标题:Highly efficient and selective photocatalytic hydrogenation of functionalized nitrobenzenes
作者:Xiu-Jie Yang;Bin Chen;Li-Qiang Zheng
作者机构:[Yang, X.-J] Key Laboratory of Colloid and Interface Chemistry, Shandong University, Ministry of Education, Jinan, Shandong 250100, China;[ Chen, B] K 更多
通讯作者:Yang, XJ
通讯作者地址:[Yang, XJ]Shandong Univ, Minist Educ, Key Lab Colloid & Interface Chem, Jinan 250100, Shandong, Peoples R China.
来源:Green chemistry
出版年:2014
卷:16
期:3
页码:1082-1086
DOI:10.1039/c3gc42042f
摘要:We report a simple but efficient photocatalytic nitrobenzene reduction method employing eosin Y as the photocatalyst and TEOA as the reducing agent. With green LED light irradiation, the nitro group in the nitrobenzenes containing other reducible groups was chemoselectively reduced into an amino group, and the corresponding anilines were isolated in quantitative yields. The photoinduced electron transfer mechanism suggests that the high chemoselectivity originates from the better electron-withdrawing ability of the nitro group.
收录类别:SCOPUS;SCIE
WOS核心被引频次:70
Scopus被引频次:73
资源类型:期刊论文
原文链接:https://www.scopus.com/inward/record.uri?eid=2-s2.0-84894640289&doi=10.1039%2fc3gc42042f&partnerID=40&md5=e4e84bacd642622ed0ce81af963cbf8e
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