标题:Efficient transfer hydrogenation of carbonyl compounds catalyzed by selenophenolato hydrido iron(II) complexes
作者:Wang, Yangyang; Du, Zhengyin; Zheng, Tingting; Sun, Hongjian; Li, Xiaoyan
作者机构:[Wang, Yangyang; Du, Zhengyin] Northwest Normal Univ, Coll Chem & Chem Engn, Lanzhou 730070, Gansu, Peoples R China.; [Wang, Yangyang; Zheng, Tingti 更多
通讯作者:Du, Zhengyin;Du, ZY;Li, XY;Zheng, TT
通讯作者地址:[Du, ZY]Northwest Normal Univ, Coll Chem & Chem Engn, Lanzhou 730070, Gansu, Peoples R China;[Li, XY]Shandong Univ, Minist Educ, Key Lab Special Funct 更多
来源:CATALYSIS COMMUNICATIONS
出版年:2019
卷:124
页码:32-35
DOI:10.1016/j.catcom.2019.02.027
关键词:TH; Iron hydride; Ketone; Aldehyde; Isopropanol
摘要:Selenophenolato hydrido iron(II) complexes 1-3 cis-[(H)(SeAr)Fe(PMe3)(4)] (Ar = C6H5 (1), p-MeOC6H4 (2) and o-MeC6H4 (3)) could catalyze transfer hydrogenation of aldehydes and ketones. Among the three complexes, catalyst 1 exhibited the highest catalytic activity. The catalytic reactions took place under very mild conditions, using isopropanol as solvent and hydrogen source, (BuONa)-Bu-t as base under 60-80 degrees C. This catalytic system has good tolerance for many functional groups, such as halides, C=C double bonds, nitro groups and cyano groups at the phenyl ring of the substrates.
收录类别:EI;SCOPUS;SCIE
资源类型:期刊论文
原文链接:https://www.scopus.com/inward/record.uri?eid=2-s2.0-85062266592&doi=10.1016%2fj.catcom.2019.02.027&partnerID=40&md5=d1b1048dae0a13562f6daa94d478c639
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