标题:Crystallographic Investigations into the Polar Polymorphism of BaTeW2O9: Phase Transformation, Controlled Crystallization, and Linear and Nonlinear Optical Properties
作者:Li, Conggang; Gao, Zeliang; Zhao, Peng; Tian, Xiangxin; Wang, Haoyuan; Wu, Qian; Lu, Weiqun; Sun, Youxuan; Cui, Deliang; Tao, Xutang
作者机构:[Li, Conggang; Gao, Zeliang; Zhao, Peng; Tian, Xiangxin; Wang, Haoyuan; Wu, Qian; Lu, Weiqun; Sun, Youxuan; Cui, Deliang; Tao, Xutang] Shandong Univ, 更多
通讯作者:Gao, ZL;Tao, XT;Gao, Zeliang
通讯作者地址:[Gao, ZL; Tao, XT]Shandong Univ, State Key Lab Crystal Mat, Jinan 250100, Shandong, Peoples R China.
来源:CRYSTAL GROWTH & DESIGN
出版年:2019
卷:19
期:3
页码:1767-1777
DOI:10.1021/acs.cgd.8b01750
摘要:Controlling polymorphism crystallization can be used to tune the intrinsic properties of a material without introducing any other atoms and is, therefore, of important technological significance. Although diversity in polymorphisms has been extensively studied, an intensive understanding of the relationships between their structure and properties is limited. Herein, a systematic investigation on the phase transformation, synthesis, structure, controlled growth, as well as the functional properties was performed for the polar metastable polymorph beta-BaTeW2O9, which was grown via the top-seeded solution growth method using TeO2-WO3 as a flux. beta-BaTeW2O9 crystallizes in an acentric space group P2(1) (No. 4, a = 5.499 (6) angstrom, b = 7.469 (9) angstrom, c = 8.936 (10) angstrom, and Z = 2), with a two-dimensional layered structure consisting of WO6 octahedra linked to TeO4 polyhedra. A notable phase transformation occurred from beta-BaTeW2O9 to alpha-BaTeW2O9 at, similar to 608 degrees C and was demonstrated by the differential scanning calorimetry analysis combined with the in situ powder X-ray pattern measurements. This phase transformation was irreversible. This compound exhibited strong second harmonic generation response of 1.5 x KTiOPO4 (KTP) with a type-I phase-matching characteristic. Moreover, it also showed an excellent thermal stability and possessed a greatly broad transparent range from 0.325 to 5.70 mu m with a large bandgap of 3.50 eV. In addition, electronic structure calculations revealed that WO6 and TeO4 are critical for producing a substantial nonlinear optical (NLO) response. These outstanding attributes indicate that beta-BaTeW2O9 is a promising NLO material.
收录类别:EI;SCOPUS;SCIE
资源类型:期刊论文
原文链接:https://www.scopus.com/inward/record.uri?eid=2-s2.0-85061527763&doi=10.1021%2facs.cgd.8b01750&partnerID=40&md5=e513c564648f40f89abe5960fc728d45
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