标题:Synthesis and Structure of Low-valent (4)-Cinnamaldehyde Cobalt Complexes
作者:Geng, Yizheng; Chen, Junyu; Zhao, Haiwei; Sun, Hongjian; Xue, Benjing; Li, Xiaoyan; Fuhr, Olaf; Fenske, Dieter
作者机构:[Geng, Yizheng; Sun, Hongjian; Xue, Benjing; Li, Xiaoyan] Shandong Univ, Sch Chem & Chem Engn, Key Lab Special Funct Aggregated Mat, Minist Educ, Shan 更多
通讯作者:Li, XY
通讯作者地址:[Li, XY]Shandong Univ, Sch Chem & Chem Engn, Key Lab Special Funct Aggregated Mat, Minist Educ, Shanda Nanlu 27, Jinan 250199, Peoples R China.
来源:ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
出版年:2017
卷:643
期:11
页码:712-716
DOI:10.1002/zaac.201700073
关键词:(4)-Coordination; (2)-Coordination; Cinnamaldehyde; Cobalt
摘要:Three (4)-(C=C-C=O) coordination cobalt(I) complexes 1-3 were synthesized by the reactions of cinnamaldehyde, p-fluorocinnamaldehyde, and p-chlorocinnamaldehyde with CoMe(PMe3)(4). Complex 4 as (2)-(C=C) coordination was prepared by the reaction of chalcone with Co(PMe3)(4). The structures of complexes 1-4 were confirmed by single-crystal X-ray diffraction. Although the reactions didn't undergo C-H bond activation and decarbonylation, the formation of complexes 1-4 deepens our understanding of the reactions between ,-unsaturated aldehyde or ketone with low-valent central cobalt atom.
收录类别:SCOPUS;SCIE
资源类型:期刊论文
原文链接:https://www.scopus.com/inward/record.uri?eid=2-s2.0-85018968560&doi=10.1002%2fzaac.201700073&partnerID=40&md5=717d834b0deee8a32f51e7dfc401cac7
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