标题：Polyoxometalate as effective catalyst for the deep desulfurization of diesel oil
作者：Wang, Rui; Zhang, Gaofei; Zhao, Haixia
作者机构：[Wang, Rui; Zhang, Gaofei; Zhao, Haixia] Shandong Univ, Sch Environm Sci & Engn, Jinan 250100, Peoples R China.
会议名称：International Symposium on Catalysis
会议日期：JUL 21-24, 2008
关键词：Oxidative desulfurization; Hydrogen peroxide; Polyoxometalate
摘要：Aiming at the deep desulfurization of the diesel oil. a comparison of the catalytic effects of several Keggin type POMs, including H(3)PW(x)Mo(12-x)O(40)(x = 1. 3. 6), Cs(2.5)H(0.5)PW(12)O(40), and H(3)PW(12)O(40), was made, using the solution of DBT in normal octane as simulated diesel oil, H(2)O(2) as oxidant, and acetonitrile as extractant. H(3)PW(6)Mo(6)O(40) was found to be the best catalyst, with a desulfurization efficiency of 99.79% or higher Hence, it is promising for the deep desulfurization of actual ODS process. The role of the main factors affecting the process including temperature, O/S molar ratio, initial sulfur concentration, and catalyst dosage. was investigated, whereby the favourable operating conditions were recommended as T = 60 degrees C, O/S = 15, and a catalyst dosage of 6.93 g (H(3)PW(6)Mo(6)O(40))/L (simulated diesel) With the aid of GC-MS analysis. sulfone species was confirmed to be the only product after reaction for 150 min Furthermore. macro-kinetics of the process catalyzed by H(3)PW(6)Mo(6)O(40) was studied, from which the reaction orders were found to be 1.02 to DBT and 0 38 to H(2)O(2), and the activation energy of the reaction was found to be 43.3 kJ/mol. Moreover, the catalyst recovered demonstrated almost the same activity as the fresh (C) 2009 Elsevier B.V. All rights reserved.