标题:A copper-based sorbent with oxygen-vacancy defects from mechanochemical reduction for carbon disulfide absorption
作者:Chen, Haipeng; Zhou, Shixue; Han, Zongying; Jiang, Yaoyao; Yu, Hao; Zhou, Xinpei; Jiang, Ruiqian; Liu, Xiaojing; Li, Xinyuan
作者机构:[Chen, Haipeng; Zhou, Shixue; Han, Zongying; Yu, Hao; Zhou, Xinpei; Jiang, Ruiqian; Liu, Xiaojing; Li, Xinyuan] Shandong Univ Sci & Technol, Coll Chem 更多
通讯作者:Zhou, Shixue
通讯作者地址:[Chen, HP]Shandong Univ Sci & Technol, Coll Chem & Environm Engn, Qingdao 266590, Peoples R China;[Chen, HP]Shandong Univ Sci & Technol, State Key Lab 更多
来源:JOURNAL OF MATERIALS CHEMISTRY A
出版年:2016
卷:4
期:43
页码:17207-17214
DOI:10.1039/c6ta07134a
摘要:This work innovatively provides an efficient method to prepare a Cu-based sorbent with oxygen-vacancy (O-vac) defects via mechanochemical reduction of CuO for CS2 absorption. Crystalline structures based on XRD measurement show that mechanical force can lead to CuO reduction and O-vac defect generation during ball milling of CuO with Mg as a reducing agent. Sulfur content measurement shows that the prepared Cu-based sorbent with O-vac defects can realize efficient CS2 absorption at 150 degrees C with a breakthrough sulfur capacity of 10.7 wt%. Electronic structures based on first-principles calculation show that the O-vac defects can decrease copper coordination, increase the surface energy and electron density, and reduce the band gap by forming coordinatively unsaturated Cu, which benefit the chemisorption of CS2 molecules. Cu2O with O-vac defects, the main phase for CS2 absorption in the sorbent, can grab CS2 molecules by the trapping effect of its O-vac defects with a chemisorption distance of 1.53 angstrom and an energy of -110.45 kJ mol(-1), and offer electrons for breaking C-S bonds. This work paves a new pathway for the preparation of Cu-based sorbents with high performance for sulfur compound absorption.
收录类别:EI;SCIE
WOS核心被引频次:3
资源类型:期刊论文
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