标题:A novel porousmetal-organic framework from a new bis(acylhydrazone) ligand capable of reversibly adsorbing/desorbing water and small alcohol molecules
作者:Guo, Chun-Li; Li, Xiao-Zeng; Zhang, Xing-Mei; Wang, Lu; Zhu, Li-Na
作者机构:[Guo, Chun-Li; Li, Xiao-Zeng; Zhang, Xing-Mei; Wang, Lu; Zhu, Li-Na] Tianjin Univ, Sch Sci, Dept Chem, Tianjin 300072, Peoples R China.; [Guo, Chun- 更多
通讯作者:Guo, CL
通讯作者地址:[Guo, CL]Tianjin Univ, Sch Sci, Dept Chem, Tianjin 300072, Peoples R China.
来源:CRYSTENGCOMM
出版年:2014
卷:16
期:20
页码:4095-4099
DOI:10.1039/c4ce00140k
摘要:A porous metal-organic material of the doubly deprotonated form of a new bis(aroylhydrazone) ligand (L1(2-)) was self-assembled from 2,3-butanedione, isonicotinoyl hydrazine and lead nitrate. X-ray single crystal analysis revealed that six L1(2-) and six Pb2+ are arranged alternately to form a metallomacrocycle in the porous material. Weak coordination bonds together with p. p interactions connect the metallomacrocycle units rather strongly into two interpenetrating unique 3D networks. TG, PXRD and dehydration investigation showed that all of the coordination and guest water molecules in the material can be removed upon heating to give the activated structure with vacant pores and open Pb sites. The material can reversibly adsorb/desorb water and small alcohol molecules.
收录类别:SCOPUS;SCIE
WOS核心被引频次:4
Scopus被引频次:4
资源类型:期刊论文
原文链接:https://www.scopus.com/inward/record.uri?eid=2-s2.0-84899476798&doi=10.1039%2fc4ce00140k&partnerID=40&md5=dcdeba5b50452d0ce12067ba21da9c29
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