标题:Two Cyanide-Bridged Heterometallic One-Dimensional Chain Complexes Constructed by Hydrogen Bond Interactions: Synthesis, Crystal Structures, and Magnetic Properties
作者:Zhang, Daopeng; Zhang, Lifang; Zhao, Zengdian; Ni, Zhonghai
作者机构:[Zhang, Lifang; Zhao, Zengdian; Ni, Zhonghai] China Univ Min & Technol, Sch Chem Engn & Technol, Xuzhou 221116, Peoples R China.; [Zhang, Daopeng] S 更多
通讯作者:Ni, ZH
通讯作者地址:[Ni, ZH]China Univ Min & Technol, Sch Chem Engn & Technol, Xuzhou 221116, Peoples R China.
来源:SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY
出版年:2011
卷:41
期:10
页码:1288-1292
DOI:10.1080/15533174.2011.594842
关键词:crystal structure; cyanide-bridged; heterometallic; hydrogen bond;; magnetic property
摘要:Two trinuclear cyanide-bridged heterometallic Ni(II)-Mn(III) complexes {[Mn(L-1)(H2O)](2)[Ni(CN)(4)]} 2H(2)O (1) and {[Mn(L-2)(H2O)](2)[Ni(CN)(4)]} (2) (L-1 = N,N-ethylenebis(3-methoxysalicylideneiminate; L-2 = N,N-ethylene-bis(3-ethoxysalicylideneiminate) have been obtained by using [Ni(CN)(4)](2-) and two manganese(III) compounds containing bicompartimental Schiff base ligands as assembling segments. X-ray diffraction reveals that the two cyanide-bridged trinuclear complexes are self-complementary through intermolecular O-H center dot center dot center dot O hydrogen bond interactions formed by a coordinated aqua ligand from one molecule and the four phenolic oxygen atoms from the neighboring one, giving a supramolecular one-dimensional chain structure. Investigation of the magnetic susceptibilities of these two complexes reveals the overall weak antiferromagnetic interactions between the adjacent Mn(III) ions.
收录类别:SCIE
WOS核心被引频次:3
资源类型:期刊论文
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