标题：Synthesis of silicone-acrylate copolymer latexes and their film properties
作者：Kan, CY; Yuan, Q; Wang, MC; Kong, XZ
作者机构：[Kan, CY; Yuan, Q; Wang, MC; Kong, XZ]SHANDONG UNIV,DEPT CHEM,JINAN 250100,PEOPLES R CHINA.
会议名称：5th International Symposium on Functional Polymers and Fine Chemistry
会议日期：OCT 12-15, 1994
来源：POLYMERS FOR ADVANCED TECHNOLOGIES
关键词：emulsion copolymerization; siloxanes; silicone-acrylate copolymer;; polymerization process; film properties
摘要：Emulsion copolymerization of silicones (octomethyl tetracyclosiloxane, D-4 and methacryloxypropyl trimethoxy silane, MATS) and acrylics was carried out using three different polymerization processes: semicontinuous monomer emulsion addition, batch and initiator solution addition. Results showed that only the semicontinuous process led to a stable latex with monodisperse particles. Various polymerizations were carried out through this process with varying silicone/acrylic ratios and MATS content. Films were obtained from different latexes: their properties are significantly influenced by silicone and MATS contents in copolymers.