标题:A new route to achieve the side-chain-type sulfone-containing polysiloxanes via sulfide oxidation-induced cleavage and rearrangement of Si-O-Si bonds with fine selectivity toward cyclosiloxanes
作者:Gou, Zhiming; Zuo, Yujing; Qi, Jinwan; Li, Zhaoyue; Feng, Shengyu
作者机构:[Feng, Shengyu] Shandong Univ, Sch Chem & Chem Engn, Key Lab Special Funct Aggregated Mat, Jinan 250100, Peoples R China.; Shandong Univ, Sch Chem & 更多
通讯作者:Feng, Shengyu
通讯作者地址:[Feng, SY]Shandong Univ, Sch Chem & Chem Engn, Key Lab Special Funct Aggregated Mat, Jinan 250100, Peoples R China.
来源:POLYMER CHEMISTRY
出版年:2016
卷:7
期:35
页码:5496-5500
DOI:10.1039/c6py01000h
摘要:A novel approach, with high selectivity, to obtain novel polysiloxanes containing sulfone groups from sulfur-bridged cyclosiloxane monomers was carried out without the use of catalysts; instead, sulfur oxidation was performed. The sulfide oxidation reaction can induce ring-opening polymerization of the cyclosiloxanes through cleavage and rearrangement of Si-O-Si bonds. Our findings present novel insights to synthesize new polysiloxanes.
收录类别:EI;SCOPUS;SCIE
WOS核心被引频次:1
Scopus被引频次:1
资源类型:期刊论文
原文链接:https://www.scopus.com/inward/record.uri?eid=2-s2.0-84985991721&doi=10.1039%2fc6py01000h&partnerID=40&md5=378274a848029da4c31669a28b70a858
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