标题:A highly emissive cruciform triarylborane as a ratiometric and solid state fluorescence sensor for fluoride ions
作者:Yi-Hong Zhao;Hong Pan;Guang-Liang Fu
作者机构:[Zhao, Y.-H] School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China;[ Pan, H] School of Chemistry and Chemical Enginee 更多
通讯作者:Zhao, CH
通讯作者地址:[Zhao, CH]Shandong Univ, Sch Chem & Chem Engn, Jinan 250100, Peoples R China.
来源:Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry
出版年:2011
卷:52
期:29
页码:3832-3835
DOI:10.1016/j.tetlet.2011.05.076
关键词:Cruciform triarylborane;Highly emissive;Ratiometric;Solid state;Fluoride sensing
摘要:We disclosed a novel cruciform tri-coordinate organoboron compound, 2\',5\'-bis{[(4-dimesitylbo-ryl)phenyl]ethynyl)-1\',4\'-bis[(4-N,N-diphenylamino)phenyl]-[1,1\':4\',1\']terphenyls, which displays a characteristic intramolecular charge transfer transition and is highly emissive both in solutions and solid state. The complexation with fluoride ions induces a large blue shift in fluorescence, enabling ratiometric fluorescence sensing of fluoride. In addition, its prompt response to fluoride ions was also observed even in the solid state.
收录类别:SCOPUS;SCIE
WOS核心被引频次:29
Scopus被引频次:29
资源类型:期刊论文
原文链接:https://www.scopus.com/inward/record.uri?eid=2-s2.0-79959216366&doi=10.1016%2fj.tetlet.2011.05.076&partnerID=40&md5=0a56d8b340569428e145ababd62dff31
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