标题:Two carboxylic ligands controlled coordination polymers based on Cd-II ion
作者:Liu, Ruichao; Liu, Jie; Zhang, Jian; Yan, Xiangzhen; Yuan, Chunxue
作者机构:[Liu, Ruichao; Yuan, Chunxue] Tongji Univ, Coll Mat Sci & Engn, Caoan Rd 4800, Shanghai 201804, Peoples R China.; [Liu, Jie; Zhang, Jian] Shandong U 更多
通讯作者:Yuan, CX
通讯作者地址:[Yuan, CX]Tongji Univ, Coll Mat Sci & Engn, Caoan Rd 4800, Shanghai 201804, Peoples R China.
来源:JOURNAL OF MOLECULAR STRUCTURE
出版年:2018
卷:1164
页码:45-49
DOI:10.1016/j.molstruc.2018.03.036
关键词:Coordination polymers; Crystal structure; Cd-II
摘要:Two new coordination polymers {Cd(BPDC)center dot H2O}(n) (1) and {Cd(BTC)center dot 2H(2)O)(n) (2) (H2BPDC = 4,4'-biphenyl dicarboxylic acid; H3BTC = 1,3,5 -benzene tricarboxylic acid) based on different organic ligands with Cdli ion were synthesized under hydrothermal/solvothermal conditions. The compounds were characterized by single crystal diffraction, infrared spectroscopy, elemental analysis and PXRD. Crystal structure analysis indicates that the coordination environment of Cd-II in these two compounds are completely different that the Cd-II ion is six coordination number in compound 1 and seven coordination in compound 2. Furthermore, thermal stabilities for 1 and 2 were also discussed in detail. (C) 2018 Elsevier B.V. All rights reserved.
收录类别:SCOPUS;SCIE
资源类型:期刊论文
原文链接:https://www.scopus.com/inward/record.uri?eid=2-s2.0-85046006146&doi=10.1016%2fj.molstruc.2018.03.036&partnerID=40&md5=ee1d16882ed9e2b27949e940fd8074b9
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