标题：Palladium-catalyzed three-component reaction of N-tosylhydrazone, norbornene and aryl halide
作者：Fangdong Hu;Ying Xia;Zhenxing Liu;Chen Ma;Yan Zhang;Jianbo Wang
作者机构：[Hu, F] School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China, Beijing National Laboratory of Molecular Sciences (BNL 更多[Hu, F] School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China, Beijing National Laboratory of Molecular Sciences (BNLMS), College of Chemistry, Peking University, Beijing 100871, China;[ Xia, Y] Beijing National Laboratory of Molecular Sciences (BNLMS), College of Chemistry, Peking University, Beijing 100871, China;[ Liu, Z] Beijing National Laboratory of Molecular Sciences (BNLMS), College of Chemistry, Peking University, Beijing 100871, China;[ Ma, C] School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China;[ Zhang, Y] Beijing National Laboratory of Molecular Sciences (BNLMS), College of Chemistry, Peking University, Beijing 100871, China;[ Wang, J] Beijing National Laboratory of Molecular Sciences (BNLMS), College of Chemistry, Peking University, Beijing 100871, China 收起
摘要：A palladium-catalyzed three-component reaction of N-tosylhydrazone, norbornene and aryl halide has been demonstrated. In this reaction, an intermolecular Heck-type reaction occurs, which is followed by the alkyl palladium carbene migratory insertion process. This transformation provides an efficient and convenient methodology for the double functionalization of norbornene with good to excellent yields.
