标题:Synthesis, crystal structures, and magnetic properties of one-dimensional mixed cyanide- and phenolate-bridged heterotrimetallic complexes
作者:Wang, H.;Zhang, L.-F.;Ni, Z.-H.;Zhong, W.-F.;Tian, L.-J.;Jiang, J.
通讯作者:Ni, ZH
作者机构:[Wang, H] Department of Chemistry, Shandong University, Jinan 250100, China, Department of Chemistry, University of Science and Technology Beijing, Be 更多
来源:Crystal growth & design
出版年:2010
卷:10
期:10
页码:4231-4234
DOI:10.1021/cg100789s
摘要:Two one-dimensional (1D) cyanide- and phenolate-bridged heterotrimetallic complexes {[Cu~(II)Mn~(II)(L!1)][Fe ~(III)(bpb)(CN)_2]}_n?(ClO_4) _n?(H_2O)_n (1) and {[Cu~(II)Mn ~(II)(L~1)][Cr~(III)(bpb)(CN)_2]} _n?(ClO_4)_n?(H_2O) _n (2) (bpb~(2-) = 1,2-Bis(pyridine-2-carboxamido)benzenate) have been designed and prepared based on cyanide-containing building blocks K[M(bpb)(CN)_2] [M = Fe(III) and Cr(III)] together with compartmental macrocyclic Schiff-base complex [CuMn(L1)]?(ClO _4)_2, in which H_2L~1 is derived from 2,6-diformyl-4-methyl-phenol, ethylenediamine, and diethylenetriamine. Investigation of their magnetic properties reveals the overall antiferromagnetic behavior of these two complexes. These results seem to represent the first example of 1D infinite cyanide- and phenolate-bridged single chain-like compounds containing three kinds of spin carriers 3d-3d′-3d″prepared by a stepwise method.
收录类别:EI;SCOPUS;SCIE
WOS核心被引频次:34
Scopus被引频次:36
资源类型:会议论文;期刊论文
原文链接:https://www.scopus.com/inward/record.uri?eid=2-s2.0-77957715855&doi=10.1021%2fcg100789s&partnerID=40&md5=6a8fa0afdba71659f8bdcb9b26fe3b3d
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