标题：Hydrosilylation of aldehydes and ketones catalyzed by hydrido iron complexes bearing imine ligands
作者：Zuo, Zhenyu; Sun, Hongjian; Wang, Lin; Li, Xiaoyan
作者机构：[Zuo, Zhenyu; Sun, Hongjian; Wang, Lin; Li, Xiaoyan] Shandong Univ, Minist Educ, Sch Chem & Chem Engn, Key Lab Special Funct Aggregated Mat, Jinan 250 更多
通讯作者地址：[Li, XY]Shandong Univ, Minist Educ, Sch Chem & Chem Engn, Key Lab Special Funct Aggregated Mat, Shanda Nanlu 27, Jinan 250199, Peoples R China.
摘要：Two new hydrido iron complexes (2 and 4) were synthesized by the reactions of (4-methoxypheny)phenylketimine ((4-MeOPh)PhC=NH) with Fe(PMe3)(4) or FeMe2(PMe3)(4). The molecular structures of complexes 2 and 4 were confirmed by X-ray single crystal diffraction. Using hydrido iron complexes (1-4) as catalysts, the hydrosilytations of aldehydes and ketones were investigated. The four complexes were effective catalysts for this reduction reaction. Complex 1 among them is the best catalyst.