标题：Thermo-sensitive amphiphilic supramolecular assembly based on cyclodextrin inclusion
作者：Lv, C.;Chen, X.;Jing, B.;Zhao, Y.;Ma, F.
作者机构：[Lv, C] Key Laboratory of Colloid and Interface Chemistry, Shandong University, Ministry of Education, Jinan 250100, China;[ Chen, X] Key Laboratory o 更多
通讯作者地址：[Chen, XA]Shandong Univ, Key Lab Colloid & Interface Chem, Jinan 250100, Peoples R China.
来源：Journal of Colloid and Interface Science
摘要：The ionic self-assembled organic microrods are obtained through complexing two functional molecules, sodium deoxycholate and 1-adamantanamine hydro-chloride. Meanwhile, the amphiphilicity of the complex could be changed by a supramolecular approach with cyclodextrin (CD) inclusion to obtain a thermo-sensitive system. The microrod morphology and structure are characterized by optical microscopy, scanning electron microscopy, single crystal analysis and X-ray powder diffraction. The mechanism of thermo-sensitivity induced by β-CD inclusion complex is discussed in view of dynamic balance between the host β-CDs and guest molecules. Experimental results indicate the feasibility of single crystal culture in ionic self-assembly and potential application of CDs in thermo-sensitive supramolecular systems.