标题:Chlorido(2-iminomethyl-3-fluorophenyl-kappa 2 C 1,N)tris(trimethylphosphane-kappa P)iron
作者:Xu, Xiaofeng; Li, Xiaoyan
作者机构:[Xu, Xiaofeng; Li, Xiaoyan] Shandong Univ, Sch Chem & Chem Engn, Jinan 250100, Peoples R China.
通讯作者:Li, XY
通讯作者地址:[Li, XY]Shandong Univ, Sch Chem & Chem Engn, Jinan 250100, Peoples R China.
来源:ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
出版年:2011
卷:67
页码:M679-U397
DOI:10.1107/S1600536811015030
摘要:The title compound, [Fe(C(7)H(5)FN)Cl(C(3)H(9)P)(3)], was obtained as a product of the reaction of [Fe(Me(3)P)(4)] with a molar equivalent of (2-chloro-6-fluorophenyl)methanimine in diethyl ether. This compound is sensitive to air, and rapidly decomposes when exposed to air for a few minutes. The Fe atom has an octahedral coordination geometry in which the bidentate fluorophenyl methanimine ligand forms the equatorial plane with the Cl atom and one of the trimethylphosphane ligands. The other two trimethylphosphane ligands are located in the axial positions. In the crystal, an N-H...Cl hydrogen bond occurs.
收录类别:SCIE
资源类型:期刊论文
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