标题：Reactions and mechanisms of chloroplatinic acid hexahydrate with dimethyldi(4-N,N-dimethylaminophenyl)silane
作者：Peng Wang;Zheng Yue;Jie Zhang
作者机构：[Wang, P] Key Laboratory of Special Functional Aggregated Materials, School of Chemistry and Chemical Engineering, Shandong University, Jinan, 250100, 更多
通讯作者地址：[Feng, SY]Shandong Univ, Key Lab Special Funct Aggregated Mat, Minist Educ, Sch Chem & Chem Engn, Jinan 250100, Peoples R China.
来源：Inorganic Chemistry Communications
关键词：Dimethyldi(4-N;N-dimethylaminophenyl);silane;Chloroplatinic acid hexahydrate;Si-C bond cleavage;C-N bond cleavage;σ-complex
摘要：The reaction of dimethyldi(4-N,N-dimethylaminophenyl)silane (1) and chloroplatinic acid hexahydrate was carried out in acetone (ace). A complex salt, [H(dma)]2(PtCl6) ·0.5ace (2·0.5ace) (dma = N,N-dimethylphe-nylamine), was obtained and characterized by Single-crystal X-ray diffraction. At the same time, byproducts (4-dimethylaminophenyl)dimethylsilanol (3), dma, 4-(dimethylphenyl silyl)-N,N- dimethylaniline (4), and 1,3-Bis(4-(dimethylamino)phenyl)-1,1,3,3-tetra-methyldi- siloxane (5), structurally confirmed by FT-IR, ~1H NMR, ~(13)C NMR, ~(29)Si and ESI MS NMR spectra, were found. This indicates that the cleavages of Si-C and C-N bonds of 1 in the reaction occurred. In addition, the reaction mechanisms were referred.