标题:Synthesis of silyl iron hydride via Si-H activation and its dual catalytic application in the hydrosilylation of carbonyl compounds and dehydration of benzamides
作者:Ren, Shishuai; Xie, Shangqing; Zheng, Tingting; Wang, Yangyang; Xu, Shilu; Xue, Benjing; Li, Xiaoyan; Sun, Hongjian; Fuhr, Olaf; Fen 更多
作者机构:[Ren, Shishuai; Xie, Shangqing; Zheng, Tingting; Wang, Yangyang; Xu, Shilu; Xue, Benjing; Li, Xiaoyan; Sun, Hongjian] Shandong Univ, Minist Educ, Key 更多
通讯作者:Sun, Hongjian
通讯作者地址:[Sun, HJ]Shandong Univ, Minist Educ, Key Lab Special Funct Aggregated Mat, Sch Chem & Chem Engn, Shanda Nanlu 27, Jinan 250199, Shandong, Peoples R Ch 更多
来源:DALTON TRANSACTIONS
出版年:2018
卷:47
期:12
页码:4352-4359
DOI:10.1039/c8dt00289d
摘要:The hydrido silyl iron complex (o-Ph2PC6H4SiMe2)Fe(PMe3)(3)H (2) was obtained via the activation of the Si-H bond of the bidentate silyl ligand o-Ph2P(C6H4)SiMe2H (1) by Fe(PMe3)(4). 2 showed good to excellent catalytic activity in both the reduction of aldehydes/ketones and the dehydration of benzamide. In addition, with complex 2 as a catalyst, ,-unsaturated carbonyls could be selectively reduced to the corresponding ,-unsaturated alcohols. The mechanisms of the formation of 2 and the catalytic dehydration process are proposed and partly experimentally verified.
收录类别:EI;SCOPUS;SCIE
资源类型:期刊论文
原文链接:https://www.scopus.com/inward/record.uri?eid=2-s2.0-85044239778&doi=10.1039%2fc8dt00289d&partnerID=40&md5=b54416c73601362d365f71d1df138add
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