标题:Acetonitrile[2-({bis[2,4,6-tris(trifluoridomethyl)phenyl]phosphanyloxy}m ethyl)pyridine]methylpalladium(II) hexafluoroantimonate dichloromethane hemisolvate
作者:Li, Liuzhong; White, Peter S.; Hao, Aiyou
作者机构:[Li, Liuzhong; Hao, Aiyou] Shandong Univ, Sch Chem & Chem Engn, Jinan 250100, Peoples R China.; [Li, Liuzhong; White, Peter S.] Univ N Carolina, Dep 更多
通讯作者:Hao, AY
通讯作者地址:[Hao, AY]Shandong Univ, Sch Chem & Chem Engn, Jinan 250100, Peoples R China.
来源:ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
出版年:2011
卷:67
页码:M366-U797
DOI:10.1107/S1600536811005757
摘要:In the title compound, [Pd(CH3)(C24H10F18NOP)(CH3CN)][SbF6]center dot 0.5CH(2)Cl(2), the Pd-II atom has a distorted square-planar environment being coordinated by an acetonitrile N atom [Pd-N = 2.079 (3) angstrom], a methyl C atom [Pd-C = 2.047 (4) angstrom] and the bidentate ligand 2-({[2,4,6-tris(trifluoromethyl) phenyl] phosphanyloxy} methyl) pyridine (L). In L, the short distance of 3.621 (3) angstrom between the centroids of pyridine and benzene rings indicates the presence of a pi-pi interaction. The crystal packing exhibits weak intermolecular C-H center dot center dot center dot F contacts. The solvent molecule has been treated as disordered between two positions of equal occupancy related by an inversion center.
收录类别:SCOPUS;SCIE
资源类型:期刊论文
原文链接:https://www.scopus.com/inward/record.uri?eid=2-s2.0-79952402794&doi=10.1107%2fS1600536811005757&partnerID=40&md5=6ead9cffd781b12b8cbc265c0f0e9a10
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