标题:Synthesis of 1-Vinyl/Arylbenzotriazole 3-Oxides through a Copper-Mediated C-N Bond Coupling Reaction
作者:Shi, Wei-Min; Liu, Feng-Ping; Wang, Zhi-Xin; Bi, Hong-Yan; Liang, Cui; Xu, Li-Ping; Su, Gui-Fa; Mo, Dong-Liang
作者机构:[Shi, Wei-Min; Liu, Feng-Ping; Wang, Zhi-Xin; Bi, Hong-Yan; Liang, Cui; Su, Gui-Fa; Mo, Dong-Liang] Guangxi Normal Univ, Minist Sci & Technol China, S 更多
通讯作者:Su, GF;Mo, DL;Su, GF;Mo, DL;Xu, LP;Xu, LP
通讯作者地址:[Su, GF; Mo, DL]Guangxi Normal Univ, Minist Sci & Technol China, State Key Lab Chem & Mol Engn Med Resources, 15 Yu Cai Rd, Guilin 541004, Peoples R C 更多
来源:ADVANCED SYNTHESIS & CATALYSIS
出版年:2017
卷:359
期:16
页码:2741-2746
DOI:10.1002/adsc.201700462
关键词:benzotriazole oxides; C-N bond formation; copper catalysis; N-O; compounds; organoboronic acids
摘要:An efficient synthesis of 1-vinyl/arylbenzotriazole 3-oxides via the copper-promoted coupling of N-hydroxybenzotriazoles with alkenyl- or arylboronic acids is reported. This strategy features mild reaction conditions, good functional group tolerance, broad substrate scope and rapid introduction of benzotriazole N-oxide moieties into molecules. Density functional theory calculations revealed that the formation of the favored N-coupling product depends on the kinetically more favorable C-N bond formation pathway.
收录类别:SCIE
WOS核心被引频次:4
资源类型:期刊论文
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