标题:Design and Synthesis of a Novel Banana-Shaped Functional Molecule via Double Cross-Coupling
作者:Yang, Bingchuan; Shen, Guodong; Huang, Xianqiang; Liu, Rutao
作者机构:[Yang, Bingchuan; Shen, Guodong; Huang, Xianqiang] Liaocheng Univ, Sch Chem & Chem Engn, Liaocheng 252000, Peoples R China.; [Yang, Bingchuan; Liu, 更多
通讯作者:Yang, BC;Yang, BC;Liu, RT;Yang, BC
通讯作者地址:[Yang, BC]Liaocheng Univ, Sch Chem & Chem Engn, Liaocheng 252000, Peoples R China;[Yang, BC; Liu, RT]Shandong Univ, Sch Environm Sci & Engn, Jinan 250 更多
来源:MOLECULES
出版年:2019
卷:24
期:4
DOI:10.3390/molecules24040698
关键词:bent-core; Troger's base; double Sonogashira coupling
摘要:A novel banana-shaped molecule using 2,8-Dimethyl-6H,12H-5,11-methanodibenzo [b,f] [1,5]diazocine (Troger's base) as bent-core was synthesized via double Carbon-Carbon cross-coupling reaction. The double Sonogashira cross-coupling reaction was optimized by using Pd(PPh3)(2)Cl-2 as catalyst, CuI as cocatalyst and diisopropylamine as base in place of triethylamine. The structure of this compound was confirmed by H-1-NMR, C-13-NMR, Fourier transform infrared (FT-IR) spectroscopy and mass spectrometry.
收录类别:SCOPUS;SCIE
资源类型:期刊论文
原文链接:https://www.scopus.com/inward/record.uri?eid=2-s2.0-85061594458&doi=10.3390%2fmolecules24040698&partnerID=40&md5=2f5d5b70dbc4c1a358d1bfe30e74981d
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