标题:Poly(bis(2,2\'-bipyridine-kappa(2)N,N\')bis(mu(6)-2,4,6-trimethylbenzene-1,3,5-tric arboxylato)tricadmium(II)), a two-dimensional \'Kagome dual\' (kgd) sheet structure.
作者:Guo J;Zhang LL;He HY;Li XW;Sun D
作者机构:[Guo, J] School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China;[ Zhang, L.-L] School of Chemistry and Chemical Engine 更多
通讯作者:Sun, D
来源:Acta Crystallographica. Sect.C, Section C. Crystal Structure Communications
出版年:2011
卷:67
期:12
页码:m387-m390
DOI:10.1107/S0108270111048591
摘要:The title metal-organic framework, [Cd(3)(C(12)H(9)O(6))(2)(C(10)H(8)N(2))(2)](n), has been synthesized by a solvothermal reaction. The Cd(II) ions are located in CdO(4)N(2) and CdO(6) six-coordinated environments, with the latter Cd(II) ion lying on an inversion centre. The 2,4,6-trimethylbenzene-1,3,5-tricarboxylate ligand (TMBTC) connects the Cd(II) ions to form a two-dimensional sheet incorporating hourglass-like [Cd(3)(COO)(6)] secondary building units (SBUs). Topologically, taking the TMBTC ligand and the [Cd(3)(COO)(6)] SBU as 3- and 6-connected nodes, respectively, the overall two-dimensional sheet can be simplified to a rare (3,6)-connected 2-nodal kgd (Kagome dual) net with a short Schlafli vertex notation of {4(3)}(2){4(6).6(6).8(3)}, which further stacks into a three-dimensional supramolecular framework through pi-pi stacking interactions.
收录类别:EI;SCOPUS
Scopus被引频次:1
资源类型:期刊论文
原文链接:https://www.scopus.com/inward/record.uri?eid=2-s2.0-82955239885&doi=10.1107%2fS0108270111048591&partnerID=40&md5=708b75fcea704f55ba83cc10bddc0d9b
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