标题：E-Selective Hydrothiolation of Terminal Arylallenes with Arylthiols Catalyzed by Ni (PMe3)(4)
作者：Ren, Shishuai; Xue, Benjing; Zheng, Tingting; Wang, Yangyang; Sun, Hongjian; Li, Xiaoyan; Fuhr, Olaf; Fenske, Dieter
作者机构：[Ren, Shishuai; Xue, Benjing; Zheng, Tingting; Sun, Hongjian; Li, Xiaoyan] Shandong Univ, Sch Chem & Chem Engn, Key Lab Special Funct Aggregated Mat, 更多
通讯作者地址：[Li, XY]Shandong Univ, Sch Chem & Chem Engn, Key Lab Special Funct Aggregated Mat, Minist Educ, Shanda Nanlu 27, Jinan 250100, Shandong, Peoples R Chi 更多
来源：APPLIED ORGANOMETALLIC CHEMISTRY
关键词：allyl sulfide; hydrothiolation; nickel complex; terminal arylallene;; thiophenol
摘要：A catalytic system of regioselective synthesis of allyl sulfides via hydrothiolation of terminal arylallenes with arylthiols has been developed using nickel(0) complex Ni (PMe3)(4) as a catalyst. In most cases the excellent to moderate yields were obtained under mild conditions. A catalytic mechanism was suggested and partially-experimentally verified. To the best of our knowledge, this is the first example of regioselective addition of thiophenols to terminal arylallenes catalyzed by nickel(0) complex. It was noteworthy that this catalytic system was only applicable to thiophenol compounds with terminal arylallenes.