标题:Synthesis,Structure and Thermal Stability of a Cadmium Coordination Polymer:[Cd(phen)(4,6-dimethyl-5-nitro-isophthalic Acid)]_n
作者:XU Yu-Min[1];ZHAO Xiao-Liang[2];HU Tuo-Ping[1]
作者机构:[Xu Yumin] Department of Chemistry, School of Science, North University of China, Taiyuan, Shanxi 030051, China.;[Hu Tuoping] Department of Chemistry, 更多
通讯作者:Xu, YM(yuminzaizher@163.com)
通讯作者地址:[Xu, YM]N Univ China, Dept Chem, Sch Sci, Taiyuan 030051, Shanxi, Peoples R China.
来源:结构化学
出版年:2011
卷:30
期:10
页码:1442-1446
关键词:镉配位聚合物;二甲基亚砜;晶体结构分析;间苯二甲酸;PHEN;热稳定性;硝基;合成;
摘要:One cadmium(II) coordination polymer [Cd(phen)(4,6-dimethyl-5-nitro-isophthalie acid)](n) (1) has been synthesized with 4,6-dimethyl-5-nitro-isophthalic acid, phen (phen = 10-phenanthroline), and cadmium nitrate in the mixture of DMSO:H2O (V:V = 2:1). Crystallographic data for this complex: monoclinic, space group P2(1)/c, with a = 11.668(2), b = 11.841(6), c = 14.446(2) angstrom, beta = 102.440(4), V = 1.9491(8) angstrom(3), D-c = 1.805 g/cm(3), Z = 1, F(000) = 1056, GOOF = 0.999, R = 0.0280 and wR = 0.0662. The crystal structure analysis indicates that the cadmium ion is coordinated with two nitrogen atoms of one 1,10-phenanthroline molecule and five oxygen atoms from three 4,6-dimethyl-5-nitro-isophthalic acid molecules. The curve of TGA shows that 1 is stable up to 380.0 degrees C.
收录类别:CSCD;SCOPUS;SCIE
资源类型:期刊论文
原文链接:http://lib.cqvip.com/qk/95925X/201110/39726712.html
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