标题：Electrodeposition of Free-Standing Poly(o-dihydroxybenzene-co-3-methylthiophene) Films with Tunable Fluorescence Properties
作者：Congcong Liu;Jingkun Xu;Changli Fan;Baoyang Lu;Bin Dong;Guodong Liu
作者机构：[Liu, C] Jiangxi Key Laboratory of Organic Chemistry, Jiangxi Science and Technology Normal University, Nanchang 330013, China;[ Xu, J] Jiangxi Key La 更多
通讯作者地址：[Xu, JK]Jiangxi Sci & Technol Normal Univ, Jiangxi Key Lab Organ Chem, Nanchang 330013, Peoples R China.
来源：Journal of Applied Polymer Science
摘要：Electrochemical copolymerization of o-dihydroxybenzene (oDHB) and 3-methylthiophene (3MeT) was successfully achieved in boron trifluoride diethyl etherate by direct anodic oxidation of the monomer mixtures, although the oxidation potentials of oDHB and 3MeT were quite different. The influence of the applied polymerization potential on the synthesis of the copolymers was investigated. The higher applied potential favored the incorporation of 3MeT units into the copolymers. The structure and properties of the copolymers were investigated with UV-vis spectroscopy, fluorescence spectroscopy, FTIR spectroscopy, and thermal analysis. The novel copolymers had many advantages, including good redox activity, good thermal stability, and high electrical onductivity. Additionally, the copolymers fluorescence properties that were tunable through changes in the feed ratio of the monomer mixtures.