标题:A two-dimensional silver-iodide organic network constructed from a unique [Ag6I6] hexagonal prism-based one-dimensional column motif
作者:Yuan, Shuai ;Liu, Shan-Shan ;Lu, Hai-Feng ;Xu, Meng-Zhen ;Sun, Di
作者机构:[Yuan, Shuai ;Liu, Shan-Shan ;Lu, Hai-Feng ;Xu, Meng-Zhen ;Sun, Di ] Key Laboratory of Special Functional Aggregated Materials, School of Chemistry an 更多
通讯作者:Sun, D
来源:Acta Crystallographica Section C: Crystal Structure Communications
出版年:2013
卷:69
期:3
页码:216-218
DOI:10.1107/S0108270113002916
摘要:A novel two-dimensional coordination polymer, poly[[μ2-1,3-bis(2-methyl- 1H-imidazol-1-yl)propane]di-μ4-iodido-di-μ3-iodido-silver(I)], [Ag4I4(C11H16N4)] n , (I), has been synthesized by solvothermal reaction of AgNO3, KI and 1,3-bis(2-methyl-1H-imidazol-1-yl)propane (bmimp). In (I), the two unique AgIcations have AgNI3 and AgI4 four-coordinated tetrahedral geometries. The bmimp ligand has imposed twofold symmetry. The AgIcations and iodide anions form a unique one-dimensional polymeric column motif incorporating [Ag6I6] hexagonal prisms, which are then connected by bmimp ligands to form two-dimensional organic-inorganic layers. The layers are arranged in parallel in an ABAB fashion and are packed into the resultant three-dimensional supramolecular framework by van der Waals interactions. Copyright © 2013 International Union of Crystallography.
收录类别:EI
资源类型:期刊论文
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