标题:Synthesis and Properties of Benzothieno[b]-Fused BODIPY Dyes
作者:Sun, Zuo-Bang; Guo, Man; Zhao, Cui-Hua
作者机构:[Sun, Zuo-Bang; Guo, Man; Zhao, Cui-Hua] Shandong Univ, Sch Chem & Chem Engn, Key Lab Special Funct Aggregated Mat, Minist Educ, Jinan 250100, Peoples 更多
通讯作者:Zhao, CuiHua
通讯作者地址:[Zhao, CH]Shandong Univ, Sch Chem & Chem Engn, Key Lab Special Funct Aggregated Mat, Minist Educ, Jinan 250100, Peoples R China.
来源:JOURNAL OF ORGANIC CHEMISTRY
出版年:2016
卷:81
期:1
页码:229-237
DOI:10.1021/acs.joc.5b02531
摘要:Two benzothieno[b]-fused BODIPYs, BT-BODIPY and BBT-BODIPY, in which one parent BODIPY core is fused with one and two benzothieno rings, respectively, were synthesized from BODIPYs substituted with 2-(methylsulfinyl)phenyl at the beta-position. The first H2SO4-induced cyclization and deborylation afforded benzothieno[b]-fused dipyrrin derivatives, which can easily complex with BF3 center dot OEt2 to form the desired benzothieno[b]-fused BODIPYs. It was revealed that the fusion of the benzothieno ring is more effective at extending conjugation than simple attachment of the 2-(methylthio)phenyl substituent, which presumably results from conformational restriction. Compared with the corresponding unstrained SPh-BODIPY and BSPh-BODIPY, which contain one and two 2-(methylthio)phenyl groups at the beta-position, BT-BODIPY and BBT-BODIPY display red shifted absorption, increased absorptivity, and fluorescence efficiency. Furthermore, the ring fusion is also helpful to increase stability of the formed cation in BBT-BODIPY. Thus, BBT-BODIPY exhibits very intriguing properties, such as intense absorption and emission in the red region, very sharp emission spectra, and reversible oxidation and reduction potentials.
收录类别:EI;SCOPUS;SCIE
WOS核心被引频次:18
Scopus被引频次:19
资源类型:期刊论文
原文链接:https://www.scopus.com/inward/record.uri?eid=2-s2.0-84953426383&doi=10.1021%2facs.joc.5b02531&partnerID=40&md5=ac4cc0c04f3cfbf063f5063a31e3cac8
TOP