标题:Optical and Fluorescent Dual Sensing of Aminoalcohols by in Situ Generation of BODIPY-like Chromophore
作者:Shirbhate M.E.; Kwon S.; Song A.; Kim S.; Kim D.; Huang H.; Kim Y.; Lee H.;等 更多
作者机构:[Shirbhate, M.E] Department of Chemistry and Nanosciences (BK21 Plus), Ewha Womans University, Seoul, 03760, South Korea;[ Kwon, S] Department of Chem 更多
通讯作者:Yoon, J(mbaik2805@kaist.ac.kr)
通讯作者地址:[Yoon, J] Department of Chemistry and Nanosciences (BK21 Plus), Ewha Womans UniversitySouth Korea;
来源:ACS Applied Materials and Interfaces
出版年:2020
DOI:10.1021/jacs.9b13232
摘要:A novel multifunctional aminophenylboronic acid connected to a diphenylketone gives both circular dichroism and fluorescence signals by in situ generation of a BODIPY-like chromophore in the presence of aminoalcohols. DFT calculations were used to understand the role of each functional group in the mechanism. This new sensor can distinguish different aminoalcohols and quantitatively indicate the concentration of the substrate, allowing for the convenient determination of the ee of racemic mixtures with a single probe. © Copyright © 2020 American Chemical Society.
收录类别:SCOPUS
Scopus被引频次:3
资源类型:期刊论文
原文链接:https://www.scopus.com/inward/record.uri?eid=2-s2.0-85081681803&doi=10.1021%2fjacs.9b13232&partnerID=40&md5=0cb4d8f97d8283e64b81776ea66f4711
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