标题：Voltammetric determination of dopamine and norepinphrine on a glassy carbon electrode modified with poly (L-aspartic acid)
作者：Yu, Zhangyu; Li, Xiaochun; Wang, Xueliang; Ma, Xinying; Li, Xia; Cao, Kewei
作者机构：[Yu, Zhangyu; Li, Xiaochun; Wang, Xueliang; Ma, Xinying; Li, Xia; Cao, Kewei] Heze Univ, Dept Chem & Chem Engn, Heze 274015, Peoples R China.; [Yu, 更多
通讯作者地址：[Yu, ZY]Heze Univ, Dept Chem & Chem Engn, Heze 274015, Peoples R China.
来源：JOURNAL OF CHEMICAL SCIENCES
关键词：L-aspartic acid; modified electrode; dopamine; norepinephrine
摘要：A convenient and useful method for the voltammetric determination of dopamine (DA) and norepinphrine (NE) based on poly(L-aspartic acid) modified glassy carbon electrode (GCE) is reported in this paper. The modified electrode exhibits excellent electro-catalytic activities for the oxidation-reduction of DA and NE, as well as eliminating the interference of ascorbic acid (AA) and uric acid (UA). Factors influencing the detection processes are optimized and the kinetic parameters are calculated. Under the optimal conditions, the anodic peak currents of DA and NE are linear with their concentration and the detection limits (S/N = 3) are 1.0 x 10(-9) mol L-1 for DA and 4.31 x 10(-9) mol L-1 for NE, respectively. The practical application of this method is demonstrated by determining the concentration of NE and DA in injection which is commercially available with satisfactory results. Compared with other electrochemical methods, this method is simple, highly selective and sensitive.