标题:Catalytic Enantioselective Oxidative Cross-Coupling of Benzylic Ethers with Aldehydes
作者:Zhilin Meng;Shutao Sun;Huiqing Yuan
作者机构:[Meng, Z] Department of Natural Products Chemistry, Key Lab of Chemical Biology of Ministry of Education, Shandong University, Jinan 250012, China;[ S 更多
通讯作者:Lou, H
通讯作者地址:[Lou, HX]Shandong Univ, Sch Pharmaceut Sci, Dept Nat Prod Chem, Key Lab Chem Biol,Minist Educ, Jinan 250012, Peoples R China.
来源:Angewandte Chemie
出版年:2014
卷:53
期:2
页码:543-547
DOI:10.1002/anie.201308701
关键词:aldehydes;asymmetric catalysis;benzylic ethers;C—H functionalization;organocatalysis
摘要:The first one-pot enantioselective oxidative coupling of cyclic benzylic ethers with aldehydes has been developed. A variety of benzylic ethers were transformed into the corresponding oxygen heterocycles with high enantioselcctivity. Mechanistic experiments were conducted 10 determine the nature of the reaction intermediates. The application of this strategy to coupling reactions with other nuclcophilcs besides aldehydes was also explored.
收录类别:EI;SCOPUS;SCIE
WOS核心被引频次:84
Scopus被引频次:83
资源类型:期刊论文
原文链接:https://www.scopus.com/inward/record.uri?eid=2-s2.0-84891795019&doi=10.1002%2fanie.201308701&partnerID=40&md5=eafdbd6e37a9a8cc79f7105ae1b90282
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