标题:Electrochemical simultaneous determination of nitrophenol isomers at nano-gold modified glassy carbon electrode
作者:Chu, L.;Han, L.;Zhang, X.
作者机构:[Chu, L] School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China;[ Han, L] School of Chemistry and Chemical Engineering 更多
通讯作者:Zhang, X
通讯作者地址:[Zhang, XL]Shandong Univ, Sch Chem & Chem Engn, Jinan 250100, Peoples R China.
来源:Journal of Applied Electrochemistry
出版年:2011
卷:41
期:6
页码:687-694
DOI:10.1007/s10800-011-0281-4
关键词:Nano-gold-modified electrode;Nitrophenol isomers;Simultaneous determination;Voltammetry
摘要:A novel method for simultaneous determination of nitrophenol isomers at nano-gold modified glassy carbon electrode has been developed. The gold nanoparticles were directly electrodeposited onto the glassy carbon electrode via a constant potential -0.2 V (vs. SCE) for 60 s from 0.1 mol L~(-1) KNO_3 containing 0.4 g L~(-1) HAuCl_4. The resulting electrode (nano-Au/GCE) was characterized with scanning electron microscopy (SEM). The electrochemistry response of nitrophenol isomers at the nano-Au/GCE was studied. The result indicated that o-, m-, and p- nitrophenol are separated entirely at nano-Au/GCE, and a semi-derivative voltammetric technology was adopted to enhance the determination sensitivity. This modified electrode could be applied to direct simultaneous voltammetric determination of nitrophenol isomers in water samples without preseparation with higher sensitivity.
收录类别:EI;SCOPUS;SCIE
WOS核心被引频次:74
Scopus被引频次:76
资源类型:期刊论文
原文链接:https://www.scopus.com/inward/record.uri?eid=2-s2.0-79958782932&doi=10.1007%2fs10800-011-0281-4&partnerID=40&md5=b35c76b2daa41b7dfecec4d4927cae92
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