标题：Novel in situ coordinated cerium salt/acrylonitrile-butadiene rubber composite
作者：Han, Jianjun; Lu, Haifeng; Zhang, Jie; Feng, Shengyu
作者机构：[Han, Jianjun; Lu, Haifeng; Zhang, Jie; Feng, Shengyu] Shandong Univ, Sch Chem & Chem Engn, Minist Educ, Key Lab Special Funct Aggregated Mat, Jinan 2 更多
通讯作者地址：[Lu, HF]Shandong Univ, Sch Chem & Chem Engn, Minist Educ, Key Lab Special Funct Aggregated Mat, Jinan 250100, Peoples R China.
来源：MATERIALS CHEMISTRY AND PHYSICS
关键词：Elastomers; Radiation damage; Mechanical properties; Heat treatment
摘要：A novel rubber composite of acrylonitrile-butadiene rubber (NBR) filled with cerium salt particles was vulcanized via in situ coordination for the first time. The resulting materials exhibit good mechanical properties. Curing characteristics analysis, differential scanning calorimetry, X-ray photoelectron spectroscopy, tensile testing, and an equilibrium swelling method were used for the characterization of the composite. The results in this paper indicate that the composite is a kind of elastomer based on the in situ coordination crosslinking interactions between the nitrile groups (-CN) of NBR and cerium ions. The mechanical properties of vulcanized cerium salt/ NBR rubber are altered when changing the sorts of cerium salt. Moreover, these materials show good irradiation resistance because of the introduction of the cerium salt. (c) 2012 Elsevier B.V. All rights reserved.