标题:Anion-Induced Supramolecular Isomerism in Two Preyssler P5W30 Polyoxometalate-Based Hybrid Materials
作者:Zhao, Ya-Qin; Yu, Kai; Wang, Li-Wei; Wang, Ying; Wang, Xing-Po; Sun, Di
作者机构:[Zhao, Ya-Qin; Wang, Li-Wei; Wang, Ying; Wang, Xing-Po; Sun, Di] Shandong Univ, Sch Chem & Chem Engn, Minist Educ, Key Lab Colloid & Interface Chem, J 更多
通讯作者:Sun, D
通讯作者地址:[Sun, D]Shandong Univ, Sch Chem & Chem Engn, Minist Educ, Key Lab Colloid & Interface Chem, Jinan 250100, Peoples R China.
来源:INORGANIC CHEMISTRY
出版年:2014
卷:53
期:20
页码:11046-11050
DOI:10.1021/ic501567s
摘要:Two extended Preyssler P5W30 polyoxometalate-based inorganic-organic hybrid materials exhibiting anion-induced supramolecular isomerism were reported. Because of the cis-trans isomerism in the octahedral CoN2O4 coordination geometry, the Preyssler P5W30 polyoxometalates are extended by double O-Co-O bridges in 1 alpha and a single O-Co-O bridge in 1 beta to form the isomeric 2D 4-connected 4(4)-sql and 3D 8-connected bcu networks, respectively. Both compounds show electrocatalytic abilities on the reduction of H2O2.
收录类别:SCOPUS;SCIE
WOS核心被引频次:16
Scopus被引频次:17
资源类型:期刊论文
原文链接:https://www.scopus.com/inward/record.uri?eid=2-s2.0-84907978091&doi=10.1021%2fic501567s&partnerID=40&md5=7e6d191ad8d529b69630ce40f35cb278
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