标题：A two-dimensional silver-iodide organic network constructed from a unique [Ag6I6] hexagonal prism-based one-dimensional column motif
作者：Yuan, Shuai ;Liu, Shan-Shan ;Lu, Hai-Feng ;Xu, Meng-Zhen ;Sun, Di
作者机构：[Yuan, Shuai ;Liu, Shan-Shan ;Lu, Hai-Feng ;Xu, Meng-Zhen ;Sun, Di ] Key Laboratory of Special Functional Aggregated Materials, School of Chemistry an 更多
来源：Acta Crystallographica Section C: Crystal Structure Communications
摘要：A novel two-dimensional coordination polymer, poly[[μ2-1,3-bis(2-methyl- 1H-imidazol-1-yl)propane]di-μ4-iodido-di-μ3-iodido-silver(I)], [Ag4I4(C11H16N4)] n , (I), has been synthesized by solvothermal reaction of AgNO3, KI and 1,3-bis(2-methyl-1H-imidazol-1-yl)propane (bmimp). In (I), the two unique AgIcations have AgNI3 and AgI4 four-coordinated tetrahedral geometries. The bmimp ligand has imposed twofold symmetry. The AgIcations and iodide anions form a unique one-dimensional polymeric column motif incorporating [Ag6I6] hexagonal prisms, which are then connected by bmimp ligands to form two-dimensional organic-inorganic layers. The layers are arranged in parallel in an ABAB fashion and are packed into the resultant three-dimensional supramolecular framework by van der Waals interactions. Copyright © 2013 International Union of Crystallography.