标题:Truncated cobalt hexacyanoferrate nanocubes threaded by carbon nanotubes as a high-capacity and high-rate cathode material for dual-ion rechargable aqueous batteries
作者:Zhang, Dapeng; Yang, Zengxu; Zhang, Junshu; Mao, Hongzhi; Yang, Jian; Qian, Yitai
作者机构:[Zhang, Dapeng; Yang, Zengxu; Zhang, Junshu; Mao, Hongzhi; Yang, Jian; Qian, Yitai] Shandong Univ, Sch Chem & Chem Engn, State Educ Minist, Key Lab Co 更多
通讯作者:Yang, Jian;Yang, J
通讯作者地址:[Yang, J]Shandong Univ, Sch Chem & Chem Engn, State Educ Minist, Key Lab Colloid & Interface Chem, Jinan 250100, Shandong, Peoples R China.
来源:JOURNAL OF POWER SOURCES
出版年:2018
卷:399
页码:1-7
DOI:10.1016/j.jpowsour.2018.07.084
关键词:Prussian blue; Carbon nanotubes; Nanostructures; Cathode; Rechargeable; aqueous batteries
摘要:Prussian blue (PB) and its analogues (PBAs) have been regarded as one of promising electrode candidates in aqueous batteries, due to its open framework, robust skeleton, and simple preparation protocol. However, intrinsic structure vacancies and poor electron conductivity lower their electrochemical performances, particularly in terms of reversible capacity, rate capability, and cycling stability. Here, truncated cobalt hexacyano-ferrate nanocubes threaded by carbon nanotubes are synthesized with the assistances of citrate and glycerol. The low content of structure vacancies in cobalt hexacyanoferrate, and the intimate contact between it and carbon nanotubes, well address the above issues, resulting in excellent performances in rechargeable aqueous batteries. The reversible capacity reaches 107.2 mAh g(-1) at 0.1 A g(-1), 87.3% of which is kept at 5 A g(-1). After paired with Zn foil as a dual-ion full cell, it delivers a high energy of 107.1 Wh kg(cathode)(-1) at 7.87 kW kg(cathode)(-1), exhibiting the high energy and high power simultaneously. All these results indicate the promising potential of this composite in rechargeable aqueous batteries.
收录类别:EI;SCOPUS;SCIE
资源类型:期刊论文
原文链接:https://www.scopus.com/inward/record.uri?eid=2-s2.0-85050225812&doi=10.1016%2fj.jpowsour.2018.07.084&partnerID=40&md5=58d39778c595a38ff9aea71db0b8ba71
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