标题:{1,3-Bis[(diphenylphosphanyl-κP)-oxy]prop-2-yl-κC 2}iodido(trimethyl-phosphane)cobalt(II)
作者:Xu G.; Li X.
作者机构:[Xu, G] School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China;[ Li, X] School of Chemistry and Chemical Engineering, 更多
通讯作者:Li, X(xli63@sdu.edu.cn)
通讯作者地址:[Li, X] School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China;
来源:Acta Crystallographica Section E: Structure Reports Online
出版年:2010
卷:66
期:5
DOI:10.1107/S1600536810013747
摘要:The title compound, [Co(C27H25O2P 2)I(C3H9P)], was synthesized by the addition of 1-iodo-butane to a solution of the parent cobalt complex {1,3-bis-[(diphenyl- phosphanyl)-oxy]prop-2-yl}bis-(trimethyl-phosphane)cobalt(II). Two five-membered cobaltocycles with considerable ring bending (sum of internal angles = 516.4 and 517.7°) are formed through two P atoms of the PPh2 groups and a metallated Csp 3 atom. The CoII atom is centered in a trigonal-bipyramidal configuration. © 2010.
收录类别:SCOPUS
资源类型:期刊论文
原文链接:https://www.scopus.com/inward/record.uri?eid=2-s2.0-77952023597&doi=10.1107%2fS1600536810013747&partnerID=40&md5=90a50966d870401aa8a85fa084e4da62
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