标题:Facile Construction of Defect-rich Rhenium Disulfide/Graphite Carbon Nitride Heterojunction via Electrostatic Assembly for Fast Charge Separation and Photoactivity Enhancement
作者:Li, Haiping; Liang, Zhiwei; Deng, Quanhua; Hu, Tingxia; Du, Na; Hou, Wanguo
作者机构:[Li, Haiping; Liang, Zhiwei] Shandong Univ, Natl Engn Res Ctr Colloidal Mat, Jinan 250100, Shandong, Peoples R China.; [Deng, Quanhua; Hu, Tingxia; 更多
通讯作者:Hou, Wanguo;Hou, WG
通讯作者地址:[Hou, WG]Shandong Univ, Key Lab Colloid & Interface Chem, Minist Educ, Jinan 250100, Shandong, Peoples R China.
来源:CHEMCATCHEM
出版年:2019
卷:11
期:6
页码:1633-1642
DOI:10.1002/cctc.201802021
关键词:graphite carbon nitride; rhenium disulfide; electrostatic interaction;; photocatalytic; charge separation
摘要:Graphite carbon nitride (CN) is one of the most researched visible light photocatalysts, but it still cannot be used practically because of its low photoactivity resulting mainly from rapid photogenerated charge recombination. To accelerate charge separation, CN was herein electrostatically assembled with ReS2, a two-dimensional semiconductor to construct heterojunction for the first time. The electrostatic and coordination interactions between CN and defect-rich ReS2, make them close contact to form heterojunctions. The ReS2/CN heterojunction exhibits higher photocatalytic performance in pollutant degradation owing to faster generation of reactive oxygen species than CN, as well as increased visible and near-infrared light absorption because of strong photoabsorption of defect-rich ReS2. The accelerated reactive oxygen species generation for the hetero-junction arises from accelerated charge separation, especially fast transfer of holes from CN to ReS2, in assistance of interfacial electric field and great valance-band edge difference. This work provides a novel CN-based heterojunction for photoactivity improvement and illustrates significance of electrostatic attraction in fabricating heterojunctions.
收录类别:EI;SCOPUS;SCIE
资源类型:期刊论文
原文链接:https://www.scopus.com/inward/record.uri?eid=2-s2.0-85062364668&doi=10.1002%2fcctc.201802021&partnerID=40&md5=b17ffce995d2ce18d9f11065eb83d9cc
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