标题：Effects of operating conditions on trihalomethanes formation and speciation during chloramination in reclaimed water
作者：Wang, Fang; Gao, Baoyu; Ma, Defang; Li, Ruihua; Sun, Shenglei; Yue, Qinyan; Wang, Yan; Li, Qian
作者机构：[Wang, Fang; Gao, Baoyu; Ma, Defang; Li, Ruihua; Sun, Shenglei; Yue, Qinyan; Wang, Yan; Li, Qian] Shandong Univ, Sch Environm Sci & Engn, Shandong Key 更多
会议名称：2nd Contaminated Land, Ecological Assessment and Remediation (CLEAR 2014) Conference - Environmental Pollution and Remediation
会议日期：OCT 05-08, 2014
来源：ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
关键词：Chloramination; Trihalomethanes formation; THMs speciation; Reclaimed; water; Membrane bioreactor; Powdered activated carbon
摘要：In this study, a hybrid powdered activated carbon-membrane bioreactor (PAC-MBR) system was used to treat municipal wastewater in northern China intended for recycle. In order to control microbiological hazards in PAC-MBR effluent, chloramine was chosen as the disinfectant which could reduce the disinfection by-product yields. Effects of reaction time, chloramines dose, pH value, and bromide ion concentration on trihalomethanes (THMs) formation and speciation during chloramination of the reclaimed effluent were investigated. Study results indicated that the yield of total THMs (TTHM) increased at higher reaction time and chloramines dose. The trend of growth showed that slow reacting precursors were the main components of dissolved organic matter (DOM) in PAC-MBR effluent. THMs formation potential of PAC-MBR effluent achieved the maximum at chloramines dosage of 20 mg/L. Meanwhile, THMs formation was enhanced evidently under alkaline conditions. The yields of THMs species were in following order: CHCl3 > CHBrCl2 > CHBr2Cl > CHBr3, although in different reaction time, chloramines dose, and pH value. Furthermore, the formation of Br-THMs was promoted by the increasing concentration of bromide ion.