标题：Metal vs. Chalcogen Competition in the Catalytic Mechanism of Cysteine Dioxygenase
作者：Xin Che;Jun Gao;Yongjun Liu;Chengbu Liu;
作者机构：[Xin Che;Jun Gao;Yongjun Liu;Chengbu Liu]Key Lab of Colloid and Interface Chemistry, Ministry of Education, Institute of Theoretical Chemistry, School 更多
关键词：Non-heme; Cysteine; Selenocysteine; Donation of Electron Density; Oxidation State.
摘要：Why the cysteine dioxygenase (CDO) cannot catalyze the oxidation of selenocysteine (Sec) but that of cysteine (Cys) is still an open question. In order to solve this question, the CDO model complex, the active site of CDO, and their selenium-substituted complexes have been selected as the computa...