标题：Alkylboronate Synthesis Based on Transition Metal-Catalyzed Hydroboration
作者：Huang, Saipeng; Xie, Yuanchao; Wu, Shaolei; Jia, Meirong; Wang, Junhua; Xu, Wenfeng; Fang, Hao
作者机构：[Huang, Saipeng; Xie, Yuanchao; Wu, Shaolei; Jia, Meirong; Wang, Junhua; Xu, Wenfeng; Fang, Hao] Shandong Univ, Sch Pharmaceut Sci, Dept Med Chem, Jin 更多
通讯作者地址：[Fang, H]Shandong Univ, Sch Pharmaceut Sci, Dept Med Chem, Jinan 250012, Shandong, Peoples R China.
来源：CURRENT ORGANIC SYNTHESIS
关键词：Alkylboronate; alkylboronic derivatives; catalyst; hydroboration;; transition metal
摘要：Alkylboronate derivatives are important intermediates in organic synthesis and medicinal chemistry. The research of synthesizing alkylboronic acid derivatives has attracted great attention of chemists and many papers have reported various methods for preparing alkylboronates based on transition-metal-catalyzed hydroboration. In this review, we summarize the methods of synthesizing alkylboronate derivatives with different catalysts, such as Rhodium, Palladium, Copper, Iridium, Iron, Magnesiu, Platinum, Nickel and so on. Pinacolborane, bispinacolatodiboron and catecholborane are applied as important reagents and substrates with different skeleton structures and functional groups are employed to prepare diversity of alkylboronates.