890a4a3b7a90a7d34bc56e8bff5d4f0306897416 [format_wos_No] => 7872803401ff74b6ba61720eed2ac22c1171385446 [format_title_en_issn_pub_year] => c1574bb9fb6b49360b79f1780a07b1f1-2023514826 [id] => cg5JvmUBFjIhTVEbnMeA [tags] => 0 ) [14] => Array ( [batch2] => 1,2,5,6 [batch] => 3249,0,3250,3252,3243,3241 [tag] => 0 [CSSN] => 22-1131/O6 [keyword_cn] => 电化学;扫描隧道显微镜;Au(111);Schiff碱;自组装单分子膜 [article_id] => 597474,683988,492168,330909,202743 [abstract_cn] => 利用电化学技术及扫描隧道显微镜 ( STM) ,于 0 .1 mol/L HCl O4溶液中研究了 Schiff碱 N-aete-N在单晶 Au( 1 1 1 )面上所形成的自组装单分子膜 ( SAMs)的电化学性质及结构 .N-aete-N在 Au( 1 1 1 )电极表面的吸附抑制了金的阳极氧化 ,同时使固 /液界面双层电容明显降低 .观察到 N-aete-N SAMs的高分辨 STM图像 .N-aete-N分子在 Au( 1 1 1 )表面上以 ( 6× 7)结构单胞呈二维有序排列 ,其表面浓度为5 .5× 1 0 -11mol/cm2 . [author_jg] => [孔德生] 山东大学化学与化工学院, 济南, 山东 250100, 中国.@@@[陈慎豪] 山东大学化学, 250100.@@@[万立骏] 中国科学院化学研究所, 北京 100080, 中国.@@@[雷圣宾] 中国科学院化学研究所, 北京 100080, 中国 [format_title_cn_publication_cn_pub_year] => 6466729b7f9024346ab38958260e583a1481444232 [hints] => 15 [issue] => 10 [sys_level_num] => 2_3 [sys_jg_type] => 11 [format_issn_issue_page_pub_year] => 7db330e36b0618cb5e6c50f21ddb70f8192105075 [source_type] => 351 [pub_year] => 2003 [pub_date] => OCT 10 [pages] => 5 [from_id] => 76,75,73,80,78 [author_cn] => 孔德生,陈慎豪,万立骏,雷圣宾 [issn] => 0251-0790 [uri] => https://www.scopus.com/inward/record.uri?eid=2-s2.0-34249977279&partnerID=40&md5=a0c5e926787ba9aa57e819a549f7f472 [publication_cn] => 高等学校化学学报 [title_cn] => Schiff碱N-aete-N在Au(111)上自组装单分子膜的电化学及STM研究 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => 323bb1525695f25a0c0284b02cd4e2c01898738196 [page] => 1847-1851 [hb_type] => 2 [article_dt] => Article [hb_batch] => issn_issue_page_pub_year_2_3 [publication_en] => CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE [cite_wos] => 3 [fund_No] => 国家重点基础研究专项经费(批准号:G19990650); 国家自然科学基金(批准号:20173033)资助 [check_3Y] => 3 [language] => Chinese [delivery_No] => 735VJ [format_title] => 952a385c480b2f2392342b75f9868bb2-1136366387 [cauthor_ad] => [Chen, SH]Shandong Univ, Dept Chem, Jinan 250100, Peoples R China. [author_fn] => Kong, DS; Chen, SH; Wan, LJ; Lei, SB [reference] => Alper J, 2002, SCIENCE, V295, P2396, DOI 10.1126/science.295.5564.2396@@@Andreasen G, 1997, LANGMUIR, V13, P6814, DOI 10.1021/la970417r@@@ANGERSTEINKOZLOWSKA H, 1987, J ELECTROANAL CHEM, V228, P429, DOI@@@10.1016/0022-0728(87)80122-5@@@BARBARA PF, 1980, J AM CHEM SOC, V102, P2786, DOI 10.1021/ja00528a045@@@@@@Cai WB, 1998, LANGMUIR, V14, P6992, DOI 10.1021/la980617i@@@COSTAMAGNA J, 1992, COORDIN CHEM REV, V119, P67, DOI@@@10.1016/0010-8545(92)80030-U@@@Esplandiu MJ, 2001, LANGMUIR, V17, P828, DOI 10.1021/la001139q@@@FINKLEA HO, 2000, ENCY ANAL CHEM, P1@@@Hagenstrom H, 2001, LANGMUIR, V17, P839, DOI 10.1021/la001140p@@@HAMILTON DE, 1987, J AM CHEM SOC, V109, P374, DOI 10.1021/ja00236a014@@@KIM YT, 1992, LANGMUIR, V8, P1096, DOI 10.1021/la00040a015@@@@@@KOLB DM, 1986, ELECTROCHIM ACTA, V31, P929, DOI@@@10.1016/0013-4686(86)80005-6@@@Kolb DM, 2001, ANGEW CHEM INT EDIT, V40, P1162, DOI@@@10.1002/1521-3773(20010401)40:7<1162::AID-ANIE1162>3.0.CO;2-F@@@KUNITAKE M, 1995, LANGMUIR, V11, P2337, DOI 10.1021/la00007a002@@@@@@MAGNUSSEN OM, 1990, PHYS REV LETT, V64, P2929, DOI@@@10.1103/PhysRevLett.64.2929@@@Noda H, 2001, PHYS CHEM CHEM PHYS, V3, P3336, DOI 10.1039/b101214m@@@@@@Pan GB, 2002, CHEM PHYS LETT, V359, P83, DOI@@@10.1016/S0009-2614(02)00607-3@@@Poirier GE, 1997, CHEM REV, V97, P1117, DOI 10.1021/cr960074m@@@Qian P, 2000, CHEM LETT, P1118, DOI 10.1246/cl.2000.1118@@@QUAN Z, 2002, CORRSION SCI J, V4, P703@@@SCHARDT BC, 1989, SCIENCE, V243, P1050, DOI@@@10.1126/science.243.4894.1050@@@Si Shufeng, 1999, Master Dissertation@@@TAO NJ, 1993, J PHYS CHEM-US, V97, P910, DOI 10.1021/j100106a017@@@TUCCERI RI, 1989, J ELECTROANAL CHEM, V270, P415, DOI@@@10.1016/0022-0728(89)85054-5@@@@@@Ulman A, 1996, CHEM REV, V96, P1533, DOI 10.1021/cr9502357@@@Van Alsten J G, 1999, Langmuir, V15, P7605@@@Wan LJ, 2000, J PHYS CHEM B, V104, P3563, DOI 10.1021/jp993328r@@@Xia YN, 1998, ANGEW CHEM INT EDIT, V37, P550, DOI@@@10.1002/(SICI)1521-3773(19980316)37:5<550::AID-ANIE550>3.0.CO;2-G@@@Xu QM, 2001, LANGMUIR, V17, P6203, DOI 10.1021/la010670y@@@孙命, 2001, 高等学校化学学报, V22, P1160@@@杨生荣, 2001, 高等学校化学学报, V22, P470@@@白春礼, 1992, 扫描隧道显微术及其应用, P1 [publication_29] => CHEM J CHINESE U [end_page] => 1851 [abstract_en] => The self-assembled monolayer of Schiff base N-aete-N molecules on Au(111) in 0.1 mol/L HClO4 solution has been investigated by electrochemical measurements and in situ STM. Two-dimensional ordered molecular arrays with a (6 X 7) commensurate structure were observed. The N-aete-N molecules are adsorbed on Au in a flat-lying orientation and with a surface concentration of 5.5 X 10(-11) mol/cm(2). [researcherID] => Lei, Shengbin/D-9089-2011; Wan, Li-Jun/R-7839-2016 [author_in] => [Kong, D.-S] Department of Chemistry, Shandong University, Jinan 250100, China, Institute of Chemistry, Chinese Acad. of Sci., Beijing 100080, China@@@[ Chen, S.-H] Department of Chemistry, Shandong University, Jinan 250100, China, State Key Laboratory for Corrosion and Protection, Shenyang 110015, China@@@[ Wan, L.-J] Institute of Chemistry, Chinese Acad. of Sci., Beijing 100080, China@@@[ Lei, S.-B] Institute of Chemistry, Chinese Acad. of Sci., Beijing 100080, China [orcID] => Wan, Li-Jun/0000-0002-0656-0936 [publication_type] => J [begin_page] => 1847 [author_en] => Kong, DS; Chen, SH; Wan, LJ; Lei, SB [volume] => 24 [get_data] => 2018-08-29 [publisher] => HIGHER EDUCATION PRESS [keyword_en] => electrochemistry; in situ STM; Au(111); Schiff base; self-assembled; monolayer film [format_publication_cn] => 112be9cb2f30361719ed2bc572ba4a22192440272 [keyword_plu] => SCANNING-TUNNELING-MICROSCOPY; ALKANETHIOL MONOLAYERS; ELECTRODES; ADSORPTION; GOLD(111); OXIDATION; DYNAMICS; ACID [publication_iso] => Chem. J. Chin. Univ.-Chin. [format_title_en] => 46f5c6f012dca11fd3e428f5c87974b7-540986769 [publisher_city] => BEIJING [hx_id] => 2378,2377,2378,2371 [reference_No] => 32 [email] => shchen@sdu.edu.cn [cite_awos] => 4 [wos_No] => WOS:000186135000030 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [check_180] => 0 [publisher_ad] => SHATANHOU ST 55, BEIJING 100009, PEOPLES R CHINA [title_en] => An electrochemistry and in situ STM studies of self-assembled monolayer of Schiff base N-aete-N on Au(111) surface [format_publication_en] => 4eabdd9afe3fe566a165b6e1c3e0dbbd-130083487 [jl_language] => chinese [jl_publication_cn] => 高等学校化学学报 [jl_article_dt] => 期刊论文 [jl_publication_en] => chemicaljournalofchineseuniversitieschinese [jl_country] => 中国 [jl_keyword_en] => au111,electrochemistry,monolayerfilm,schiffbase,insitustm,selfassembled [jl_keyword_cn] => schiff碱,自组装单分子膜,au111,扫描隧道显微镜,电化学 [jl_publisher] => highereducationpress [company_id] => 43,169 [sys_subject_sort] => 0,0 [college_parent_id] => 43,169 [company_test] => Array,Array [author_id] => [author_test] => Array ( ) [sys_author_id_arr] => [cscd_No] => CSCD:1238212 [jl_publication_cn_publication_en] => chemicaljournalofchineseuniversitieschinese,高等学校化学学报 [jl_keyword_cn_keyword_en] => 自组装单分子膜,扫描隧道显微镜,au111,electrochemistry,monolayerfilm,schiffbase,insitustm,selfassembled,电化学,schiff碱 [imf_once] => [author_first] => [jcr_wos] => [imf_5] => [profession_stu] => [thesis_au] => [highly_article] => [student_No] => [grant_bulletin_No] => [dom_ranking] => [province] => [complete_time] => [clc] => KTHPD [format_title_en_issn_pub_year] => 99ffd1be82824cd76138dc541c63c64f-1427385963 [format_scopus_No] => f3aa3d43ebcfc01b9626ba5d786ebc25264133245 [bulletin_date] => [fund_amount] => [attachment_text] => [name_editor] => [format_cscd_No] => e1304942c5df1c81203a7e22571c885b861737466 [subject_gb1] => [phone] => [book_alias] => [application_date] => [fund_type] => [isbn_10] => [classification_No] => [cssci_No] => [responsibility] => [uncontrolled_terms] => [controlled_terms] => [top_article] => [student_type] => [agency] => [classification_pub] => KTHPD [format_wos_No] => b73183d5c847f1d4b64d1468ba4035ea2142168362 [standard_in] => Department of Chemistry, Shandong University, Jinan 250100, China; Institute of Chemistry, Chinese Acad. of Sci., Beijing 100080, China; State Key Laboratory for Corrosion and Protection, Shenyang 110015, China [country] => [open_time] => [institution_first] => Shandong University [cauthor] => Chen, SH(shchen@sdu.edu.cn) [ei_No] => [datebase] => Scopus [fund_CSSCI] => [school_stu] => [main_cword] => [create_time] => [degree] => [job_no] => [volume_label] => [main_eword] => [numerical_index] => [awards_type] => [birthday] => [sponsor] => [imf] => [bulletin_No] => [format_title_en_publication_en_pub_year] => 94d2e4928bf97f0c84fd687954198293-1570724685 [cite_scopus] => 4 [institution_name] => [grant_bulletin_date] => [department_tutor1] => [abstract_type] => [legal_status] => [email_c] => [discipline_name] => [institution_type] => [sys_priority_field] => 76 [oral_time] => [name_tutor1] => [cauthor_back] => [scopus_No] => 2-s2.0-34249977279 [positional_titles] => [sys_author_jg_last_arr] => 中国,250100,中国,中国 [jl_company_test] => uircu0,unameuu5316u5b66u4e0eu5316u5de5u5b66u9662,uparentidu43,uorgidu43,ulevelu1 [sys_author_in_last_arr] => china [jl_clc] => kthpd [sys_author_id] => [id] => iw5HvmUBFjIhTVEbZSLp [tags] => 0 ) [15] => Array ( [batch2] => 1,2 [batch] => 3250,3241,3254,3252 [tag] => 0 [CSSN] => 22-1131/O6 [keyword_cn] => NO二聚体阳离子;密度泛函理论计算;过渡态 [article_id] => 202755,583483,106789,331715 [abstract_cn] => 用 B3LYP/ 6 -31 1 + + G* *方法对 NO二聚体阳离子 ( NO) +2 进行了研究 .几何优化并结合振动分析表明 ,该复合物存在 5种可能的稳定构型 .能量最低的是 N—N相连的反式异构体 ,具有 C2 h对称性 .分析了各稳定构型的相对稳定性及成键特征 .建立了态态相关并给出异构化过渡态 ,分析了各构型之间转化的途径 . [author_jg] => [孙立祥,步宇翔,陈志达]曲阜师范大学化学系,曲阜师范大学化学系,北京大学稀土化学及应用国家重点实验室 曲阜273165,曲阜273165,山东大学理论化学研究所,济南250100,北京大学稀土化学及应用国家重点实验室,北京100871,北京100871 [format_title_cn_publication_cn_pub_year] => 11588123853b0b7b8545e689c5843d13-1176711610 [hints] => 12 [issue] => 1 [sys_level_num] => 2_3 [sys_jg_type] => 5 [format_issn_issue_page_pub_year] => 2ed00d451b6403188e76f1c6fb7b7985821776007 [source_type] => 351 [pub_year] => 2003 [pub_date] => JAN [pages] => 4 [from_id] => 80,78,73,85 [author_cn] => 孙立祥,步宇翔,陈志达 [issn] => 0251-0790 [uri] => http://kns.cnki.net/kns/detail/detail.aspx?FileName=GDXH200301032&DbName=CJFQ2003 [publication_cn] => 高等学校化学学报 [title_cn] => (NO)_2~+复合物阳离子的结构和性质研究 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => cebde88775d6c309ab3a587a00f6d551-1680098185 [page] => 113-116 [hb_type] => 2 [article_dt] => Article [hb_batch] => title_cn_publication_cn_pub_year_2_3 [format_title_en] => f4d81c40d543bf538c0acef45d9d91ee-713543721 [format_title] => e9dbc6de7728e009922ae910d61016c0465125577 [hx_id] => 2371 [format_publication_cn] => 112be9cb2f30361719ed2bc572ba4a22192440272 [format_publication_en] => 4eabdd9afe3fe566a165b6e1c3e0dbbd-130083487 [jl_publication_cn] => 高等学校化学学报 [jl_article_dt] => 期刊论文 [jl_keyword_cn] => no二聚体阳离子,密度泛函理论计算,过渡态 [author_in] => [Sun, LX]Qufu Normal Univ, Dept Chem, Qufu, Peoples R China.@@@[ Bu, YX] Shandong Univ, Inst Theoret Chem, Jinan 250100, Peoples R China.@@@[ Chen, ZD] Peking Univ, State Key Lab Rare Earth Mat & Applicat, Beijing 100871, Peoples R China. [company_id] => 0,0,0,0,0 [author_id] => 20105 [author_test] => Array ( [0] => Array ( [sure] => 0 [irmagnum] => 0 [u_index] => 2 [name] => 步宇翔 [irtag] => 7 [t_index] => 0 [person_id] => 20105 ) ) [sys_author_id_arr] => [jl_publication_cn_publication_en] => 高等学校化学学报 [jl_keyword_cn_keyword_en] => no二聚体阳离子,密度泛函理论计算,过渡态 [sys_author_id] => [publication_en] => CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE [cite_wos] => 0 [check_3Y] => 2 [language] => Chinese [delivery_No] => 674YX [cauthor_ad] => [Bu, YX]Qufu Normal Univ, Dept Chem, Qufu, Peoples R China. [author_fn] => Sun, LX; Bu, YX; Chen, ZD [format_title_en_issn_pub_year] => ad3c2821530cc761bdaad43dc3fcbe131520852270 [publication_29] => CHEM J CHINESE U [end_page] => 116 [abstract_en] => The NO dimer cation, (NO)(2)(+), has been studied by using density functional theory. The geometries and the harmonic vibrational frequency of (NO)(2)(+) have been calculated at B3LYP/6-311++G* level. The results indicate that there are five stable doublet states. The ground state is determined to be the trans isomer with N-N bond linkage, which has C-2h symmetry. The relative stability of all stable geometric structures has been analyzed. The state-state correlation and the isomerization mechanism are predicted by searching the transition states and using the same methods. [publication_type] => J [begin_page] => 113 [author_en] => Sun, LX; Bu, YX; Chen, ZD [volume] => 24 [get_data] => 2018-08-29 [publisher] => HIGHER EDUCATION PRESS [keyword_en] => NO dimer cation; density function theory; transition state [keyword_plu] => NO DIMER CATION; NITRIC-OXIDE [publication_iso] => Chem. J. Chin. Univ.-Chin. [format_title_en_publication_en_pub_year] => 3560e8fb8031c3945701ad21efb8111b1380249826 [publisher_city] => BEIJING [cauthor_order] => 2 [reference_No] => 13 [cite_awos] => 0 [wos_No] => WOS:000182666400032 [format_wos_No] => 6787a343a2c046b3a908f9ebacb4451b515055450 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [cauthor_back] => Bu, YX [check_180] => 0 [publisher_ad] => SHATANHOU ST 55, BEIJING 100009, PEOPLES R CHINA [title_en] => Theoretical studies on structures and properties of (NO)(2)(+) complex cation [id] => Zg5IvmUBFjIhTVEbKVm1 [tags] => 0 ) [16] => Array ( [batch2] => 1,2 [uri] => http://kns.cnki.net/kns/detail/detail.aspx?FileName=GDXH200307043&DbName=CJFQ2003 [tag] => 0 [CSSN] => 22-1131/O6 [keyword_cn] => 李代数方法;;代数Hamiltonian;;高激发振动态 [fund_No] => 国家自然科学基金(批准号:20173031,29892168); 山东省自然科学基金(批准号:Y99B04)资助 [article_id] => 106791,202747,538709,331001,683910 [abstract_cn] => The highly excited vibrational states of quasi-linear tetraatomic molecule HCNO are studied in the framework of U(4) algebra. By using symmetric group with which the tetraatomic molecules satisfy, we construct the algebraic Hamiltonian that not only includes Majorana operator M 12 but also M 1... [author_jg] => [冯东太] 山东大学物理与微电子学院,化学学院, 济南, 山东 250100, 中国.@@@[丁世良] 山东大学物理与微电子学院,化学学院, 济南, 山东 250100, 中国.@@@[王美山] 山东大学物理与微电子学院,化学学院, 济南, 山东 250100, 中国 [format_title_cn_publication_cn_pub_year] => 82399d145a1f6c1b97201555e03883c3-478071243 [hints] => 20 [issue] => 7 [author_first] => 冯东太 [sys_level_num] => 2_3 [sys_jg_type] => 0,3,5 [format_issn_issue_page_pub_year] => e3323691bf44e9cb77e06916d0316c7d-607433415 [source_type] => 351 [pub_year] => 2003 [pub_date] => JUL [pages] => 3 [from_id] => 75,78,73,80,85 [author_cn] => 冯东太;丁世良;王美山 [issn] => 0251-0790 [batch] => 3250,3249,3241,3254,3252 [publication_cn] => 高等学校化学学报 [title_cn] => 准线型四原子分子高激发振动能级的动力学李代数方法 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => f49e380223b06ce49140e441f1fff7ca-1604692754 [page] => 1299-1301 [hb_type] => 2 [article_dt] => Article [hb_batch] => title_cn_publication_cn_pub_year_2_3 [publication_en] => CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE [cite_wos] => 0 [check_3Y] => 1 [language] => Chinese [delivery_No] => 704TN [format_title] => 6f6a5c762bb3a91f661134d033dd414a1951332249 [cauthor_ad] => [Ding, SL]Shandong Univ, Sch Chem, Sch Phys & Microelect, Jinan 250100, Peoples R China. [author_fn] => Feng, DT; Ding, SL; Wang, MS [reference] => Guan D, 1997, CHEM PHYS, V218, P1, DOI 10.1016/S0301-0104(97)00011-6@@@Guan DR, 1997, INT J QUANTUM CHEM, V65, P159, DOI@@@10.1002/(SICI)1097-461X(1997)65:2<159::AID-QUA7>3.0.CO;2-V@@@IACHELLO F, 1992, J MOL SPECTROSC, V156, P190, DOI@@@10.1016/0022-2852(92)90102-T@@@IACHELLO F, 1994, ALGEBRAIC THEORY MOL, P90@@@Van Roosmalen O S, 1983, J. Chem. Phys., V79, P2515@@@[王美山 Wang Meishan], 2002, [高等学校化学学报, Chemical Journal of Chinese@@@Universities], V23, P709@@@Wybourne B G, 1982, 典型群及其在物理学上的应用, P295@@@Zheng YJ, 2000, J MOL SPECTROSC, V201, P109, DOI 10.1006/jmsp.2000.8060@@@Zheng YJ, 2001, PHYS REV A, V64, DOI 10.1103/PhysRevA.64.032720@@@@@@戴瑛, 1998, 物理学报, V47, P922@@@王美山, 2002, 高等学校化学学报, V23, P1164 [publication_29] => CHEM J CHINESE U [end_page] => 1301 [abstract_en] => The highly-excited vibrational, states of quasi-linear tetraatomic molecule HCNO are studied in the framework of U(4) algebra. By using symmetric group with which the tetraatomic molecules satisfy, we construct the algebraib-Har\'niltonian that not only includes Majorana operator M-12 but also M-13 and M-23 which are very useful; for getting potential energy surface and force constants in Lie algebra. method. And the eigenvalue of the Hamiltonian are obtained by Lie algebra-treatment: [author_in] => [Feng, DT; Ding, SL; Wang, MS]Shandong Univ, Sch Chem, Sch Phys & Microelect, Jinan 250100, Peoples R China.@@@[Feng, DT; Ding, SL; Wang, MS] Shandong Univ Technol, Dept Phys, Zibo 255000, Peoples R China. [publication_type] => J [begin_page] => 1299 [author_en] => Feng, DT; Ding, SL; Wang, MS [volume] => 24 [get_data] => 2018-08-29 [publisher] => HIGHER EDUCATION PRESS [keyword_en] => Lie algebra method; algebraic Hamiltonian; highly excited vibrational; states [format_publication_cn] => 112be9cb2f30361719ed2bc572ba4a22192440272 [keyword_plu] => 4-ATOMIC MOLECULES; MATRIX ELEMENT; COLLISIONS; OPERATORS; SPECTRA [publication_iso] => Chem. J. Chin. Univ.-Chin. [format_title_en] => 101ca4512a719fe48ded9d61d5de80781293128986 [publisher_city] => BEIJING [hx_id] => 2377,2371 [reference_No] => 11 [email] => shlaudin@sdu.edu.cn [cite_awos] => 0 [wos_No] => WOS:000184356400041 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [check_180] => 0 [publisher_ad] => SHATANHOU ST 55, BEIJING 100009, PEOPLES R CHINA [title_en] => Dynamical Lie algebra method for highly excited vibrational state of quasi-linear tetraatomic molecules [format_publication_en] => 4eabdd9afe3fe566a165b6e1c3e0dbbd-130083487 [jl_language] => chinese [jl_publication_cn] => 高等学校化学学报 [jl_article_dt] => 期刊论文 [jl_publication_en] => chemicaljournalofchineseuniversitieschinese [jl_country] => 中国,中国 [jl_keyword_en] => algebraichamiltonian,liealgebramethod,states,highlyexcitedvibrational [jl_keyword_cn] => ,代数hamiltonian,高激发振动态,李代数方法 [jl_publisher] => highereducationpress [company_id] => 43,35,133,5,169,161 [sys_subject_sort] => 0,0,0,0,0,0 [college_parent_id] => 43,35,133,5,169,161 [company_test] => Array,Array,Array,Array,Array,Array [author_id] => [author_test] => Array ( ) [sys_author_id_arr] => [cscd_No] => CSCD:1209597 [jl_publication_cn_publication_en] => chemicaljournalofchineseuniversitieschinese,高等学校化学学报 [jl_keyword_cn_keyword_en] => algebraichamiltonian,highlyexcitedvibrational,liealgebramethod,代数hamiltonian,states,李代数方法,高激发振动态 [sys_author_id] => [format_cscd_No] => 33fc01995f212cca5deb28f212b23d401908237389 [format_title_en_publication_en_pub_year] => f9ca7c598601278f2dade3a424af8be11556000059 [format_wos_No] => 1232616d18f471c9d370a51b01e7570933417932 [format_title_en_issn_pub_year] => c345a5e815067a49e427c354ba2dd33d1908653430 [id] => 4Q9KvmUBFjIhTVEbfhHC [tags] => 0 ) [17] => Array ( [batch2] => 1,2,6 [batch] => 3250,3243,3249,3252,3241 [tag] => 0 [CSSN] => 22-1131/O6 [keyword_cn] => 从头算;反应机理;动力学;乙烯酮 [article_id] => 495286,539178,332143,683974,220160 [abstract_cn] => 用 G3 (MP2 )方法对 F与 CH2 CO的反应进行研究 ,揭示了该反应的加成 -消除机理 .F原子首先与CH2 CO作用形成富能的中间体 CH2 FCO*,此加成反应为无势垒过程 .富能的 CH2 FCO*可进一步发生解离或异构化反应生成各种可能的产物 .其中 CO和 CH2 F可能为反应的主要产物 .根据从头算的结果 ,用RRKM-TST理论计算该反应的速率常数 .总包反应速率常数与温度存在弱的依赖关系 ,与总压力无关 [author_jg] => [侯华] 山东大学化学与化工学院, 济南, 山东 250100, 中国.@@@[王少坤] 山东大学化学与化工学院, 济南, 山东 250100, 中国.@@@[王宝山] 山东大学化学与化工学院, 济南, 山东 250100, 中国.@@@[顾月姝] 山东大学化学与化工学院, 济南, 山东 250100, 中国 [format_title_cn_publication_cn_pub_year] => 0787f93ade77bbff426d99ffe55aa7bd1984554021 [hints] => 15 [issue] => 6 [sys_level_num] => 2_3 [sys_jg_type] => 10,5 [format_issn_issue_page_pub_year] => f4b56b5d259e9a072c0a63969c94e341-1649861619 [source_type] => 351 [pub_year] => 2002 [pub_date] => JUN [pages] => 4 [from_id] => 76,75,73,80,78 [author_cn] => 侯华,王少坤,王宝山,顾月姝 [issn] => 0251-0790 [uri] => https://www.scopus.com/inward/record.uri?eid=2-s2.0-0346638467&partnerID=40&md5=9a82f4efccd3c824905213c4cebf41ae [publication_cn] => 高等学校化学学报 [title_cn] => F+CH_2CO的反应机理和动力学研究 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => b2da369c2251d540fe686f109944728b332453791 [page] => 1131-1134 [hb_type] => 2 [article_dt] => Article [hb_batch] => title_cn_publication_cn_pub_year_2_3 [publication_en] => CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE [cite_wos] => 3 [fund_No] => 高等学校博士学科点专项科研基金(批准号:1999042201) [check_3Y] => 3 [language] => Chinese [delivery_No] => 563TU [format_title] => c715711be7cabca06e3dbaa62cb1d966760278228 [cauthor_ad] => [Gu, YS]Shandong Univ, Sch Chem & Chem Engn, Jinan 250100, Peoples R China. [author_fn] => Hou, H; Wang, SK; Wang, BS; Gu, YS [reference] => Ebrecht J, 1990, Phys. Chem., V94, P587@@@Grussdorf J, 1994, Phys. Chem., V98, P546@@@Hou H, 2000, J PHYS CHEM A, V104, P320, DOI 10.1021/jp992829+@@@HUDGENS JW, 1987, J CHEM PHYS, V87, P4546, DOI 10.1063/1.452867@@@Maricq MM, 1997, INT J CHEM KINET, V29, P421, DOI@@@10.1002/(SICI)1097-4601(1997)29:6<421::AID-KIN3>3.0.CO;2-W@@@Wallington TJ, 1996, INT J CHEM KINET, V28, P627, DOI@@@10.1002/(SICI)1097-4601(1996)28:8<627::AID-KIN8>3.0.CO;2-X@@@@@@WASHIDA N, 1983, J CHEM PHYS, V78, P4533, DOI 10.1063/1.445346@@@ [publication_29] => CHEM J CHINESE U [end_page] => 1134 [abstract_en] => G3(MP2) theory is used to study the F+CH2CO reaction. The calculations reveal a typical addition-elimination mechanism for the title reaction. The reaction starts with F and (CH2CO) reacting with each other to form the activated intermediate (CH2FCO)(.) . This association reaction is found to be a barrierless process. CH2FCO. can undergo further decomposition and isomerization reactions leading to various possible products. CO and CH2F are found to be the dominant products. RRKM-TST method is used to calculate the total and individual rate constants. The total rate constant shows a weak temperature dependence and a pressure independence. [author_in] => [Hou, H] Sch. of Chem. and Chem. Engineering, Shandong University, Jinan 250100, China@@@[ Wang, S.-K] Sch. of Chem. and Chem. Engineering, Shandong University, Jinan 250100, China@@@[ Wang, B.-S] Sch. of Chem. and Chem. Engineering, Shandong University, Jinan 250100, China@@@[ Gu, Y.-S] Sch. of Chem. and Chem. Engineering, Shandong University, Jinan 250100, China [publication_type] => J [begin_page] => 1131 [author_en] => Hou, H; Wang, SK; Wang, BS; Gu, YS [volume] => 23 [get_data] => 2018-08-29 [publisher] => HIGHER EDUCATION PRESS [keyword_en] => ab initio; reaction mechanism; kinetics; ketene [format_publication_cn] => 112be9cb2f30361719ed2bc572ba4a22192440272 [keyword_plu] => ELEMENTARY REACTIONS; CH2CO KETENE; GAS-PHASE; PRODUCTS; ATOMS; CL [publication_iso] => Chem. J. Chin. Univ.-Chin. [format_title_en] => f0b622d248765a470278f1e518e59ba1-1456727226 [publisher_city] => BEIJING [hx_id] => 2377,2378,2371 [reference_No] => 7 [email] => guojz@icm.sdu.edu.cn [cite_awos] => 4 [wos_No] => WOS:000176272300039 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [check_180] => 0 [publisher_ad] => SHATANHOU ST 55, BEIJING 100009, PEOPLES R CHINA [title_en] => Reaction mechanism and kinetics for the F+CH2CO reaction [format_publication_en] => 4eabdd9afe3fe566a165b6e1c3e0dbbd-130083487 [jl_language] => chinese [jl_publication_cn] => 高等学校化学学报 [jl_article_dt] => 期刊论文 [jl_publication_en] => chemicaljournalofchineseuniversitieschinese [jl_country] => 中国,中国 [jl_keyword_en] => ketene,abinitio,kinetics,reactionmechanism [jl_keyword_cn] => 乙烯酮,从头算,反应机理,动力学 [jl_publisher] => highereducationpress [author_id] => 24162 [author_test] => Array ( [0] => Array ( [sure] => 1 [irmagnum] => 0 [u_index] => 0 [name] => 王少坤 [sys_author_id] => Array ( [0] => 24162 ) [irtag] => 0 [t_index] => 0 [person_id] => 24162 ) ) [company_id] => 43,169 [sys_subject_sort] => 0,0 [college_parent_id] => 43,169 [company_test] => Array,Array [sys_author_id_arr] => 24162王少坤 [cscd_No] => CSCD:993526 [jl_publication_cn_publication_en] => chemicaljournalofchineseuniversitieschinese,高等学校化学学报 [jl_keyword_cn_keyword_en] => 乙烯酮,kinetics,反应机理,动力学,从头算,reactionmechanism,ketene,abinitio [sys_author_id] => 24162 [format_cscd_No] => 49a55ece0f376165498f4b1115fa66841549392629 [format_title_en_publication_en_pub_year] => 1068d6fb20c0ae6a25d728ff6a0b8265-322523189 [format_wos_No] => d9ff6b0a22b0e311b63a8ab1793d005d1803474775 [format_title_en_issn_pub_year] => 1bfa816857b3d33bf7c63b4a57b29c2c-469725786 [format_scopus_No] => 55cad3c5fd8b5f49b0b454ce673f6b02-356501939 [classification_pub] => KTHPD [standard_in] => Sch. of Chem. and Chem. Engineering, Shandong University, Jinan 250100, China [datebase] => Scopus [cite_scopus] => 2 [sys_priority_field] => 76 [scopus_No] => 2-s2.0-0346638467 [id] => FQ9KvmUBFjIhTVEbYAQa [tags] => 0 ) [18] => Array ( [batch2] => 1,2,6 [batch] => 3249,3250,3252,3254,3243,3241 [tag] => 0 [CSSN] => 22-1131/O6 [keyword_cn] => 伯胺N1923;萃取体系;反胶束 [article_id] => 495449,220621,106788,332146,681449,583494 [abstract_cn] => The formation of reversed micelle of primary amine N1923 in different solvents is firstly investigated by determining the interfacial tension and electric conductivity in the organic phase and the IR spectra. A significant difference has been discovered for the formation of reversed micelle between... [author_jg] => [宋新宇] 山东大学化学与化工学院, 济南, 山东 250100, 中国.@@@[印志磊] 山东大学化学与化工学院, 济南, 山东 250100, 中国.@@@[张卫民] 山东大学化学与化工学院, 济南, 山东 250100, 中国.@@@[俞海云] 山东大学化学与化工学院, 济南, 山东 250100, 中国.@@@[孙思修] 山东大学化学与化工学院, 济南, 山东 250100, 中国 [format_title_cn_publication_cn_pub_year] => 93d580aea48faa297b33ccf5889b8585491232298 [hints] => 23 [issue] => 6 [sys_level_num] => 2_3 [sys_jg_type] => 9,10,5 [format_issn_issue_page_pub_year] => cd85a428a444eee8d4745037ca6b1fda-2074524838 [source_type] => 351 [pub_year] => 2002 [pub_date] => JUN [pages] => 3 [from_id] => 76,75,73,80,78,85 [author_cn] => 宋新宇,印志磊,张卫民,俞海云,孙思修 [issn] => 0251-0790 [uri] => https://www.scopus.com/inward/record.uri?eid=2-s2.0-0346707637&partnerID=40&md5=8a917a48042ecd017ec4a7da65f336bb [publication_cn] => 高等学校化学学报 [title_cn] => 伯胺N1923萃取体系反胶束的形成研究 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => 082a1a170fecd1526828d23aa32cfd671619965811 [page] => 1177-1179 [hb_type] => 2 [article_dt] => Article [hb_batch] => title_cn_publication_cn_pub_year_2_3 [publication_en] => CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE [cite_wos] => 2 [fund_No] => 国家自然科学基金(批准号:20171029) [check_3Y] => 0 [language] => Chinese [delivery_No] => 563TU [format_title] => df48a6be259cb8b1df016f26b2d32b67-1762378101 [cauthor_ad] => [Sun, SX]Shandong Univ, Coll Chem & Chem Engn, Jinan 250100, Peoples R China. [author_fn] => Song, XY; Yin, ZL; Zhang, WM; Yu, HY; Sun, SX [reference] => Andrew C Law, 1987, Schechter. J. Colloid Interfince Sci., V120, P42@@@KERTES AS, 1976, SURF COLLOID SCI, P194@@@Nieuwkoop J Van, 1985, J. Colloid Interface Sci., V103, P417@@@李雪梅, 2001, 高等学校化学学报, V22, P59@@@孙思修, 1989, 高等学校化学学报, V10, P431@@@高宏成, 1994, 高等学校化学学报, V15, P1425@@@赵国玺, 1991, 表面活性剂物理化学(第2版), P204 [publication_29] => CHEM J CHINESE U [end_page] => 1179 [abstract_en] => The formation of reversed micelle of primary amine N1923 in different solvents is firstly investigated by determining the interfacial tension and electric conductivity in the organic phase and the IR spectra. A significant difference has been discovered for the formation of reversed micelle between the sulfate and the chloride. [author_in] => [Song, X.-Y] Coll. of Chem. and Chem. Engineering, Shangdong University, Jinan 250100, China@@@[ Yin, Z.-L] Coll. of Chem. and Chem. Engineering, Shangdong University, Jinan 250100, China@@@[ Zhang, W.-M] Coll. of Chem. and Chem. Engineering, Shangdong University, Jinan 250100, China@@@[ Yu, H.-Y] Coll. of Chem. and Chem. Engineering, Shangdong University, Jinan 250100, China@@@[ Sun, S.-X] Coll. of Chem. and Chem. Engineering, Shangdong University, Jinan 250100, China [publication_type] => J [begin_page] => 1177 [author_en] => Song, XY; Yin, ZL; Zhang, WM; Yu, HY; Sun, SX [volume] => 23 [get_data] => 2018-08-29 [publisher] => HIGHER EDUCATION PRESS [keyword_en] => primary amine N1923; extraction system; reversed micelle [format_publication_cn] => 112be9cb2f30361719ed2bc572ba4a22192440272 [publication_iso] => Chem. J. Chin. Univ.-Chin. [format_title_en] => 8bc5f7aeebe3db49037b45272c7d5e40-1315110913 [publisher_city] => BEIJING [hx_id] => 2377,2378,2371 [reference_No] => 7 [email] => ssx@sdu.edu.cn [cite_awos] => 3 [wos_No] => WOS:000176272300051 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [check_180] => 0 [publisher_ad] => SHATANHOU ST 55, BEIJING 100009, PEOPLES R CHINA [title_en] => The formation of the reversed micelle in the extraction system of primary amine N1923 [format_publication_en] => 4eabdd9afe3fe566a165b6e1c3e0dbbd-130083487 [jl_language] => chinese [jl_publication_cn] => 高等学校化学学报 [jl_article_dt] => 期刊论文 [jl_publication_en] => chemicaljournalofchineseuniversitieschinese [jl_country] => 中国,中国 [jl_keyword_en] => extractionsystem,reversedmicelle,primaryaminen1923 [jl_keyword_cn] => 伯胺n1923,萃取体系,反胶束 [jl_publisher] => highereducationpress [author_id] => 25117,23399 [author_test] => Array ( [0] => Array ( [sure] => 1 [irmagnum] => 0 [u_index] => 0 [name] => 宋新宇 [irtag] => 0 [t_index] => 0 [person_id] => 23399 ) [1] => Array ( [sure] => 1 [irmagnum] => 0 [u_index] => 0 [name] => 印志磊 [sys_author_id] => Array ( [0] => 23399 [1] => 25117 ) [irtag] => 0 [t_index] => 0 [person_id] => 25117 ) ) [company_id] => 43,169 [sys_subject_sort] => 0,0 [college_parent_id] => 43,169 [company_test] => Array,Array [sys_author_id_arr] => 23399宋新宇,25117印志磊 [cscd_No] => CSCD:993744 [jl_publication_cn_publication_en] => chemicaljournalofchineseuniversitieschinese,高等学校化学学报 [jl_keyword_cn_keyword_en] => extractionsystem,伯胺n1923,萃取体系,primaryaminen1923,反胶束,reversedmicelle [sys_author_id] => 23399,25117 [format_cscd_No] => 9e344fcf9739be553a40d7165040264e-410400719 [format_title_en_publication_en_pub_year] => 8730faaf7d99e06c3cb2b85fe92b341b2004174482 [format_wos_No] => 6544d8f996e112c9c471ef41891418dc872413411 [format_title_en_issn_pub_year] => be98d6b562cd56a2d22445674a610f8154875558 [datebase] => Scopus [format_scopus_No] => efb857640c2a689831e75c21275a70051085058885 [sys_priority_field] => 76 [classification_pub] => KTHPD [standard_in] => Coll. of Chem. and Chem. Engineering, Shangdong University, Jinan 250100, China [scopus_No] => 2-s2.0-0346707637 [id] => cQ5IvmUBFjIhTVEbKVm1 [tags] => 0 ) [19] => Array ( [batch2] => 1,2,6 [batch] => 3249,3250,3241,3254,3246,3243,3252 [tag] => 0 [abstract_cn] => 用吊片法和气泡最大压力法分别测定了烷基聚葡糖苷(APG)C9.6G1.3水溶液的平衡和动态表面张力,研究了APG水溶液表面的吸附平衡、动力学及其影响因素。测得其cmc(临界胶束浓度)为0.032g/L。吸附过程由初始的扩散控制转变到势垒控制,吸附势垒为4-7kJ/mol。温度升高,平衡和动态表面张力均减小,吸附量增加;加入无机盐,平衡和动态表面张力增大,吸附量亦增加;醇类的吸附使动态表面张力下降速度加快,表明APG与醇分子间有协同吸附作用。 [keyword_cn] => 溶液;表面吸附平衡;动态表面张力;动力学;烷基聚葡糖苷;表面活性剂; [clc] => O647.1 [author_jg] => [柴金岭] 山东大学, 胶体与界面化学教育部重点实验室, 济南, 山东 250100, 中国.@@@[李干佐] 山东大学, 胶体与界面化学教育部重点实验室, 济南, 山东 250100, 中国.@@@[张高勇] 山东大学, 胶体与界面化学教育部重点实验室, 济南, 山东 250100, 中国.@@@[李英] 山东大学, 胶体与界面化学教育部重点实验室, 济南, 山东 250100, 中国.@@@[陈文君] 山东大学, 胶体与界面化学教育部重点实验室, 济南, 山东 250100, 中国.@@@[徐军] 中国石油化工集团金陵石油化工研究院, 南京, 江苏 210046, 中国 [format_title_cn_publication_cn_pub_year] => 1afb0c6e3aa90f06ed22017a3cfb8df8 [from_id] => 76,75,74,73,80,78,85 [issue] => 10 [sys_level_num] => 2_1 [sys_jg_type] => 10,3 [source_type] => 351 [pub_year] => 2002 [article_id] => 46198,331853,682073,202711,495104,400977,583467 [pages] => 6 [hints] => 8 [author_cn] => 柴金岭[1];徐军[2];等 [issn] => 0251-0790 [uri] => https://www.scopus.com/inward/record.uri?eid=2-s2.0-0347269233&partnerID=40&md5=e0bc15875bd88b39ec46cc36e588531f [publication_cn] => 高等学校化学学报 [title_cn] => 烷基聚葡糖苷溶液的表面吸附平衡与动力学 [CSSN] => 22-1131/06 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => 28259c73f6bee1b44e54f742f60995d8 [hb_type] => 2 [hb_batch] => title_cn_publication_cn_pub_year_2_3 [publication_en] => CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE [cite_wos] => 7 [fund_No] => 国家自然科学基金(批准号:29903006); 国家自然科学基金(批准号:29973023) [check_3Y] => 1 [language] => Chinese [delivery_No] => 606WU [format_title] => b5a40fa9dddad0976923466c09177073456729686 [cauthor_ad] => [Li, GZ]Shandong Univ, Key Lab Colloid & Interface Chem, State Educ Minist, Jinan 250100, Peoples R China. [author_fn] => Chai, JL; Xu, J; Li, GZ; Zhang, GY; Li, Y; Chen, WJ [reference] => ADAMCZYK Z, 1986, J COLLOID INTERF SCI, V120, P477@@@BALZER D, 2000, Nonionic Surfactants: Slkyl Polyglucosides. Surfactant@@@ScienceSeries: Vol91, P184@@@JOHNER A, 1990, MACROMOLECULES, V23, P5299, DOI 10.1021/ma00228a001@@@@@@Julian E, 1997, J COLLOID INTERF SCI, V188, P423@@@Kjellin URM, 2001, LANGMUIR, V17, P1941, DOI 10.1021/la001309z@@@KOELTZOW DE, 1984, J AM OIL CHEM SOC, V61, P1651, DOI 10.1007/BF02541651@@@MATSUMURA S, 1990, J AM OIL CHEM SOC, V67, P996, DOI 10.1007/BF02541865@@@MILLER R, 1994, ADV COLLOID INTERFAC, V49, P249, DOI@@@10.1016/0001-8686(94)80017-0@@@Persson CM, 2000, LANGMUIR, V16, P10227, DOI 10.1021/la000665e@@@RAVERA F, 1993, J COLLOID INTERF SCI, V156, P109, DOI@@@10.1006/jcis.1993.1088@@@@@@Shinoda K, 1961, Rull. Chem. Soc. Jpn, V34, P23@@@WARD AFH, 1946, J CHEM PHYS, V14, P453, DOI 10.1063/1.1724167@@@郑利强, 2001, 化学学报, V59, P637@@@王正武, 2001, 高等学校化学学报, V22, P1225@@@牟建海, 1999, 高等学校化学学报, V20, P1776@@@李干佐, 1999, 日用化学工业, P21 [publication_29] => CHEM J CHINESE U [end_page] => 1920 [abstract_en] => The air-solution equilibrium (gamma(e)) and dynamic surface tensions[gamma(t)] were measured by Wilhelmy method and maximum bubble pressure method (MBPM), respectively, of alkyl polyglucoside (APG) aqueous solution C(9.6)G(1.3). The adsorption equilibrium and kinetics of APG on the air-solution interface were studied. The CMC of APG was determined to be 0. 032 g/L. The above results show that at the start , the adsorption process is controlled by a diffusion step; Then it changes to a barrier control mechanism with a adsorption barrier between 4 and 7 kJ/mol. The effects of temperature, inorganic salts and alcohols on the adsorption equilibrium and kinetics were also discussed. [author_in] => [] Key Laboratory for Colloid, Interface Chem. of State Educ. Min., Shandong University, Jinan 250100, China@@@[] Jinling Res. Inst. Petrochem. I., Nanjing 210046, China@@@[] Department of Chemistry, Shandong Normal University, Jinan 250014, China [publication_type] => J [begin_page] => 1915 [article_dt] => Article [author_en] => Chai, JL; Xu, J; Li, GZ; Zhang, GY; Li, Y; Chen, WJ [volume] => 23 [get_data] => 2018-08-29 [publisher] => HIGHER EDUCATION PRESS [keyword_en] => dynamic surface tension; adsorption equilibrium and kinetics; alkyl; polyglucoside [format_publication_cn] => 112be9cb2f30361719ed2bc572ba4a22192440272 [keyword_plu] => SURFACE-TENSION; GLUCOSIDES [publication_iso] => Chem. J. Chin. Univ.-Chin. [format_title_en] => efe2284190dd119492c409ee1fe7e27a795962246 [publisher_city] => BEIJING [pub_date] => OCT [hx_id] => 2376,2377,2378,2371 [reference_No] => 16 [email] => coliw@sdu.edu.cn [cite_awos] => 12 [wos_No] => WOS:000178758400021 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [check_180] => 0 [publisher_ad] => SHATANHOU ST 55, BEIJING 100009, PEOPLES R CHINA [title_en] => Adsorption equilibrium and kinetics of alkyl polyglucoside on the air/water interface [format_publication_en] => 4eabdd9afe3fe566a165b6e1c3e0dbbd-130083487 [jl_language] => chinese [jl_publication_cn] => 高等学校化学学报 [jl_article_dt] => 期刊论文 [jl_publication_en] => chemicaljournalofchineseuniversitieschinese [jl_country] => 中国,纳米比亚,瑞士,印度 [jl_keyword_en] => alkyl,dynamicsurfacetension,polyglucoside,adsorptionequilibriumandkinetics [jl_keyword_cn] => 表面吸附平衡,动力学,表面活性剂,溶液,烷基聚葡糖苷,动态表面张力 [jl_clc] => o6471 [jl_publisher] => highereducationpress [company_id] => [author_id] => 21993,21994 [author_test] => Array ( [0] => Array ( [sure] => 0 [irmagnum] => 0 [u_index] => 0 [name] => 李英 [irtag] => 7 [t_index] => 0 [person_id] => 21993 ) [1] => Array ( [sure] => 0 [irmagnum] => 0 [u_index] => 0 [name] => 李英 [irtag] => 7 [t_index] => 0 [person_id] => 21994 ) ) [sys_author_id_arr] => 21994李英,24739徐健 [cscd_No] => CSCD:1020998 [jl_publication_cn_publication_en] => 高等学校化学学报,chemicaljournalofchineseuniversitieschinese [jl_keyword_cn_keyword_en] => 表面吸附平衡,polyglucoside,alkyl,dynamicsurfacetension,动力学,烷基聚葡糖苷,溶液,adsorptionequilibriumandkinetics,表面活性剂,动态表面张力 [sys_author_id] => [format_cscd_No] => 679d143c1de36c011cc031609d39df87 [format_title_en_publication_en_pub_year] => 9aad75fd1e8d8ed4a92cdde53e131d82 [format_wos_No] => 924ba33202219e5bd6c5f0ce6d13b1e8 [format_title_en_issn_pub_year] => 69ff2438c3ac8ab6f81a1eaa293102c8 [format_scopus_No] => cd0d3765a3c4ce39b15d8bdb8929d367 [format_ei_No] => e84aa99ab8c78ccb729d82c22c95ca52 [classification_pub] => KTHPD [standard_in] => Key Laboratory for Colloid, Interface Chem. of State Educ. Min., Shandong University, Jinan 250100, China; Department of Chemistry, Shandong Normal University, Jinan 250014, China; Jinling Res. Inst. Petrochem. I., Nanjing 210046, China [ei_No] => 2004057995199 [datebase] => Scopus [page] => 1919-1920 [cite_scopus] => 1 [format_issn_issue_page_pub_year] => c45fe29c8de066766486c263a7b40a93 [sys_priority_field] => 74 [scopus_No] => 2-s2.0-0347269233 [jl_pub_year] => 2002 [jl_author_test] => usureu0,uuindex0,unameuu674eu82f1,utindex0,uirtag7,upersonid21994,upersonid21993,uirmagnum0 [sys_author_jg_last_arr] => 中国 [sys_author_in_last_arr] => china [id] => vgoyvmUBFjIhTVEbXUUb [tags] => 0 ) ) 1-->
81. I+HI(υ=0)→IH(υ′=0)+I体系散射共振态的理论研究 CSCD SCIE

作者:孙孝敏;王华阳;蔡政亭;冯大诚;边文生

作者机构:[孙孝敏] 山东大学理论化学研究所, 济南, 山东 250100, 中国.;[王华阳] 山东大学理论化学研究所, 济南, 山东 250100, 中国.;[蔡政亭] 山东大学理论化学研究所, 济南, 山东 250100, 中国.;[冯大诚] 山东大学理论化学研究所, 济南, 山东 250100, 中国.;[边文生] 中国科学院化学研究所, 分子反应动力学国家重点实验室, 北京 100080, 中国

来源:高等学校化学学报,CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2004,Vol.25,Issue.9,1702-1705

WOS被引数:5

资源类型:期刊论文

WOS:000224014600029

82. 二氟亚烷基卡宾与甲醛环加成反应机理的理论研究 CSCD SCIE

作者:卢秀慧;武卫荣;步宇翔;刘成卜

作者机构:[卢秀慧] 济南大学化学化工学院, 济南, 山东 250002, 中国.;[武卫荣] 济南大学化学化工学院, 济南, 山东 250002, 中国.;[步宇翔] 山东大学理论化学研究所, 济南, 山东 250100, 中国.;[刘成卜] 山东大学理论化学研究所, 济南, 山东 250100, 中国

来源:高等学校化学学报,CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2004,Vol.25,Issue.4,681-684+5

WOS被引数:2

资源类型:期刊论文

WOS:000220774500023

83. Enterococcus durans产胞外多糖EPS-Ⅰ的分离纯化和结构分析 CSCD SCIE

作者:顾笑梅,吴厚铭,马桂荣

作者机构:[顾笑梅] 山东大学生命科学院, 微生物技术国家重点实验室, 济南, 山东 250100, 中国.;[马桂荣] 山东大学生命科学院, 微生物技术国家重点实验室, 济南, 山东 250100, 中国.;[吴厚铭] 中国科学院上海有机化学研究所, 生命有机化学国家重点实验室, 上海 200032, 中国

来源:高等学校化学学报,CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2004,Vol.25,Issue.7,1288-1290

WOS被引数:4

资源类型:期刊论文

WOS:000222906300025

84. 助表面活性剂对介孔二氧化硅孔径的影响 CSCD SCIE

作者:韩书华;侯万国;许军;李正民

作者机构:[韩书华] 山东大学, 胶体与界面化学教育部重点实验室, 济南, 山东 250100, 中国.;[侯万国] 山东大学, 胶体与界面化学教育部重点实验室, 济南, 山东 250100, 中国.;[许军] 山东大学, 胶体与界面化学教育部重点实验室, 济南, 山东 250100, 中国.;[李正民] 山东大学化学学院, 济南, 山东 250100, 中国

来源:高等学校化学学报,CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2004,Vol.25,Issue.3,509-511+391

WOS被引数:2

资源类型:期刊论文

WOS:000220526000029

85. 端基含己氧基偶氮苯基元的一代光致变色液晶碳硅烷树状物的光响应行为研究 CSCD SCIE

作者:张其震;刘建强;殷晓颖;张静智

作者机构:[张其震] 山东大学化学化工学院, 济南, 山东 250100, 中国.;[刘建强] 山东大学化学化工学院, 济南, 山东 250100, 中国.;[殷晓颖] 山东大学化学化工学院, 济南, 山东 250100, 中国.;[张静智] 山东大学化学化工学院, 济南, 山东 250100, 中国

来源:高等学校化学学报,CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2004,Vol.25,Issue.7,1368-1372

WOS被引数:11

资源类型:期刊论文

WOS:000222906300045

86. 水热条件对立方状Co_3O_4形貌的影响 CSCD SCIE

作者:张卫民,宋新宇,李大枝,俞海云,孙思修

作者机构:[张卫民] 山东大学化学与化工学院, 济南, 山东 250100, 中国.;[宋新宇] 山东大学化学与化工学院, 济南, 山东 250100, 中国.;[李大枝] 山东大学化学与化工学院, 济南, 山东 250100, 中国.;[俞海云] 山东大学化学与化工学院, 济南, 山东 250100, 中国.;[孙思修] 山东大学化学与化工学院, 济南, 山东 250100, 中国

来源:高等学校化学学报,CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2004,Vol.25,Issue.5,797-801

WOS被引数:14

资源类型:期刊论文

WOS:000221514700002

87. 利用双光子聚合技术制备的聚合物型光栅光波导和耦合光栅 CSCD SCIE

作者:于晓强 [1];张献 [1];许贵宝 [1];赵华平 [1];何畏 [1];邵宗书 [1];蒋民华 [1];孙渝明 [2];刘恩泉 [2]

作者机构:[于晓强] 山东大学, 晶体材料国家重点实验室,中国.;[张献] 山东大学, 晶体材料国家重点实验室,中国.;[许贵宝] 山东大学, 晶体材料国家重点实验室,中国.;[赵华平] 山东大学, 晶体材料国家重点实验室,中国.;[何畏] 山东大学, 晶体材料国家重点实验室,中国.;[邵宗书] 山东大学, 晶体材料国家重点实验室,中国.;[蒋民华] 山东大学, 晶体材料国家重点实验室,中国.;[孙渝明] 山东大学信息科学与工程学院, 济南, 山东 250100, 中国.;[刘恩泉] 山东大学信息科学与工程学院, 济南, 山东 250100, 中国

来源:高等学校化学学报,CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2004,Vol.25,Issue.10

WOS被引数:3

资源类型:期刊论文

WOS:000224628000039

88. 端基含12个己氧基偶氮苯介晶基元的树状碳硅烷液晶的合成 CSCD SCIE

作者:张其震[1];刘建强[1];殷晓颖[1];张静智[1];李光[2];赵晓光[2];季怡萍[2]

作者机构:[张其震] 山东大学化学化工学院, 济南, 山东 250100, 中国.;[刘建强] 山东大学化学化工学院, 济南, 山东 250100, 中国.;[殷晓颖] 山东大学化学化工学院, 济南, 山东 250100, 中国.;[张静智] 山东大学化学化工学院, 济南, 山东 250100, 中国.;[李光] 中国科学院长春应用化学研究所, 长春, 吉林 130022, 中国.;[赵晓光] 中国科学院长春应用化学研究所, 长春, 吉林 130022, 中国.;[季怡萍] 中国科学院长春应用化学研究所, 长春, 吉林 130022, 中国

来源:高等学校化学学报,CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2003,Vol.24,Issue.10

WOS被引数:12

资源类型:期刊论文

WOS:000186135000041

89. 二代树状碳硅烷液晶研究——端基含36个己氧基偶氮苯介晶基元 EI CSCD SCOPUS SCIE

作者:张其震,刘建强,殷晓颖,张静智,赵晓光,李光,季怡萍

作者机构:[张其震,刘建强,殷晓颖,张静智,赵晓光,李光,季怡萍]山东大学化学化工学院,山东大学化学化工学院,山东大学化学化工学院,山东大学化学化工学院,中国科学院长春应用化学研究所,中国科学院长春应用化学研究所,中国科学院长春应用化学研究所 济南 250100,济南 250100,济南 250100,济南 250100,长春 130022,长春 130022,长春 130022

来源:高等学校化学学报,CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2003,Vol.24,Issue.9,1704-1707

WOS被引数:12

资源类型:期刊论文

WOS:000186134800041

90. 聚合物PVP与表面活性剂AOT相互作用的介观模拟 CSCD SCIE

作者:苑世领,刘成卜,徐桂英,蔡政亭

作者机构:[苑世领] 山东大学理论化学研究所, 济南, 山东 250100, 中国.;[刘成卜] 山东大学理论化学研究所, 济南, 山东 250100, 中国.;[蔡政亭] 山东大学理论化学研究所, 济南, 山东 250100, 中国.;[徐桂英] 山东大学, 胶体与界面化学教育部重点实验室, 济南, 山东 250100, 中国

来源:高等学校化学学报,CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2003,Vol.24,Issue.6,1048-1051

WOS被引数:11

资源类型:期刊论文

WOS:000183863200027

91. 水热-固相热解法制备不同形貌的四氧化三钴纳米微粉 CSCD SCIE

作者:张卫民;孙思修;俞海云;宋新宇

作者机构:[张卫民] 山东大学化学与化工学院, 济南, 山东 250100, 中国.;[孙思修] 山东大学化学与化工学院, 济南, 山东 250100, 中国.;[俞海云] 山东大学化学与化工学院, 济南, 山东 250100, 中国.;[宋新宇] 山东大学化学与化工学院, 济南, 山东 250100, 中国

来源:高等学校化学学报,CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2003,Vol.24,Issue.12

WOS被引数:7

资源类型:期刊论文

WOS:000187660500004

92. 带相反电荷胶体颗粒混和悬浮体的流变学性能 CSCD SCIE

作者:郭培志;孙德军;金志琳;张春光

作者机构:[郭培志] 山东大学胶体与界面化学研究所, 胶体与界面化学教育部重点实验室, 济南, 山东 250100, 中国.;[孙德军] 山东大学胶体与界面化学研究所, 胶体与界面化学教育部重点实验室, 济南, 山东 250100, 中国.;[金志琳] 山东大学胶体与界面化学研究所, 胶体与界面化学教育部重点实验室, 济南, 山东 250100, 中国.;[张春光] 山东大学胶体与界面化学研究所, 胶体与界面化学教育部重点实验室, 济南, 山东 250100, 中国

来源:高等学校化学学报,CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2003,Vol.24,Issue.6,1052-1055

资源类型:期刊论文

WOS:000183863200028

93. 降凝剂对蜡油中蜡析出与溶解影响的物理化学研究 CSCD SCIE

作者:李传宪;张春光;孙德军;孙洁

作者机构:[李传宪] 山东大学, 胶体与界面化学教育部重点实验室, 济南, 山东 250100, 中国.;[张春光] 山东大学, 胶体与界面化学教育部重点实验室, 济南, 山东 250100, 中国.;[孙德军] 山东大学, 胶体与界面化学教育部重点实验室, 济南, 山东 250100, 中国.;[孙洁] 石油大学(华东), 东营, 山东 257061, 中国

来源:高等学校化学学报,CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2003,Vol.24,Issue.8,1451-1455

WOS被引数:5

资源类型:期刊论文

WOS:000184995100028

94. P(St-co-MAA)乳液体系对CaCO_3结晶的调控 CSCD SCIE

作者:陈亚坤,赵莹,王笃金,徐怡庄,沈强,王家君,郑爱国,吴瑾光,徐端夫

作者机构:[陈亚坤] 中国科学院化学研究所分子科学中心, 高分子物理与化学国家重点实验室, 北京 100080, 中国.;[赵莹] 中国科学院化学研究所分子科学中心, 高分子物理与化学国家重点实验室, 北京 100080, 中国.;[王笃金] 中国科学院化学研究所分子科学中心, 高分子物理与化学国家重点实验室, 北京 100080, 中国.;[王家君] 中国科学院化学研究所分子科学中心, 高分子物理与化学国家重点实验室, 北京 100080, 中国.;[郑爱国] 中国科学院化学研究所分子科学中心, 高分子物理与化学国家重点实验室, 北京 100080, 中国.;[徐端夫] 中国科学院化学研究所分子科学中心, 高分子物理与化学国家重点实验室, 北京 100080, 中国.;[徐怡庄] 北京大学化学与分子工程学院, 稀土材料化学及应用国家重点实验室, 北京 250100, 中国.;[吴瑾光] 北京大学化学与分子工程学院, 稀土材料化学及应用国家重点实验室, 北京 250100, 中国.;[沈强] 山东大学, 胶体界面化学教育部重点实验室, 济南, 山东 250100, 中国

来源:高等学校化学学报,CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2003,Vol.24,Issue.2,332-334

WOS被引数:1

资源类型:期刊论文

WOS:000182543000034

95. Schiff碱N-aete-N在Au(111)上自组装单分子膜的电化学及STM研究 SCOPUS CSCD SCOPUS SCIE

作者:孔德生,陈慎豪,万立骏,雷圣宾

作者机构:[孔德生] 山东大学化学与化工学院, 济南, 山东 250100, 中国.;[陈慎豪] 山东大学化学, 250100.;[万立骏] 中国科学院化学研究所, 北京 100080, 中国.;[雷圣宾] 中国科学院化学研究所, 北京 100080, 中国

来源:高等学校化学学报,CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2003,Vol.24,Issue.10,1847-1851

WOS被引数:3

资源类型:期刊论文

WOS:000186135000030

96. (NO)_2~+复合物阳离子的结构和性质研究 SCIE

作者:孙立祥,步宇翔,陈志达

作者机构:[孙立祥,步宇翔,陈志达]曲阜师范大学化学系,曲阜师范大学化学系,北京大学稀土化学及应用国家重点实验室 曲阜273165,曲阜273165,山东大学理论化学研究所,济南250100,北京大学稀土化学及应用国家重点实验室,北京100871,北京100871

来源:高等学校化学学报,CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2003,Vol.24,Issue.1,113-116

资源类型:期刊论文

WOS:000182666400032

97. 准线型四原子分子高激发振动能级的动力学李代数方法 CSCD SCIE

作者:冯东太;丁世良;王美山

作者机构:[冯东太] 山东大学物理与微电子学院,化学学院, 济南, 山东 250100, 中国.;[丁世良] 山东大学物理与微电子学院,化学学院, 济南, 山东 250100, 中国.;[王美山] 山东大学物理与微电子学院,化学学院, 济南, 山东 250100, 中国

来源:高等学校化学学报,CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2003,Vol.24,Issue.7,1299-1301

资源类型:期刊论文

WOS:000184356400041

98. F+CH_2CO的反应机理和动力学研究 CSCD SCOPUS SCIE

作者:侯华,王少坤,王宝山,顾月姝

作者机构:[侯华] 山东大学化学与化工学院, 济南, 山东 250100, 中国.;[王少坤] 山东大学化学与化工学院, 济南, 山东 250100, 中国.;[王宝山] 山东大学化学与化工学院, 济南, 山东 250100, 中国.;[顾月姝] 山东大学化学与化工学院, 济南, 山东 250100, 中国

来源:高等学校化学学报,CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2002,Vol.23,Issue.6,1131-1134

WOS被引数:3

资源类型:期刊论文

WOS:000176272300039

99. 伯胺N1923萃取体系反胶束的形成研究 CSCD SCOPUS SCIE

作者:宋新宇,印志磊,张卫民,俞海云,孙思修

作者机构:[宋新宇] 山东大学化学与化工学院, 济南, 山东 250100, 中国.;[印志磊] 山东大学化学与化工学院, 济南, 山东 250100, 中国.;[张卫民] 山东大学化学与化工学院, 济南, 山东 250100, 中国.;[俞海云] 山东大学化学与化工学院, 济南, 山东 250100, 中国.;[孙思修] 山东大学化学与化工学院, 济南, 山东 250100, 中国

来源:高等学校化学学报,CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2002,Vol.23,Issue.6,1177-1179

WOS被引数:2

资源类型:期刊论文

WOS:000176272300051

100. 烷基聚葡糖苷溶液的表面吸附平衡与动力学 EI CSCD SCOPUS SCIE

作者:柴金岭[1];徐军[2];等

作者机构:[柴金岭] 山东大学, 胶体与界面化学教育部重点实验室, 济南, 山东 250100, 中国.;[李干佐] 山东大学, 胶体与界面化学教育部重点实验室, 济南, 山东 250100, 中国.;[张高勇] 山东大学, 胶体与界面化学教育部重点实验室, 济南, 山东 250100, 中国.;[李英] 山东大学, 胶体与界面化学教育部重点实验室, 济南, 山东 250100, 中国.;[陈文君] 山东大学, 胶体与界面化学教育部重点实验室, 济南, 山东 250100, 中国.;[徐军] 中国石油化工集团金陵石油化工研究院, 南京, 江苏 210046, 中国

来源:高等学校化学学报,CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2002,Vol.23,Issue.10,1919-1920

WOS被引数:7

资源类型:期刊论文

WOS:000178758400021

共 9 页, 168 条记录

TOP