标题:Reactions and mechanisms of chloroplatinic acid hexahydrate with dimethyldi(4-N,N-dimethylaminophenyl)silane
作者:Peng Wang;Zheng Yue;Jie Zhang
作者机构:[Wang, P] Key Laboratory of Special Functional Aggregated Materials, School of Chemistry and Chemical Engineering, Shandong University, Jinan, 250100, 更多
通讯作者:Feng, SY
通讯作者地址:[Feng, SY]Shandong Univ, Key Lab Special Funct Aggregated Mat, Minist Educ, Sch Chem & Chem Engn, Jinan 250100, Peoples R China.
来源:Inorganic Chemistry Communications
出版年:2011
卷:14
期:6
页码:1027-1031
DOI:10.1016/j.inoche.2011.03.063
关键词:Dimethyldi(4-N;N-dimethylaminophenyl);silane;Chloroplatinic acid hexahydrate;Si-C bond cleavage;C-N bond cleavage;σ-complex
摘要:The reaction of dimethyldi(4-N,N-dimethylaminophenyl)silane (1) and chloroplatinic acid hexahydrate was carried out in acetone (ace). A complex salt, [H(dma)]2(PtCl6) ·0.5ace (2·0.5ace) (dma = N,N-dimethylphe-nylamine), was obtained and characterized by Single-crystal X-ray diffraction. At the same time, byproducts (4-dimethylaminophenyl)dimethylsilanol (3), dma, 4-(dimethylphenyl silyl)-N,N- dimethylaniline (4), and 1,3-Bis(4-(dimethylamino)phenyl)-1,1,3,3-tetra-methyldi- siloxane (5), structurally confirmed by FT-IR, ~1H NMR, ~(13)C NMR, ~(29)Si and ESI MS NMR spectra, were found. This indicates that the cleavages of Si-C and C-N bonds of 1 in the reaction occurred. In addition, the reaction mechanisms were referred.
收录类别:SCOPUS;SCIE
WOS核心被引频次:1
Scopus被引频次:1
资源类型:期刊论文
原文链接:https://www.scopus.com/inward/record.uri?eid=2-s2.0-79955851141&doi=10.1016%2fj.inoche.2011.03.063&partnerID=40&md5=00af3c57325683d055502cf803ec914c
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