标题:Synthesis, Crystal Structures and Physicochemical Properties of Poly[bis(N,N-Dimethylformamide)tetra(thiocyanato)metal(II) Mercury(II)] (Metal = Cadmium and Manganese)
作者:Wang, XQ;Zhu, LY;Fan, JD;Yu, WT;Yu, G;Xu, D
作者机构:[Wang, X.Q] State Key Laboratory of Crystal Materials, Institute of Crystal Materials, Shandong University, Jinan 250100, China;[ Zhu, L.Y] State Key 更多
通讯作者:Wang, XQ
通讯作者地址:[Wang, XQ]Shandong Univ, State Key Lab Crystal Mat, Jinan 250100, Peoples R China.
来源:Journal of chemical crystallography
出版年:2010
卷:40
期:2
页码:93-99
DOI:10.1007/s10870-009-9607-z
关键词:Synthesis;Structures;Cadmium
摘要:Two novel single crystals, poly[bis(N,N-dimethylformamide)tetra(thiocyanato)metal(II)mercury(II)] (metal = cadmium and manganese, abbreviated as DTCM and DTMM, respectively) were prepared. The characterizations of DTCM and DTMM were performed by elemental analyses, infrared, X-ray single crystal diffraction. The two title complexes crystallized in the same monoclinic crystallographic system and P2(1)/n space group with unit cell parameters: a = 9.2515(2) a\"<<, b = 14.1670(3) a\"<<, c = 16.5898(3) a\"<<, beta = 93.0320(10)A degrees, z = 4, D (x) = 2.115 g/cm(3) for DTCM, and a = 9.24580(10) a\"<<, b = 14.1110(2) a\"<<, c = 16.4937(2) a\"<<, beta = 92.9120(10)A degrees, z = 4, D (x) = 1.960 g/cm(3) for DTMM, respectively. The two structures are isostructural. The thermal decomposition processes of the two crystals were investigated by means of thermogravimetric analysis and differential thermal analysis measurements in air.
收录类别:SCOPUS;SCIE
WOS核心被引频次:2
Scopus被引频次:2
资源类型:期刊论文
原文链接:https://www.scopus.com/inward/record.uri?eid=2-s2.0-77951258332&doi=10.1007%2fs10870-009-9607-z&partnerID=40&md5=21df1f47c9f6cbeadf6faa58a32500f5
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