标题:Bioinspired Modification via Green Synthesis of Mussel-Inspired Nanoparticles on Carbon Fiber Surface for Advanced Composite Materials
作者:Gao, Bo; Du, Wentao; Hao, Zhenna; Zhou, Haifeng; Zou, Dechun; Zhang, Ruliang
作者机构:[Gao, Bo; Zou, Dechun] Peking Univ, Coll Chem & Mol Engn, Beijing Natl Lab Mol Sci, Key Lab Polymer Chem & Phys,Minist Educ, Beijing 100871, Peoples R 更多
通讯作者:Zou, Dechun;Zou, DC;Zhang, RL
通讯作者地址:[Zou, DC]Peking Univ, Coll Chem & Mol Engn, Beijing Natl Lab Mol Sci, Key Lab Polymer Chem & Phys,Minist Educ, Beijing 100871, Peoples R China;[Zhang, 更多
来源:ACS SUSTAINABLE CHEMISTRY & ENGINEERING
出版年:2019
卷:7
期:6
页码:5638-5648
DOI:10.1021/acssuschemeng.8b03590
关键词:Carbon fiber; Bioinspired modification; Polymer composites; Mechanical; properties; Interface/interphase
摘要:Carbon fibers with excellent performances suffer from their low surface activity in many applications. Modifying fiber surfaces can improve the properties of fiber-matrix interface, which can expand the usage of carbon fiber in the field of energy. However, there are two main problems in the most traditional researches: the damaged structure of fiber by pretreatment to build the active site, and the weak interaction between fiber and nanoparticles by deposition. Herein, we first report the bioinspired copolymerization of dopamine and poly(amidoamine) on the fiber surface using polydopamine (the versatile adhesives) as an efficient and robust platform to graft poly(amidoamine) onto fiber surface at room temperature. Systematic investigations were performed to explore optimum conditions and the reaction mechanism of copolymerization of dopamine/poly(amidoamine) at different quantities of poly(amidoamine) on carbon fiber surfaces. The novel modification can introduce sufficient functionalization groups on fiber surface without decreasing fiber tensile strength, which can significantly increase the interfacial shear strength and impact strength of the resulting composites to 124.05 MPa and 91.17 KJ/m(2), respectively. The novel strategy presents a promising and "green" platform to prepare advanced composite materials for the demand of highly mechanical properties and the usages of energy conservation.
收录类别:EI;SCIE
资源类型:期刊论文
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