标题:Ultra-broadband nonlinear optical response of two-dimensional h-BN nanosheets and their hybrid gel glasses
作者:Xie, Zheng; Wu, Yongzhong; Sun, Xingming; Liu, Shixin; Ma, Fukun; Zhao, Gang; Hao, Xiaopeng; Zhou, Shuyun
作者机构:[Wu, Yongzhong; Ma, Fukun; Zhao, Gang; Hao, Xiaopeng] Shandong Univ, State Key Lab Crystal Mat, 27 Shandanan Rd, Jinan 250100, Shandong, Peoples R Chi 更多
通讯作者:Xie, Zheng
通讯作者地址:[Hao, XP]Shandong Univ, State Key Lab Crystal Mat, 27 Shandanan Rd, Jinan 250100, Shandong, Peoples R China;[Xie, Z]Chinese Acad Sci, Tech Inst Phys & 更多
来源:NANOSCALE
出版年:2018
卷:10
期:9
页码:4276-4283
DOI:10.1039/c7nr08804c
摘要:Hydrophilic hydroxylated hexagonal boron nitride nanosheets (BNNSs), also called 'white graphene', exhibit high water solubility, compatibility, dispersity with physical and/or chemical effects on the gel matrix, and unexpected but outstanding near-infrared adsorption and nonlinear optical limiting properties. These properties mean that hydroxylated BNNSs are suitable for practical applications in solidification and devices. Hydroxylated BNNSs are doped into an organically modified silicate matrix through a facile solgel process. The resulting BNNS-organically modified silicate glass hybrids demonstrate various solid structures (glass, coating, and film), good uniformity, thermostability, toughness, and high linear transmittance in the visible and near-infrared regions. Hybrid glasses showed large optical limiting effects and high doping concentrations without the addition of a compatibiliser, and their limiting thresholds and concentration exceed those of the corresponding suspensions by factors of 1.3-2 and 20-130, respectively. The optical limiting performance of BNNSs is almost equal to or may exceed those of graphene oxide and graphene in solutions and doped glasses. The combined mechanisms of nonlinear absorption, refraction, and scattering are deduced. A solid organically modified silicate hybrid transparent system doped with BNNSs is a promising candidate material for optical limiters and nonlinear optical devices. This system could be an efficient solid-state optical limiter in the visible and long-wavelength near-infrared regions (532-2000 nm).
收录类别:EI;SCOPUS;SCIE
WOS核心被引频次:2
Scopus被引频次:2
资源类型:期刊论文
原文链接:https://www.scopus.com/inward/record.uri?eid=2-s2.0-85042848230&doi=10.1039%2fc7nr08804c&partnerID=40&md5=55cb0ed15a10d0471665323291920a7d
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