标题:Synthesis of novel organonickel(II) complexes with thiosalicylaldehyde as a chelate ligand
作者:Zhang, Wenbo; Li, Xiaoyan; Sun, Hongjian
作者机构:[Zhang, Wenbo; Li, Xiaoyan; Sun, Hongjian] Shandong Univ, Minist Educ, Key Lab Special Funct Aggregated Mat, Sch Chem & Chem Engn, Jinan 250199, Peopl 更多
通讯作者:Sun, HJ
通讯作者地址:[Sun, HJ]Shandong Univ, Minist Educ, Key Lab Special Funct Aggregated Mat, Sch Chem & Chem Engn, Shanda Nanlu 27, Jinan 250199, Peoples R China.
来源:INORGANICA CHIMICA ACTA
出版年:2014
卷:419
页码:7-10
DOI:10.1016/j.ica.2014.05.001
关键词:Thiosalicylaldehyde; Trimethylphosphine; Nickel complex; C,S-coupling
摘要:Two sulfur-coordinated acyl nickel(II) complexes 3 and 4 Ni(S boolean AND C@O)(PMe3)(3) (boolean AND = phenyl (3), 5-methylphenyl (4)) were synthesized by reactions of thiosalicylaldehyde (1) and 5-methylthiosalicylal-dehyde (2) with NiMe2(PMe3)(3). Complex 3 reacted with excess iodomethane affording (2-methyl-mercapto-phenyl)nickel(II) complex 5. The mechanisms of formation of 3-5 were proposed and discussed. The molecular structures of 4 and 5 were determined by X-ray diffraction. (C) 2014 Elsevier B.V. All rights reserved.
收录类别:SCOPUS;SCIE
WOS核心被引频次:1
Scopus被引频次:1
资源类型:期刊论文
原文链接:https://www.scopus.com/inward/record.uri?eid=2-s2.0-84901794030&doi=10.1016%2fj.ica.2014.05.001&partnerID=40&md5=15a5d3426a88702e661ed56b5025346a
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