标题:Two birds with one stone: anion templated ball-shaped Ag-56 and disc-like Ag-20 clusters
作者:Sun, Di; Wang, Hua; Lu, Hai-Feng; Feng, Sheng-Yu; Zhang, Zhen-Wei; Sun, Guo-Xin; Sun, Dao-Feng
作者机构:[Sun, Di; Wang, Hua; Lu, Hai-Feng; Feng, Sheng-Yu; Sun, Dao-Feng] Shandong Univ, Sch Chem & Chem Engn, Key Lab Special Funct Aggregated Mat, Minist Ed 更多
通讯作者:Sun, D
通讯作者地址:[Sun, D]Shandong Univ, Sch Chem & Chem Engn, Key Lab Special Funct Aggregated Mat, Minist Educ, Jinan 250100, Peoples R China.
来源:DALTON TRANSACTIONS
出版年:2013
卷:42
期:18
页码:6281-6284
DOI:10.1039/c3dt50342a
摘要:One-pot reaction of AgSBut and AgOAc in the methanol-ethanol-DMF solvent system under room temperature gave a ball-shaped Ag-56 cluster and a disc-like Ag-20 cluster. The formations of clusters 1 and 2 are templated by an in situ generated S2- ion from the cleavage of the S-C bond of SBut and CO32- ion from the fixation of atmospheric carbon dioxide, respectively. Interestingly, cluster 1 only emits bright-red light in the solid state at 77 K and is not emissive at room temperature.
收录类别:EI;SCOPUS;SCIE
WOS核心被引频次:41
Scopus被引频次:42
资源类型:期刊论文
原文链接:https://www.scopus.com/inward/record.uri?eid=2-s2.0-84879950658&doi=10.1039%2fc3dt50342a&partnerID=40&md5=112c371553eb6b8ab894a028594f7bce
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